Kern‐Schale‐Strukturierung rein metallischer Aerogele für eine hocheffiziente Nutzung von Platin für die Sauerstoffreduktion

Cai, Bin; Hübner, René; Sasaki, Kotaro; Zhang, Yuanzhe; Su, Dong; Ziegler, Christoph; Vukmirovic, Miomir B.; Rellinghaus, Bernd; Adzic, Radoslav R.; Eychmüller, Alexander

doi:10.1002/ange.201710997

Title: Kern‐Schale‐Strukturierung rein metallischer Aerogele für eine hocheffiziente Nutzung von Platin für die Sauerstoffreduktion

Journal Article · 07 February 2018 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.201710997 · OSTI ID:1419898

Cai, Bin ^[1]; Hübner, René ^[2]; Sasaki, Kotaro ^[3]; Zhang, Yuanzhe ^[4]; Su, Dong ^[3]; Ziegler, Christoph ^[4]; Vukmirovic, Miomir B. ^[3]; Rellinghaus, Bernd ^[5]; Adzic, Radoslav R. ^[3];

^[4]

Physical Chemistry TU Dresden Bergstraße 66b 01062 Dresden Deutschland, Chemistry Division and Center for Functional Nanomaterials Brookhaven National Laboratory Upton NY 11973 USA
Helmholtz-Zentrum Dresden-Rossendorf Bautzner Landstraße 400 01328 Dresden Deutschland
Chemistry Division and Center for Functional Nanomaterials Brookhaven National Laboratory Upton NY 11973 USA
Physical Chemistry TU Dresden Bergstraße 66b 01062 Dresden Deutschland
Institute for Metallic Materials IFW Dresden Helmholtzstraße 20 01069 Dresden Deutschland

Abstract Die Entwicklung von rein metallischen Aerogelen mit Kern‐Schale‐Strukturen ist nach wie vor eine grundlegende Herausforderung. Hier stellen wir die Synthese von Pd _x Au‐Pt‐Kern‐Schale‐Aerogelen vor, welche aus einer ultradünnen Pt‐Schale und einem Kern aus einer Pd _x Au‐Legierung mit einstellbarer Zusammensetzung bestehen. Die universelle Synthesestrategie ermöglicht eine Erweiterung der Kern‐Zusammensetzung hin zu Pd‐Übergangsmetall‐Legierungen. Die Kern‐Schale‐Aerogele zeigen eine stark verbesserte Nutzungseffizienz von Pt in der Sauerstoffreduktion und ihre Aktivitäten folgen einem vulkanförmigen Verlauf bezüglich der Gitterparameter des Kern‐Substrats. Mit einer maximalen massenbezogenen bzw. spezifischen Aktivität von 5.25 A mg ⁻¹ _Pt bzw. 2.53 mA cm ⁻² , welche 18.7‐ bzw. 4.1‐mal höher sind als die für Pt/C, zeigt sich die Überlegenheit dieser metallischen Kern‐Schale‐Aerogele. Die vorgeschlagene Kern‐basierte Aktivitätsabhängigkeit liefert eine neue mögliche Strategie für den Entwurf zukünftiger Kern‐Schale‐Elektrokatalysatoren.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0012704

OSTI ID:: 1419898

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 11 Vol. 130; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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