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Title: Development and Elucidation of Superior Turnover Rates and Selectivity of Supported Molecular Catalysts

Authors:
ORCiD logo [1];  [1];  [2]; ORCiD logo [3]
  1. Department of Chemistry, University of California, Berkeley, Kavli Energy Nanosciences Institute at Berkeley, Berkeley CA 94720 USA, Chemical Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road Berkeley CA 94720 USA
  2. Department of Chemistry, University of California, Berkeley, Kavli Energy Nanosciences Institute at Berkeley, Berkeley CA 94720 USA, Materials Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road Berkeley CA 94720 USA
  3. Department of Chemistry, University of California, Berkeley, Kavli Energy Nanosciences Institute at Berkeley, Berkeley CA 94720 USA, Chemical Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road Berkeley CA 94720 USA, Materials Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road Berkeley CA 94720 USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1419695
Grant/Contract Number:  
DEAC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemCatChem
Additional Journal Information:
Journal Name: ChemCatChem Journal Volume: 10 Journal Issue: 8; Journal ID: ISSN 1867-3880
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Ye, Rong, Liu, Wen-Chi, Han, Hui-Ling, and Somorjai, Gabor A. Development and Elucidation of Superior Turnover Rates and Selectivity of Supported Molecular Catalysts. Germany: N. p., 2018. Web. doi:10.1002/cctc.201701546.
Ye, Rong, Liu, Wen-Chi, Han, Hui-Ling, & Somorjai, Gabor A. Development and Elucidation of Superior Turnover Rates and Selectivity of Supported Molecular Catalysts. Germany. doi:10.1002/cctc.201701546.
Ye, Rong, Liu, Wen-Chi, Han, Hui-Ling, and Somorjai, Gabor A. Tue . "Development and Elucidation of Superior Turnover Rates and Selectivity of Supported Molecular Catalysts". Germany. doi:10.1002/cctc.201701546.
@article{osti_1419695,
title = {Development and Elucidation of Superior Turnover Rates and Selectivity of Supported Molecular Catalysts},
author = {Ye, Rong and Liu, Wen-Chi and Han, Hui-Ling and Somorjai, Gabor A.},
abstractNote = {},
doi = {10.1002/cctc.201701546},
journal = {ChemCatChem},
number = 8,
volume = 10,
place = {Germany},
year = {2018},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/cctc.201701546

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Cited by: 1 work
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Works referenced in this record:

Trends in the catalytic reduction of CO2 by hydrogen over supported monometallic and bimetallic catalysts
journal, May 2013


Metal Nanoparticles Catalyzed Selective Carbon–Carbon Bond Activation in the Liquid Phase
journal, June 2016

  • Ye, Rong; Yuan, Bing; Zhao, Jie
  • Journal of the American Chemical Society, Vol. 138, Issue 27
  • DOI: 10.1021/jacs.6b03977

Heterogeneities of individual catalyst particles in space and time as monitored by spectroscopy
journal, October 2012

  • Buurmans, Inge L. C.; Weckhuysen, Bert M.
  • Nature Chemistry, Vol. 4, Issue 11
  • DOI: 10.1038/nchem.1478

In Situ Microscopy and Spectroscopy Applied to Surfaces at Work
journal, October 2015


Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol
journal, March 2014

  • Studt, Felix; Sharafutdinov, Irek; Abild-Pedersen, Frank
  • Nature Chemistry, Vol. 6, Issue 4
  • DOI: 10.1038/nchem.1873

Molecular catalysis science: Perspective on unifying the fields of catalysis
journal, April 2016

  • Ye, Rong; Hurlburt, Tyler J.; Sabyrov, Kairat
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 19
  • DOI: 10.1073/pnas.1601766113

Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures
journal, May 2011

  • Christopher, Phillip; Xin, Hongliang; Linic, Suljo
  • Nature Chemistry, Vol. 3, Issue 6
  • DOI: 10.1038/nchem.1032

On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
journal, April 2006

  • Phan, Nam T. S.; Van Der Sluys, Matthew; Jones, Christopher W.
  • Advanced Synthesis & Catalysis, Vol. 348, Issue 6
  • DOI: 10.1002/adsc.200505473

Molecular Rulers for Scaling Down Nanostructures
journal, February 2001


Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts
journal, September 2016

  • Matsubu, John C.; Zhang, Shuyi; DeRita, Leo
  • Nature Chemistry, Vol. 9, Issue 2
  • DOI: 10.1038/nchem.2607

Evidence of Structure Sensitivity in the Fischer-Tropsch Reaction on Model Cobalt Nanoparticles by Time-Resolved Chemical Transient Kinetics
journal, May 2017

  • Ralston, Walter T.; Melaet, Gérôme; Saephan, Tommy
  • Angewandte Chemie International Edition, Vol. 56, Issue 26
  • DOI: 10.1002/anie.201701186

The selective oxidation of n-butanol to butyraldehyde by oxygen using stable Pt-based nanoparticulate catalysts: an efficient route for upgrading aqueous biobutanol
journal, January 2016

  • Gandarias, Inaki; Nowicka, Ewa; May, Blake J.
  • Catalysis Science & Technology, Vol. 6, Issue 12
  • DOI: 10.1039/C5CY01726B

Effect of Heteroatom Concentration in SSZ-13 on the Methanol-to-Olefins Reaction
journal, December 2015


Metal Nanocrystals Embedded in Single Nanocrystals of MOFs Give Unusual Selectivity as Heterogeneous Catalysts
journal, September 2014

  • Na, Kyungsu; Choi, Kyung Min; Yaghi, Omar M.
  • Nano Letters, Vol. 14, Issue 10
  • DOI: 10.1021/nl503007h

Activation of Tungsten Oxide for Propane Dehydrogenation and Its High Catalytic Activity and Selectivity
journal, February 2017


Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
journal, April 2013

  • Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar300361m

Heterogeneously Catalyzed Alcohol Oxidation for the Fine Chemical Industry
journal, August 2014

  • Ciriminna, Rosaria; Pandarus, Valerica; Béland, Francois
  • Organic Process Research & Development, Vol. 19, Issue 11
  • DOI: 10.1021/acs.oprd.5b00204

Gas management and multiphase flow in direct alcohol fuel cells
journal, May 2014


Polyelemental nanoparticle libraries
journal, June 2016


Mesoporous Aluminosilicate Catalysts for the Selective Isomerization of n -Hexane: The Roles of Surface Acidity and Platinum Metal
journal, August 2015

  • Musselwhite, Nathan; Na, Kyungsu; Sabyrov, Kairat
  • Journal of the American Chemical Society, Vol. 137, Issue 32
  • DOI: 10.1021/jacs.5b04808

Enantioselective catalysis with homochiral metal–organic frameworks
journal, January 2009

  • Ma, Liqing; Abney, Carter; Lin, Wenbin
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256
  • DOI: 10.1039/b807083k

Copper Nanocrystals Encapsulated in Zr-based Metal–Organic Frameworks for Highly Selective CO 2 Hydrogenation to Methanol
journal, November 2016


Evidence of Structure Sensitivity in the Fischer-Tropsch Reaction on Model Cobalt Nanoparticles by Time-Resolved Chemical Transient Kinetics
journal, May 2017

  • Ralston, Walter T.; Melaet, Gérôme; Saephan, Tommy
  • Angewandte Chemie, Vol. 129, Issue 26
  • DOI: 10.1002/ange.201701186

Dramatically Different Kinetics and Mechanism at Solid/Liquid and Solid/Gas Interfaces for Catalytic Isopropanol Oxidation over Size-Controlled Platinum Nanoparticles
journal, July 2014

  • Wang, Hailiang; Sapi, Andras; Thompson, Christopher M.
  • Journal of the American Chemical Society, Vol. 136, Issue 29
  • DOI: 10.1021/ja505641r

The Nature of the Molybdenum Surface in Iron Molybdate. The Active Phase in Selective Methanol Oxidation
journal, October 2014

  • Brookes, Catherine; Wells, Peter P.; Dimitratos, Nikolaos
  • The Journal of Physical Chemistry C, Vol. 118, Issue 45
  • DOI: 10.1021/jp5081753

Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water
journal, August 2002

  • Cortright, R. D.; Davda, R. R.; Dumesic, J. A.
  • Nature, Vol. 418, Issue 6901
  • DOI: 10.1038/nature01009

Insight into the Effect of Water on the Methanol-to-Olefins Conversion in H-SAPO-34 from Molecular Simulations and in Situ Microspectroscopy
journal, February 2016

  • De Wispelaere, Kristof; Wondergem, Caterina S.; Ensing, Bernd
  • ACS Catalysis, Vol. 6, Issue 3
  • DOI: 10.1021/acscatal.5b02139

Supported molecular catalysts: metal complexes and clusters on oxides and zeolites
journal, January 2003

  • Guzman, Javier; Gates, Bruce C.
  • Dalton Transactions, Issue 17
  • DOI: 10.1039/b303285j

Converting homogeneous to heterogeneous in electrophilic catalysis using monodisperse metal nanoparticles
journal, November 2009

  • Witham, Cole A.; Huang, Wenyu; Tsung, Chia-Kuang
  • Nature Chemistry, Vol. 2, Issue 1
  • DOI: 10.1038/nchem.468

Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water
journal, August 2015


Dependence of Gas-Phase Crotonaldehyde Hydrogenation Selectivity and Activity on the Size of Pt Nanoparticles (1.7–7.1 nm) Supported on SBA-15
journal, November 2008

  • Grass, Michael E.; Rioux, Robert M.; Somorjai, Gabor A.
  • Catalysis Letters, Vol. 128, Issue 1-2
  • DOI: 10.1007/s10562-008-9754-4

Site-Selective Oxidative Coupling Reactions for the Attachment of Enzymes to Glass Surfaces through DNA-Directed Immobilization
journal, January 2017

  • Palla, Kanwal S.; Hurlburt, Tyler J.; Buyanin, Alexander M.
  • Journal of the American Chemical Society, Vol. 139, Issue 5
  • DOI: 10.1021/jacs.6b11716

Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
journal, December 2008

  • Xia, Younan; Xiong, Yujie; Lim, Byungkwon
  • Angewandte Chemie International Edition, Vol. 48, Issue 1, p. 60-103
  • DOI: 10.1002/anie.200802248

Selective conversion of syngas to light olefins
journal, March 2016


Chemical Environment Control and Enhanced Catalytic Performance of Platinum Nanoparticles Embedded in Nanocrystalline Metal–Organic Frameworks
journal, June 2015

  • Choi, Kyung Min; Na, Kyungsu; Somorjai, Gabor A.
  • Journal of the American Chemical Society, Vol. 137, Issue 24
  • DOI: 10.1021/jacs.5b03540

Effect of Acidic Properties of Mesoporous Zeolites Supporting Pt Nanoparticles on Hydrogenative Conversion of Methylcyclopentane
journal, November 2014

  • Na, Kyungsu; Alayoglu, Selim; Ye, Rong
  • Journal of the American Chemical Society, Vol. 136, Issue 49
  • DOI: 10.1021/ja509273h

Industrielle Anwendungen von Goldkatalysatoren
journal, September 2016

  • Ciriminna, Rosaria; Falletta, Ermelinda; Della Pina, Cristina
  • Angewandte Chemie, Vol. 128, Issue 46
  • DOI: 10.1002/ange.201604656

Reactivity of a Carbon-Supported Single-Site Molybdenum Dioxo Catalyst for Biodiesel Synthesis
journal, September 2016


Silver and oxide hybrids of catalysts during formaldehyde production
journal, June 2010


Insights into the Mechanism of Tandem Alkene Hydroformylation over a Nanostructured Catalyst with Multiple Interfaces
journal, September 2016

  • Su, Ji; Xie, Chenlu; Chen, Chen
  • Journal of the American Chemical Society, Vol. 138, Issue 36
  • DOI: 10.1021/jacs.6b03915

In Situ Spectroscopic Investigation into the Active Sites for Crotonaldehyde Hydrogenation at the Pt Nanoparticle–Co 3 O 4 Interface
journal, September 2016


Hydrogen Transfer versus Methylation: On the Genesis of Aromatics Formation in the Methanol-To-Hydrocarbons Reaction over H-ZSM-5
journal, August 2017

  • Martínez-Espín, Juan S.; De Wispelaere, Kristof; Janssens, Ton V. W.
  • ACS Catalysis, Vol. 7, Issue 9
  • DOI: 10.1021/acscatal.7b01643

Identification of single-site gold catalysis in acetylene hydrochlorination
journal, March 2017


Supported Iron Nanoparticles as Catalysts for Sustainable Production of Lower Olefins
journal, February 2012

  • Torres Galvis, H. M.; Bitter, J. H.; Khare, C. B.
  • Science, Vol. 335, Issue 6070, p. 835-838
  • DOI: 10.1126/science.1215614

Time-Resolved (2 s) Study of the Initial Steps of the Catalytic Hydrogenation of CO: From Branched Isomers to Unsaturated Molecules
journal, November 2014

  • Melaet, Gérôme; Ralston, Walter T.; Liu, Wen-Chi
  • The Journal of Physical Chemistry C, Vol. 118, Issue 46
  • DOI: 10.1021/jp5095917

Nanoporous Gold Catalysts for Selective Gas-Phase Oxidative Coupling of Methanol at Low Temperature
journal, January 2010


Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
journal, September 2011

  • Zhang, Jie-Peng; Zhang, Yue-Biao; Lin, Jian-Bin
  • Chemical Reviews, Vol. 112, Issue 2
  • DOI: 10.1021/cr200139g

High-spatial-resolution mapping of catalytic reactions on single particles
journal, January 2017

  • Wu, Chung-Yeh; Wolf, William J.; Levartovsky, Yehonatan
  • Nature, Vol. 541, Issue 7638
  • DOI: 10.1038/nature20795

Nanostructured materials for applications in heterogeneous catalysis
journal, January 2013


Self-assembly of noble metal monolayers on transition metal carbide nanoparticle catalysts
journal, May 2016


Industrial Applications of Gold Catalysis
journal, September 2016

  • Ciriminna, Rosaria; Falletta, Ermelinda; Della Pina, Cristina
  • Angewandte Chemie International Edition, Vol. 55, Issue 46
  • DOI: 10.1002/anie.201604656

Formkontrolle bei der Synthese von Metallnanokristallen: einfache Chemie, komplexe Physik?
journal, December 2008


Structure Sensitivity of the Hydrogenation of Crotonaldehyde over Pt/SiO2and Pt/TiO2
journal, February 1997

  • Englisch, Martin; Jentys, Andreas; Lercher, Johannes A.
  • Journal of Catalysis, Vol. 166, Issue 1
  • DOI: 10.1006/jcat.1997.1494

A Pt-Cluster-Based Heterogeneous Catalyst for Homogeneous Catalytic Reactions: X-ray Absorption Spectroscopy and Reaction Kinetic Studies of Their Activity and Stability against Leaching
journal, August 2011

  • Li, Yimin; Liu, Jack Hung-Chang; Witham, Cole A.
  • Journal of the American Chemical Society, Vol. 133, Issue 34
  • DOI: 10.1021/ja204191t

In Situ IR and X-ray High Spatial-Resolution Microspectroscopy Measurements of Multistep Organic Transformation in Flow Microreactor Catalyzed by Au Nanoclusters
journal, February 2014

  • Gross, Elad; Shu, Xing-Zhong; Alayoglu, Selim
  • Journal of the American Chemical Society, Vol. 136, Issue 9
  • DOI: 10.1021/ja412740p

The Pathway to Total Isomer Selectivity: n -Hexane Conversion (Reforming) on Platinum Nanoparticles Supported on Aluminum Modified Mesoporous Silica (MCF-17)
journal, November 2014

  • Musselwhite, Nathan; Na, Kyungsu; Alayoglu, Selim
  • Journal of the American Chemical Society, Vol. 136, Issue 47
  • DOI: 10.1021/ja509638w

Supported Dendrimer-Encapsulated Metal Clusters: Toward Heterogenizing Homogeneous Catalysts
journal, July 2017

  • Ye, Rong; Zhukhovitskiy, Aleksandr V.; Deraedt, Christophe V.
  • Accounts of Chemical Research, Vol. 50, Issue 8
  • DOI: 10.1021/acs.accounts.7b00232

Effects of Nanoparticle Size and Metal/Support Interactions in Pt-Catalyzed Methanol Oxidation Reactions in Gas and Liquid Phases
journal, September 2014


Shape-selective zeolite catalysis for bioplastics production
journal, July 2015

  • Dusselier, Michiel; Van Wouwe, Pieter; Dewaele, Annelies
  • Science, Vol. 349, Issue 6243
  • DOI: 10.1126/science.aaa7169

New Insights into Aldol Reactions of Methyl Isocyanoacetate Catalyzed by Heterogenized Homogeneous Catalysts
journal, December 2016


Product distribution change in the early stages of carbon monoxide hydrogenation over cobalt magnesium Fischer-Tropsch catalyst
journal, September 2016


Combining theory and experiment in electrocatalysis: Insights into materials design
journal, January 2017


Recent advances in catalysts for direct methanol fuel cells
journal, January 2011

  • Zhao, Xiao; Yin, Min; Ma, Liang
  • Energy & Environmental Science, Vol. 4, Issue 8
  • DOI: 10.1039/c1ee01307f

Alcohol Oxidation at Platinum–Gas and Platinum–Liquid Interfaces: The Effect of Platinum Nanoparticle Size, Water Coadsorption, and Alcohol Concentration
journal, March 2017

  • Tatsumi, Hironori; Liu, Fudong; Han, Hui-Ling
  • The Journal of Physical Chemistry C, Vol. 121, Issue 13
  • DOI: 10.1021/acs.jpcc.7b01432

Strong metal-support interactions
journal, November 1987