Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Application, Deactivation, and Regeneration of Heterogeneous Catalysts in Bio-Oil Upgrading

Abstract

The massive consumption of fossil fuels and associated environmental issues are leading to an increased interest in alternative resources such as biofuels. The renewable biofuels can be upgraded from bio-oils that are derived from biomass pyrolysis. Catalytic cracking and hydrodeoxygenation (HDO) are two of the most promising bio-oil upgrading processes for biofuel production. Heterogeneous catalysts are essential for upgrading bio-oil into hydrocarbon biofuel. Although advances have been achieved, the deactivation and regeneration of catalysts still remains a challenge. This review focuses on the current progress and challenges of heterogeneous catalyst application, deactivation, and regeneration. The technologies of catalysts deactivation, reduction, and regeneration for improving catalyst activity and stability are discussed. Some suggestions for future research including catalyst mechanism, catalyst development, process integration, and biomass modification for the production of hydrocarbon biofuels are provided.

Authors:
ORCiD logo; ; ;
Publication Date:
Research Org.:
South Dakota State Univ., Brookings, SD (United States)
Sponsoring Org.:
USDOE; Dept. of Transportation (DOT) (United States)
OSTI Identifier:
1419689
Alternate Identifier(s):
OSTI ID: 1395954
Grant/Contract Number:  
SA0900160; SA0700149; SA1600799
Resource Type:
Published Article
Journal Name:
Catalysts
Additional Journal Information:
Journal Name: Catalysts Journal Volume: 6 Journal Issue: 12; Journal ID: ISSN 2073-4344
Publisher:
MDPI AG
Country of Publication:
Switzerland
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 09 BIOMASS FUELS; biomass; biofuel; pyrolysis; bio-oil; catalyst; catalytic cracking; hydrodeoxygenation; coking; deactivation; regeneration

Citation Formats

Cheng, Shouyun, Wei, Lin, Zhao, Xianhui, and Julson, James. Application, Deactivation, and Regeneration of Heterogeneous Catalysts in Bio-Oil Upgrading. Switzerland: N. p., 2016. Web. doi:10.3390/catal6120195.
Copy to clipboard
Cheng, Shouyun, Wei, Lin, Zhao, Xianhui, & Julson, James. Application, Deactivation, and Regeneration of Heterogeneous Catalysts in Bio-Oil Upgrading. Switzerland. https://doi.org/10.3390/catal6120195
Copy to clipboard
Cheng, Shouyun, Wei, Lin, Zhao, Xianhui, and Julson, James. Wed . "Application, Deactivation, and Regeneration of Heterogeneous Catalysts in Bio-Oil Upgrading". Switzerland. https://doi.org/10.3390/catal6120195.
Copy to clipboard
@article{osti_1419689,
title = {Application, Deactivation, and Regeneration of Heterogeneous Catalysts in Bio-Oil Upgrading},
author = {Cheng, Shouyun and Wei, Lin and Zhao, Xianhui and Julson, James},
abstractNote = {The massive consumption of fossil fuels and associated environmental issues are leading to an increased interest in alternative resources such as biofuels. The renewable biofuels can be upgraded from bio-oils that are derived from biomass pyrolysis. Catalytic cracking and hydrodeoxygenation (HDO) are two of the most promising bio-oil upgrading processes for biofuel production. Heterogeneous catalysts are essential for upgrading bio-oil into hydrocarbon biofuel. Although advances have been achieved, the deactivation and regeneration of catalysts still remains a challenge. This review focuses on the current progress and challenges of heterogeneous catalyst application, deactivation, and regeneration. The technologies of catalysts deactivation, reduction, and regeneration for improving catalyst activity and stability are discussed. Some suggestions for future research including catalyst mechanism, catalyst development, process integration, and biomass modification for the production of hydrocarbon biofuels are provided.},
doi = {10.3390/catal6120195},
journal = {Catalysts},
number = 12,
volume = 6,
place = {Switzerland},
year = {2016},
month = {12}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.3390/catal6120195
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 25 works
Citation information provided by
Web of Science

Figures / Tables:

Table 1 Table 1: Typical properties of bio-oil and heavy fuel oil.
All figures and tables (7 total)
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Highly valuable chemicals production from catalytic upgrading of radiata pine sawdust-derived pyrolytic vapors over mesoporous MFI zeolites
journal, April 2010

Pyrolytic lignin removal for the valorization of biomass pyrolysis crude bio-oil by catalytic transformation
journal, January 2010

  • Gayubo, A. G.; Valle, B.; Aguayo, A. T.
  • Journal of Chemical Technology & Biotechnology, Vol. 85, Issue 1
  • DOI: 10.1002/jctb.2289

Bio-oil production from fast pyrolysis of waste furniture sawdust in a fluidized bed
journal, January 2010

Natural magnesium oxide (MgO) catalysts: A cost-effective sustainable alternative to acid zeolites for the in situ upgrading of biomass fast pyrolysis oil
journal, November 2016

Upgrading of the liquid fuel from fast pyrolysis of biomass over MoNi/γ-Al2O3 catalysts
journal, September 2010

Bio-oil and bio-char production from corn cobs and stover by fast pyrolysis
journal, January 2010

Catalytic Pyrolysis of Wild Reed over a Zeolite-Based Waste Catalyst
journal, March 2016

  • Yoo, Myung; Park, Yong; Park, Young-Kwon
  • Energies, Vol. 9, Issue 3
  • DOI: 10.3390/en9030201

Deactivation of Ni-MoS2 by bio-oil impurities during hydrodeoxygenation of phenol and octanol
journal, August 2016

Comparison of Lignin, Macroalgae, Wood, and Straw Fast Pyrolysis
journal, February 2013

  • Trinh, Trung Ngoc; Jensen, Peter Arendt; Dam-Johansen, Kim
  • Energy & Fuels, Vol. 27, Issue 3
  • DOI: 10.1021/ef301927y

Catalytic fast pyrolysis of jatropha wastes
journal, March 2012

  • Murata, Kazuhisa; Liu, Yanyong; Inaba, Megumu
  • Journal of Analytical and Applied Pyrolysis, Vol. 94
  • DOI: 10.1016/j.jaap.2011.11.008

Deactivation of hydroprocessing catalysts
journal, September 1999

Development of hydrocarbon biofuel from sunflower seed and sunflower meat oils over ZSM-5
journal, January 2016

  • Zhao, Xianhui; Wei, Lin; Cheng, Shouyun
  • Journal of Renewable and Sustainable Energy, Vol. 8, Issue 1
  • DOI: 10.1063/1.4941911

Organic chemistry of coke formation
journal, April 2001

Deactivation of FCC catalysts
journal, September 2008

Catalytic Hydroprocessing of Fast Pyrolysis Bio-oil from Pine Sawdust
journal, May 2012

  • Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.
  • Energy & Fuels, Vol. 26, Issue 6
  • DOI: 10.1021/ef3004587

Hydrotreatment of Fast Pyrolysis Oil Using Heterogeneous Noble-Metal Catalysts
journal, December 2009

  • Wildschut, Jelle; Mahfud, Farchad H.; Venderbosch, Robbie H.
  • Industrial & Engineering Chemistry Research, Vol. 48, Issue 23, p. 10324-10334
  • DOI: 10.1021/ie9006003

Pyro-catalytic deoxgenated bio-oil from palm oil empty fruit bunch and fronds with boric oxide in a fixed-bed reactor
journal, September 2011

Aromatic hydrocarbon production by the online catalytic cracking of lignin fast pyrolysis vapors using Mo2N/γ-Al2O3
journal, November 2013

Catalytic Activities of NiMo Carbide Supported on SiO2 for the Hydrodeoxygenation of Ethyl Benzoate, Acetone, and Acetaldehyde
journal, March 2010

  • Zhang, Wei; Zhang, Ye; Zhao, Liangfu
  • Energy & Fuels, Vol. 24, Issue 3, p. 2052-2059
  • DOI: 10.1021/ef901222z

Norms and standards for fast pyrolysis liquids
journal, June 2005

Heterogeneous Catalyst Deactivation and Regeneration: A Review
journal, February 2015

Catalytic upgrading of the light fraction of a simulated bio-oil over CeZrOx catalyst
journal, October 2013

  • Hakim, Sikander H.; Shanks, Brent H.; Dumesic, James A.
  • Applied Catalysis B: Environmental, Vol. 142-143
  • DOI: 10.1016/j.apcatb.2013.05.021

Role of transalkylation reactions in the conversion of anisole over HZSM-5
journal, May 2010

Guaiacol transformation over unsupported molybdenum-based nitride catalysts
journal, January 2012

Bio-oil from fast pyrolysis of rice husk: Yields and related properties and improvement of the pyrolysis system
journal, August 2007

Hydrous pyrolysis of Scenedesmus algae and algaenan-like residue
journal, August 2015

Directly catalytic upgrading bio-oil vapor produced by prairie cordgrass pyrolysis over Ni/HZSM-5 using a two stage reactor
journal, January 2015

Amorphous Co–Mo–B catalyst with high activity for the hydrodeoxygenation of bio-oil
journal, February 2011

In-situ upgrading of biomass pyrolysis vapors: Catalyst screening on a fixed bed reactor
journal, September 2011

Catalytic fast pyrolysis of wood and alcohol mixtures in a fluidized bed reactor
journal, January 2012

  • Zhang, Huiyan; Carlson, Torren R.; Xiao, Rui
  • Green Chem., Vol. 14, Issue 1
  • DOI: 10.1039/C1GC15619E

Catalytic upgrading of pyrolysis oil
journal, March 1993

  • Sharma, Ramesh K.; Bakhshi, Narendra N.
  • Energy & Fuels, Vol. 7, Issue 2
  • DOI: 10.1021/ef00038a022

Carbon-supported bimetallic Pd–Fe catalysts for vapor-phase hydrodeoxygenation of guaiacol
journal, October 2013

Efficient Hydrogenolysis of Guaiacol over Highly Dispersed Ni/MCM-41 Catalyst Combined with HZSM-5
journal, September 2016

Bio-Oil Upgrading via Catalytic Pyrolysis of Waste Mandarin Residue Over SBA-15 Catalysts
journal, April 2013

  • Kim, Jeong Wook; Joo, Sang Hoon; Seo, Bora
  • Journal of Nanoscience and Nanotechnology, Vol. 13, Issue 4
  • DOI: 10.1166/jnn.2013.7391

Hydrodeoxygenation of model compounds and catalytic systems for pyrolysis bio-oils upgrading
journal, January 2012

Screening acidic zeolites for catalytic fast pyrolysis of biomass and its components
journal, September 2011

  • Mihalcik, David J.; Mullen, Charles A.; Boateng, Akwasi A.
  • Journal of Analytical and Applied Pyrolysis, Vol. 92, Issue 1
  • DOI: 10.1016/j.jaap.2011.06.001

Catalytic pyrolysis of rice husk by mixing with zinc oxide: Characterization of bio-oil and its rheological behavior
journal, February 2013

Hydrotreatment of wood-based pyrolysis oil using zirconia-supported mono- and bimetallic (Pt, Pd, Rh) catalysts
journal, November 2011

Hydrodeoxygenation of bio-crude in supercritical hexane with sulfided CoMo and CoMoP catalysts supported on MgO: A model compound study using phenol
journal, June 2009

Bio-oil hydrodeoxygenation: Adsorption of phenolic compounds on sulfided (Co)Mo catalysts
journal, January 2013

Kinetic modelling and reactor simulation for methanol synthesis from hydrogen and carbon monoxide on a copper-base catalyst
journal, March 1984

  • Lee, Kyu Sung; Hong, Chang Shik; Lee, Chai-sung
  • Korean Journal of Chemical Engineering, Vol. 1, Issue 1
  • DOI: 10.1007/BF02697412

Deactivating species in the transformation of crude bio-oil with methanol into hydrocarbons on a HZSM-5 catalyst
journal, January 2012

Pyrolysis of algal biomass
journal, September 2013

  • Yanik, Jale; Stahl, Ralph; Troeger, Nicole
  • Journal of Analytical and Applied Pyrolysis, Vol. 103
  • DOI: 10.1016/j.jaap.2012.08.016

Fast pyrolysis technology development
journal, March 2010

  • Venderbosch, Rh; Prins, W.
  • Biofuels, Bioproducts and Biorefining, Vol. 4, Issue 2
  • DOI: 10.1002/bbb.205

Hydrodeoxygenation of prairie cordgrass bio-oil over Ni based activated carbon synergistic catalysts combined with different metals
journal, June 2016

Conversion of Prairie Cordgrass to Hydrocarbon Biofuel over Co-Mo/HZSM-5 Using a Two-Stage Reactor System
journal, February 2016

Catalytic hydrodeoxygenation (HDO) of phenol over supported molybdenum carbide, nitride, phosphide and oxide catalysts
journal, March 2014

In-situ and ex-situ upgrading of pyrolysis vapors from beetle-killed trees
journal, February 2016

Hydrotreatment of bio-oil over Ni-based catalyst
journal, January 2013

Synergy effect in the HDO of phenol over Ni–W catalysts supported on active carbon: Effect of tungsten precursors
journal, November 2010

Hydrodeoxygenation of anisole as bio-oil model compound over supported Ni and Co catalysts: Effect of metal and support properties
journal, April 2015

  • Sankaranarayanan, Thangaraju M.; Berenguer, Antonio; Ochoa-Hernández, Cristina
  • Catalysis Today, Vol. 243
  • DOI: 10.1016/j.cattod.2014.09.004

Hydrodeoxygenation of 2-furyl methyl ketone as a model compound in bio-oil from pyrolysis of Saccharina Japonica Alga in fixed-bed reactor
journal, August 2014

Upgrading pine sawdust pyrolysis oil to green biofuels by HDO over zinc-assisted Pd/C catalyst
journal, May 2016

Catalytic conversion of fast pyrolysis oil to hydrocarbon fuels over HZSM-5 in a dual reactor system
journal, January 1993

The effect of storage duration on bio-oil properties
journal, May 2012

  • Kim, Tae-Seung; Kim, Jae-Young; Kim, Kwang-Ho
  • Journal of Analytical and Applied Pyrolysis, Vol. 95
  • DOI: 10.1016/j.jaap.2012.01.015

Bio-oil valorization: A review
journal, July 2013

  • Jacobson, Kathlene; Maheria, Kalpana C.; Kumar Dalai, Ajay
  • Renewable and Sustainable Energy Reviews, Vol. 23
  • DOI: 10.1016/j.rser.2013.02.036

Overview of fuel properties of biomass fast pyrolysis oils
journal, May 2009

Vapor-phase hydrodeoxygenation of guaiacol on Al-MCM-41 supported Ni and Co catalysts
journal, February 2016

Catalytic hydrotreatment of fast-pyrolysis oil using non-sulfided bimetallic Ni-Cu catalysts on a δ-Al2O3 support
journal, May 2012

Fast Pyrolysis of Pine Sawdust in a Fluidized-Bed Reactor
journal, April 2010

  • DeSisto, William J.; Hill, Nathan; Beis, Sedat H.
  • Energy & Fuels, Vol. 24, Issue 4
  • DOI: 10.1021/ef901120h

Hydrodeoxygenation of guaiacol over Ni@Pd and Ni@Pt bimetallic overlayer catalysts
journal, November 2016

Prevention of zeolite deactivation by coking
journal, June 2009

  • Guisnet, Michel; Costa, Luís; Ribeiro, Fernando Ramôa
  • Journal of Molecular Catalysis A: Chemical, Vol. 305, Issue 1-2
  • DOI: 10.1016/j.molcata.2008.11.012

Effect of different catalysts on the cracking of Jatropha oil
journal, November 2014

From biomass to bio-gasoline by FCC co-processing: effect of feed composition and catalyst structure on product quality
journal, January 2011

  • Fogassy, Gabriella; Thegarid, Nicolas; Schuurman, Yves
  • Energy & Environmental Science, Vol. 4, Issue 12
  • DOI: 10.1039/c1ee02012a

Hydrodeoxygenation of pyrolysis oil for hydrocarbon production using nanospring based catalysts
journal, January 2016

  • Han, Yinglei; McIlroy, David N.; McDonald, Armando G.
  • Journal of Analytical and Applied Pyrolysis, Vol. 117
  • DOI: 10.1016/j.jaap.2015.12.011

Selectively catalytic upgrading of bio-oil to aromatic hydrocarbons over Zn, Ce or Ni-doped mesoporous rod-like alumina catalysts
journal, September 2016

Fast pyrolysis of palm kernel shells: Influence of operation parameters on the bio-oil yield and the yield of phenol and phenolic compounds
journal, December 2010

Development of a bifunctional Ni/HZSM-5 catalyst for converting prairie cordgrass to hydrocarbon biofuel
journal, August 2016

  • Cheng, S.; Wei, L.; Zhao, X.
  • Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, Vol. 38, Issue 16
  • DOI: 10.1080/15567036.2015.1065298

Upgrading of liquid fuel from the pyrolysis of biomass
journal, March 2005

Fast Pyrolysis of Forestry Residue. 3. Storage Stability of Liquid Fuel
journal, July 2003

Hydrodeoxygenation of m-cresol with Pt supported over mild acid materials
journal, July 2014

Hydrothermally stable HZSM-5 zeolite catalysts for the transformation of crude bio-oil into hydrocarbons
journal, October 2010

Analysis of switchgrass-derived bio-oil and associated aqueous phase generated in a semi-pilot scale auger pyrolyzer
journal, May 2016

  • Ren, Shoujie; Ye, X. Philip; Borole, Abhijeet P.
  • Journal of Analytical and Applied Pyrolysis, Vol. 119
  • DOI: 10.1016/j.jaap.2016.03.013

Nannochloropsis algae pyrolysis with ceria-based catalysts for production of high-quality bio-oils
journal, October 2015

Rapid and catalytic pyrolysis of corn stalks
journal, May 2009

NiFe/γ-Al2O3: A universal catalyst for the hydrodeoxygenation of bio-oil and its model compounds
journal, November 2013

High quality bio-oil from catalytic flash pyrolysis of lignocellulosic biomass over alumina-supported sodium carbonate
journal, November 2014

Coke formation during the hydrotreatment of bio-oil using NiMo and CoMo catalysts
journal, January 2017

A review of catalytic upgrading of bio-oil to engine fuels
journal, November 2011

  • Mortensen, P. M.; Grunwaldt, J.-D.; Jensen, P. A.
  • Applied Catalysis A: General, Vol. 407, Issue 1-2, p. 1-19
  • DOI: 10.1016/j.apcata.2011.08.046

The effect of mild hydrogenation on the catalytic cracking of bio-oil for aromatic hydrocarbon production
journal, October 2016

Conversion of Guaiacol on Noble Metal Catalysts: Reaction Performance and Deactivation Studies
journal, March 2014

  • Gao, Danni; Schweitzer, Christopher; Hwang, Hyun Tae
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 49
  • DOI: 10.1021/ie500495z

Fast pyrolysis of rice husk under different reaction conditions
journal, January 2010

  • Heo, Hyeon Su; Park, Hyun Ju; Dong, Jong-In
  • Journal of Industrial and Engineering Chemistry, Vol. 16, Issue 1
  • DOI: 10.1016/j.jiec.2010.01.026

Bulk and γ‑Al2O3-supported Ni2P and MoP for hydrodeoxygenation of palmitic acid
journal, January 2016

Characterization and hydrodeoxygenation properties of Co promoted Ni–Mo–B amorphous catalysts: influence of Co content
journal, May 2010

  • Wang, Weiyan; Yang, Yunquan; Luo, Hean
  • Reaction Kinetics, Mechanisms and Catalysis, Vol. 101, Issue 1
  • DOI: 10.1007/s11144-010-0201-3

Continuous Catalytic Hydrodeoxygenation of Guaiacol over Pt/SiO2 and Pt/H-MFI-90
journal, July 2015

  • Hellinger, Melanie; Baier, Sina; Mortensen, Peter
  • Catalysts, Vol. 5, Issue 3
  • DOI: 10.3390/catal5031152

In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst
journal, June 2017

Upgrading of bio-oil and subsequent co-processing under FCC conditions for fuel production
journal, January 2016

  • Huynh, Thuan Minh; Armbruster, Udo; Atia, Hanan
  • Reaction Chemistry & Engineering, Vol. 1, Issue 2
  • DOI: 10.1039/C5RE00068H

A comparative study of straw, perennial grasses and hardwoods in terms of fast pyrolysis products
journal, June 2013

Upgrading of Bio-Oil Using Supercritical 1-Butanol over a Ru/C Heterogeneous Catalyst: Role of the Solvent
journal, May 2014

  • Xu, Xingmin; Zhang, Changsen; Zhai, Yunpu
  • Energy & Fuels, Vol. 28, Issue 7
  • DOI: 10.1021/ef500968a

Biofuels Production through Biomass Pyrolysis —A Technological Review
journal, November 2012

  • Jahirul, Mohammad; Rasul, Mohammad; Chowdhury, Ashfaque
  • Energies, Vol. 5, Issue 12
  • DOI: 10.3390/en5124952

Bio-oils Hydrodeoxygenation: Adsorption of Phenolic Molecules on Oxidic Catalyst Supports
journal, August 2010

  • Popov, Andrey; Kondratieva, Elena; Goupil, Jean Michel
  • The Journal of Physical Chemistry C, Vol. 114, Issue 37
  • DOI: 10.1021/jp101949j

Selective Production of Aromatics by Crude Bio-oil Valorization with a Nickel-Modified HZSM-5 Zeolite Catalyst
journal, March 2010

  • Valle, Beatriz; Gayubo, Ana G.; Aguayo, Andrés T.
  • Energy & Fuels, Vol. 24, Issue 3
  • DOI: 10.1021/ef901231j

Effect of operating conditions on the coke nature and HZSM-5 catalysts deactivation in the transformation of crude bio-oil into hydrocarbons
journal, November 2012

Production of phenolic-rich bio-oil from catalytic fast pyrolysis of biomass using magnetic solid base catalyst
journal, December 2015

Biofuel production from catalytic microwave pyrolysis of Douglas fir pellets over ferrum-modified activated carbon catalyst
journal, March 2015

Upgrading of pyrolysis bio-oil using nickel phosphide catalysts
journal, January 2016

Liquid phase in-situ hydrodeoxygenation of bio-derived phenol over Raney Ni and Nafion/SiO2
journal, November 2015

Hydrodeoxygenation of dibenzofuran to bicyclic hydrocarbons using bimetallic Cu–Ni catalysts supported on metal oxides
journal, September 2016

Projection of world fossil fuels by country
journal, February 2015

Effects of nano-structured CoMo catalysts on hydrodeoxygenation of fast pyrolysis oil in supercritical ethanol
journal, July 2016

Selective catalytic conversion of bio-oil over high-silica zeolites
journal, March 2015

The catalytic activity of Sulfided Ni/W/TiO2 (anatase) for the hydrodeoxygenation of Guaiacol
journal, October 2014

Co-hydrotreating of used engine oil and the low-boiling fraction of bio-oil blends for the production of liquid fuel
journal, June 2016

Hydrodeoxygenation of oxidized distilled bio-oil for the production of gasoline fuel type
journal, March 2016

Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study
journal, November 2010

  • Lu, Qiang; Zhang, Zhi-Fei; Dong, Chang-Qing
  • Energies, Vol. 3, Issue 11
  • DOI: 10.3390/en3111805

Catalytic hydrodeoxygenation of simulated phenolic bio-oil to cycloalkanes and aromatic hydrocarbons over bifunctional metal/acid catalysts of Ni/HBeta, Fe/HBeta and NiFe/HBeta
journal, March 2016

  • Shafaghat, Hoda; Rezaei, Pouya Sirous; Daud, Wan Mohd Ashri Wan
  • Journal of Industrial and Engineering Chemistry, Vol. 35
  • DOI: 10.1016/j.jiec.2016.01.001

Gas-phase hydrodeoxygenation of guaiacol over Fe/SiO2 catalyst
journal, April 2012

Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review
journal, May 2006

  • Mohan, Dinesh; Pittman,, Charles U.; Steele, Philip H.
  • Energy & Fuels, Vol. 20, Issue 3, p. 848-889
  • DOI: 10.1021/ef0502397

Ce-promoted Ni/SBA-15 catalysts for anisole hydrotreating under mild conditions
journal, November 2016

  • Yang, Yongxing; Ochoa-Hernández, Cristina; Pizarro, Patricia
  • Applied Catalysis B: Environmental, Vol. 197
  • DOI: 10.1016/j.apcatb.2016.01.001

Effects of Support Surface Chemistry in Hydrodeoxygenation Reactions over CoMo/Activated Carbon Sulfided Catalysts †
journal, August 1999

  • de la Puente, G.; Gil, A.; Pis, J. J.
  • Langmuir, Vol. 15, Issue 18
  • DOI: 10.1021/la981225e

Activated carbons for the hydrothermal upgrading of crude duckweed bio-oil
journal, October 2016

Hydrodeoxygenation of guaiacol over Pt loaded zeolitic materials
journal, May 2016

  • Lee, Eun Hwa; Park, Rae-su; Kim, Hannah
  • Journal of Industrial and Engineering Chemistry, Vol. 37
  • DOI: 10.1016/j.jiec.2016.03.019

Upgrading of bio-oil from biomass pyrolysis over Cu-modified β-zeolite catalyst with high selectivity and stability
journal, June 2016

Improving HZSM-5 resistance to phenolic compounds for the bio-oils/FCC feedstocks co-processing
journal, January 2015

Comparison of catalytic pyrolysis of biomass with MCM-41 and CaO catalysts by using TGA–FTIR analysis
journal, November 2010

  • Wang, Denghui; Xiao, Rui; Zhang, Huiyan
  • Journal of Analytical and Applied Pyrolysis, Vol. 89, Issue 2
  • DOI: 10.1016/j.jaap.2010.07.008

Olefin Production by Catalytic Transformation of Crude Bio-Oil in a Two-Step Process
journal, January 2010

  • Gayubo, Ana G.; Valle, Beatriz; Aguayo, Andrés T.
  • Industrial & Engineering Chemistry Research, Vol. 49, Issue 1
  • DOI: 10.1021/ie901204n

Bio-oil upgrading by means of ethyl ester production in reactive distillation to remove water and to improve storage and fuel characteristics
journal, November 2008

Catalytic cracking of carinata oil for hydrocarbon biofuel over fresh and regenerated Zn/Na-ZSM-5
journal, October 2015

From biomass to fuels: Hydrotreating of oxygenated compounds
journal, July 2008

Characterization and catalytic properties of Ni and NiCu catalysts supported on ZrO2–SiO2 for guaiacol hydrodeoxygenation
journal, March 2013

Co-processing raw bio-oil and gasoil in an FCC Unit
journal, March 2015

  • Pinho, Andrea de Rezende; de Almeida, Marlon B. B.; Mendes, Fabio Leal
  • Fuel Processing Technology, Vol. 131
  • DOI: 10.1016/j.fuproc.2014.11.008

Catalytic hydrodeoxygenation of crude bio-oil over an unsupported bimetallic dispersed catalyst in supercritical ethanol
journal, July 2016

Catalytic pyrolysis of biomass for biofuels production
journal, January 2010

Catalytic fast pyrolysis of mushroom waste to upgraded bio-oil products via pre-coked modified HZSM-5 catalyst
journal, July 2016

Hydrodeoxygenation of lignin-derived monomers and lignocellulose pyrolysis oil on the carbon-supported Ru catalysts
journal, May 2016

Hydrodeoxygenation of fast-pyrolysis bio-oils from various feedstocks using carbon-supported catalysts
journal, July 2014

Influence on nickel particle size on the hydrodeoxygenation of phenol over Ni/SiO 2
journal, January 2016

Sewage sludge-to-energy approaches based on anaerobic digestion and pyrolysis: Brief overview and energy efficiency assessment
journal, April 2012

Catalytic conversion of aqueous fraction of bio-oil to alcohols over CNT-supported catalysts
journal, September 2016

Catalytic cracking of camelina oil for hydrocarbon biofuel over ZSM-5-Zn catalyst
journal, November 2015

Bio-oil, solid and gaseous biofuels from biomass pyrolysis processes-An overview
journal, January 2011

  • Vamvuka, D.
  • International Journal of Energy Research, Vol. 35, Issue 10
  • DOI: 10.1002/er.1804

Preparation of Ni–W–P–B amorphous catalyst for the hydrodeoxygenation of p-cresol
journal, February 2015

Bio-fuels from thermochemical conversion of renewable resources: A review
journal, February 2008

  • Goyal, H. B.; Seal, Diptendu; Saxena, R. C.
  • Renewable and Sustainable Energy Reviews, Vol. 12, Issue 2
  • DOI: 10.1016/j.rser.2006.07.014

Upgrading of bio-oil in supercritical ethanol: Catalysts screening, solvent recovery and catalyst stability study
journal, November 2014

Catalytic upgrading of pyrolytic vapors from the vacuum pyrolysis of rape straw over nanocrystalline HZSM-5 zeolite in a two-stage fixed-bed reactor
journal, July 2014

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Biomass Energy Technological Paradigm (BETP): Trends in This Sector
    journal, April 2017

    Overview of catalytic upgrading of biomass pyrolysis vapors toward the production of fuels and high-value chemicals
    journal, August 2018

    • Iliopoulou, Eleni F.; Triantafyllidis, Kostas S.; Lappas, Angelos A.
    • Wiley Interdisciplinary Reviews: Energy and Environment, Vol. 8, Issue 1
    • DOI: 10.1002/wene.322

    Efficient deoxygenation of waste cooking oil over Co 3 O 4 –La 2 O 3 -doped activated carbon for the production of diesel-like fuel
    journal, January 2020

    • Abdulkareem-Alsultan, G.; Asikin-Mijan, N.; Mustafa-Alsultan, G.
    • RSC Advances, Vol. 10, Issue 9
    • DOI: 10.1039/c9ra09516k

    Transition Metal Phosphides for the Catalytic Hydrodeoxygenation of Waste Oils into Green Diesel
    journal, March 2019

    • Alvarez-Galvan, M.; Campos-Martin, Jose; Fierro, Jose
    • Catalysts, Vol. 9, Issue 3
    • DOI: 10.3390/catal9030293

    Catalyst Performance in the HDPE Pyrolysis-Reforming under Reaction-Regeneration Cycles
    journal, May 2019

    • Barbarias, Itsaso; Artetxe, Maite; Lopez, Gartzen
    • Catalysts, Vol. 9, Issue 5
    • DOI: 10.3390/catal9050414
      Sort by:
      [ × clear filter / sort ]

      Figures / Tables found in this record:

      Table 1 (p. 3)table
      Table 2 (p. 4)table
      Table 3 : Part 1 (p. 4)table
      Table 3 : Part 2 (p. 5)table
      Figure 1 (p. 7)figure
      Table 4 : Part 1 (p. 10)table
      Table 4 : Part 2 (p. 11)table
        [ × clear filter / sort ]
        Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

        Similar Records in DOE PAGES and OSTI.GOV collections: