Unravelling the Chemical Influence of Water on the PMMA/Aluminum Oxide Hybrid Interface In Situ

Pletincx, Sven; Marcoen, Kristof; Trotochaud, Lena; Fockaert, Laura-Lynn; Mol, Johannes M.  C.; Head, Ashley R.; Karslioğlu, Osman; Bluhm, Hendrik; Terryn, Herman; Hauffman, Tom

doi:10.1038/s41598-017-13549-z

Title: Unravelling the Chemical Influence of Water on the PMMA/Aluminum Oxide Hybrid Interface In Situ

Abstract

Understanding the stability of chemical interactions at the polymer/metal oxide interface under humid conditions is vital to understand the long-term durability of hybrid systems. Therefore, the interface of ultrathin PMMA films on native aluminum oxide, deposited by reactive adsorption, was studied. The characterization of the interface of the coated substrates was performed using ambient pressure X-ray photoelectron spectroscopy (APXPS), Fourier transform infrared spectroscopy in the Kretschmann geometry (ATR-FTIR Kretschmann) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). The formation of hydrogen bonds and carboxylate ionic bonds at the interface are observed. The formed ionic bond is stable up to 5 Torr water vapour pressure as shown by APXPS. However, when the coated samples are exposed to an excess of aqueous electrolyte, an increase in the amount of carboxylate bonds at the interface, as a result of hydrolysis of the methoxy group, is observed by ATR-FTIR Kretschmann. In conclusion, these observations, supported by ToF-SIMS spectra, lead to the proposal of an adsorption mechanism of PMMA on aluminum oxide, which shows the formation of methanol at the interface and the effect of water molecules on the different interfacial interactions.

Authors:

^[1]; Marcoen, Kristof ^[2]; Trotochaud, Lena ^[3]; Fockaert, Laura-Lynn ^[4];

^[4];

^[3];

^[3]; Bluhm, Hendrik ^[3]; Terryn, Herman ^[2];

^[2]

Vrije Univ. Brussel, Brussels, (Belgium). Dept. of Electrochemical and Surface Engineering (SURF); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
Vrije Univ. Brussel, Brussels, (Belgium). Dept. of Electrochemical and Surface Engineering (SURF)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
Delft Univ. of Technology (Netherlands). Dept. of Materials Science and Engineering

Publication Date:: 2017-10-17

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOD; Research Foundation Flanders (FWO)

OSTI Identifier:: 1419452

Grant/Contract Number:: AC02-05CH11231; HDTRA11510005

Resource Type:: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Pletincx, Sven, Marcoen, Kristof, Trotochaud, Lena, Fockaert, Laura-Lynn, Mol, Johannes M.  C., Head, Ashley R., Karslioğlu, Osman, Bluhm, Hendrik, Terryn, Herman, and Hauffman, Tom. Unravelling the Chemical Influence of Water on the PMMA/Aluminum Oxide Hybrid Interface In Situ.  United States: N. p., 2017. 
Web.  doi:10.1038/s41598-017-13549-z.

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                    Pletincx, Sven, Marcoen, Kristof, Trotochaud, Lena, Fockaert, Laura-Lynn, Mol, Johannes M.  C., Head, Ashley R., Karslioğlu, Osman, Bluhm, Hendrik, Terryn, Herman, & Hauffman, Tom. Unravelling the Chemical Influence of Water on the PMMA/Aluminum Oxide Hybrid Interface In Situ.  United States.  https://doi.org/10.1038/s41598-017-13549-z

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                    Pletincx, Sven, Marcoen, Kristof, Trotochaud, Lena, Fockaert, Laura-Lynn, Mol, Johannes M.  C., Head, Ashley R., Karslioğlu, Osman, Bluhm, Hendrik, Terryn, Herman, and Hauffman, Tom. Tue .  
"Unravelling the Chemical Influence of Water on the PMMA/Aluminum Oxide Hybrid Interface In Situ".  United States.  https://doi.org/10.1038/s41598-017-13549-z.  https://www.osti.gov/servlets/purl/1419452.

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@article{osti_1419452,

  title        = {Unravelling the Chemical Influence of Water on the PMMA/Aluminum Oxide Hybrid Interface In Situ},

  author       = {Pletincx, Sven and Marcoen, Kristof and Trotochaud, Lena and Fockaert, Laura-Lynn and Mol, Johannes M.  C. and Head, Ashley R. and Karslioğlu, Osman and Bluhm, Hendrik and Terryn, Herman and Hauffman, Tom},

  abstractNote = {Understanding the stability of chemical interactions at the polymer/metal oxide interface under humid conditions is vital to understand the long-term durability of hybrid systems. Therefore, the interface of ultrathin PMMA films on native aluminum oxide, deposited by reactive adsorption, was studied. The characterization of the interface of the coated substrates was performed using ambient pressure X-ray photoelectron spectroscopy (APXPS), Fourier transform infrared spectroscopy in the Kretschmann geometry (ATR-FTIR Kretschmann) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). The formation of hydrogen bonds and carboxylate ionic bonds at the interface are observed. The formed ionic bond is stable up to 5 Torr water vapour pressure as shown by APXPS. However, when the coated samples are exposed to an excess of aqueous electrolyte, an increase in the amount of carboxylate bonds at the interface, as a result of hydrolysis of the methoxy group, is observed by ATR-FTIR Kretschmann. In conclusion, these observations, supported by ToF-SIMS spectra, lead to the proposal of an adsorption mechanism of PMMA on aluminum oxide, which shows the formation of methanol at the interface and the effect of water molecules on the different interfacial interactions.},

  doi          = {10.1038/s41598-017-13549-z},

  journal      = {Scientific Reports},

  number       = 1,

  volume       = 7,

  place        = {United States},

  year         = {2017},

  month        = {10}

}

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Title: Unravelling the Chemical Influence of Water on the PMMA/Aluminum Oxide Hybrid Interface In Situ

Abstract

Citation Formats

Improving the adhesion between epoxy coatings and aluminium substrates journal, December 2004

Static SIMS investigation of metal/polymer interfaces journal, May 1995

Examination of the interface of a model adhesive joint by surface analysis: a study by XPS and ToF-SIMS journal, June 2009

Photoelectron spectroscopy under ambient pressure and temperature conditions journal, March 2009

Infrared Study of the Kinetics and Mechanism of Adsorption of Acrylic Polymers on Alumina Surfaces journal, May 2004

Paint adhesion, corrosion protection, and interfacial chemistry journal, October 1994

Acid-Base Interactions in Adhesion: The Characterization of Surfaces & Interfaces by XPS journal, November 1992

Chemistry of the Metal-Polymer Interfacial Region journal, September 1988

Preparation and Characterization of Mesoporous Zirconia Made by Using a Poly (methyl methacrylate) Template journal, February 2008

In Situ Study of Buried Metal–Polymer Interfaces Exposed to an Aqueous Solution by an Integrated ATR-FTIR and Electrochemical Impedance Spectroscopy System journal, September 2013

Adsorption of PMMA on Oxidized Al and Si Substrates: An Investigation by High-Resolution X-ray Photoelectron Spectroscopy journal, March 2000

Molecular Interactions of Electroadsorbed Carboxylic Acid and Succinic Anhydride Monomers on Zinc Surfaces journal, August 2011

Degradation of Interfacial Chemistry of Epoxy/Silane/Aluminium Interfaces as a Result of Aqueous Attack journal, September 2005

The existence of quasi-two-dimensional glass-like structures at strongly interacting polymer-solid interfaces journal, September 1991

In situ study of poly(methyl methacrylate) adsorption from solution onto chemically modified Si(100) surfaces by internal reflection infrared spectroscopy journal, July 1993

In Situ Study of Buried Interfacial Bonding Mechanisms of Carboxylic Polymers on Zn Surfaces journal, February 2013

Ageing of aluminium oxide surfaces and their subsequent reactivity towards bonding with organic functional groups journal, August 2004

Robust, Functionalizable, Nanometer-Thick Poly(acrylic acid) Films Spontaneously Assembled on Oxidized Aluminum Substrates: Structures and Chemical Properties journal, April 2011

Problems and progress in organic coatings science and technology journal, May 1997

A combined Fourier transform infra-red multiple specular reflectance and inelastic electron tunnelling spectroscopy study of poly(methyl methacrylate) on oxidized aluminium journal, January 1991

The use of XPS to examine the interaction of poly(acrylic acid) with oxidised metal substrates journal, July 1997

Quantitative chemical composition of thin films with infrared spectroscopic ellipsometry: application to hydrated oxide films on aluminium journal, January 2003

A comparison of the interfacial bonding properties of carboxylic acid functional groups on zinc and iron substrates journal, January 2011

Influence of the Iron Oxide Acid−Base Properties on the Chemisorption of Model Epoxy Compounds Studied by XPS journal, September 2007

The nature of the surface acidity of anodised titanium: an XPS study using 1,2-diaminoethane journal, August 1996

Glassy relaxation at polymer-solid interfaces journal, April 1992

Chemisorption of monocarboxylic acids on alumina: A tunneling spectroscopy study journal, October 1978

Interaction of Anhydride and Carboxylic Acid Compounds with Aluminum Oxide Surfaces Studied Using Infrared Reflection Absorption Spectroscopy journal, July 2004

Interaction of epoxy model molecules with aluminium, anodised titanium and copper surfaces: an XPS study journal, August 1998

The reactions of oxidised aluminium surfaces with lubricant additives and related compounds journal, October 1991

Investigation of solid/vapor interfaces using ambient pressure X-ray photoelectron spectroscopy journal, January 2013

Changes in epoxy-coated aluminium due to exposure to water journal, December 2004

ADHESION AND DE-ADHESION MECHANISMS AT POLYMER/METAL INTERFACES: Mechanistic Understanding Based on In Situ Studies of Buried Interfaces journal, August 2005

Influence of pretreatments and aging on the adhesion performance of epoxy-coated aluminum journal, January 2013

A molecular orbital study of the interactions of acrylic polymers with aluminum: Implications for adhesion journal, November 1990

Molecular Bonding and Adhesion at Polymer-Metal Interphases journal, September 1994

Interaction of carboxylic acids with the oxyhydroxide surface of aluminium: poly(acrylic acid), acetic acid and propionic acid on pseudoboehmite journal, December 2001

Orthogonal Self-Assembled Monolayers: Alkanethiols on Gold and Alkane Carboxylic Acids on Alumina journal, August 1989

XPS studies of metal/polymer interfaces — Thin films of Al on polyacrylic acid and polyethylene journal, November 1986

High-resolution monochromated XPS of poly(methyl methacrylate) thin films on a conducting substrate journal, February 1991

Spontaneously organized molecular assemblies. 2. Quantitative infrared spectroscopic determination of equilibrium structures of solution-adsorbed n-alkanoic acids on an oxidized aluminum surface journal, January 1985

Role of acid-base interfacial bonding in adhesion journal, January 1987

Segment level chemistry and chain conformation in the reactive adsorption of poly(methyl methacrylate) on aluminum oxide surfaces journal, May 1992

Interfacial chemistry of adhesives on hydrated aluminium and hydrated aluminium treated with an organosilane journal, January 2004

Interfacial interactions of plasma-polymerized acrylic acid and an oxidized aluminium surface investigated using XPS, FTIR and poly(acrylic acid) as a model compound journal, December 1998

XPS investigations of acid-base interactions in adhesion. Part 3. Evidence for orientation of carbonyl groups from poly(methylmethacrylate) (PMMA) at the PMMA-glass and PMMA-SiO2 interfaces journal, November 1993

Transport processes of hydrated ions at polymer/oxide/metal interfaces journal, January 2009

Bonding Mechanisms at Buried Interfaces between Carboxylic Polymers and Treated Zinc Surfaces journal, January 2013

In Situ Characterization of the Initial Effect of Water on Molecular Interactions at the Interface of Organic/Inorganic Hybrid Systems journal, March 2017

The characterisation of the interfacial chemistry of adhesion of rigid polyurethane foam to aluminium journal, August 2011

Surface oxide development on aluminum alloy 6063 during heat treatment journal, February 2019

Probing the formation and degradation of chemical interactions from model molecule/metal oxide to buried polymer/metal oxide interfaces journal, June 2019

3D printing multifunctional fluorinated nanocomposites: tuning electroactivity, rheology and chemical reactivity journal, January 2018

Improving the adhesion between epoxy coatings and aluminium substrates
journal, December 2004

Static SIMS investigation of metal/polymer interfaces
journal, May 1995

Examination of the interface of a model adhesive joint by surface analysis: a study by XPS and ToF-SIMS
journal, June 2009

Photoelectron spectroscopy under ambient pressure and temperature conditions
journal, March 2009

Infrared Study of the Kinetics and Mechanism of Adsorption of Acrylic Polymers on Alumina Surfaces
journal, May 2004

Paint adhesion, corrosion protection, and interfacial chemistry
journal, October 1994

Acid-Base Interactions in Adhesion: The Characterization of Surfaces & Interfaces by XPS
journal, November 1992

Chemistry of the Metal-Polymer Interfacial Region
journal, September 1988

Preparation and Characterization of Mesoporous Zirconia Made by Using a Poly (methyl methacrylate) Template
journal, February 2008

In Situ Study of Buried Metal–Polymer Interfaces Exposed to an Aqueous Solution by an Integrated ATR-FTIR and Electrochemical Impedance Spectroscopy System
journal, September 2013

Adsorption of PMMA on Oxidized Al and Si Substrates: An Investigation by High-Resolution X-ray Photoelectron Spectroscopy
journal, March 2000

Molecular Interactions of Electroadsorbed Carboxylic Acid and Succinic Anhydride Monomers on Zinc Surfaces
journal, August 2011

Degradation of Interfacial Chemistry of Epoxy/Silane/Aluminium Interfaces as a Result of Aqueous Attack
journal, September 2005

The existence of quasi-two-dimensional glass-like structures at strongly interacting polymer-solid interfaces
journal, September 1991

In situ study of poly(methyl methacrylate) adsorption from solution onto chemically modified Si(100) surfaces by internal reflection infrared spectroscopy
journal, July 1993

In Situ Study of Buried Interfacial Bonding Mechanisms of Carboxylic Polymers on Zn Surfaces
journal, February 2013

Ageing of aluminium oxide surfaces and their subsequent reactivity towards bonding with organic functional groups
journal, August 2004

Robust, Functionalizable, Nanometer-Thick Poly(acrylic acid) Films Spontaneously Assembled on Oxidized Aluminum Substrates: Structures and Chemical Properties
journal, April 2011

Problems and progress in organic coatings science and technology
journal, May 1997

A combined Fourier transform infra-red multiple specular reflectance and inelastic electron tunnelling spectroscopy study of poly(methyl methacrylate) on oxidized aluminium
journal, January 1991

The use of XPS to examine the interaction of poly(acrylic acid) with oxidised metal substrates
journal, July 1997

Quantitative chemical composition of thin films with infrared spectroscopic ellipsometry: application to hydrated oxide films on aluminium
journal, January 2003

A comparison of the interfacial bonding properties of carboxylic acid functional groups on zinc and iron substrates
journal, January 2011

Influence of the Iron Oxide Acid−Base Properties on the Chemisorption of Model Epoxy Compounds Studied by XPS
journal, September 2007

The nature of the surface acidity of anodised titanium: an XPS study using 1,2-diaminoethane
journal, August 1996

Glassy relaxation at polymer-solid interfaces
journal, April 1992

Chemisorption of monocarboxylic acids on alumina: A tunneling spectroscopy study
journal, October 1978

Interaction of Anhydride and Carboxylic Acid Compounds with Aluminum Oxide Surfaces Studied Using Infrared Reflection Absorption Spectroscopy
journal, July 2004

Interaction of epoxy model molecules with aluminium, anodised titanium and copper surfaces: an XPS study
journal, August 1998

The reactions of oxidised aluminium surfaces with lubricant additives and related compounds
journal, October 1991

Investigation of solid/vapor interfaces using ambient pressure X-ray photoelectron spectroscopy
journal, January 2013

Changes in epoxy-coated aluminium due to exposure to water
journal, December 2004

ADHESION AND DE-ADHESION MECHANISMS AT POLYMER/METAL INTERFACES: Mechanistic Understanding Based on In Situ Studies of Buried Interfaces
journal, August 2005

Influence of pretreatments and aging on the adhesion performance of epoxy-coated aluminum
journal, January 2013

A molecular orbital study of the interactions of acrylic polymers with aluminum: Implications for adhesion
journal, November 1990

Molecular Bonding and Adhesion at Polymer-Metal Interphases
journal, September 1994

Interaction of carboxylic acids with the oxyhydroxide surface of aluminium: poly(acrylic acid), acetic acid and propionic acid on pseudoboehmite
journal, December 2001

Orthogonal Self-Assembled Monolayers: Alkanethiols on Gold and Alkane Carboxylic Acids on Alumina
journal, August 1989

XPS studies of metal/polymer interfaces — Thin films of Al on polyacrylic acid and polyethylene
journal, November 1986

High-resolution monochromated XPS of poly(methyl methacrylate) thin films on a conducting substrate
journal, February 1991

Spontaneously organized molecular assemblies. 2. Quantitative infrared spectroscopic determination of equilibrium structures of solution-adsorbed n-alkanoic acids on an oxidized aluminum surface
journal, January 1985

Role of acid-base interfacial bonding in adhesion
journal, January 1987

Segment level chemistry and chain conformation in the reactive adsorption of poly(methyl methacrylate) on aluminum oxide surfaces
journal, May 1992

Interfacial chemistry of adhesives on hydrated aluminium and hydrated aluminium treated with an organosilane
journal, January 2004

Interfacial interactions of plasma-polymerized acrylic acid and an oxidized aluminium surface investigated using XPS, FTIR and poly(acrylic acid) as a model compound
journal, December 1998

XPS investigations of acid-base interactions in adhesion. Part 3. Evidence for orientation of carbonyl groups from poly(methylmethacrylate) (PMMA) at the PMMA-glass and PMMA-SiO2 interfaces
journal, November 1993

Transport processes of hydrated ions at polymer/oxide/metal interfaces
journal, January 2009

Bonding Mechanisms at Buried Interfaces between Carboxylic Polymers and Treated Zinc Surfaces
journal, January 2013

In Situ Characterization of the Initial Effect of Water on Molecular Interactions at the Interface of Organic/Inorganic Hybrid Systems
journal, March 2017

The characterisation of the interfacial chemistry of adhesion of rigid polyurethane foam to aluminium
journal, August 2011

Surface oxide development on aluminum alloy 6063 during heat treatment
journal, February 2019

Probing the formation and degradation of chemical interactions from model molecule/metal oxide to buried polymer/metal oxide interfaces
journal, June 2019

3D printing multifunctional fluorinated nanocomposites: tuning electroactivity, rheology and chemical reactivity
journal, January 2018