Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater
Abstract
Amidoxime-functionalized polymeric adsorbents are the current state-of-the-art materials for collecting uranium (U) from seawater. However, marine tests show that vanadium (V) is preferentially extracted over U and many other cations. Here in this paper, we report a complementary and comprehensive investigation integrating ab initio simulations with thermochemical titrations and XAFS spectroscopy to understand the unusually strong and selective binding of V by polyamidoximes. While the open-chain amidoxime functionalities do not bind V, the cyclic imide-dioxime group of the adsorbent forms a peculiar non-oxido V5+ complex, exhibiting the highest stability constant value ever observed for the V5+ species. XAFS analysis of adsorbents following deployment in environmental seawater confirms V binding solely by the imide-dioximes. Our fundamental findings offer not only guidance for future optimization of selectivity in amidoxime-based sorbent materials, but may also afford insight to understanding the extensive accumulation of V in some marine organisms.
- Authors:
-
[1];
[3];
[1];
[1];
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); US Nuclear Regulatory Commission, Rockville, MD (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1419451
- Alternate Identifier(s):
- OSTI ID: 1423083
- Grant/Contract Number:
- AC02-05CH11231; AC02-06CH11357; AC02-76SF00515; AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Thermodynamics; Soft materials; Polymer chemistry
Citation Formats
Ivanov, Alexander S., Leggett, Christina J., Parker, Bernard F., Zhang, Zhicheng, Arnold, John, Dai, Sheng, Abney, Carter W., Bryantsev, Vyacheslav S., and Rao, Linfeng. Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater. United States: N. p., 2017.
Web. doi:10.1038/s41467-017-01443-1.
Ivanov, Alexander S., Leggett, Christina J., Parker, Bernard F., Zhang, Zhicheng, Arnold, John, Dai, Sheng, Abney, Carter W., Bryantsev, Vyacheslav S., & Rao, Linfeng. Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater. United States. https://doi.org/10.1038/s41467-017-01443-1
Ivanov, Alexander S., Leggett, Christina J., Parker, Bernard F., Zhang, Zhicheng, Arnold, John, Dai, Sheng, Abney, Carter W., Bryantsev, Vyacheslav S., and Rao, Linfeng. Thu .
"Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater". United States. https://doi.org/10.1038/s41467-017-01443-1. https://www.osti.gov/servlets/purl/1419451.
@article{osti_1419451,
title = {Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater},
author = {Ivanov, Alexander S. and Leggett, Christina J. and Parker, Bernard F. and Zhang, Zhicheng and Arnold, John and Dai, Sheng and Abney, Carter W. and Bryantsev, Vyacheslav S. and Rao, Linfeng},
abstractNote = {Amidoxime-functionalized polymeric adsorbents are the current state-of-the-art materials for collecting uranium (U) from seawater. However, marine tests show that vanadium (V) is preferentially extracted over U and many other cations. Here in this paper, we report a complementary and comprehensive investigation integrating ab initio simulations with thermochemical titrations and XAFS spectroscopy to understand the unusually strong and selective binding of V by polyamidoximes. While the open-chain amidoxime functionalities do not bind V, the cyclic imide-dioxime group of the adsorbent forms a peculiar non-oxido V5+ complex, exhibiting the highest stability constant value ever observed for the V5+ species. XAFS analysis of adsorbents following deployment in environmental seawater confirms V binding solely by the imide-dioximes. Our fundamental findings offer not only guidance for future optimization of selectivity in amidoxime-based sorbent materials, but may also afford insight to understanding the extensive accumulation of V in some marine organisms.},
doi = {10.1038/s41467-017-01443-1},
journal = {Nature Communications},
number = 1,
volume = 8,
place = {United States},
year = {2017},
month = {11}
}
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Works referenced in this record:
Elution of Uranium and Transition Metals from Amidoxime-Based Polymer Adsorbents for Sequestering Uranium from Seawater
journal, December 2015
- Pan, Horng-Bin; Kuo, Li-Jung; Wai, Chien M.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Vanadium speciation and cycling in coastal waters
journal, December 2009
- Wang, Deli; Sañudo Wilhelmy, Sergio A.
- Marine Chemistry, Vol. 117, Issue 1-4
Seven chemical separations to change the world
journal, April 2016
- Sholl, David S.; Lively, Ryan P.
- Nature, Vol. 532, Issue 7600
Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions
journal, May 2009
- Marenich, Aleksandr V.; Cramer, Christopher J.; Truhlar, Donald G.
- The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396
Pseudo-Jahn–Teller Effect—A Two-State Paradigm in Formation, Deformation, and Transformation of Molecular Systems and Solids
journal, January 2013
- Bersuker, Isaac B.
- Chemical Reviews, Vol. 113, Issue 3
The Chemistry and Biochemistry of Vanadium and the Biological Activities Exerted by Vanadium Compounds
journal, May 2004
- Crans, Debbie C.; Smee, Jason J.; Gaidamauskas, Ernestas
- ChemInform, Vol. 35, Issue 20
Parameter-free calculations of X-ray spectra with FEFF9
journal, January 2010
- Rehr, John J.; Kas, Joshua J.; Vila, Fernando D.
- Physical Chemistry Chemical Physics, Vol. 12, Issue 21
Theoretical Study of Oxovanadium(IV) Complexation with Formamidoximate: Implications for the Design of Uranyl-Selective Adsorbents
journal, December 2015
- Mehio, Nada; Ivanov, Alexander S.; Ladshaw, Austin P.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Extraction of Uranium from Sea Water
journal, September 1964
- Davies, R. V.; Kennedy, J.; McILROY, R. W.
- Nature, Vol. 203, Issue 4950
Vanadium (IV) and vanadium (V) complexes of deferoxamine B in aqueous solution
journal, October 1995
- Buglyó, Péter; Culeddu, Nicola; Kiss, Tamás
- Journal of Inorganic Biochemistry, Vol. 60, Issue 1
Complexation of glutarimidedioxime with Fe(iii), Cu(ii), Pb(ii), and Ni(ii), the competing ions for the sequestration of U(vi) from seawater
journal, January 2013
- Sun, Xiaoqi; Xu, Chao; Tian, Guoxin
- Dalton Transactions, Vol. 42, Issue 40
Solution Structure of Vanabin2, a Vanadium(IV)-Binding Protein from the Vanadium-Rich Ascidian Ascidia s ydneiensis samea
journal, March 2005
- Hamada, Toshiyuki; Asanuma, Miwako; Ueki, Tatsuya
- Journal of the American Chemical Society, Vol. 127, Issue 12
Amidoximes as ligand functionalities for braided polymeric materials for the recovery of uranium from seawater
journal, April 2016
- Lashley, Mark A.; Mehio, Nada; Nugent, Joseph W.
- Polyhedron, Vol. 109
Extracting Minerals from Seawater: An Energy Analysis
journal, April 2010
- Bardi, Ugo
- Sustainability, Vol. 2, Issue 4
Uranium recovery from seawater: development of fiber adsorbents prepared via atom-transfer radical polymerization
journal, January 2014
- Saito, Tomonori; Brown, Suree; Chatterjee, Sabornie
- J. Mater. Chem. A, Vol. 2, Issue 35
Novel poly(imide dioxime) sorbents: Development and testing for enhanced extraction of uranium from natural seawater
journal, August 2016
- Das, S.; Brown, S.; Mayes, R. T.
- Chemical Engineering Journal, Vol. 298
Development of Sorbers for the Recovery of Uranium from Seawater. Part 2. The Accumulation of Uranium from Seawater by Resins Containing Amidoxime and Imidoxime Functional Groups
journal, April 1983
- Astheimer, L.; Schenk, H. J.; Witte, E. G.
- Separation Science and Technology, Vol. 18, Issue 4
Highly selective extraction of the uranyl ion with hydrophobic amidoxime-functionalized ionic liquids via η2 coordination
journal, January 2012
- Barber, Patrick S.; Kelley, Steven P.; Rogers, Robin D.
- RSC Advances, Vol. 2, Issue 22
Formation of New Non-oxido Vanadium(IV) Species in Aqueous Solution and in the Solid State by Tridentate (O, N, O) Ligands and Rationalization of Their EPR Behavior
journal, June 2013
- Sanna, Daniele; Várnagy, Katalin; Lihi, Norbert
- Inorganic Chemistry, Vol. 52, Issue 14
Radiation-grafted copolymers for separation and purification purposes: Status, challenges and future directions
journal, December 2012
- Nasef, Mohamed Mahmoud; Güven, Olgun
- Progress in Polymer Science, Vol. 37, Issue 12
Highly selective extraction of the uranyl ion with hydrophobic amidoxime-functionalized ionic liquids via η2 coordination
journal, January 2012
- Barber, Patrick S.; Kelley, Steven P.; Rogers, Robin D.
- RSC Advances, Vol. 2, Issue 22
Solution Structure of Vanabin2, a Vanadium(IV)-Binding Protein from the Vanadium-Rich Ascidian Ascidia s ydneiensis samea
journal, March 2005
- Hamada, Toshiyuki; Asanuma, Miwako; Ueki, Tatsuya
- Journal of the American Chemical Society, Vol. 127, Issue 12
Radiation-grafted copolymers for separation and purification purposes: Status, challenges and future directions
journal, December 2012
- Nasef, Mohamed Mahmoud; Güven, Olgun
- Progress in Polymer Science, Vol. 37, Issue 12
Formation of New Non-oxido Vanadium(IV) Species in Aqueous Solution and in the Solid State by Tridentate (O, N, O) Ligands and Rationalization of Their EPR Behavior
journal, June 2013
- Sanna, Daniele; Várnagy, Katalin; Lihi, Norbert
- Inorganic Chemistry, Vol. 52, Issue 14
A protein engineered to bind uranyl selectively and with femtomolar affinity
journal, January 2014
- Zhou, Lu; Bosscher, Mike; Zhang, Changsheng
- Nature Chemistry, Vol. 6, Issue 3
The Uranium from Seawater Program at the Pacific Northwest National Laboratory: Overview of Marine Testing, Adsorbent Characterization, Adsorbent Durability, Adsorbent Toxicity, and Deployment Studies
journal, December 2015
- Gill, Gary A.; Kuo, Li-Jung; Janke, Chris J.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Molecular biological approaches to the accumulation and reduction of vanadium by ascidians
journal, February 2003
- Michibata, H.
- Coordination Chemistry Reviews, Vol. 237, Issue 1-2
The extraction of uranium from seawater by poly(amidoxime)/poly(hydroxamic acid) resins and fibre
journal, October 1983
- Vernon, F.; Shah, T.
- Reactive Polymers, Ion Exchangers, Sorbents, Vol. 1, Issue 4
Hyperquad simulation and speciation (HySS): a utility program for the investigation of equilibria involving soluble and partially soluble species
journal, April 1999
- Alderighi, Lucia; Gans, Peter; Ienco, Andrea
- Coordination Chemistry Reviews, Vol. 184, Issue 1
Extracting Minerals from Seawater: An Energy Analysis
journal, April 2010
- Bardi, Ugo
- Sustainability, Vol. 2, Issue 4
Solvation of the vanadate ion in seawater conditions from molecular dynamics simulations
journal, March 2017
- Priest, Chad; Zhou, Jingwei; Jiang, De-en
- Inorganica Chimica Acta, Vol. 458
Alternative Alkaline Conditioning of Amidoxime Based Adsorbent for Uranium Extraction from Seawater
journal, October 2015
- Das, S.; Liao, W. -P.; Flicker Byers, M.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Theoretical study of the coordination behavior of formate and formamidoximate with dioxovanadium( v ) cation: implications for selectivity towards uranyl
journal, January 2015
- Mehio, Nada; Johnson, J. Casey; Dai, Sheng
- Physical Chemistry Chemical Physics, Vol. 17, Issue 47
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
Vanadium(V) Compounds with the Bis-(hydroxylamino)-1,3,5-triazine Ligand, H 2 bihyat: Synthetic, Structural, and Physical Studies of [V 2 V O 3 (bihyat) 2 ] and of the Enhanced Hydrolytic Stability Species cis -[V V O 2 (bihyat)] −
journal, December 2008
- Nikolakis, Vladimiros A.; Tsalavoutis, John T.; Stylianou, Marios
- Inorganic Chemistry, Vol. 47, Issue 24
Vanadium speciation and cycling in coastal waters
journal, December 2009
- Wang, Deli; Sañudo Wilhelmy, Sergio A.
- Marine Chemistry, Vol. 117, Issue 1-4
Catalytic isomerization of glucose to fructose over organic ligands: a DFT study
journal, December 2022
- Yu, Tao; Feng, Dexin; Zhou, Jiancheng
- Journal of Molecular Modeling, Vol. 29, Issue 1
Sequestering uranium from seawater: binding strength and modes of uranyl complexes with glutarimidedioxime
journal, January 2012
- Tian, Guoxin; Teat, Simon J.; Zhang, Zhiyong
- Dalton Transactions, Vol. 41, Issue 38
Thermodynamic studies of U(vi) complexation with glutardiamidoxime for sequestration of uranium from seawater
journal, January 2013
- Tian, Guoxin; Teat, Simon J.; Rao, Linfeng
- Dalton Transactions, Vol. 42, Issue 16
A half-wave rectified alternating current electrochemical method for uranium extraction from seawater
journal, February 2017
- Liu, Chong; Hsu, Po-Chun; Xie, Jin
- Nature Energy, Vol. 2, Issue 4
Complexation of glutarimidedioxime with Fe(iii), Cu(ii), Pb(ii), and Ni(ii), the competing ions for the sequestration of U(vi) from seawater
journal, January 2013
- Sun, Xiaoqi; Xu, Chao; Tian, Guoxin
- Dalton Transactions, Vol. 42, Issue 40
Nanostructured Composites: A High Capacity, Fast Rate Li3V2(PO4)3/Carbon Cathode for Rechargeable Lithium Batteries
journal, November 2002
- Huang, H.; Yin, S. -C.; Kerr, T.
- Advanced Materials, Vol. 14, Issue 21
Vanadium (IV) and vanadium (V) complexes of deferoxamine B in aqueous solution
journal, October 1995
- Buglyó, Péter; Culeddu, Nicola; Kiss, Tamás
- Journal of Inorganic Biochemistry, Vol. 60, Issue 1
Charge-Dependent Cavity Radii for an Accurate Dielectric Continuum Model of Solvation with Emphasis on Ions: Aqueous Solutes with Oxo, Hydroxo, Amino, Methyl, Chloro, Bromo, and Fluoro Functionalities
journal, October 2008
- Ginovska, Bojana; Camaioni, Donald M.; Dupuis, Michel
- The Journal of Physical Chemistry A, Vol. 112, Issue 42
Pseudo-Jahn–Teller Effect—A Two-State Paradigm in Formation, Deformation, and Transformation of Molecular Systems and Solids
journal, January 2013
- Bersuker, Isaac B.
- Chemical Reviews, Vol. 113, Issue 3
Extracting Uranium from Seawater: Promising AI Series Adsorbents
journal, November 2015
- Das, S.; Oyola, Y.; Mayes, R. T.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Nanostructured Composites: A High Capacity, Fast Rate Li3V2(PO4)3/Carbon Cathode for Rechargeable Lithium Batteries.
journal, January 2003
- Huang, Huan; Yin, Shieh-Chieh; Kerr, Tracy
- ChemInform, Vol. 34, Issue 3
The extraction of uranium from seawater by poly(amidoxime)/poly(hydroxamic acid) resins and fibre
journal, October 1983
- Vernon, F.; Shah, T.
- Reactive Polymers, Ion Exchangers, Sorbents, Vol. 1, Issue 4
Novel poly(imide dioxime) sorbents: Development and testing for enhanced extraction of uranium from natural seawater
journal, August 2016
- Das, S.; Brown, S.; Mayes, R. T.
- Chemical Engineering Journal, Vol. 298
The Uranium from Seawater Program at the Pacific Northwest National Laboratory: Overview of Marine Testing, Adsorbent Characterization, Adsorbent Durability, Adsorbent Toxicity, and Deployment Studies
journal, December 2015
- Gill, Gary A.; Kuo, Li-Jung; Janke, Chris J.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Development of Sorbers for the Recovery of Uranium from Seawater. Part 2. The Accumulation of Uranium from Seawater by Resins Containing Amidoxime and Imidoxime Functional Groups
journal, April 1983
- Astheimer, L.; Schenk, H. J.; Witte, E. G.
- Separation Science and Technology, Vol. 18, Issue 4
Assessing ligand selectivity for uranium over vanadium ions to aid in the discovery of superior adsorbents for extraction of UO 2 2+ from seawater
journal, January 2016
- Ivanov, Alexander S.; Bryantsev, Vyacheslav S.
- Dalton Transactions, Vol. 45, Issue 26
Solvation of the vanadate ion in seawater conditions from molecular dynamics simulations
journal, March 2017
- Priest, Chad; Zhou, Jingwei; Jiang, De-en
- Inorganica Chimica Acta, Vol. 458
Amidoximes as ligand functionalities for braided polymeric materials for the recovery of uranium from seawater
journal, April 2016
- Lashley, Mark A.; Mehio, Nada; Nugent, Joseph W.
- Polyhedron, Vol. 109
The Chemistry and Biochemistry of Vanadium and the Biological Activities Exerted by Vanadium Compounds
journal, February 2004
- Crans, Debbie C.; Smee, Jason J.; Gaidamauskas, Ernestas
- Chemical Reviews, Vol. 104, Issue 2
Charge-Dependent Cavity Radii for an Accurate Dielectric Continuum Model of Solvation with Emphasis on Ions: Aqueous Solutes with Oxo, Hydroxo, Amino, Methyl, Chloro, Bromo, and Fluoro Functionalities
journal, October 2008
- Ginovska, Bojana; Camaioni, Donald M.; Dupuis, Michel
- The Journal of Physical Chemistry A, Vol. 112, Issue 42
Extracting Uranium from Seawater: Promising AF Series Adsorbents
journal, November 2015
- Das, S.; Oyola, Y.; Mayes, Richard T.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Extracting Uranium from Seawater: Promising AI Series Adsorbents
journal, November 2015
- Das, S.; Oyola, Y.; Mayes, R. T.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Extraction of Uranium from Sea Water
journal, September 1964
- Davies, R. V.; Kennedy, J.; McILROY, R. W.
- Nature, Vol. 203, Issue 4950
A report on emergent uranyl binding phenomena by an amidoxime phosphonic acid co-polymer
journal, January 2016
- Abney, C. W.; Das, S.; Mayes, R. T.
- Physical Chemistry Chemical Physics, Vol. 18, Issue 34
XAFS investigation of polyamidoxime-bound uranyl contests the paradigm from small molecule studies
journal, January 2016
- Abney, C. W.; Mayes, R. T.; Piechowicz, M.
- Energy & Environmental Science, Vol. 9, Issue 2
Theoretical Study of Oxovanadium(IV) Complexation with Formamidoximate: Implications for the Design of Uranyl-Selective Adsorbents
journal, December 2015
- Mehio, Nada; Ivanov, Alexander S.; Ladshaw, Austin P.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
A protein engineered to bind uranyl selectively and with femtomolar affinity
journal, January 2014
- Zhou, Lu; Bosscher, Mike; Zhang, Changsheng
- Nature Chemistry, Vol. 6, Issue 3
Preparation of hydrophilic amidoxime fibers by cografting acrylonitrile and methacrylic acid from an optimized monomer composition
journal, October 2000
- Kawai, Tomomi; Saito, Kyoichi; Sugita, Kazuyuki
- Radiation Physics and Chemistry, Vol. 59, Issue 4, p. 405-411
The Chemistry and Biochemistry of Vanadium and the Biological Activities Exerted by Vanadium Compounds
journal, May 2004
- Crans, Debbie C.; Smee, Jason J.; Gaidamauskas, Ernestas
- ChemInform, Vol. 35, Issue 20
Thermodynamic studies of U(vi) complexation with glutardiamidoxime for sequestration of uranium from seawater
journal, January 2013
- Tian, Guoxin; Teat, Simon J.; Rao, Linfeng
- Dalton Transactions, Vol. 42, Issue 16
Parameter-free calculations of X-ray spectra with FEFF9
journal, January 2010
- Rehr, John J.; Kas, Joshua J.; Vila, Fernando D.
- Physical Chemistry Chemical Physics, Vol. 12, Issue 21
A half-wave rectified alternating current electrochemical method for uranium extraction from seawater
journal, February 2017
- Liu, Chong; Hsu, Po-Chun; Xie, Jin
- Nature Energy, Vol. 2, Issue 4
Works referencing / citing this record:
3D hierarchical porous amidoxime fibers speed up uranium extraction from seawater
journal, January 2019
- Xu, Xiao; Zhang, Hongjun; Ao, Junxuan
- Energy & Environmental Science, Vol. 12, Issue 6
Siderophore-inspired chelator hijacks uranium from aqueous medium
journal, February 2019
- Ivanov, Alexander S.; Parker, Bernard F.; Zhang, Zhicheng
- Nature Communications, Vol. 10, Issue 1
Ultrafast and Highly Selective Uranium Extraction from Seawater by Hydrogel‐like Spidroin‐based Protein Fiber
journal, July 2019
- Yuan, Yihui; Yu, Qiuhan; Wen, Jun
- Angewandte Chemie, Vol. 131, Issue 34
Interactions of vanadium( iv ) with amidoxime ligands: redox reactivity
journal, January 2018
- Parker, B. F.; Hohloch, S.; Pankhurst, J. R.
- Dalton Transactions, Vol. 47, Issue 16
Highly fluorescent conjugated microporous polymers for concurrent adsorption and detection of uranium
journal, January 2019
- Xu, Meiyun; Wang, Tao; Gao, Peng
- Journal of Materials Chemistry A, Vol. 7, Issue 18
Ultrafast and Highly Selective Uranium Extraction from Seawater by Hydrogel-like Spidroin-based Protein Fiber
journal, July 2019
- Yuan, Yihui; Yu, Qiuhan; Wen, Jun
- Angewandte Chemie International Edition, Vol. 58, Issue 34
Polypropylene nonwoven fabric modified with oxime and guanidine for antibiofouling and highly selective uranium recovery from seawater
journal, May 2019
- Yang, Sen; Ji, Guoxun; Cai, Suya
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 321, Issue 1
Complexation-assisted reduction: complexes of glutaroimide-dioxime with tetravalent actinides (Np( iv ) and Th( iv ))
journal, January 2018
- Zhang, Zhicheng; Parker, Bernard F.; Lohrey, Trevor D.
- Dalton Transactions, Vol. 47, Issue 24
Significantly Enhanced Uranium Extraction from Seawater with Mass Produced Fully Amidoximated Nanofiber Adsorbent
journal, October 2018
- Wang, Dong; Song, Jianan; Wen, Jun
- Advanced Energy Materials, Vol. 8, Issue 33
A Marine‐Inspired Hybrid Sponge for Highly Efficient Uranium Extraction from Seawater
journal, May 2019
- Wang, Dong; Song, Jianan; Lin, Sen
- Advanced Functional Materials, Vol. 29, Issue 32
Siderophore-inspired chelator hijacks uranium from aqueous medium
journal, February 2019
- Ivanov, Alexander S.; Parker, Bernard F.; Zhang, Zhicheng
- Nature Communications, Vol. 10, Issue 1
A Bio‐inspired Nano‐pocket Spatial Structure for Targeting Uranyl Capture
journal, March 2020
- Yuan, Yihui; Feng, Shiwei; Feng, Lijuan
- Angewandte Chemie, Vol. 132, Issue 11
A Bio‐inspired Nano‐pocket Spatial Structure for Targeting Uranyl Capture
journal, January 2020
- Yuan, Yihui; Feng, Shiwei; Feng, Lijuan
- Angewandte Chemie International Edition, Vol. 59, Issue 11
An Ion‐Crosslinked Supramolecular Hydrogel for Ultrahigh and Fast Uranium Recovery from Seawater
journal, January 2020
- Yan, Bingjie; Ma, Chunxin; Gao, Jinxiang
- Advanced Materials, Vol. 32, Issue 10
Photoinduced Multiple Effects to Enhance Uranium Extraction from Natural Seawater by Black Phosphorus Nanosheets
journal, November 2019
- Yuan, Yihui; Niu, Biye; Yu, Qiuhan
- Angewandte Chemie, Vol. 132, Issue 3
Amidoxime-Functionalized Macroporous Carbon Self-Refreshed Electrode Materials for Rapid and High-Capacity Removal of Heavy Metal from Water
journal, March 2019
- Wu, Tong; Liu, Chong; Kong, Biao
- ACS Central Science, Vol. 5, Issue 4
A Molecular Coordination Template Strategy for Designing Selective Porous Aromatic Framework Materials for Uranyl Capture
journal, July 2019
- Yuan, Ye; Meng, Qinghao; Faheem, Muhammad
- ACS Central Science, Vol. 5, Issue 8
The role of mid-gap states in all-inorganic CsPbBr 3 nanoparticle one photon up-conversion
journal, January 2018
- Roman, Benjamin J.; Sheldon, Matthew
- Chemical Communications, Vol. 54, Issue 50
Predicting Stability Constants for Terbium(III) Complexes with Dipicolinic Acid and 4-Substituted Dipicolinic Acid Analogues using Density Functional Theory
journal, November 2019
- Chen, Hsieh; Shi, Rena; Ow, Hooisweng
- ACS Omega, Vol. 4, Issue 24
Photoinduced Multiple Effects to Enhance Uranium Extraction from Natural Seawater by Black Phosphorus Nanosheets
journal, December 2019
- Yuan, Yihui; Niu, Biye; Yu, Qiuhan
- Angewandte Chemie International Edition, Vol. 59, Issue 3
Rational Design of Porous Nanofiber Adsorbent by Blow-Spinning with Ultrahigh Uranium Recovery Capacity from Seawater
journal, November 2018
- Yuan, Yihui; Zhao, Shilei; Wen, Jun
- Advanced Functional Materials, Vol. 29, Issue 2
A highly efficient uranium grabber derived from acrylic fiber for extracting uranium from seawater
journal, January 2020
- Pan, Horng-Bin; Wai, Chien M.; Kuo, Li-Jung
- Dalton Transactions, Vol. 49, Issue 9