Coordination Nature of 4-Mercaptoaniline to Sn(II) Ion: Formation of a One Dimensional Coordination Polymer and Its Decomposition to a Mono Nuclear Sn(IV) Complex

Burkett, Eon; Siddiquee, Tasneem

doi:10.3390/inorganics2040652

Title: Coordination Nature of 4-Mercaptoaniline to Sn(II) Ion: Formation of a One Dimensional Coordination Polymer and Its Decomposition to a Mono Nuclear Sn(IV) Complex

Journal Article · 08 December 2014 · Inorganics

DOI: https://doi.org/10.3390/inorganics2040652 · OSTI ID:1418857

Burkett, Eon; Siddiquee, Tasneem

The coordination of the bifunctional ligand 4-mercaptoaniline with aqueo us tin(II) metal ion was studied. A coordination polymer was synthesized when an aqueous solution of SnCl2 was treated with 4-MA. The crystalline material is stable under atmospheric conditions retaining its oxidation state. However, when submerged in a solution saturated with oxygen, the compound oxidizes to a mononuclear tin(IV) complex. Both the compounds were characterized by single crystal X-ray diffraction studies. Although the structure of the tin(IV) complex was previously reported, crystal structure of this compound was redetermined.

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Sponsoring Organization:: USDOE

OSTI ID:: 1418857

Journal Information:: Inorganics, Journal Name: Inorganics Journal Issue: 4 Vol. 2; ISSN 2304-6740; ISSN INORCW

Publisher:: MDPI AGCopyright Statement

Country of Publication:: Switzerland

Language:: English

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