Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode
Abstract
Defects are important features in two-dimensional (2D) materials that have a strong influence on their chemical and physical properties. Through the enhanced chemical reactivity at defect sites (point defects, line defects, etc.), one can selectively functionalize 2D materials via chemical reactions and thereby tune their physical properties. We demonstrate the selective atomic layer deposition of LiF on defect sites of h-BN prepared by chemical vapor deposition. The LiF deposits primarily on the line and point defects of h-BN, thereby creating seams that hold the h-BN crystallites together. The chemically and mechanically stable hybrid LiF/h-BN film successfully suppresses lithium dendrite formation during both the initial electrochemical deposition onto a copper foil and the subsequent cycling. In conclusion, the protected lithium electrodes exhibit good cycling behavior with more than 300 cycles at relatively high coulombic efficiency (>95%) in an additive-free carbonate electrolyte.
- Authors:
-
- Stanford Univ., Stanford, CA (United States)
- Bosch Research and Technology Center North America, Palo Alto, CA (United States)
- Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1419315
- Grant/Contract Number:
- award338316; Battery Materials Research (BMR) & Battery 500 Consortium program; award338315; (BERN) Grant No. 03.25.SS.15; AC02-76SF00515
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Science Advances
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 11; Journal ID: ISSN 2375-2548
- Publisher:
- AAAS
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Xie, Jin, Liao, Lei, Gong, Yongji, Li, Yanbin, Shi, Feifei, Pei, Allen, Sun, Jie, Zhang, Rufan, Kong, Biao, Subbaraman, Ram, Christensen, Jake, and Cui, Yi. Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode. United States: N. p., 2017.
Web. doi:10.1126/sciadv.aao3170.
Xie, Jin, Liao, Lei, Gong, Yongji, Li, Yanbin, Shi, Feifei, Pei, Allen, Sun, Jie, Zhang, Rufan, Kong, Biao, Subbaraman, Ram, Christensen, Jake, & Cui, Yi. Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode. United States. https://doi.org/10.1126/sciadv.aao3170
Xie, Jin, Liao, Lei, Gong, Yongji, Li, Yanbin, Shi, Feifei, Pei, Allen, Sun, Jie, Zhang, Rufan, Kong, Biao, Subbaraman, Ram, Christensen, Jake, and Cui, Yi. Wed .
"Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode". United States. https://doi.org/10.1126/sciadv.aao3170. https://www.osti.gov/servlets/purl/1419315.
@article{osti_1419315,
title = {Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode},
author = {Xie, Jin and Liao, Lei and Gong, Yongji and Li, Yanbin and Shi, Feifei and Pei, Allen and Sun, Jie and Zhang, Rufan and Kong, Biao and Subbaraman, Ram and Christensen, Jake and Cui, Yi},
abstractNote = {Defects are important features in two-dimensional (2D) materials that have a strong influence on their chemical and physical properties. Through the enhanced chemical reactivity at defect sites (point defects, line defects, etc.), one can selectively functionalize 2D materials via chemical reactions and thereby tune their physical properties. We demonstrate the selective atomic layer deposition of LiF on defect sites of h-BN prepared by chemical vapor deposition. The LiF deposits primarily on the line and point defects of h-BN, thereby creating seams that hold the h-BN crystallites together. The chemically and mechanically stable hybrid LiF/h-BN film successfully suppresses lithium dendrite formation during both the initial electrochemical deposition onto a copper foil and the subsequent cycling. In conclusion, the protected lithium electrodes exhibit good cycling behavior with more than 300 cycles at relatively high coulombic efficiency (>95%) in an additive-free carbonate electrolyte.},
doi = {10.1126/sciadv.aao3170},
journal = {Science Advances},
number = 11,
volume = 3,
place = {United States},
year = {Wed Nov 29 00:00:00 EST 2017},
month = {Wed Nov 29 00:00:00 EST 2017}
}
Web of Science
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Engineering stable interfaces for three-dimensional lithium metal anodes
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An Investigation on the Relationship between the Stability of Lithium Anode and Lithium Nitrate in Electrolyte
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Discontinuous evolution of the structure of stretching polycrystalline graphene
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Engineering stable interfaces for three-dimensional lithium metal anodes
journal, July 2018
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An ultrastable lithium metal anode enabled by designed metal fluoride spansules
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