Fine-Tuning the Activity of Metal–Organic Framework Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane
Abstract
Few-atom cobalt-oxide clusters, when dispersed on a Zr-based metal–organic framework (MOF) NU-1000, have previously been shown to be active for the oxidative dehydrogenation (ODH) of propane at low temperatures (< 230 °C), affording a selective and stable propene production catalyst. In our current work, a series of promoter ions with varying Lewis acidity, including Ni(II), Zn(II), Al(III), Ti(IV) and Mo(VI), are anchored as metal-oxide,hydroxide clusters to NU-1000 via SIM (solvothermal deposition within MOFs–specifically the nodes) followed by incorporation of Co(II) ions via vapor-phase AIM (atomic layer deposition (ALD) in MOFs). This process yields a series of NU-1000-supported bimetallic-oxo,hydroxo,aqua clusters. Using difference envelope density (DED) analyses, the spatial locations of the promoter ions and catalytic cobalt ions are determined. For all samples the SIM-anchored promoter ions are sited between pairs of Zr6 nodes along the MOF c-axis (channel-aligned axis) whereas the location of the AIM-anchored cobalt ions varies depending on the identity of promoter metal ion. With Ni(II)-, Al(III)-, or Ti(IV)-containing clusters as promoters, the oxy-cobalt species are sited atop the promoter sites; with Mo(VI) they grow exclusively on the MOF nodes sites (hexa-Zr(IV)- oxo,hydroxo,aqua units); with Zn(II) they grow on both the node and promoter. The NU-1000- supported bimetallic-oxide clustersmore »
- Authors:
-
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS), X-ray Science Division
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemical and Biological Engineering
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; King Abdulaziz Univ., Jeddah (Saudi Arabia). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOD; ational Science Foundation (NSF); Ministry of Economy and Knowledge from the Catalan Government; Ministry of Science and Technology (Taiwan)
- OSTI Identifier:
- 1419945
- Grant/Contract Number:
- AC02-06CH11357; SC0012702
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 139; Journal Issue: 42; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Li, Zhanyong, Peters, Aaron W., Platero-Prats, Ana E., Liu, Jian, Kung, Chung-Wei, Noh, Hyunho, DeStefano, Matthew R., Schweitzer, Neil M., Chapman, Karena W., Hupp, Joseph T., and Farha, Omar K.. Fine-Tuning the Activity of Metal–Organic Framework Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane. United States: N. p., 2017.
Web. doi:10.1021/jacs.7b09365.
Li, Zhanyong, Peters, Aaron W., Platero-Prats, Ana E., Liu, Jian, Kung, Chung-Wei, Noh, Hyunho, DeStefano, Matthew R., Schweitzer, Neil M., Chapman, Karena W., Hupp, Joseph T., & Farha, Omar K.. Fine-Tuning the Activity of Metal–Organic Framework Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane. United States. https://doi.org/10.1021/jacs.7b09365
Li, Zhanyong, Peters, Aaron W., Platero-Prats, Ana E., Liu, Jian, Kung, Chung-Wei, Noh, Hyunho, DeStefano, Matthew R., Schweitzer, Neil M., Chapman, Karena W., Hupp, Joseph T., and Farha, Omar K.. Wed .
"Fine-Tuning the Activity of Metal–Organic Framework Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane". United States. https://doi.org/10.1021/jacs.7b09365. https://www.osti.gov/servlets/purl/1419945.
@article{osti_1419945,
title = {Fine-Tuning the Activity of Metal–Organic Framework Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane},
author = {Li, Zhanyong and Peters, Aaron W. and Platero-Prats, Ana E. and Liu, Jian and Kung, Chung-Wei and Noh, Hyunho and DeStefano, Matthew R. and Schweitzer, Neil M. and Chapman, Karena W. and Hupp, Joseph T. and Farha, Omar K.},
abstractNote = {Few-atom cobalt-oxide clusters, when dispersed on a Zr-based metal–organic framework (MOF) NU-1000, have previously been shown to be active for the oxidative dehydrogenation (ODH) of propane at low temperatures (< 230 °C), affording a selective and stable propene production catalyst. In our current work, a series of promoter ions with varying Lewis acidity, including Ni(II), Zn(II), Al(III), Ti(IV) and Mo(VI), are anchored as metal-oxide,hydroxide clusters to NU-1000 via SIM (solvothermal deposition within MOFs–specifically the nodes) followed by incorporation of Co(II) ions via vapor-phase AIM (atomic layer deposition (ALD) in MOFs). This process yields a series of NU-1000-supported bimetallic-oxo,hydroxo,aqua clusters. Using difference envelope density (DED) analyses, the spatial locations of the promoter ions and catalytic cobalt ions are determined. For all samples the SIM-anchored promoter ions are sited between pairs of Zr6 nodes along the MOF c-axis (channel-aligned axis) whereas the location of the AIM-anchored cobalt ions varies depending on the identity of promoter metal ion. With Ni(II)-, Al(III)-, or Ti(IV)-containing clusters as promoters, the oxy-cobalt species are sited atop the promoter sites; with Mo(VI) they grow exclusively on the MOF nodes sites (hexa-Zr(IV)- oxo,hydroxo,aqua units); with Zn(II) they grow on both the node and promoter. The NU-1000- supported bimetallic-oxide clusters are active for propane ODH after thermal activation under O2 to open a cobalt coordination site and to oxidize Co(II) to Co(III), as evidenced by operando Xray absorption spectroscopy at the Co K-edge. The cobalt component is exclusively responsible for the observed catalysis. In accord with the decreasing Lewis acidity of the promoter ion, catalytic activity increases in the order: Mo(VI)},
doi = {10.1021/jacs.7b09365},
journal = {Journal of the American Chemical Society},
number = 42,
volume = 139,
place = {United States},
year = {2017},
month = {10}
}
Web of Science
Works referenced in this record:
Experimental and modeling study of thermal and catalytic cracking of n-decane
journal, November 2014
- Gong, ChunMing; Ning, HongBo; Xu, JiaQi
- Journal of Analytical and Applied Pyrolysis, Vol. 110
Catalytic Dehydrogenation of Light Alkanes on Metals and Metal Oxides
journal, August 2014
- Sattler, Jesper J. H. B.; Ruiz-Martinez, Javier; Santillan-Jimenez, Eduardo
- Chemical Reviews, Vol. 114, Issue 20
Critical Literature Review of the Kinetics for the Oxidative Dehydrogenation of Propane over Well-Defined Supported Vanadium Oxide Catalysts
journal, September 2014
- Carrero, C. A.; Schloegl, R.; Wachs, I. E.
- ACS Catalysis, Vol. 4, Issue 10
Oxidative dehydrogenation of ethane and propane: How far from commercial implementation?
journal, September 2007
- Cavani, F.; Ballarini, N.; Cericola, A.
- Catalysis Today, Vol. 127, Issue 1-4, p. 113-131
Selective oxidative dehydrogenation of propane to propene using boron nitride catalysts
journal, December 2016
- Grant, J. T.; Carrero, C. A.; Goeltl, F.
- Science, Vol. 354, Issue 6319
Catalytic oxidative dehydrogenation of propane over Mg–V/Mo oxides
journal, April 2004
- Pless, J.
- Journal of Catalysis, Vol. 223, Issue 2
Structure and Catalytic Properties of Supported Vanadium Oxides: Support Effects on Oxidative Dehydrogenation Reactions
journal, January 1999
- Khodakov, Andrei; Olthof, Bryan; Bell, Alexis T.
- Journal of Catalysis, Vol. 181, Issue 2
Ni–Me–O mixed metal oxides for the effective oxidative dehydrogenation of ethane to ethylene – Effect of promoting metal Me
journal, March 2010
- Heracleous, E.; Lemonidou, A. A.
- Journal of Catalysis, Vol. 270, Issue 1
The selective oxidative activation of light alkanes. From supported vanadia to multicomponent bulk V-containing catalysts
journal, December 2006
- Nieto, José M. López
- Topics in Catalysis, Vol. 41, Issue 1-4
Alkali Effects on Molybdenum Oxide Catalysts for the Oxidative Dehydrogenation of Propane
journal, October 2000
- Chen, Kaidong; Xie, Shuibo; Bell, Alexis T.
- Journal of Catalysis, Vol. 195, Issue 2
The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
- Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
- Science, Vol. 341, Issue 6149, p. 1230444-1230444
Bottom-up construction of a superstructure in a porous uranium-organic crystal
journal, April 2017
- Li, Peng; Vermeulen, Nicolaas A.; Malliakas, Christos D.
- Science, Vol. 356, Issue 6338
Applying the Power of Reticular Chemistry to Finding the Missing alb-MOF Platform Based on the (6,12)-Coordinated Edge-Transitive Net
journal, February 2017
- Chen, Zhijie; Weseliński, Łukasz J.; Adil, Karim
- Journal of the American Chemical Society, Vol. 139, Issue 8
Hydrogen storage in metal–organic frameworks
journal, January 2009
- Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011
- Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
- Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
Record Atmospheric Fresh Water Capture and Heat Transfer with a Material Operating at the Water Uptake Reversibility Limit
journal, May 2017
- Rieth, Adam J.; Yang, Sungwoo; Wang, Evelyn N.
- ACS Central Science, Vol. 3, Issue 6
Water harvesting from air with metal-organic frameworks powered by natural sunlight
journal, April 2017
- Kim, Hyunho; Yang, Sungwoo; Rao, Sameer R.
- Science, Vol. 356, Issue 6336
A Fine-Tuned Metal–Organic Framework for Autonomous Indoor Moisture Control
journal, July 2017
- AbdulHalim, Rasha G.; Bhatt, Prashant M.; Belmabkhout, Youssef
- Journal of the American Chemical Society, Vol. 139, Issue 31
Metal–organic framework materials as catalysts
journal, January 2009
- Lee, JeongYong; Farha, Omar K.; Roberts, John
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
Enantioselective catalysis with homochiral metal–organic frameworks
journal, January 2009
- Ma, Liqing; Abney, Carter; Lin, Wenbin
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256
Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst
journal, February 2016
- Metzger, Eric D.; Brozek, Carl K.; Comito, Robert J.
- ACS Central Science, Vol. 2, Issue 3
Mechanism of Single-Site Molecule-Like Catalytic Ethylene Dimerization in Ni-MFU-4 l
journal, January 2017
- Metzger, Eric D.; Comito, Robert J.; Hendon, Christopher H.
- Journal of the American Chemical Society, Vol. 139, Issue 2
Zr-based metal–organic frameworks: design, synthesis, structure, and applications
journal, January 2016
- Bai, Yan; Dou, Yibo; Xie, Lin-Hua
- Chemical Society Reviews, Vol. 45, Issue 8
Chemical, thermal and mechanical stabilities of metal–organic frameworks
journal, February 2016
- Howarth, Ashlee J.; Liu, Yangyang; Li, Peng
- Nature Reviews Materials, Vol. 1, Issue 3
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008
- Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
- Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
Confinement of Ultrasmall Cu/ZnO x Nanoparticles in Metal–Organic Frameworks for Selective Methanol Synthesis from Catalytic Hydrogenation of CO 2
journal, March 2017
- An, Bing; Zhang, Jingzheng; Cheng, Kang
- Journal of the American Chemical Society, Vol. 139, Issue 10
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012
- Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
- Angewandte Chemie International Edition, Vol. 51, Issue 41
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012
- Morris, William; Volosskiy, Boris; Demir, Selcuk
- Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013
- Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
- Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
Atomically Precise Growth of Catalytically Active Cobalt Sulfide on Flat Surfaces and within a Metal–Organic Framework via Atomic Layer Deposition
journal, July 2015
- Peters, Aaron W.; Li, Zhanyong; Farha, Omar K.
- ACS Nano, Vol. 9, Issue 8
Toward Inexpensive Photocatalytic Hydrogen Evolution: A Nickel Sulfide Catalyst Supported on a High-Stability Metal–Organic Framework
journal, August 2016
- Peters, Aaron W.; Li, Zhanyong; Farha, Omar K.
- ACS Applied Materials & Interfaces, Vol. 8, Issue 32
Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes
journal, June 2015
- Yang, Dong; Odoh, Samuel O.; Wang, Timothy C.
- Journal of the American Chemical Society, Vol. 137, Issue 23, p. 7391-7396
Cooperative Cluster Metalation and Ligand Migration in Zirconium Metal-Organic Frameworks
journal, October 2015
- Yuan, Shuai; Chen, Ying-Pin; Qin, Junsheng
- Angewandte Chemie International Edition, Vol. 54, Issue 49
An Exceptionally Stable Metal–Organic Framework Supported Molybdenum(VI) Oxide Catalyst for Cyclohexene Epoxidation
journal, October 2016
- Noh, Hyunho; Cui, Yuexing; Peters, Aaron W.
- Journal of the American Chemical Society, Vol. 138, Issue 44
Production of ultra-deep sulfur-free diesels using a sustainable catalytic system based on UiO-66(Zr)
journal, January 2015
- Granadeiro, Carlos M.; Ribeiro, Susana O.; Karmaoui, Mohamed
- Chemical Communications, Vol. 51, Issue 72
Catalytic Zirconium/Hafnium-Based Metal–Organic Frameworks
journal, December 2016
- Rimoldi, Martino; Howarth, Ashlee J.; DeStefano, Matthew R.
- ACS Catalysis, Vol. 7, Issue 2
Defining the Proton Topology of the Zr6-Based Metal–Organic Framework NU-1000
journal, October 2014
- Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723
Targeted Single-Site MOF Node Modification: Trivalent Metal Loading via Atomic Layer Deposition
journal, June 2015
- Kim, In Soo; Borycz, Joshua; Platero-Prats, Ana E.
- Chemistry of Materials, Vol. 27, Issue 13
Stable Metal–Organic Framework-Supported Niobium Catalysts
journal, October 2016
- Ahn, Sol; Thornburg, Nicholas E.; Li, Zhanyong
- Inorganic Chemistry, Vol. 55, Issue 22
Synthetic Access to Atomically Dispersed Metals in Metal–Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach
journal, February 2016
- Klet, Rachel C.; Wang, Timothy C.; Fernandez, Laura E.
- Chemistry of Materials, Vol. 28, Issue 4
Sintering-Resistant Single-Site Nickel Catalyst Supported by Metal–Organic Framework
journal, February 2016
- Li, Zhanyong; Schweitzer, Neil M.; League, Aaron B.
- Journal of the American Chemical Society, Vol. 138, Issue 6
Methane Oxidation to Methanol Catalyzed by Cu-Oxo Clusters Stabilized in NU-1000 Metal–Organic Framework
journal, July 2017
- Ikuno, Takaaki; Zheng, Jian; Vjunov, Aleksei
- Journal of the American Chemical Society, Vol. 139, Issue 30
Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires
journal, July 2017
- Platero-Prats, Ana E.; League, Aaron B.; Bernales, Varinia
- Journal of the American Chemical Society, Vol. 139, Issue 30
Metal–Organic Framework Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane at Low Temperature
journal, November 2016
- Li, Zhanyong; Peters, Aaron W.; Bernales, Varinia
- ACS Central Science, Vol. 3, Issue 1
Configuring Bonds between First-Row Transition Metals
journal, October 2015
- Eisenhart, Reed J.; Clouston, Laura J.; Lu, Connie C.
- Accounts of Chemical Research, Vol. 48, Issue 11
Study of Guest Molecules in Metal–Organic Frameworks by Powder X-ray Diffraction: Analysis of Difference Envelope Density
journal, October 2014
- Yakovenko, Andrey A.; Wei, Zhangwen; Wriedt, Mario
- Crystal Growth & Design, Vol. 14, Issue 11
Regioselective Atomic Layer Deposition in Metal–Organic Frameworks Directed by Dispersion Interactions
journal, October 2016
- Gallington, Leighanne C.; Kim, In Soo; Liu, Wei-Guang
- Journal of the American Chemical Society, Vol. 138, Issue 41
XANES investigation of the Co oxidation state in solution and in cancer cells treated with Co(III) complexes
journal, May 2006
- Bonnitcha, Paul D.; Hall, Matthew D.; Underwood, Clare K.
- Journal of Inorganic Biochemistry, Vol. 100, Issue 5-6
Lewis Acids as Catalysts in Oxidation Reactions: From Homogeneous to Heterogeneous Systems
journal, October 2002
- Corma, Avelino; García, Hermenegildo
- Chemical Reviews, Vol. 102, Issue 10
Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum, and Tungsten Oxides
journal, February 2000
- Chen, Kaidong; Bell, Alexis T.; Iglesia, Enrique
- The Journal of Physical Chemistry B, Vol. 104, Issue 6
Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation
journal, September 2015
- Cammarota, Ryan C.; Lu, Connie C.
- Journal of the American Chemical Society, Vol. 137, Issue 39
Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters
journal, March 2013
- Tsui, Emily Y.; Tran, Rosalie; Yano, Junko
- Nature Chemistry, Vol. 5, Issue 4
Influence of Lewis acid charge and proximity in Mo Mo⋯M linear chain compounds with M = Na+, Ca2+, Sr2+, and Y3+
journal, January 2016
- Dolinar, Brian S.; Berry, John F.
- Polyhedron, Vol. 103
Works referencing / citing this record:
3D Enantiomorphic Mg‐Based Metal–Organic Frameworks as Chemical Sensor of Nitrobenzene and Efficient Catalyst for CO 2 Cycloaddition
journal, April 2019
- Xue, Yun‐Shan; Cheng, Weiwei; Cao, Jia‐Peng
- Chemistry – An Asian Journal, Vol. 14, Issue 11
Insights into interface engineering in steam reforming reactions for hydrogen production
journal, January 2019
- Chen, Sai; Pei, Chunlei; Gong, Jinlong
- Energy & Environmental Science, Vol. 12, Issue 12
The chemistry of multi-component and hierarchical framework compounds
journal, January 2019
- Feng, Liang; Wang, Kun-Yu; Day, Gregory S.
- Chemical Society Reviews, Vol. 48, Issue 18
Synthesis of ( E )-2-Alkenylazaarenes via Dehydrogenative Coupling of (Hetero)aryl-fused 2-Alkylcyclic Amines and Aldehydes with a Cobalt Nanocatalyst
journal, April 2018
- Zhou, Changjian; Tan, Zhenda; Jiang, Huanfeng
- ChemCatChem, Vol. 10, Issue 13
Synthesis, characterization, and evaluation of high selectivity mixed molybdenum and vanadium oxide catalysts for oxidative dehydrogenation of propane
journal, February 2019
- Alasiri, Hassan; Ahmed, Shakeel; Rahman, Faizur
- The Canadian Journal of Chemical Engineering, Vol. 97, Issue 8
Sensing and capture of toxic and hazardous gases and vapors by metal–organic frameworks
journal, January 2018
- Wang, Hao; Lustig, William P.; Li, Jing
- Chemical Society Reviews, Vol. 47, Issue 13
Ethane/ethylene separation in a metal-organic framework with iron-peroxo sites
journal, October 2018
- Li, Libo; Lin, Rui-Biao; Krishna, Rajamani
- Science, Vol. 362, Issue 6413
Hybridization of Pd Nanoparticles with UiO-66(Hf) Metal-Organic Framework and the Effect of Nanostructure on the Catalytic Properties
journal, October 2018
- Bakuru, Vasudeva Rao; Velaga, Bharath; Peela, Nageswara Rao
- Chemistry - A European Journal, Vol. 24, Issue 60
A multifunctional Co-based metal–organic framework: heterogeneous catalysis, chemiluminescence sensing and moisture-dependent solvatochromism
journal, January 2018
- Xie, Ming-Hua; Wang, Ya; Li, Ruo-Fei
- Dalton Transactions, Vol. 47, Issue 35
From IR to x-rays: gaining molecular level insights on metal-organic frameworks through spectroscopy
journal, August 2019
- Hanna, Lauren; Lockard, Jenny V.
- Journal of Physics: Condensed Matter, Vol. 31, Issue 48
Aerobic Homocoupling of Arylboronic Acids Catalyzed by Regenerable Pd(II)@MIL‐88B‐NH 2 (Cr)
journal, May 2019
- Valiente, Alejandro; Carrasco, Sergio; Sanz‐Marco, Amparo
- ChemCatChem, Vol. 11, Issue 16
Chiral metal-organic frameworks with tunable catalytic selectivity in asymmetric transfer hydrogenation reactions
journal, June 2020
- Chen, Xu; Qiao, Zhiwei; Hou, Bang
- Nano Research
A sustainable oxidative esterification of thiols with alcohols by a cobalt nanocatalyst supported on doped carbon
journal, January 2018
- Zhou, Changjian; Tan, Zhenda; Jiang, Huanfeng
- Green Chemistry, Vol. 20, Issue 9
Two Lanthanide Metal–Organic Frameworks Based on Semi-Rigid T-Shaped Tricarboxylate Ligand: Syntheses, Structures, and Properties
journal, May 2019
- Xue, Yun-Shan; Chen, Zhuo-Lin; Dong, Youzhen
- Polymers, Vol. 11, Issue 5
Chemical looping beyond combustion – a perspective
journal, January 2020
- Zhu, Xing; Imtiaz, Qasim; Donat, Felix
- Energy & Environmental Science, Vol. 13, Issue 3
Subnanometer cobalt oxide clusters as selective low temperature oxidative dehydrogenation catalysts
journal, February 2019
- Lee, Sungsik; Halder, Avik; Ferguson, Glen A.
- Nature Communications, Vol. 10, Issue 1
Metal‐Organic Frameworks as Platform for Lewis‐Acid‐Catalyzed Organic Transformations
journal, July 2019
- Yadav, Anand; Kanoo, Prakash
- Chemistry – An Asian Journal, Vol. 14, Issue 20
Chemical looping beyond combustion – a perspective
text, January 2020
- Xing, Zhu,; Qasim, Imtiaz,; Felix, Donat,
- ETH Zurich
Computational Approach to Molecular Catalysis by 3d Transition Metals: Challenges and Opportunities
journal, October 2018
- Vogiatzis, Konstantinos D.; Polynski, Mikhail V.; Kirkland, Justin K.
- Chemical Reviews, Vol. 119, Issue 4
Subnanometer cobalt oxide clusters as selective low temperature oxidative dehydrogenation catalysts
journal, February 2019
- Lee, Sungsik; Halder, Avik; Ferguson, Glen A.
- Nature Communications, Vol. 10, Issue 1
Bioengineering of Metal-organic Frameworks for Nanomedicine
journal, January 2019
- Liu, Yuan; Zhao, Yanli; Chen, Xiaoyuan
- Theranostics, Vol. 9, Issue 11