Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction

Weng, Zhe; Wu, Yueshen; Wang, Maoyu; Jiang, Jianbing; Yang, Ke; Huo, Shengjuan; Wang, Xiao-Feng; Ma, Qing; Brudvig, Gary W.; Batista, Victor S.; Liang, Yongye; Feng, Zhenxing; Wang, Hailiang

doi:10.1038/s41467-018-02819-7

Title: Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction

Abstract

Restructuring-induced catalytic activity is an intriguing phenomenon of fundamental importance to rational design of high-performance catalyst materials. We study three coppercomplex materials for electrocatalytic carbon dioxide reduction. Among them, the copper(II) phthalocyanine exhibits by far the highest activity for yielding methane with a Faradaic efficiency of 66% and a partial current density of 13 mA cm^-2 at the potential of – 1.06 V versus the reversible hydrogen electrode. Utilizing in-situ and operando X-ray absorption spectroscopy, we find that under the working conditions copper(II) phthalocyanine undergoes reversible structural and oxidation state changes to form ~ 2 nm metallic copper clusters, which catalyzes the carbon dioxide-to-methane conversion. Density functional calculations rationalize the restructuring behavior and attribute the reversibility to the strong divalent metal ion–ligand coordination in the copper(II) phthalocyanine molecular structure and the small size of the generated copper clusters under the reaction conditions.

Authors:

^[1]; Wu, Yueshen ^[2]; Wang, Maoyu ^[3]; Jiang, Jianbing ^[2]; Yang, Ke ^[2]; Huo, Shengjuan ^[4]; Wang, Xiao-Feng ^[5]; Ma, Qing ^[6]; Brudvig, Gary W. ^[2]; Batista, Victor S. ^[2]; Liang, Yongye ^[7]; Feng, Zhenxing ^[3];

^[2]

South University of Science and Technology of China, Shenzhen (China); Yale Univ., New Haven, CT (United States)
Yale Univ., New Haven, CT (United States)
Oregon State Univ., Corvallis, OR (United States)
Yale Univ., New Haven, CT (United States); Shanghai University (China)
University of South China, Hengyang, Hunan (China)
Northwestern Univ., Evanston, IL (United States)
South University of Science and Technology of China, Shenzhen (China)

Publication Date:: 2018-01-29

Research Org.:: Yale Univ., New Haven, CT (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; National Science Foundation (NSF)

OSTI Identifier:: 1419868

Grant/Contract Number:: FG02-07ER15909; AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Nature Communications

Additional Journal Information:: Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041-1723

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: ENGLISH

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats


                    Weng, Zhe, Wu, Yueshen, Wang, Maoyu, Jiang, Jianbing, Yang, Ke, Huo, Shengjuan, Wang, Xiao-Feng, Ma, Qing, Brudvig, Gary W., Batista, Victor S., Liang, Yongye, Feng, Zhenxing, and Wang, Hailiang. Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction.  United States: N. p., 2018. 
Web.  doi:10.1038/s41467-018-02819-7.

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                    Weng, Zhe, Wu, Yueshen, Wang, Maoyu, Jiang, Jianbing, Yang, Ke, Huo, Shengjuan, Wang, Xiao-Feng, Ma, Qing, Brudvig, Gary W., Batista, Victor S., Liang, Yongye, Feng, Zhenxing, & Wang, Hailiang. Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction.  United States.  https://doi.org/10.1038/s41467-018-02819-7

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                    Weng, Zhe, Wu, Yueshen, Wang, Maoyu, Jiang, Jianbing, Yang, Ke, Huo, Shengjuan, Wang, Xiao-Feng, Ma, Qing, Brudvig, Gary W., Batista, Victor S., Liang, Yongye, Feng, Zhenxing, and Wang, Hailiang. Mon .  
"Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction".  United States.  https://doi.org/10.1038/s41467-018-02819-7.  https://www.osti.gov/servlets/purl/1419868.

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@article{osti_1419868,

  title        = {Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction},

  author       = {Weng, Zhe and Wu, Yueshen and Wang, Maoyu and Jiang, Jianbing and Yang, Ke and Huo, Shengjuan and Wang, Xiao-Feng and Ma, Qing and Brudvig, Gary W. and Batista, Victor S. and Liang, Yongye and Feng, Zhenxing and Wang, Hailiang},

  abstractNote = {Restructuring-induced catalytic activity is an intriguing phenomenon of fundamental importance to rational design of high-performance catalyst materials. We study three coppercomplex materials for electrocatalytic carbon dioxide reduction. Among them, the copper(II) phthalocyanine exhibits by far the highest activity for yielding methane with a Faradaic efficiency of 66% and a partial current density of 13 mA cm-2 at the potential of – 1.06 V versus the reversible hydrogen electrode. Utilizing in-situ and operando X-ray absorption spectroscopy, we find that under the working conditions copper(II) phthalocyanine undergoes reversible structural and oxidation state changes to form ~ 2 nm metallic copper clusters, which catalyzes the carbon dioxide-to-methane conversion. Density functional calculations rationalize the restructuring behavior and attribute the reversibility to the strong divalent metal ion–ligand coordination in the copper(II) phthalocyanine molecular structure and the small size of the generated copper clusters under the reaction conditions.},

  doi          = {10.1038/s41467-018-02819-7},

  journal      = {Nature Communications},

  number       = 1,

  volume       = 9,

  place        = {United States},

  year         = {2018},

  month        = {1}

}

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Figures / Tables:

Fig. 1: Molecular structures of three Cu-complex materials and their electrocatalytic performance for CO₂ reduction. Molecular structures of a CuPc, b HKUST-1, and c [Cu(cyclam)]Cl₂. Potential-dependent d Faradaic efficiencies and e partial current densities of products for CO₂ electroreduction reaction catalyzed by CuPc. Comparison of f Faradaic efficiency and gmore »

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Atomic‐Scale Spacing between Copper Facets for the Electrochemical Reduction of Carbon Dioxide

Journal Article Jeong, Hyung Mo ; Kwon, Youngkook ; Won, Jong Ho ; ... - Advanced Energy Materials

Abstract Copper (Cu) offers a means for producing value‐added fuels through the electrochemical reduction of carbon dioxide (CO ₂ ), i.e., the CO ₂ reduction reaction (CO ₂ RR), but designing Cu catalysts with significant Faradaic efficiency to C ₂₊ products remains as a great challenge. This work demonstrates that the high activity and selectivity of Cu to C ₂₊ products can be achieved by atomic‐scale spacings between two facets of Cu particles. These spacings are created by lithiating CuO _x particles, removing lithium oxides formed, and electrochemically reducing CuO _x to metallic Cu. Also, the range of spacing (more »« less
Cited by 35
https://doi.org/10.1002/aenm.201903423
A metal-supported single-atom catalytic site enables carbon dioxide hydrogenation

Journal Article Hung, Sung-Fu ; Xu, Aoni ; Wang, Xue ; ... - Nature Communications

Nitrogen-doped graphene-supported single atoms convert CO₂ to CO, but fail to provide further hydrogenation to methane – a finding attributable to the weak adsorption of CO intermediates. To regulate the adsorption energy, here we investigate the metal-supported single atoms to enable CO₂ hydrogenation. We find a copper-supported iron-single-atom catalyst producing a high-rate methane. Density functional theory calculations and in-situ Raman spectroscopy show that the iron atoms attract surrounding intermediates and carry out hydrogenation to generate methane. The catalyst is realized by assembling iron phthalocyanine on the copper surface, followed by in-situ formation of single iron atoms during electrocatalysis, identified usingmore »« less
https://doi.org/10.1038/s41467-022-28456-9

Full Text Available
Promoting CO₂ methanation via ligand-stabilized metal oxide clusters as hydrogen-donating motifs

Journal Article Li, Yuhang ; Xu, Aoni ; Lum, Yanwei ; ... - Nature Communications

Electroreduction uses renewable energy to upgrade carbon dioxide to value-added chemicals and fuels. Renewable methane synthesized using such a route stands to be readily deployed using existing infrastructure for the distribution and utilization of natural gas. Here we design a suite of ligand-stabilized metal oxide clusters and find that these modulate carbon dioxide reduction pathways on a copper catalyst, enabling thereby a record activity for methane electroproduction. Density functional theory calculations show adsorbed hydrogen donation from clusters to copper active sites for the *CO hydrogenation pathway towards *CHO. We promote this effect via control over cluster size and composition andmore »« less
https://doi.org/10.1038/s41467-020-20004-7

Full Text Available
Highly selective electrocatalytic CO₂ reduction to ethanol by metallic clusters dynamically formed from atomically dispersed copper

Journal Article Xu, Haiping ; Rebollar, Dominic ; He, Haiying ; ... - Nature Energy

Direct electrochemical conversion of CO₂ to ethanol offers a promising strategy of lowering CO₂ emission while storing energy from renewable electricity. However, current electrocatalysts offer only limited selectivity toward ethanol. Here we report a copper catalyst synthesized by a unique Cu-Li amalgm method over a commercial carbon support that achieved Faradaic efficiency (FE) higher than 91% at -0.7 V (RHE) and the active potential as low as -0.4 V (RHE) during direct electrocatalytic CO₂-to-ethanol conversion. The catalyst also demonstrated stability over an extended period of operation. A strong correlation between the catalytic selectivity and the initial Cu atoms dispersion wasmore »« less
https://doi.org/10.1038/s41560-020-0666-x

Full Text Available
Poly-Amide Modified Copper Foam Electrodes for Enhanced Electrochemical Reduction of Carbon Dioxide

Journal Article Ahn, Sunyhik ; Klyukin, Konstantin ; Wakeham, Russell J. ; ... - ACS Catalysis

A strategy to modulate the electrocatalytic activity of copper toward CO₂ reduction involving adsorption of acrylamide, acrylic acid, and allylamine polymers is presented. Modification of electrodeposited copper foam with poly(acrylamide) leads to a significant enhancement in faradaic efficiency for ethylene from 13% (unmodified foam) to 26% at -0.96 V vs RHE, whereas methane yield is unaffected. Effects from crystalline phase distribution and copper oxide phases are ruled out as the source of enhancement through XPS and in situ XRD analysis. DFT calculations reveal that poly(acrylamide) adsorbs on the copper surface via the oxygen atom on the carbonyl groups and enhancesmore »« less
Cited by 105
https://doi.org/10.1021/acscatal.7b04347

Full Text Available

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Title: Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction

Abstract

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Figures / Tables:

Valence Change Ability and Geometrical Occupation of Substitution Cations Determine the Pseudocapacitance of Spinel Ferrite XFe 2 O 4 (X = Mn, Co, Ni, Fe) journal, June 2016

Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide journal, October 2015

Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO journal, January 2012

Electrochemical CO 2 Reduction to Hydrocarbons on a Heterogeneous Molecular Cu Catalyst in Aqueous Solution journal, June 2016

Active sites of ligand-protected Au 25 nanoparticle catalysts for CO 2 electroreduction to CO journal, May 2016

Metal/Oxide Interface Nanostructures Generated by Surface Segregation for Electrocatalysis journal, October 2015

Reconstruction of Clean and Adsorbate-Covered Metal Surfaces journal, January 1996

EXAFS Studies on the Size Dependence of Structural and Dynamic Properties of CdS Nanoparticles journal, April 1997

Iron-Doped Cobalt Monophosphide Nanosheet/Carbon Nanotube Hybrids as Active and Stable Electrocatalysts for Water Splitting journal, April 2017

In situ Growth of NixCu1-x Alloy Nanocatalysts on Redox-reversible Rutile (Nb,Ti)O4 Towards High-Temperature Carbon Dioxide Electrolysis journal, June 2014

A rational design for enhanced oxygen reduction: Strongly coupled silver nanoparticles and engineered perovskite nanofibers journal, August 2017

Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO 2 Electroreduction by Process Conditions journal, December 2014

A highly active and stable hydrogen evolution catalyst based on pyrite-structured cobalt phosphosulfide journal, February 2016

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions journal, May 2009

Size-dependent cohesive energy of nanocrystals journal, December 2002

Particle Size Effects in the Catalytic Electroreduction of CO 2 on Cu Nanoparticles journal, May 2014

Recent Progress on Synchrotron-Based In-Situ Soft X-ray Spectroscopy for Energy Materials journal, May 2014

Modeling the Structure and Composition of Nanoparticles by Extended X-Ray Absorption Fine-Structure Spectroscopy journal, July 2011

Catalytic Activity and Stability of Oxides: The Role of Near-Surface Atomic Structures and Compositions journal, April 2016

Self‐consistent molecular orbital methods. XX. A basis set for correlated wave functions journal, January 1980

Catalytic conversion of CO2 to value added fuels: Current status, challenges, and future directions journal, July 2016

Ternary Hybrid Material for High-Performance Lithium–Sulfur Battery journal, September 2015

X-ray-absorption fine-structure standards: A comparison of experiment and theory journal, September 1995

Structural characterization study of FeCo alloy nanoparticles in a highly porous aerogel silica matrix journal, November 2007

Self-Cleaning Catalyst Electrodes for Stabilized CO 2 Reduction to Hydrocarbons journal, September 2017

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts journal, February 2015

Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water journal, August 2015

Insights into Electrochemical Reactions from Ambient Pressure Photoelectron Spectroscopy journal, August 2015

Spectroscopic Observation of Reversible Surface Reconstruction of Copper Electrodes under CO 2 Reduction journal, May 2017

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy journal, January 2005

Density‐functional thermochemistry. III. The role of exact exchange journal, April 1993

Reconstruction phenomena at metal-electrolyte interfaces journal, February 1996

Highly selective and active CO2 reduction electrocatalysts based on cobalt phthalocyanine/carbon nanotube hybrid structures journal, March 2017

Electrocatalytic CO2 Conversion to Oxalate by a Copper Complex journal, January 2010

Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers journal, January 2016

Electrochemical Reduction of CO 2 at Functionalized Au Electrodes journal, February 2017

Atomic-scale cation dynamics in a monolayer VO X /α-Fe 2 O 3 catalyst journal, January 2015

Highly Dense Cu Nanowires for Low-Overpotential CO2 Reduction journal, September 2015

Activation of Cu(111) surface by decomposition into nanoclusters driven by CO adsorption journal, January 2016

Catalysis in real time using X-ray lasers journal, May 2017

Evaluation of the Impact of Surface Reconstruction on Rough Electrodeposited Copper-Based Catalysts for Carbon Dioxide Electroreduction journal, December 2016

Electroreduction of CO 2 Catalyzed by a Heterogenized Zn–Porphyrin Complex with a Redox-Innocent Metal Center journal, July 2017

A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst journal, October 2012

Structure-Sensitive CO 2 Electroreduction to Hydrocarbons on Ultrathin 5-fold Twinned Copper Nanowires journal, January 2017

Catalysts Transform While Molecules React: An Atomic-Scale View journal, January 2013

Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin journal, September 2015

Chemical reconstruction and catalysis of metal and bimetallic surfaces journal, June 1996

Tailoring Copper Nanocrystals towards C 2 Products in Electrochemical CO 2 Reduction journal, April 2016

Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst journal, September 2014

A Pt-Cluster-Based Heterogeneous Catalyst for Homogeneous Catalytic Reactions: X-ray Absorption Spectroscopy and Reaction Kinetic Studies of Their Activity and Stability against Leaching journal, August 2011

Coupled Metal/Oxide Catalysts with Tunable Product Selectivity for Electrocatalytic CO 2 Reduction journal, August 2017

Covalent Attachment of Catalyst Molecules to Conductive Diamond: CO 2 Reduction Using “Smart” Electrodes journal, September 2012

Solving the structure of nanoparticles by multiple-scattering EXAFS analysis journal, May 1999

Estimation of mean size and shape of small metal particles by EXAFS journal, January 1999

A nickel iron diselenide-derived efficient oxygen-evolution catalyst journal, August 2016

Electrochemical CO2 reduction: Electrocatalyst, reaction mechanism, and process engineering journal, November 2016

Copper-Based Metal-Organic Porous Materials for CO 2 Electrocatalytic Reduction to Alcohols journal, August 2016

Molecular Catalysts for Water Oxidation journal, July 2015

Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO 2 Reduction journal, November 2016

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts journal, February 2015

Self-Cleaning Catalyst Electrodes for Stabilized CO 2 Reduction to Hydrocarbons journal, September 2017

Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density text, January 1988

Tailoring Copper Nanocrystals towards C 2 Products in Electrochemical CO 2 Reduction journal, April 2016

Iron-Doped Cobalt Monophosphide Nanosheet/Carbon Nanotube Hybrids as Active and Stable Electrocatalysts for Water Splitting journal, April 2017

Recent Progress on Synchrotron-Based In-Situ Soft X-ray Spectroscopy for Energy Materials journal, May 2014

Tailoring Copper Nanocrystals towards C 2 Products in Electrochemical CO 2 Reduction journal, April 2016

Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO 2 Electroreduction by Process Conditions journal, December 2014

Evaluation of the Impact of Surface Reconstruction on Rough Electrodeposited Copper-Based Catalysts for Carbon Dioxide Electroreduction journal, December 2016

Catalytic isomerization of glucose to fructose over organic ligands: a DFT study journal, December 2022

Investigations on the E/Z-isomerism of neonicotinoids journal, July 2020

Chemical reconstruction and catalysis of metal and bimetallic surfaces journal, June 1996

Reconstruction phenomena at metal-electrolyte interfaces journal, February 1996

Structure and function of a novel antioxidant peptide from the skin of tropical frogs journal, February 2018

A rational design for enhanced oxygen reduction: Strongly coupled silver nanoparticles and engineered perovskite nanofibers journal, August 2017

Valence Change Ability and Geometrical Occupation of Substitution Cations Determine the Pseudocapacitance of Spinel Ferrite XFe 2 O 4 (X = Mn, Co, Ni, Fe) journal, June 2016

Molecular Catalysts for Water Oxidation journal, July 2015

Valence Change Ability and Geometrical Occupation of Substitution Cations Determine the Pseudocapacitance of Spinel Ferrite XFe ₂ O ₄ (X = Mn, Co, Ni, Fe)
journal, June 2016

Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide
journal, October 2015

Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO
journal, January 2012

Electrochemical CO ₂ Reduction to Hydrocarbons on a Heterogeneous Molecular Cu Catalyst in Aqueous Solution
journal, June 2016

Active sites of ligand-protected Au ₂₅ nanoparticle catalysts for CO ₂ electroreduction to CO
journal, May 2016

Metal/Oxide Interface Nanostructures Generated by Surface Segregation for Electrocatalysis
journal, October 2015

Reconstruction of Clean and Adsorbate-Covered Metal Surfaces
journal, January 1996

EXAFS Studies on the Size Dependence of Structural and Dynamic Properties of CdS Nanoparticles
journal, April 1997

Iron-Doped Cobalt Monophosphide Nanosheet/Carbon Nanotube Hybrids as Active and Stable Electrocatalysts for Water Splitting
journal, April 2017

In situ Growth of NixCu1-x Alloy Nanocatalysts on Redox-reversible Rutile (Nb,Ti)O4 Towards High-Temperature Carbon Dioxide Electrolysis
journal, June 2014

A rational design for enhanced oxygen reduction: Strongly coupled silver nanoparticles and engineered perovskite nanofibers
journal, August 2017

Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO ₂ Electroreduction by Process Conditions
journal, December 2014

A highly active and stable hydrogen evolution catalyst based on pyrite-structured cobalt phosphosulfide
journal, February 2016

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions
journal, May 2009

Size-dependent cohesive energy of nanocrystals
journal, December 2002

Particle Size Effects in the Catalytic Electroreduction of CO ₂ on Cu Nanoparticles
journal, May 2014

Recent Progress on Synchrotron-Based In-Situ Soft X-ray Spectroscopy for Energy Materials
journal, May 2014

Modeling the Structure and Composition of Nanoparticles by Extended X-Ray Absorption Fine-Structure Spectroscopy
journal, July 2011

Catalytic Activity and Stability of Oxides: The Role of Near-Surface Atomic Structures and Compositions
journal, April 2016

Self‐consistent molecular orbital methods. XX. A basis set for correlated wave functions
journal, January 1980

Catalytic conversion of CO2 to value added fuels: Current status, challenges, and future directions
journal, July 2016

Ternary Hybrid Material for High-Performance Lithium–Sulfur Battery
journal, September 2015

X-ray-absorption fine-structure standards: A comparison of experiment and theory
journal, September 1995

Structural characterization study of FeCo alloy nanoparticles in a highly porous aerogel silica matrix
journal, November 2007

Self-Cleaning Catalyst Electrodes for Stabilized CO ₂ Reduction to Hydrocarbons
journal, September 2017

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015

Covalent organic frameworks comprising cobalt porphyrins for catalytic CO ₂ reduction in water
journal, August 2015

Insights into Electrochemical Reactions from Ambient Pressure Photoelectron Spectroscopy
journal, August 2015

Spectroscopic Observation of Reversible Surface Reconstruction of Copper Electrodes under CO ₂ Reduction
journal, May 2017

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy
journal, January 2005

Density‐functional thermochemistry. III. The role of exact exchange
journal, April 1993

Reconstruction phenomena at metal-electrolyte interfaces
journal, February 1996

Highly selective and active CO2 reduction electrocatalysts based on cobalt phthalocyanine/carbon nanotube hybrid structures
journal, March 2017

Electrocatalytic CO2 Conversion to Oxalate by a Copper Complex
journal, January 2010

Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers
journal, January 2016

Electrochemical Reduction of CO ₂ at Functionalized Au Electrodes
journal, February 2017

Atomic-scale cation dynamics in a monolayer VO _X /α-Fe ₂ O ₃ catalyst
journal, January 2015

Highly Dense Cu Nanowires for Low-Overpotential CO₂ Reduction
journal, September 2015

Activation of Cu(111) surface by decomposition into nanoclusters driven by CO adsorption
journal, January 2016

Catalysis in real time using X-ray lasers
journal, May 2017

Evaluation of the Impact of Surface Reconstruction on Rough Electrodeposited Copper-Based Catalysts for Carbon Dioxide Electroreduction
journal, December 2016

Electroreduction of CO ₂ Catalyzed by a Heterogenized Zn–Porphyrin Complex with a Redox-Innocent Metal Center
journal, July 2017

A Local Proton Source Enhances CO ₂ Electroreduction to CO by a Molecular Fe Catalyst
journal, October 2012

Structure-Sensitive CO ₂ Electroreduction to Hydrocarbons on Ultrathin 5-fold Twinned Copper Nanowires
journal, January 2017

Catalysts Transform While Molecules React: An Atomic-Scale View
journal, January 2013

Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin
journal, September 2015

Chemical reconstruction and catalysis of metal and bimetallic surfaces
journal, June 1996

Tailoring Copper Nanocrystals towards C ₂ Products in Electrochemical CO ₂ Reduction
journal, April 2016

Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
journal, September 2014

A Pt-Cluster-Based Heterogeneous Catalyst for Homogeneous Catalytic Reactions: X-ray Absorption Spectroscopy and Reaction Kinetic Studies of Their Activity and Stability against Leaching
journal, August 2011

Coupled Metal/Oxide Catalysts with Tunable Product Selectivity for Electrocatalytic CO ₂ Reduction
journal, August 2017

Covalent Attachment of Catalyst Molecules to Conductive Diamond: CO ₂ Reduction Using “Smart” Electrodes
journal, September 2012

Solving the structure of nanoparticles by multiple-scattering EXAFS analysis
journal, May 1999

Estimation of mean size and shape of small metal particles by EXAFS
journal, January 1999

A nickel iron diselenide-derived efficient oxygen-evolution catalyst
journal, August 2016

Electrochemical CO2 reduction: Electrocatalyst, reaction mechanism, and process engineering
journal, November 2016

Copper-Based Metal-Organic Porous Materials for CO ₂ Electrocatalytic Reduction to Alcohols
journal, August 2016

Molecular Catalysts for Water Oxidation
journal, July 2015

Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO ₂ Reduction
journal, November 2016

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015

Self-Cleaning Catalyst Electrodes for Stabilized CO ₂ Reduction to Hydrocarbons
journal, September 2017

Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
text, January 1988

Tailoring Copper Nanocrystals towards C ₂ Products in Electrochemical CO ₂ Reduction
journal, April 2016

Iron-Doped Cobalt Monophosphide Nanosheet/Carbon Nanotube Hybrids as Active and Stable Electrocatalysts for Water Splitting
journal, April 2017

Recent Progress on Synchrotron-Based In-Situ Soft X-ray Spectroscopy for Energy Materials
journal, May 2014

Tailoring Copper Nanocrystals towards C ₂ Products in Electrochemical CO ₂ Reduction
journal, April 2016

Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO ₂ Electroreduction by Process Conditions
journal, December 2014

Evaluation of the Impact of Surface Reconstruction on Rough Electrodeposited Copper-Based Catalysts for Carbon Dioxide Electroreduction
journal, December 2016

Catalytic isomerization of glucose to fructose over organic ligands: a DFT study
journal, December 2022

Investigations on the E/Z-isomerism of neonicotinoids
journal, July 2020

Chemical reconstruction and catalysis of metal and bimetallic surfaces
journal, June 1996

Reconstruction phenomena at metal-electrolyte interfaces
journal, February 1996

Structure and function of a novel antioxidant peptide from the skin of tropical frogs
journal, February 2018

A rational design for enhanced oxygen reduction: Strongly coupled silver nanoparticles and engineered perovskite nanofibers
journal, August 2017

Valence Change Ability and Geometrical Occupation of Substitution Cations Determine the Pseudocapacitance of Spinel Ferrite XFe ₂ O ₄ (X = Mn, Co, Ni, Fe)
journal, June 2016

Molecular Catalysts for Water Oxidation
journal, July 2015

Spectroscopic Observation of Reversible Surface Reconstruction of Copper Electrodes under CO ₂ Reduction
journal, May 2017

Highly Dense Cu Nanowires for Low-Overpotential CO₂ Reduction
journal, September 2015

Metal/Oxide Interface Nanostructures Generated by Surface Segregation for Electrocatalysis
journal, October 2015

Structure-Sensitive CO ₂ Electroreduction to Hydrocarbons on Ultrathin 5-fold Twinned Copper Nanowires
journal, January 2017