Multidimensional photon correlation spectroscopy of cavity polaritons
Abstract
Significance We propose a spectroscopic technique that can track the time-dependent state of a dressed molecule in an optical cavity (polariton) by measuring coincidence of two emitted photons. The proposed technique offers an independent control of the spectral and temporal resolution; single-photon detection allows for low-intensity measurements, which do not disturb the state of the cavity field, and time-dependent atom/cavity coupling provides a control tool. Tracking the evolution of the polariton states with time-dependent atom/cavity coupling should be of interest in photochemistry and photobiology and could improve fundamental understanding of many physical processes in strongly coupled atom/radiation states. Possible applications include chemical sensors and quantum information processing.
- Authors:
-
[2]
- State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai 200062, China,
- Department of Chemistry, University of California, Irvine, CA 92697,, Department of Physics and Astronomy, University of California, Irvine, CA 92697
- Publication Date:
- Research Org.:
- Univ. of California, Irvine, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; National Science Foundation (NSF)
- OSTI Identifier:
- 1418899
- Alternate Identifier(s):
- OSTI ID: 1527163
- Grant/Contract Number:
- FG02-04ER15571; CHE-1663822
- Resource Type:
- Published Article
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 115 Journal Issue: 7; Journal ID: ISSN 0027-8424
- Publisher:
- Proceedings of the National Academy of Sciences
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS; multidimensional spectroscopy; photon correlation; cavity polaritons
Citation Formats
Dorfman, Konstantin E., and Mukamel, Shaul. Multidimensional photon correlation spectroscopy of cavity polaritons. United States: N. p., 2018.
Web. doi:10.1073/pnas.1719443115.
Dorfman, Konstantin E., & Mukamel, Shaul. Multidimensional photon correlation spectroscopy of cavity polaritons. United States. https://doi.org/10.1073/pnas.1719443115
Dorfman, Konstantin E., and Mukamel, Shaul. Wed .
"Multidimensional photon correlation spectroscopy of cavity polaritons". United States. https://doi.org/10.1073/pnas.1719443115.
@article{osti_1418899,
title = {Multidimensional photon correlation spectroscopy of cavity polaritons},
author = {Dorfman, Konstantin E. and Mukamel, Shaul},
abstractNote = {Significance We propose a spectroscopic technique that can track the time-dependent state of a dressed molecule in an optical cavity (polariton) by measuring coincidence of two emitted photons. The proposed technique offers an independent control of the spectral and temporal resolution; single-photon detection allows for low-intensity measurements, which do not disturb the state of the cavity field, and time-dependent atom/cavity coupling provides a control tool. Tracking the evolution of the polariton states with time-dependent atom/cavity coupling should be of interest in photochemistry and photobiology and could improve fundamental understanding of many physical processes in strongly coupled atom/radiation states. Possible applications include chemical sensors and quantum information processing.},
doi = {10.1073/pnas.1719443115},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 7,
volume = 115,
place = {United States},
year = {2018},
month = {1}
}
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https://doi.org/10.1073/pnas.1719443115
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Cited by: 2 works
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Figures / Tables:
Fig. 1: (Top) Atom in the cavity emitting photons into the longitudinal cavity mode as well as noncavity vertical modes. Two TF-resolved detectors outside of the cavity register noncavity modes photon coincidence events. One photon number-resolving detector on the main optical axis measures photon number of the cavity mode photons.more »
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Works referenced in this record:
Characterization of Strong Light-Matter Coupling in Semiconductor Quantum-Dot Microcavities via Photon-Statistics Spectroscopy
journal, August 2008
- Schneebeli, L.; Kira, M.; Koch, S. W.
- Physical Review Letters, Vol. 101, Issue 9
Probing biological light-harvesting phenomena by optical cavities
journal, March 2012
- Caruso, Filippo; Saikin, Semion K.; Solano, Enrique
- Physical Review B, Vol. 85, Issue 12
Quantum theory of collective strong coupling of molecular vibrations with a microcavity mode
journal, May 2015
- Pino, Javier del; Feist, Johannes; Garcia-Vidal, Francisco J.
- New Journal of Physics, Vol. 17, Issue 5
Enhanced Raman Scattering from Vibro-Polariton Hybrid States
journal, June 2015
- Shalabney, Atef; George, Jino; Hiura, Hidefumi
- Angewandte Chemie International Edition, Vol. 54, Issue 27
Quantum Nonlinear Optics with Polar J-Aggregates in Microcavities
journal, October 2014
- Herrera, Felipe; Peropadre, Borja; Pachon, Leonardo A.
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 21
Single-Photon Spectroscopy of a Single Molecule
journal, February 2012
- Rezus, Y. L. A.; Walt, S. G.; Lettow, R.
- Physical Review Letters, Vol. 108, Issue 9
Atomic emission and cavity field spectra for a two-photon Jaynes–Cummings model in the presence of the Stark shift
journal, January 1993
- Nasreen, Tahira; Razmi, M. S. K.
- Journal of the Optical Society of America B, Vol. 10, Issue 7
Superradiance: An essay on the theory of collective spontaneous emission
journal, December 1982
- Gross, M.; Haroche, S.
- Physics Reports, Vol. 93, Issue 5
Prospects for the cavity-assisted laser cooling of molecules
journal, February 2008
- Lev, Benjamin L.; Vukics, András; Hudson, Eric R.
- Physical Review A, Vol. 77, Issue 2
Observation of quantum collapse and revival in a one-atom maser
journal, January 1987
- Rempe, Gerhard; Walther, Herbert; Klein, Norbert
- Physical Review Letters, Vol. 58, Issue 4
Resonance Absorption by Nuclear Magnetic Moments in a Solid
journal, January 1946
- Purcell, E. M.; Torrey, H. C.; Pound, R. V.
- Physical Review, Vol. 69, Issue 1-2, p. 37-38
Two-photon probe of the Jaynes–Cummings model and controlled symmetry breaking in circuit QED
journal, June 2008
- Deppe, Frank; Mariantoni, Matteo; Menzel, E. P.
- Nature Physics, Vol. 4, Issue 9
Coherent coupling of molecular resonators with a microcavity mode
journal, January 2015
- Shalabney, A.; George, J.; Hutchison, J.
- Nature Communications, Vol. 6, Issue 1
Strong Coupling between Plasmons and Organic Semiconductors
journal, May 2014
- Bellessa, Joel; Symonds, Clementine; Laverdant, Julien
- Electronics, Vol. 3, Issue 2
Cavity-Controlled Chemistry in Molecular Ensembles
journal, June 2016
- Herrera, Felipe; Spano, Frank C.
- Physical Review Letters, Vol. 116, Issue 23
Atoms and molecules in cavities, from weak to strong coupling in quantum-electrodynamics (QED) chemistry
journal, March 2017
- Flick, Johannes; Ruggenthaler, Michael; Appel, Heiko
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 12
Cavity polaritons in an organic single-crystalline rubrene microcavity
journal, June 2014
- Tsuchimoto, Yuta; Nagai, Hikaru; Amano, Masamitsu
- Applied Physics Letters, Vol. 104, Issue 23
Cavity Femtochemistry: Manipulating Nonadiabatic Dynamics at Avoided Crossings
journal, May 2016
- Kowalewski, Markus; Bennett, Kochise; Mukamel, Shaul
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 11
SU(1,1), SU(2), and SU(3) coherence-preserving Hamiltonians and time-ordering techniques
journal, February 1987
- Dattoli, G.; Di Lazzaro, P.; Torre, A.
- Physical Review A, Vol. 35, Issue 4
Up on the Jaynes–Cummings ladder of a quantum-dot/microcavity system
journal, March 2010
- Kasprzak, J.; Reitzenstein, S.; Muljarov, E. A.
- Nature Materials, Vol. 9, Issue 4
Modifying Chemical Landscapes by Coupling to Vacuum Fields
journal, January 2012
- Hutchison, James A.; Schwartz, Tal; Genet, Cyriaque
- Angewandte Chemie International Edition, Vol. 51, Issue 7
Superoperator nonequilibrium Green’s function theory of many-body systems; applications to charge transfer and transport in open junctions
journal, September 2008
- Harbola, U.; Mukamel, S.
- Physics Reports, Vol. 465, Issue 5
Distilling one, two and entangled pairs of photons from a quantum dot with cavity QED effects and spectral filtering
journal, February 2013
- Valle, Elena del
- New Journal of Physics, Vol. 15, Issue 2
Lie Algebraic Solution of Linear Differential Equations
journal, April 1963
- Wei, James; Norman, Edward
- Journal of Mathematical Physics, Vol. 4, Issue 4
Nonlinear optical signals and spectroscopy with quantum light
journal, December 2016
- Dorfman, Konstantin E.; Schlawin, Frank; Mukamel, Shaul
- Reviews of Modern Physics, Vol. 88, Issue 4
Optimization of photon correlations by frequency filtering
journal, April 2015
- González-Tudela, Alejandro; del Valle, Elena; Laussy, Fabrice P.
- Physical Review A, Vol. 91, Issue 4
Generalized Jaynes-Cummings models with a time-dependent atom-field coupling
journal, September 1993
- Joshi, Amitabh; Lawande, S. V.
- Physical Review A, Vol. 48, Issue 3
Two-dimensional infrared spectroscopy of vibrational polaritons of molecules in an optical cavity
journal, March 2016
- Saurabh, Prasoon; Mukamel, Shaul
- The Journal of Chemical Physics, Vol. 144, Issue 12
Cavity sideband cooling of trapped molecules
journal, September 2011
- Kowalewski, Markus; Morigi, Giovanna; Pinkse, Pepijn W. H.
- Physical Review A, Vol. 84, Issue 3
Room-temperature polariton lasing in an organic single-crystal microcavity
journal, April 2010
- Kéna-Cohen, S.; Forrest, S. R.
- Nature Photonics, Vol. 4, Issue 6
Coherence in Spontaneous Radiation Processes
journal, January 1954
- Dicke, R. H.
- Physical Review, Vol. 93, Issue 1
Influence of multi-exciton correlations on nonlinear polariton dynamics in semiconductor microcavities
journal, February 2013
- Wen, P.; Christmann, G.; Baumberg, J. J.
- New Journal of Physics, Vol. 15, Issue 2
Ultrafast all-optical switching by single photons
journal, August 2012
- Volz, Thomas; Reinhard, Andreas; Winger, Martin
- Nature Photonics, Vol. 6, Issue 9
Direct measurement of polariton–polariton interaction strength
journal, June 2017
- Sun, Yongbao; Yoon, Yoseob; Steger, Mark
- Nature Physics, Vol. 13, Issue 9
Strong light-matter coupling between a molecular vibrational mode in a PMMA film and a low-loss mid-IR microcavity: Strong light-matter coupling between a molecular vibrational mode in a PMMA film…
journal, November 2015
- Muallem, Merav; Palatnik, Alex; Nessim, Gilbert D.
- Annalen der Physik, Vol. 528, Issue 3-4
Up-conversion single-photon detector using multi-wavelength sampling techniques
journal, January 2011
- Ma, Lijun; Bienfang, Joshua C.; Slattery, Oliver
- Optics Express, Vol. 19, Issue 6
Hybrid Light–Matter States in a Molecular and Material Science Perspective
journal, October 2016
- Ebbesen, Thomas W.
- Accounts of Chemical Research, Vol. 49, Issue 11
Cavity Quantum Electrodynamics
journal, January 1989
- Haroche, Serge; Kleppner, Daniel
- Physics Today, Vol. 42, Issue 1
Exact isolated solutions for the class of quantum optical systems
journal, February 1986
- Kus, M.; Lewenstein, M.
- Journal of Physics A: Mathematical and General, Vol. 19, Issue 2
Ultrastrong Coupling of Plasmons and Excitons in a Nanoshell
journal, October 2014
- Cacciola, Adriano; Di Stefano, Omar; Stassi, Roberto
- ACS Nano, Vol. 8, Issue 11
Strong coupling between chlorosomes of photosynthetic bacteria and a confined optical cavity mode
journal, November 2014
- Coles, David M.; Yang, Yanshen; Wang, Yaya
- Nature Communications, Vol. 5, Issue 1
Quantum Interference of Tunably Indistinguishable Photons from Remote Organic Molecules
journal, March 2010
- Lettow, R.; Rezus, Y. L. A.; Renn, A.
- Physical Review Letters, Vol. 104, Issue 12
The time-dependent physical spectrum of light*
journal, January 1977
- Eberly, J. H.; Wódkiewicz, K.
- Journal of the Optical Society of America, Vol. 67, Issue 9
Time-and-frequency-gated photon coincidence counting; a novel multidimensional spectroscopy tool
journal, July 2016
- Dorfman, Konstantin E.; Mukamel, Shaul
- Physica Scripta, Vol. 91, Issue 8
Nonclassical Photon Statistics in Single-Molecule Fluorescence at Room Temperature
journal, February 2000
- Fleury, L.; Segura, J. -M.; Zumofen, G.
- Physical Review Letters, Vol. 84, Issue 6
Indistinguishability and correlations of photons generated by quantum emitters undergoing spectral diffusion
journal, February 2014
- Dorfman, Konstantin E.; Mukamel, Shaul
- Scientific Reports, Vol. 4, Issue 1
Quantum efficiency of single-photon sources in the cavity-QED strong-coupling regime
journal, January 2005
- Cui, Guoqiang; Raymer, M. G.
- Optics Express, Vol. 13, Issue 24
Comparison of quantum and semiclassical radiation theories with application to the beam maser
journal, January 1963
- Jaynes, E. T.; Cummings, F. W.
- Proceedings of the IEEE, Vol. 51, Issue 1
Optical microcavities enhance the exciton coherence length and eliminate vibronic coupling in J-aggregates
journal, May 2015
- Spano, F. C.
- The Journal of Chemical Physics, Vol. 142, Issue 18
Exact solutions to a class of Jahn-Teller systems
journal, May 1979
- Judd, B. R.
- Journal of Physics C: Solid State Physics, Vol. 12, Issue 9
Optical multidimensional coherent spectroscopy
journal, July 2013
- Cundiff, Steven T.; Mukamel, Shaul
- Physics Today, Vol. 66, Issue 7
Vacuum-stimulated cooling of single atoms in three dimensions
journal, October 2005
- Nußmann, Stefan; Murr, Karim; Hijlkema, Markus
- Nature Physics, Vol. 1, Issue 2
Algebraic treatment of the time-dependent Jaynes–Cummings Hamiltonian including nonlinear terms
journal, August 2012
- Cordero, Sergio; Récamier, José
- Journal of Physics A: Mathematical and Theoretical, Vol. 45, Issue 38
Spanning Strong to Weak Normal Mode Coupling between Vibrational and Fabry–Pérot Cavity Modes through Tuning of Vibrational Absorption Strength
journal, September 2015
- Simpkins, B. S.; Fears, Kenan P.; Dressick, Walter J.
- ACS Photonics, Vol. 2, Issue 10
Tracking the ultrafast motion of a single molecule by femtosecond orbital imaging
journal, November 2016
- Cocker, Tyler L.; Peller, Dominik; Yu, Ping
- Nature, Vol. 539, Issue 7628
Theory of Frequency-Filtered and Time-Resolved -Photon Correlations
journal, October 2012
- del Valle, E.; Gonzalez-Tudela, A.; Laussy, F. P.
- Physical Review Letters, Vol. 109, Issue 18
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