Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All‐Solid‐State Sodium Batteries
Abstract
Abstract All‐solid‐state sodium batteries (ASSSBs) with nonflammable electrolytes and ubiquitous sodium resource are a promising solution to the safety and cost concerns for lithium‐ion batteries. However, the intrinsic mismatch between low anodic decomposition potential of superionic sulfide electrolytes and high operating potentials of sodium‐ion cathodes leads to a volatile cathode–electrolyte interface and undesirable cell performance. Here we report a high‐capacity organic cathode, Na 4 C 6 O 6 , that is chemically and electrochemically compatible with sulfide electrolytes. A bulk‐type ASSSB shows high specific capacity (184 mAh g −1 ) and one of the highest specific energies (395 Wh kg −1 ) among intercalation compound‐based ASSSBs. The capacity retentions of 76 % after 100 cycles at 0.1 C and 70 % after 400 cycles at 0.2 C represent the record stability for ASSSBs. Additionally, Na 4 C 6 O 6 functions as a capable anode material, enabling a symmetric all‐organic ASSSB with Na 4 C 6 O 6 as both cathode and anode materials.
- Authors:
-
[1]
- Department of Electrical and Computer Engineering and Materials Science and Engineering Program University of Houston Houston TX 77204 USA
- Department of Mechanical Engineering University of Colorado at Boulder Boulder CO 80309 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1419899
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 130 Journal Issue: 10; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Chi, Xiaowei, Liang, Yanliang, Hao, Fang, Zhang, Ye, Whiteley, Justin, Dong, Hui, Hu, Pu, Lee, Sehee, and Yao, Yan. Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All‐Solid‐State Sodium Batteries. Germany: N. p., 2018.
Web. doi:10.1002/ange.201712895.
Chi, Xiaowei, Liang, Yanliang, Hao, Fang, Zhang, Ye, Whiteley, Justin, Dong, Hui, Hu, Pu, Lee, Sehee, & Yao, Yan. Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All‐Solid‐State Sodium Batteries. Germany. https://doi.org/10.1002/ange.201712895
Chi, Xiaowei, Liang, Yanliang, Hao, Fang, Zhang, Ye, Whiteley, Justin, Dong, Hui, Hu, Pu, Lee, Sehee, and Yao, Yan. Thu .
"Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All‐Solid‐State Sodium Batteries". Germany. https://doi.org/10.1002/ange.201712895.
@article{osti_1419899,
title = {Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All‐Solid‐State Sodium Batteries},
author = {Chi, Xiaowei and Liang, Yanliang and Hao, Fang and Zhang, Ye and Whiteley, Justin and Dong, Hui and Hu, Pu and Lee, Sehee and Yao, Yan},
abstractNote = {Abstract All‐solid‐state sodium batteries (ASSSBs) with nonflammable electrolytes and ubiquitous sodium resource are a promising solution to the safety and cost concerns for lithium‐ion batteries. However, the intrinsic mismatch between low anodic decomposition potential of superionic sulfide electrolytes and high operating potentials of sodium‐ion cathodes leads to a volatile cathode–electrolyte interface and undesirable cell performance. Here we report a high‐capacity organic cathode, Na 4 C 6 O 6 , that is chemically and electrochemically compatible with sulfide electrolytes. A bulk‐type ASSSB shows high specific capacity (184 mAh g −1 ) and one of the highest specific energies (395 Wh kg −1 ) among intercalation compound‐based ASSSBs. The capacity retentions of 76 % after 100 cycles at 0.1 C and 70 % after 400 cycles at 0.2 C represent the record stability for ASSSBs. Additionally, Na 4 C 6 O 6 functions as a capable anode material, enabling a symmetric all‐organic ASSSB with Na 4 C 6 O 6 as both cathode and anode materials.},
doi = {10.1002/ange.201712895},
journal = {Angewandte Chemie},
number = 10,
volume = 130,
place = {Germany},
year = {Thu Feb 08 00:00:00 EST 2018},
month = {Thu Feb 08 00:00:00 EST 2018}
}
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