Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join

Marcial, José; Kabel, Joey; Saleh, Muad; Washton, Nancy; Shaharyar, Yaqoot; Goel, Ashutosh; McCloy, John S.

doi:10.1111/jace.15439

Title: Structural dependence of crystallization in glasses along the nepheline (NaAlSiO ₄ ) ‐ eucryptite (LiAlSiO ₄ ) join

Abstract

Abstract Lithium and sodium aluminosilicates are important glass‐forming systems for commercial glass‐ceramics, as well as being important model systems for ion transport in battery studies. In addition, uncontrolled crystallization of LiAlSiO ₄ (eucryptite) in high‐Li ₂ O compositions, analogous to the more well‐known problem of NaAlSiO ₄ (nepheline) crystallization, can cause concerns for long‐term chemical durability in nuclear waste glasses. To study the relationships between glass structure and crystallization, nine glasses were synthesized in the Li _x Na _1‐ _x AlSiO ₄ series, from x = 0 to x = 1. Raman spectra, nuclear magnetic resonance ( NMR ) spectroscopy (Li‐7, Na‐23, Al‐27, Si‐29), and X‐ray diffraction were used to study the quenched and heat‐treated glasses. It was found that different LiAlSiO ₄ and NaAlSiO ₄ crystal phases crystallize from the glass depending on the Li/Na ratio. Raman and NMR spectra of quenched glasses suggest similar structures regardless of alkali substitution. Li‐7 and Na‐23 NMR spectra of the glass‐ceramics near the endmember compositions show evidence of several differentiable sites distinct from known Li _x Na _1‐ _x AlSiO ₄ crystalline phases, suggesting that these measurements can reveal subtle chemical environment differences inmore »« less

Authors:

^[1]; Kabel, Joey ^[2]; Saleh, Muad ^[1]; Washton, Nancy ^[3]; Shaharyar, Yaqoot ^[4];

^[4];

^[5]

Materials Science and Engineering Program Washington State University Pullman Washington
School of Mechanical &, Materials Engineering Washington State University Pullman Washington
Pacific Northwest National Laboratory Richland Washington
Department of Materials Science and Engineering Rutgers‐The State University of New Jersey Piscataway New Jersey
Materials Science and Engineering Program Washington State University Pullman Washington, School of Mechanical &, Materials Engineering Washington State University Pullman Washington, Pacific Northwest National Laboratory Richland Washington

Publication Date:: Thu Feb 01 00:00:00 EST 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1419091

Grant/Contract Number:: DE‐AC05‐76RL01830

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of the American Ceramic Society

Additional Journal Information:: Journal Name: Journal of the American Ceramic Society Journal Volume: 101 Journal Issue: 7; Journal ID: ISSN 0002-7820

Publisher:: Wiley-Blackwell

Country of Publication:: United States

Language:: English

Citation Formats


                    Marcial, José, Kabel, Joey, Saleh, Muad, Washton, Nancy, Shaharyar, Yaqoot, Goel, Ashutosh, and McCloy, John S. Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join.  United States: N. p., 2018. 
Web.  doi:10.1111/jace.15439.

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                    Marcial, José, Kabel, Joey, Saleh, Muad, Washton, Nancy, Shaharyar, Yaqoot, Goel, Ashutosh, & McCloy, John S. Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join.  United States.  https://doi.org/10.1111/jace.15439

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                    Marcial, José, Kabel, Joey, Saleh, Muad, Washton, Nancy, Shaharyar, Yaqoot, Goel, Ashutosh, and McCloy, John S. Thu .  
"Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join".  United States.  https://doi.org/10.1111/jace.15439.

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@article{osti_1419091,

  title        = {Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join},

  author       = {Marcial, José and Kabel, Joey and Saleh, Muad and Washton, Nancy and Shaharyar, Yaqoot and Goel, Ashutosh and McCloy, John S.},

  abstractNote = {Abstract Lithium and sodium aluminosilicates are important glass‐forming systems for commercial glass‐ceramics, as well as being important model systems for ion transport in battery studies. In addition, uncontrolled crystallization of LiAlSiO 4 (eucryptite) in high‐Li 2 O compositions, analogous to the more well‐known problem of NaAlSiO 4 (nepheline) crystallization, can cause concerns for long‐term chemical durability in nuclear waste glasses. To study the relationships between glass structure and crystallization, nine glasses were synthesized in the Li x Na 1‐ x AlSiO 4 series, from x = 0 to x = 1. Raman spectra, nuclear magnetic resonance ( NMR ) spectroscopy (Li‐7, Na‐23, Al‐27, Si‐29), and X‐ray diffraction were used to study the quenched and heat‐treated glasses. It was found that different LiAlSiO 4 and NaAlSiO 4 crystal phases crystallize from the glass depending on the Li/Na ratio. Raman and NMR spectra of quenched glasses suggest similar structures regardless of alkali substitution. Li‐7 and Na‐23 NMR spectra of the glass‐ceramics near the endmember compositions show evidence of several differentiable sites distinct from known Li x Na 1‐ x AlSiO 4 crystalline phases, suggesting that these measurements can reveal subtle chemical environment differences in mixed‐alkali systems, similar to what has been observed for zeolites.},

  doi          = {10.1111/jace.15439},

  journal      = {Journal of the American Ceramic Society},

  number       = 7,

  volume       = 101,

  place        = {United States},

  year         = {Thu Feb 01 00:00:00 EST 2018},

  month        = {Thu Feb 01 00:00:00 EST 2018}

}

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Works referenced in this record:

Nepheline crystallization in boron-rich alumino-silicate glasses as investigated by multi-nuclear NMR, Raman, & Mössbauer spectroscopies
journal, February 2015

McCloy, John; Washton, Nancy; Gassman, Paul
Journal of Non-Crystalline Solids, Vol. 409
DOI: 10.1016/j.jnoncrysol.2014.11.013

Solid-state nuclear magnetic resonance investigation of cation siting in LiNaLSX zeolites
journal, December 1998

Feuerstein, M.; Engelhardt, G.; McDaniel, P. L.
Microporous and Mesoporous Materials, Vol. 26, Issue 1-3
DOI: 10.1016/S1387-1811(98)00211-X

Phase Equilibria in the System Lithium Metasilicate-beta-Eucryptite
journal, January 1954

Krishna Murthy, M.; Hummel, F. A.
Journal of the American Ceramic Society, Vol. 37, Issue 1
DOI: 10.1111/j.1151-2916.1954.tb13971.x

High-resolution 23Na, 27Al and 29Si NMR spectroscopy of framework Aluminosilicate glasses
journal, August 1987

Oestrike, Richard; Yang, Wang-hong; Kirkpatrick, R. James
Geochimica et Cosmochimica Acta, Vol. 51, Issue 8
DOI: 10.1016/0016-7037(87)90269-9

Glass-Ceramics by Photosensitive Processes
journal, August 2015

Borrelli, Nicholas F.
International Journal of Applied Glass Science, Vol. 6, Issue 3
DOI: 10.1111/ijag.12130

Cristobalite-Related Phases in the NaAlO2–NaAlSiO4 System. II. A Commensurately Modulated Cubic Structure
journal, October 1998

Withers, R. L.; Thompson, J. G.; Melnitchenko, A.
Acta Crystallographica Section B Structural Science, Vol. 54, Issue 5
DOI: 10.1107/S0108768197019939

Characterisation of sodium cations in dehydrated zeolite NaX by 23Na NMR spectroscopy
journal, November 1996

Feuerstein, M.; Hunger, M.; Engelhardt, G.
Solid State Nuclear Magnetic Resonance, Vol. 7, Issue 2
DOI: 10.1016/S0926-2040(96)01246-5

Magic angle spinning NMR observation of sodium site exchange in nepheline at 500° C
journal, November 1989

Stebbins, Jonathan F.; Farnan, Ian; Williams, Evan H.
Physics and Chemistry of Minerals, Vol. 16, Issue 8
DOI: 10.1007/BF00209699

Radiation effects and tolerance mechanism in β-eucryptite
journal, January 2013

Narayanan, Badri; Reimanis, Ivar E.; Huang, Hanchen
Journal of Applied Physics, Vol. 113, Issue 3
DOI: 10.1063/1.4775838

Submixture model to predict nepheline precipitation in waste glasses
journal, May 2016

Vienna, John D.; Kroll, Jared O.; Hrma, Pavel R.
International Journal of Applied Glass Science, Vol. 8, Issue 2
DOI: 10.1111/ijag.12207

Nepheline structural and chemical dependence on melt composition
journal, February 2016

Marcial, José; Crum, Jarrod; Neill, Owen
American Mineralogist, Vol. 101, Issue 2
DOI: 10.2138/am-2016-5370

Insight into sodium silicate glass structural organization by multinuclear NMR combined with first-principles calculations
journal, May 2011

Angeli, Frédéric; Villain, Olivier; Schuller, Sophie
Geochimica et Cosmochimica Acta, Vol. 75, Issue 9
DOI: 10.1016/j.gca.2011.02.003

Lithium conductivity in glasses of the Li ₂ O–Al ₂ O ₃ –SiO ₂ system
journal, January 2015

Ross, Sebastian; Welsch, Anna-Maria; Behrens, Harald
Physical Chemistry Chemical Physics, Vol. 17, Issue 1
DOI: 10.1039/C4CP03609C

Thermal transformation of zeolite Li-A(BW). The crystal structure of γ-eucryptite, a polymorph of LiAlSiO4
journal, March 1990

Norby, P.
Zeolites, Vol. 10, Issue 3
DOI: 10.1016/0144-2449(90)90045-S

Site Preferences in the Mixed Cation Zeolite, Li,Na-Chabazite: A Combined Solid-State NMR and Neutron Diffraction Study
journal, March 2000

Smith, Luis J.; Eckert, Hellmut; Cheetham, Anthony K.
Journal of the American Chemical Society, Vol. 122, Issue 8
DOI: 10.1021/ja992882b

Elucidating the Effect of Iron Speciation (Fe ²⁺ /Fe ³⁺ ) on Crystallization Kinetics of Sodium Aluminosilicate Glasses
journal, April 2016

Shaharyar, Yaqoot; Cheng, Justin Y.; Han, Edmund
Journal of the American Ceramic Society, Vol. 99, Issue 7
DOI: 10.1111/jace.14239

Control of Nepheline Crystallization in Nuclear Waste Glass
journal, November 2008

Fox, Kevin M.; Edwards, Thomas B.; Peeler, David K.
International Journal of Applied Ceramic Technology, Vol. 5, Issue 6
DOI: 10.1111/j.1744-7402.2008.02250.x

The mixed alkali effect in lithium-sodium aluminosilicate glasses
journal, December 1987

Lapp, Josef C.; Shelby, James E.
Journal of Non-Crystalline Solids, Vol. 95-96
DOI: 10.1016/S0022-3093(87)80695-6

Advances in understanding the structure of borosilicate glasses: A Raman spectroscopy study
journal, May 2009

Manara, D.; Grandjean, A.; Neuville, D. R.
American Mineralogist, Vol. 94, Issue 5-6
DOI: 10.2138/am.2009.3027

Compositional and Stability Relationships Among the Lithium Aluminosilicates: Eucryptite, Spodumene, and Petalite
journal, May 1950

Roy, Rustum; Roy, Della M.; Osborn, E. F.
Journal of the American Ceramic Society, Vol. 33, Issue 5
DOI: 10.1111/j.1151-2916.1950.tb12780.x

23Na NMR chemical shifts and local Na coordination environments in silicate crystals, melts and glasses
journal, October 1993

Xue, Xianyu; Stebbins, JonathanF.
Physics and Chemistry of Minerals, Vol. 20, Issue 5
DOI: 10.1007/BF00215100

Structural characterization of lithium aluminosilicate glass and glass ceramics derived from spodumene mineral
journal, April 1995

Nordmann, A.; Cheng, Y.; Bastow, T. J.
Journal of Physics: Condensed Matter, Vol. 7, Issue 16
DOI: 10.1088/0953-8984/7/16/007

Interstitial cristobalite-type compounds (Na2O)≤0.33Na[AlSiO4]
journal, January 1986

Klingenberg, R.; Felsche, J.
Journal of Solid State Chemistry, Vol. 61, Issue 1
DOI: 10.1016/0022-4596(86)90004-6

Structure of mineral glasses—II. The SiO2NaAlSiO4 join
journal, September 1979

Taylor, Mark; Brown, Gordon E.
Geochimica et Cosmochimica Acta, Vol. 43, Issue 9
DOI: 10.1016/0016-7037(79)90141-8

Inhomogeneous distribution of Na+ in alkali silicate glasses
journal, January 2011

Tokuda, Yomei; Oka, Takanori; Takahashi, Masahide
Journal of the Ceramic Society of Japan, Vol. 119, Issue 1396
DOI: 10.2109/jcersj2.119.909

Silicate structures of the cristobalite type: III. Structural relationship of high-cristobalite, α-carnegieite, and Na₂CaSiO₄
journal, October 1932

Barth, Tom. F. W.; Posnjak, E.
Zeitschrift für Kristallographie - Crystalline Materials, Vol. 81, Issue 1-6
DOI: 10.1524/zkri.1932.81.1.376

Cristobalite-Related Phases in the NaAlO2–NaAlSiO4 System. I. Two Tetragonal and Two Orthorhombic Structures
journal, October 1998

Thompson, J. G.; Withers, R. L.; Melnitchenko, A.
Acta Crystallographica Section B Structural Science, Vol. 54, Issue 5
DOI: 10.1107/S0108768197019927

Characterization of Li Cations in Zeolite LiX by Solid-State NMR Spectroscopy and Neutron Diffraction
journal, August 1998

Feuerstein, M.; Lobo, R. F.
Chemistry of Materials, Vol. 10, Issue 8
DOI: 10.1021/cm980112d

Structural characterization of pure Na-nephelines synthesized by zeolite conversion route
journal, October 2004

Dimitrijevic, Radovan; Dondur, Vera; Vulic, Predrag
Journal of Physics and Chemistry of Solids, Vol. 65, Issue 10
DOI: 10.1016/j.jpcs.2004.03.005

Examination of the mixed-alkali effect in (Li,Na) disilicate glasses by nuclear magnetic resonance and conductivity measurements
journal, October 1995

Ali, F.; Chadwick, A. V.; Greaves, G. N.
Solid State Nuclear Magnetic Resonance, Vol. 5, Issue 1
DOI: 10.1016/0926-2040(95)00033-M

Effects of cation field strength on the structure of aluminoborosilicate glasses: High-resolution 11B, 27Al and 23Na MAS NMR
journal, April 2009

Wu, Jingshi; Stebbins, Jonathan F.
Journal of Non-Crystalline Solids, Vol. 355, Issue 9
DOI: 10.1016/j.jnoncrysol.2009.01.025

Crystallization of iron-containing sodium aluminosilicate glasses in the NaAlSiO ₄ -NaFeSiO ₄ join : CRYSTALLIZATION NAALSIO
journal, April 2017

Ahmadzadeh, Mostafa; Marcial, José; McCloy, John
Journal of Geophysical Research: Solid Earth, Vol. 122, Issue 4
DOI: 10.1002/2016JB013661

Al,Si order in the crystal structure of α-eucryptite (LiAlSiO ₄ )
journal, March 2001

Daniels, Peter; Fyfe, Colin A.
American Mineralogist, Vol. 86, Issue 3
DOI: 10.2138/am-2001-2-310

Average and super structure of β eucryptite (LiAlSiO ₄ ) Part I. Average structure*
journal, July 1972

Tscherry, V.; Schulz, H.; Laves, F.
Zeitschrift für Kristallographie, Vol. 135, Issue 3-4
DOI: 10.1524/zkri.1972.135.3-4.161

Local cation environments in mixed alkali silicate glasses studied by multinuclear single and double resonance magic-angle spinning NMR
journal, July 1997

Gee, Becky; Janssen, Michael; Eckert, Hellmut
Journal of Non-Crystalline Solids, Vol. 215, Issue 1
DOI: 10.1016/S0022-3093(97)00037-9

A Reinvestigation of Low-Carnegieite by XRD, NMR, and TEM
journal, May 1993

Thompson, John G.; Withers, Ray L.; Whittaker, Andrew K.
Journal of Solid State Chemistry, Vol. 104, Issue 1
DOI: 10.1006/jssc.1993.1141

Thirty-year quest for structure–nucleation relationships in oxide glasses
journal, October 2015

Zanotto, E. D.; Tsuchida, J. E.; Schneider, J. F.
International Materials Reviews, Vol. 60, Issue 7
DOI: 10.1080/09506608.2015.1114706

High-resolution aluminum-27 NMR of aluminosilicates
journal, April 1986

Lippmaa, E.; Samoson, A.; Magi, M.
Journal of the American Chemical Society, Vol. 108, Issue 8
DOI: 10.1021/ja00268a002

Cation Distribution in Mixed-Alkali Silicate Glasses. NMR Studies by ²³ Na−{ ⁷ Li} and ²³ Na−{ ⁶ Li} Spin Echo Double Resonance
journal, January 1996

Gee, Becky; Eckert, Hellmut
The Journal of Physical Chemistry, Vol. 100, Issue 9
DOI: 10.1021/jp9521722

Viscosity Behavior and Mixed Alkali Effect of Alkali Aluminosilicate Glass Melts
journal, January 1997

Kim, Ki-Dong; Lee, Seung-Heun
Journal of the Ceramic Society of Japan, Vol. 105, Issue 1226
DOI: 10.2109/jcersj.105.827

Leaching of Devitrified Glass Containing Simulated SRP Nuclear Waste
journal, January 1984

Jantzen, Carol M.; Bickford, Dennis F.
MRS Proceedings, Vol. 44
DOI: 10.1557/PROC-44-135

Crystal structure of hexagonal trinepheline; a new synthetic NaAlSiO ₄ modification
journal, June 1998

Kahlenberg, V.; Bohn, H.
American Mineralogist, Vol. 83, Issue 5-6
DOI: 10.2138/am-1998-5-623

Properties and structure of (1−x)Li2O–xNa2O–Al2O3–4SiO2 glass systems
journal, July 2007

Wang, Moo-Chin; Cheng, Chih-Wei; Shih, Ping-Yu
Journal of Non-Crystalline Solids, Vol. 353, Issue 22-23
DOI: 10.1016/j.jnoncrysol.2006.09.040

Nepheline Crystallization in High-Alumina High-Level Waste Glass
journal, January 2015

Marcial, José; McCloy, John; Neill, Owen
MRS Proceedings, Vol. 1744
DOI: 10.1557/opl.2015.382

The Crystal Chemistry of Nepheline
journal, February 2003

Tait, K. T.; Sokolova, E.; Hawthorne, F. C.
The Canadian Mineralogist, Vol. 41, Issue 1
DOI: 10.2113/gscanmin.41.1.61

6Li nuclear magnetic resonance chemical shifts, coordination number and relaxation in crystalline and glassy silicates
journal, October 1995

Xu, Z.; Stebbins, Jonathan F.
Solid State Nuclear Magnetic Resonance, Vol. 5, Issue 1
DOI: 10.1016/0926-2040(95)00026-M

An XRD and Electron Diffraction Study of Cristobalite-Related Phases in the NaAlO2–NaAlSiO4System
journal, June 1997

Thompson, John G.; Melnitchenko, Alexandra; Palethorpe, Stephen R.
Journal of Solid State Chemistry, Vol. 131, Issue 1
DOI: 10.1006/jssc.1997.7295

Structural Origin of the Thermal and Diffusion Behaviors of Lithium Aluminosilicate Crystal Polymorphs and Glasses
journal, May 2016

Ren, Mengguo; Du, Jincheng
Journal of the American Ceramic Society, Vol. 99, Issue 8
DOI: 10.1111/jace.14292

The thermal transformation of Na LiA zeolites. A new polymorph in the system Li2OAl2O3SiO2
journal, June 1986

Dondur, Vera; Dimitrijević, Radovan
Journal of Solid State Chemistry, Vol. 63, Issue 1
DOI: 10.1016/0022-4596(86)90150-7

Electron microscopy of Li ₂ O–Al ₂ O ₃ –SiO ₂ glass ceramics
journal, September 1982

Gai, P. L.; Chen, Q. Q.
Acta Crystallographica Section A, Vol. 38, Issue 5
DOI: 10.1107/S0567739482001491

A theoretical study of structural factors correlated with ²³ Na NMR parameters
journal, August 2004

Liu, Yun; Tossell, John; Nekvasil, Hanna
American Mineralogist, Vol. 89, Issue 8-9
DOI: 10.2138/am-2004-8-920

Nepheline gradient solid solutions
journal, May 1995

Ota, Toshitaka; Yamai, Iwao; Hayashi, Takashi
Journal of Materials Science, Vol. 30, Issue 10
DOI: 10.1007/BF00362155

Temperature-induced amorphization of Na-zeolite A: A view from multi-nuclear high-resolution solid-state NMR
journal, October 2014

Kim, H. N.; Lee, S. K.
American Mineralogist, Vol. 99, Issue 10
DOI: 10.2138/am-2014-4928

Percolation channels: a universal idea to describe the atomic structure and dynamics of glasses and melts
journal, November 2017

Le Losq, Charles; Neuville, Daniel R.; Chen, Wenlin
Scientific Reports, Vol. 7, Issue 1
DOI: 10.1038/s41598-017-16741-3

Effect of the substitution of boron for aluminium in the β-eucryptite LiAlSiO4 structure
journal, January 1994

Mazza, Daniele; Lucco-Borlera, Maria
Journal of the European Ceramic Society, Vol. 13, Issue 1
DOI: 10.1016/0955-2219(94)90059-0

Melt structure in the system nepheline-diopside
journal, January 1990

Sykes, Dan; Scarfe, Christopher M.
Journal of Geophysical Research, Vol. 95, Issue B10
DOI: 10.1029/JB095iB10p15745

The crystallisation of glasses based on the eutectic compositions in the system Li2O-Al2O3-SiO2: Part 2 Lithium metasilicate-?-eucryptite
journal, February 1970

Barry, T. I.; Clinton, D.; Lay, L. A.
Journal of Materials Science, Vol. 5, Issue 2
DOI: 10.1007/BF00554629

Structural Characterisation of Kaolinite:NaCl Intercalate and its Derivatives
journal, January 1992

Thompson, John G.
Clays and Clay Minerals, Vol. 40, Issue 4
DOI: 10.1346/CCMN.1992.0400401

Modulation wave approach to the structural parameterization and Rietveld refinement of low carnegieite
journal, August 1993

Withers, R. L.; Thompson, J. G.
Acta Crystallographica Section B Structural Science, Vol. 49, Issue 4
DOI: 10.1107/S010876819300134X

Thermochemistry of Charge-Coupled Substitutions in Silicate Glasses: The Systems M _l/n ⁿ⁺ AlO ₂ -SiO ₂ (M = Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Pb)
journal, September 1984

Roy, Bimalendu N.; Navrotsky, Alexandra
Journal of the American Ceramic Society, Vol. 67, Issue 9
DOI: 10.1111/j.1151-2916.1984.tb19603.x

Li+ ion mobility in eucryptite phases
journal, November 1988

Donduft, Vera; Dimitrijević, Radovan; Petranović, Nadežda
Journal of Materials Science, Vol. 23, Issue 11
DOI: 10.1007/BF01106839

The nepheline-kalsilite system; Part I, X-ray data for the crystalline phases
journal, April 1957

Smith, J. V.; Tuttle, O. F.
American Journal of Science, Vol. 255, Issue 4
DOI: 10.2475/ajs.255.4.282

283. The hydrothermal chemistry of silicates. Part I. Synthetic lithium aluminosilicates
journal, January 1951

Barrer, R. M.; White, E. A. D.
Journal of the Chemical Society (Resumed)
DOI: 10.1039/jr9510001267

A neutron diffraction and Rietveld analysis of cooperative Li motion in beta-eucryptite
journal, July 2004

Sartbaeva, Asel; Redfern, Simon A. T.; Lee, William T.
Journal of Physics: Condensed Matter, Vol. 16, Issue 29
DOI: 10.1088/0953-8984/16/29/018

Molecular dynamics simulations of liquids and glasses in the system NaAlSiO ₄ -SiO ₂ ; methodology and melt structures
journal, June 1995

Stein, Daniel J.; Spera, Frank J.
American Mineralogist, Vol. 80, Issue 5-6
DOI: 10.2138/am-1995-5-601

The distribution of sodium ions in aluminosilicate glasses: a high-field Na-23 MAS and 3Q MAS NMR study
journal, May 2003

Lee, Sung Keun; Stebbins, Jonathan F.
Geochimica et Cosmochimica Acta, Vol. 67, Issue 9
DOI: 10.1016/S0016-7037(03)00026-7

²⁹ Si and ²⁷ Al MAS-NMR spectroscopy of β-eucryptite (LiAlSiO ₄ ): The enthalpy of Si,Al ordering
journal, January 2000

Phillips, Brian L.; Xu, Hongwu; Heaney, Peter J.
American Mineralogist, Vol. 85, Issue 1
DOI: 10.2138/am-2000-0117

Al–O–Al and Si–O–Si sites in framework aluminosilicate glasses with Si/Al=1: quantification of framework disorder
journal, May 2000

Lee, Sung Keun; Stebbins, Jonathan F.
Journal of Non-Crystalline Solids, Vol. 270, Issue 1-3
DOI: 10.1016/S0022-3093(00)00089-2

Defects and short-range order in nepheline group minerals: a silicon-29 nuclear magnetic resonance study
journal, November 1986

Stebbins, J. F.; Murdoch, J. B.; Carmichael, I. S. E.
Physics and Chemistry of Minerals, Vol. 13, Issue 6
DOI: 10.1007/BF00309182

Understanding the structural origin of crystalline phase transformations in nepheline (NaAlSiO ₄ )‐based glass‐ceramics
journal, April 2017

Deshkar, Ambar; Marcial, José; Southern, Scott A.
Journal of the American Ceramic Society, Vol. 100, Issue 7
DOI: 10.1111/jace.14845

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Understanding the structural origin of crystalline phase transformations in nepheline (NaAlSiO ₄ )‐based glass‐ceramics

Journal Article Deshkar, Ambar ; Marcial, José ; Southern, Scott A. ; ... - Journal of the American Ceramic Society

Abstract Nepheline (Na ₆ K ₂ Al ₈ Si ₈ O ₃₂ ) is a rock‐forming tectosilicate mineral which is by far the most abundant of the feldspathoids. The crystallization in nepheline‐based glass‐ceramics proceeds through several polymorphic transformations — mainly orthorhombic, hexagonal, cubic — depending on their thermochemistry. However, the fundamental science governing these transformations is poorly understood. In this article, an attempt has been made to elucidate the structural drivers controlling these polymorphic transformations in nepheline‐based glass‐ceramics. Accordingly, two different sets of glasses (meta‐aluminous and per‐alkaline) have been designed in the system Na ₂ O–CaO–Al ₂ O ₃ –SiOmore »« less
Cited by 32
https://doi.org/10.1111/jace.14845
Formation of {alpha}-eucryptite, LiAlSiO{sub 4}: An in-situ synchrotron X-ray powder diffraction study of a high temperature hydrothermal synthesis

Journal Article Norby, P ; Hanson, J C ; Fitch, A N ; ... - Chemistry of Materials

Hydrothermal conversion of zeolite Li-A(BW), LiAlSiO{sub 4}{center_dot}H{sub 2}O, into {alpha}-eucryptite, LiAlSiO{sub 4}, occurs at temperatures above 350 C. The authors report here the first in-situ study of a high-temperature hydrothermal synthesis using time-resolved power diffraction. The hydrothermal syntheses were performed in stainless steel capillaries. To maintain hydrothermal conditions, a hydraulic pressure of 2--300 atm was applied. Synchrotron X-ray radiation with energies of 35--40 keV was used in order to penetrate the steel capillaries. Room temperature Imaging Plate powder diffraction data were collected on a sample of zeolite Li-A(BW) contained in a steel capillary in an aqueous solution at 200 atm.more »« less
https://doi.org/10.1021/cm991210h
Experimental Determination of the Effect of the Ratio of B/Al on Glass Dissolution along the Nepheline (NaAlSiO₄) – Malinkoite (NaBSiO₄) Join

Journal Article Pierce, Eric M ; Reed, Lunde R ; Shaw, Wendy J ; ... - Geochimica et Cosmochimica Acta

The dissolution kinetics of five glasses along the NaAlSiO₄-NaBSiO₄ join were used to evaluate how the structural variations associated with boron-aluminum substitution affect the rate of dissolution. The composition of each glass varied inversely in mol% of Al₂O₃ (5 to 25 mol%) and B₂O₃ (20 to 0 mol%) with Na₂O (25 mol%) and SiO₂ (50 mol%) making up the remaining amount, in every case Na/(Al+B) = 1.0. Single-pass flow-through experiments (SPFT) were conducted under dilute conditions as a function of solution pH (from 7.0 to 12.0) and temperature (from 23° to 90°C). Analysis by ²⁷Al and ²⁹Si MAS-NMR suggests Almore »« less
https://doi.org/10.1016/j.gca.2009.09.006

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Title: Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join

Abstract

Citation Formats

Nepheline crystallization in boron-rich alumino-silicate glasses as investigated by multi-nuclear NMR, Raman, & Mössbauer spectroscopies journal, February 2015

Solid-state nuclear magnetic resonance investigation of cation siting in LiNaLSX zeolites journal, December 1998

Phase Equilibria in the System Lithium Metasilicate-beta-Eucryptite journal, January 1954

High-resolution 23Na, 27Al and 29Si NMR spectroscopy of framework Aluminosilicate glasses journal, August 1987

Glass-Ceramics by Photosensitive Processes journal, August 2015

Cristobalite-Related Phases in the NaAlO2–NaAlSiO4 System. II. A Commensurately Modulated Cubic Structure journal, October 1998

Characterisation of sodium cations in dehydrated zeolite NaX by 23Na NMR spectroscopy journal, November 1996

Magic angle spinning NMR observation of sodium site exchange in nepheline at 500° C journal, November 1989

Radiation effects and tolerance mechanism in β-eucryptite journal, January 2013

Submixture model to predict nepheline precipitation in waste glasses journal, May 2016

Nepheline structural and chemical dependence on melt composition journal, February 2016

Insight into sodium silicate glass structural organization by multinuclear NMR combined with first-principles calculations journal, May 2011

Lithium conductivity in glasses of the Li 2 O–Al 2 O 3 –SiO 2 system journal, January 2015

Thermal transformation of zeolite Li-A(BW). The crystal structure of γ-eucryptite, a polymorph of LiAlSiO4 journal, March 1990

Site Preferences in the Mixed Cation Zeolite, Li,Na-Chabazite: A Combined Solid-State NMR and Neutron Diffraction Study journal, March 2000

Elucidating the Effect of Iron Speciation (Fe 2+ /Fe 3+ ) on Crystallization Kinetics of Sodium Aluminosilicate Glasses journal, April 2016

Control of Nepheline Crystallization in Nuclear Waste Glass journal, November 2008

The mixed alkali effect in lithium-sodium aluminosilicate glasses journal, December 1987

Advances in understanding the structure of borosilicate glasses: A Raman spectroscopy study journal, May 2009

Compositional and Stability Relationships Among the Lithium Aluminosilicates: Eucryptite, Spodumene, and Petalite journal, May 1950

23Na NMR chemical shifts and local Na coordination environments in silicate crystals, melts and glasses journal, October 1993

Structural characterization of lithium aluminosilicate glass and glass ceramics derived from spodumene mineral journal, April 1995

Interstitial cristobalite-type compounds (Na2O)≤0.33Na[AlSiO4] journal, January 1986

Structure of mineral glasses—II. The SiO2NaAlSiO4 join journal, September 1979

Inhomogeneous distribution of Na+ in alkali silicate glasses journal, January 2011

Silicate structures of the cristobalite type: III. Structural relationship of high-cristobalite, α-carnegieite, and Na2CaSiO4 journal, October 1932

Cristobalite-Related Phases in the NaAlO2–NaAlSiO4 System. I. Two Tetragonal and Two Orthorhombic Structures journal, October 1998

Characterization of Li Cations in Zeolite LiX by Solid-State NMR Spectroscopy and Neutron Diffraction journal, August 1998

Structural characterization of pure Na-nephelines synthesized by zeolite conversion route journal, October 2004

Examination of the mixed-alkali effect in (Li,Na) disilicate glasses by nuclear magnetic resonance and conductivity measurements journal, October 1995

Effects of cation field strength on the structure of aluminoborosilicate glasses: High-resolution 11B, 27Al and 23Na MAS NMR journal, April 2009

Crystallization of iron-containing sodium aluminosilicate glasses in the NaAlSiO 4 -NaFeSiO 4 join : CRYSTALLIZATION NAALSIO journal, April 2017

Al,Si order in the crystal structure of α-eucryptite (LiAlSiO 4 ) journal, March 2001

Average and super structure of β eucryptite (LiAlSiO 4 ) Part I. Average structure* journal, July 1972

Local cation environments in mixed alkali silicate glasses studied by multinuclear single and double resonance magic-angle spinning NMR journal, July 1997

A Reinvestigation of Low-Carnegieite by XRD, NMR, and TEM journal, May 1993

Thirty-year quest for structure–nucleation relationships in oxide glasses journal, October 2015

High-resolution aluminum-27 NMR of aluminosilicates journal, April 1986

Cation Distribution in Mixed-Alkali Silicate Glasses. NMR Studies by 23 Na−{ 7 Li} and 23 Na−{ 6 Li} Spin Echo Double Resonance journal, January 1996

Viscosity Behavior and Mixed Alkali Effect of Alkali Aluminosilicate Glass Melts journal, January 1997

Leaching of Devitrified Glass Containing Simulated SRP Nuclear Waste journal, January 1984

Crystal structure of hexagonal trinepheline; a new synthetic NaAlSiO 4 modification journal, June 1998

Properties and structure of (1−x)Li2O–xNa2O–Al2O3–4SiO2 glass systems journal, July 2007

Nepheline Crystallization in High-Alumina High-Level Waste Glass journal, January 2015

The Crystal Chemistry of Nepheline journal, February 2003

6Li nuclear magnetic resonance chemical shifts, coordination number and relaxation in crystalline and glassy silicates journal, October 1995

An XRD and Electron Diffraction Study of Cristobalite-Related Phases in the NaAlO2–NaAlSiO4System journal, June 1997

Structural Origin of the Thermal and Diffusion Behaviors of Lithium Aluminosilicate Crystal Polymorphs and Glasses journal, May 2016

The thermal transformation of Na LiA zeolites. A new polymorph in the system Li2OAl2O3SiO2 journal, June 1986

Electron microscopy of Li 2 O–Al 2 O 3 –SiO 2 glass ceramics journal, September 1982

A theoretical study of structural factors correlated with 23 Na NMR parameters journal, August 2004

Nepheline gradient solid solutions journal, May 1995

Temperature-induced amorphization of Na-zeolite A: A view from multi-nuclear high-resolution solid-state NMR journal, October 2014

Percolation channels: a universal idea to describe the atomic structure and dynamics of glasses and melts journal, November 2017

Effect of the substitution of boron for aluminium in the β-eucryptite LiAlSiO4 structure journal, January 1994

Melt structure in the system nepheline-diopside journal, January 1990

The crystallisation of glasses based on the eutectic compositions in the system Li2O-Al2O3-SiO2: Part 2 Lithium metasilicate-?-eucryptite journal, February 1970

Structural Characterisation of Kaolinite:NaCl Intercalate and its Derivatives journal, January 1992

Modulation wave approach to the structural parameterization and Rietveld refinement of low carnegieite journal, August 1993

Thermochemistry of Charge-Coupled Substitutions in Silicate Glasses: The Systems M l/n n+ AlO 2 -SiO 2 (M = Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Pb) journal, September 1984

Li+ ion mobility in eucryptite phases journal, November 1988

The nepheline-kalsilite system; Part I, X-ray data for the crystalline phases journal, April 1957

283. The hydrothermal chemistry of silicates. Part I. Synthetic lithium aluminosilicates journal, January 1951

A neutron diffraction and Rietveld analysis of cooperative Li motion in beta-eucryptite journal, July 2004

Molecular dynamics simulations of liquids and glasses in the system NaAlSiO 4 -SiO 2 ; methodology and melt structures journal, June 1995

The distribution of sodium ions in aluminosilicate glasses: a high-field Na-23 MAS and 3Q MAS NMR study journal, May 2003

29 Si and 27 Al MAS-NMR spectroscopy of β-eucryptite (LiAlSiO 4 ): The enthalpy of Si,Al ordering journal, January 2000

Al–O–Al and Si–O–Si sites in framework aluminosilicate glasses with Si/Al=1: quantification of framework disorder journal, May 2000

Defects and short-range order in nepheline group minerals: a silicon-29 nuclear magnetic resonance study journal, November 1986

Understanding the structural origin of crystalline phase transformations in nepheline (NaAlSiO 4 )‐based glass‐ceramics journal, April 2017

Title: Structural dependence of crystallization in glasses along the nepheline (NaAlSiO ₄ ) ‐ eucryptite (LiAlSiO ₄ ) join

Nepheline crystallization in boron-rich alumino-silicate glasses as investigated by multi-nuclear NMR, Raman, & Mössbauer spectroscopies
journal, February 2015

Solid-state nuclear magnetic resonance investigation of cation siting in LiNaLSX zeolites
journal, December 1998

Phase Equilibria in the System Lithium Metasilicate-beta-Eucryptite
journal, January 1954

High-resolution 23Na, 27Al and 29Si NMR spectroscopy of framework Aluminosilicate glasses
journal, August 1987

Glass-Ceramics by Photosensitive Processes
journal, August 2015

Cristobalite-Related Phases in the NaAlO2–NaAlSiO4 System. II. A Commensurately Modulated Cubic Structure
journal, October 1998

Characterisation of sodium cations in dehydrated zeolite NaX by 23Na NMR spectroscopy
journal, November 1996

Magic angle spinning NMR observation of sodium site exchange in nepheline at 500° C
journal, November 1989

Radiation effects and tolerance mechanism in β-eucryptite
journal, January 2013

Submixture model to predict nepheline precipitation in waste glasses
journal, May 2016

Nepheline structural and chemical dependence on melt composition
journal, February 2016

Insight into sodium silicate glass structural organization by multinuclear NMR combined with first-principles calculations
journal, May 2011

Lithium conductivity in glasses of the Li ₂ O–Al ₂ O ₃ –SiO ₂ system
journal, January 2015

Thermal transformation of zeolite Li-A(BW). The crystal structure of γ-eucryptite, a polymorph of LiAlSiO4
journal, March 1990

Site Preferences in the Mixed Cation Zeolite, Li,Na-Chabazite: A Combined Solid-State NMR and Neutron Diffraction Study
journal, March 2000

Elucidating the Effect of Iron Speciation (Fe ²⁺ /Fe ³⁺ ) on Crystallization Kinetics of Sodium Aluminosilicate Glasses
journal, April 2016

Control of Nepheline Crystallization in Nuclear Waste Glass
journal, November 2008

The mixed alkali effect in lithium-sodium aluminosilicate glasses
journal, December 1987

Advances in understanding the structure of borosilicate glasses: A Raman spectroscopy study
journal, May 2009

Compositional and Stability Relationships Among the Lithium Aluminosilicates: Eucryptite, Spodumene, and Petalite
journal, May 1950

23Na NMR chemical shifts and local Na coordination environments in silicate crystals, melts and glasses
journal, October 1993

Structural characterization of lithium aluminosilicate glass and glass ceramics derived from spodumene mineral
journal, April 1995

Interstitial cristobalite-type compounds (Na2O)≤0.33Na[AlSiO4]
journal, January 1986

Structure of mineral glasses—II. The SiO2NaAlSiO4 join
journal, September 1979

Inhomogeneous distribution of Na+ in alkali silicate glasses
journal, January 2011

Silicate structures of the cristobalite type: III. Structural relationship of high-cristobalite, α-carnegieite, and Na₂CaSiO₄
journal, October 1932

Cristobalite-Related Phases in the NaAlO2–NaAlSiO4 System. I. Two Tetragonal and Two Orthorhombic Structures
journal, October 1998

Characterization of Li Cations in Zeolite LiX by Solid-State NMR Spectroscopy and Neutron Diffraction
journal, August 1998

Structural characterization of pure Na-nephelines synthesized by zeolite conversion route
journal, October 2004

Examination of the mixed-alkali effect in (Li,Na) disilicate glasses by nuclear magnetic resonance and conductivity measurements
journal, October 1995

Effects of cation field strength on the structure of aluminoborosilicate glasses: High-resolution 11B, 27Al and 23Na MAS NMR
journal, April 2009

Crystallization of iron-containing sodium aluminosilicate glasses in the NaAlSiO ₄ -NaFeSiO ₄ join : CRYSTALLIZATION NAALSIO
journal, April 2017

Al,Si order in the crystal structure of α-eucryptite (LiAlSiO ₄ )
journal, March 2001

Average and super structure of β eucryptite (LiAlSiO ₄ ) Part I. Average structure*
journal, July 1972

Local cation environments in mixed alkali silicate glasses studied by multinuclear single and double resonance magic-angle spinning NMR
journal, July 1997

A Reinvestigation of Low-Carnegieite by XRD, NMR, and TEM
journal, May 1993

Thirty-year quest for structure–nucleation relationships in oxide glasses
journal, October 2015

High-resolution aluminum-27 NMR of aluminosilicates
journal, April 1986

Cation Distribution in Mixed-Alkali Silicate Glasses. NMR Studies by ²³ Na−{ ⁷ Li} and ²³ Na−{ ⁶ Li} Spin Echo Double Resonance
journal, January 1996

Viscosity Behavior and Mixed Alkali Effect of Alkali Aluminosilicate Glass Melts
journal, January 1997

Leaching of Devitrified Glass Containing Simulated SRP Nuclear Waste
journal, January 1984

Crystal structure of hexagonal trinepheline; a new synthetic NaAlSiO ₄ modification
journal, June 1998

Properties and structure of (1−x)Li2O–xNa2O–Al2O3–4SiO2 glass systems
journal, July 2007

Nepheline Crystallization in High-Alumina High-Level Waste Glass
journal, January 2015

The Crystal Chemistry of Nepheline
journal, February 2003

6Li nuclear magnetic resonance chemical shifts, coordination number and relaxation in crystalline and glassy silicates
journal, October 1995

An XRD and Electron Diffraction Study of Cristobalite-Related Phases in the NaAlO2–NaAlSiO4System
journal, June 1997

Structural Origin of the Thermal and Diffusion Behaviors of Lithium Aluminosilicate Crystal Polymorphs and Glasses
journal, May 2016

The thermal transformation of Na LiA zeolites. A new polymorph in the system Li2OAl2O3SiO2
journal, June 1986

Electron microscopy of Li ₂ O–Al ₂ O ₃ –SiO ₂ glass ceramics
journal, September 1982

A theoretical study of structural factors correlated with ²³ Na NMR parameters
journal, August 2004

Nepheline gradient solid solutions
journal, May 1995

Temperature-induced amorphization of Na-zeolite A: A view from multi-nuclear high-resolution solid-state NMR
journal, October 2014

Percolation channels: a universal idea to describe the atomic structure and dynamics of glasses and melts
journal, November 2017

Effect of the substitution of boron for aluminium in the β-eucryptite LiAlSiO4 structure
journal, January 1994

Melt structure in the system nepheline-diopside
journal, January 1990

The crystallisation of glasses based on the eutectic compositions in the system Li2O-Al2O3-SiO2: Part 2 Lithium metasilicate-?-eucryptite
journal, February 1970

Structural Characterisation of Kaolinite:NaCl Intercalate and its Derivatives
journal, January 1992

Modulation wave approach to the structural parameterization and Rietveld refinement of low carnegieite
journal, August 1993

Thermochemistry of Charge-Coupled Substitutions in Silicate Glasses: The Systems M _l/n ⁿ⁺ AlO ₂ -SiO ₂ (M = Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Pb)
journal, September 1984

Li+ ion mobility in eucryptite phases
journal, November 1988

The nepheline-kalsilite system; Part I, X-ray data for the crystalline phases
journal, April 1957

283. The hydrothermal chemistry of silicates. Part I. Synthetic lithium aluminosilicates
journal, January 1951

A neutron diffraction and Rietveld analysis of cooperative Li motion in beta-eucryptite
journal, July 2004

Molecular dynamics simulations of liquids and glasses in the system NaAlSiO ₄ -SiO ₂ ; methodology and melt structures
journal, June 1995

The distribution of sodium ions in aluminosilicate glasses: a high-field Na-23 MAS and 3Q MAS NMR study
journal, May 2003

²⁹ Si and ²⁷ Al MAS-NMR spectroscopy of β-eucryptite (LiAlSiO ₄ ): The enthalpy of Si,Al ordering
journal, January 2000

Al–O–Al and Si–O–Si sites in framework aluminosilicate glasses with Si/Al=1: quantification of framework disorder
journal, May 2000

Defects and short-range order in nepheline group minerals: a silicon-29 nuclear magnetic resonance study
journal, November 1986

Understanding the structural origin of crystalline phase transformations in nepheline (NaAlSiO ₄ )‐based glass‐ceramics
journal, April 2017