Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex
Abstract
Here, a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [FeV(NTs)(TAML)]– (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [FeV(NTs)(TAML+•)] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML+•). 2 is a competent oxidant in C–H bond functionalization and nitrene transfer reaction, showing that the reactivity of 2 is greater than that of 1.
- Authors:
-
[1];
[2];
[6]
- Ewha Womans Univ., Seoul (Korea); Sookmyung Women's Univ., Seoul (Korea)
- Ewha Womans Univ., Seoul (Korea)
- Univ. of Hyogo, Hyogo (Japan)
- Univ. Grenoble Alpes, Grenoble (France)
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Ewha Womans Univ., Seoul (Korea); Chinese Academy of Sciences, Lanzhou (China)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1419655
- Grant/Contract Number:
- AC02-76SF00515; ANR-11-LABX-003; NRF-2010-00353; NRF-2012R1A3A2048842; NRF-2017R1C1B2002037; 15H00960; P41GM103393
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 139; Journal Issue: 41; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Hong, Seungwoo, Lu, Xiaoyan, Lee, Yong -Min, Seo, Mi Sook, Ohta, Takehiro, Ogura, Takashi, Clemancey, Martin, Maldivi, Pascale, Latour, Jean -Marc, Sarangi, Ritimukta, and Nam, Wonwoo. Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex. United States: N. p., 2017.
Web. doi:10.1021/jacs.7b08161.
Hong, Seungwoo, Lu, Xiaoyan, Lee, Yong -Min, Seo, Mi Sook, Ohta, Takehiro, Ogura, Takashi, Clemancey, Martin, Maldivi, Pascale, Latour, Jean -Marc, Sarangi, Ritimukta, & Nam, Wonwoo. Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex. United States. https://doi.org/10.1021/jacs.7b08161
Hong, Seungwoo, Lu, Xiaoyan, Lee, Yong -Min, Seo, Mi Sook, Ohta, Takehiro, Ogura, Takashi, Clemancey, Martin, Maldivi, Pascale, Latour, Jean -Marc, Sarangi, Ritimukta, and Nam, Wonwoo. Fri .
"Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex". United States. https://doi.org/10.1021/jacs.7b08161. https://www.osti.gov/servlets/purl/1419655.
@article{osti_1419655,
title = {Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex},
author = {Hong, Seungwoo and Lu, Xiaoyan and Lee, Yong -Min and Seo, Mi Sook and Ohta, Takehiro and Ogura, Takashi and Clemancey, Martin and Maldivi, Pascale and Latour, Jean -Marc and Sarangi, Ritimukta and Nam, Wonwoo},
abstractNote = {Here, a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [FeV(NTs)(TAML)]– (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [FeV(NTs)(TAML+•)] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML+•). 2 is a competent oxidant in C–H bond functionalization and nitrene transfer reaction, showing that the reactivity of 2 is greater than that of 1.},
doi = {10.1021/jacs.7b08161},
journal = {Journal of the American Chemical Society},
number = 41,
volume = 139,
place = {United States},
year = {Fri Sep 29 00:00:00 EDT 2017},
month = {Fri Sep 29 00:00:00 EDT 2017}
}
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