Understanding the structure–property relationships of the ferroelectric to relaxor transition of the (1-x)BaTiO3–(x)BiInO3 lead-free piezoelectric system
Abstract
A structural and electromechanical investigation has been performed on (1-x)BaTiO3–(x)BiInO3 in the region 0.03 ≤ x ≤ 0.12. A gradual structural phase transition has been observed where the structure changes from tetragonal (P4mm) and passes through two regions of coexisting phases: (1) P4mm + R3m in the range 0.03 ≤ x ≤ 0.075 and (2) Pm$$\bar{3}$$m + R3m for 0.10 ≤ x ≤ 0.12. The properties also transition from ferroelectric (x ≤ 0.03) to relaxor ferroelectric (x ≥ 0.05) as the dielectric permittivity maximum becomes temperature and frequency dependent. This transition was also confirmed via polarization-electric field measurements as well as strain-electric field measurements. At the critical composition of x = 0.065, a moderate strain of ~0.104% and an effective piezoelectric coefficient (d$$*\atop{33}$$) of 260 pm/V were observed. Finally, the original purpose of this study was to demonstrate the polarization extension mechanism as predicted in the literature, but due to the ferroelectric to relaxor transition, this mechanism was not found to be present in this system. However, this demonstrates that BaTiO3-based lead-free ceramics could be modified to obtain enhanced electromechanical properties for actuator applications.
- Authors:
-
- Oregon State Univ., Corvallis, OR (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Oregon State Univ., Corvallis, OR (United States)
- Sponsoring Org.:
- National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1418520
- Grant/Contract Number:
- AC02-06CH11357; DMR- 1606909
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Science
- Additional Journal Information:
- Journal Volume: 52; Journal Issue: 9; Journal ID: ISSN 0022-2461
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Manjón-Sanz, Alicia, Berger, Caitlin, and Dolgos, Michelle R. Understanding the structure–property relationships of the ferroelectric to relaxor transition of the (1-x)BaTiO3–(x)BiInO3 lead-free piezoelectric system. United States: N. p., 2017.
Web. doi:10.1007/s10853-017-0770-x.
Manjón-Sanz, Alicia, Berger, Caitlin, & Dolgos, Michelle R. Understanding the structure–property relationships of the ferroelectric to relaxor transition of the (1-x)BaTiO3–(x)BiInO3 lead-free piezoelectric system. United States. https://doi.org/10.1007/s10853-017-0770-x
Manjón-Sanz, Alicia, Berger, Caitlin, and Dolgos, Michelle R. Mon .
"Understanding the structure–property relationships of the ferroelectric to relaxor transition of the (1-x)BaTiO3–(x)BiInO3 lead-free piezoelectric system". United States. https://doi.org/10.1007/s10853-017-0770-x. https://www.osti.gov/servlets/purl/1418520.
@article{osti_1418520,
title = {Understanding the structure–property relationships of the ferroelectric to relaxor transition of the (1-x)BaTiO3–(x)BiInO3 lead-free piezoelectric system},
author = {Manjón-Sanz, Alicia and Berger, Caitlin and Dolgos, Michelle R.},
abstractNote = {A structural and electromechanical investigation has been performed on (1-x)BaTiO3–(x)BiInO3 in the region 0.03 ≤ x ≤ 0.12. A gradual structural phase transition has been observed where the structure changes from tetragonal (P4mm) and passes through two regions of coexisting phases: (1) P4mm + R3m in the range 0.03 ≤ x ≤ 0.075 and (2) Pm$\bar{3}$m + R3m for 0.10 ≤ x ≤ 0.12. The properties also transition from ferroelectric (x ≤ 0.03) to relaxor ferroelectric (x ≥ 0.05) as the dielectric permittivity maximum becomes temperature and frequency dependent. This transition was also confirmed via polarization-electric field measurements as well as strain-electric field measurements. At the critical composition of x = 0.065, a moderate strain of ~0.104% and an effective piezoelectric coefficient (d$*\atop{33}$) of 260 pm/V were observed. Finally, the original purpose of this study was to demonstrate the polarization extension mechanism as predicted in the literature, but due to the ferroelectric to relaxor transition, this mechanism was not found to be present in this system. However, this demonstrates that BaTiO3-based lead-free ceramics could be modified to obtain enhanced electromechanical properties for actuator applications.},
doi = {10.1007/s10853-017-0770-x},
journal = {Journal of Materials Science},
number = 9,
volume = 52,
place = {United States},
year = {Mon May 01 00:00:00 EDT 2017},
month = {Mon May 01 00:00:00 EDT 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 8 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Compositionally driven ferroelectric phase transition in xBiInO3–(1−x)BaTiO3: a lead-free perovskite-based piezoelectric material
journal, May 2010
- Datta, K.; Suard, E.; Thomas, P. A.
- Applied Physics Letters, Vol. 96, Issue 22
Factors influencing the piezoelectric behaviour of PZT and other “morphotropic phase boundary” ferroelectrics
journal, January 2006
- Bell, Andrew J.
- Journal of Materials Science, Vol. 41, Issue 1
Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics
journal, January 2000
- Fu, Huaxiang; Cohen, Ronald E.
- Nature, Vol. 403, Issue 6767
Comments on Origins of Enhanced Piezoelectric Properties in Ferroelectrics
journal, August 2009
- Damjanovic, D.; Damjanovic, Dragan; Damjanovic, Dragan
- IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control, Vol. 56, Issue 8
Perspective on the Development of Lead-free Piezoceramics
journal, June 2009
- Rödel, Jürgen; Jo, Wook; Seifert, Klaus T. P.
- Journal of the American Ceramic Society, Vol. 92, Issue 6
Whole-profile structure solution from powder diffraction data using simulated annealing
journal, June 2000
- Coelho, A. A.
- Journal of Applied Crystallography, Vol. 33, Issue 3
Origin of the Anomalous Piezoelectric Response in Wurtzite Alloys
journal, April 2010
- Tasnádi, Ferenc; Alling, Björn; Höglund, Carina
- Physical Review Letters, Vol. 104, Issue 13
First-principles study of the structure, electronic, and optical properties of orthorhombic BiInO3
journal, August 2007
- Li, Chenliang; Wang, Hai; Wang, Biao
- Applied Physics Letters, Vol. 91, Issue 7
Preparation and Characterization of High Temperature Perovskite Ferroelectrics in the Solid-Solution (1- x )BiScO 3 – x PbTiO 3
journal, April 2002
- Eitel, Richard E.; Randall, Clive A.; Shrout, Thomas R.
- Japanese Journal of Applied Physics, Vol. 41, Issue Part 1, No. 4A
Enhancement of Piezoelectric Response in Scandium Aluminum Nitride Alloy Thin Films Prepared by Dual Reactive Cosputtering
journal, December 2008
- Akiyama, Morito; Kamohara, Toshihiro; Kano, Kazuhiko
- Advanced Materials, Vol. 21, Issue 5
Phenomenological model of anisotropic peak broadening in powder diffraction
journal, April 1999
- Stephens, Peter W.
- Journal of Applied Crystallography, Vol. 32, Issue 2
Nanoscale ferroelectric/relaxor composites: Origin of large strain in lead–free Bi–based incipient piezoelectric ceramics
journal, November 2016
- Dinh, Thi Hinh; Kang, Jin-Kyu; Lee, Jae-Shin
- Journal of the European Ceramic Society, Vol. 36, Issue 14
Lead-free piezoelectric ceramics: Alternatives for PZT?
journal, February 2007
- Shrout, Thomas R.; Zhang, Shujun J.
- Journal of Electroceramics, Vol. 19, Issue 1
Local structure and evolution of relaxor behavior in BaTiO3–Bi(Zn0.5Ti0.5)O3 ceramics
journal, November 2014
- Bootchanont, Atipong; Triamnak, Narit; Rujirawat, Saroj
- Ceramics International, Vol. 40, Issue 9
Review: environmental friendly lead-free piezoelectric materials
journal, October 2009
- Panda, P. K.
- Journal of Materials Science, Vol. 44, Issue 19
BiInO 3 : A Polar Oxide with GdFeO 3 -Type Perovskite Structure
journal, April 2006
- Belik, Alexei A.; Stefanovich, Sergey Yu.; Lazoryak, Bogdan I.
- Chemistry of Materials, Vol. 18, Issue 7
Contributions to the Piezoelectric Effect in Ferroelectric Single Crystals and Ceramics
journal, October 2005
- Damjanovic, Dragan
- Journal of the American Ceramic Society, Vol. 88, Issue 10
High-pressure synthesis and ferroelectric properties in perovskite-type BiScO3–PbTiO3 solid solution
journal, January 2004
- Inaguma, Yoshiyuki; Miyaguchi, Atsushi; Yoshida, Masashi
- Journal of Applied Physics, Vol. 95, Issue 1
Weakly Coupled Relaxor Behavior of BaTiO 3 -BiScO 3 Ceramics
journal, January 2009
- Ogihara, Hideki; Randall, Clive A.; Trolier-McKinstry, Susan
- Journal of the American Ceramic Society, Vol. 92, Issue 1
Origin of the High Piezoelectric Response in
journal, June 2000
- Guo, R.; Cross, L. E.; Park, S-E.
- Physical Review Letters, Vol. 84, Issue 23
Phase evolution and correlation between tolerance factor and electromechanical properties in BNT-based ternary perovskite compounds with calculated end-member Bi(Me 0.5 Ti 0.5 )O 3 (Me = Zn, Mg, Ni, Co)
journal, January 2016
- Bai, Wangfeng; Shen, Bo; Zhai, Jiwei
- Dalton Transactions, Vol. 45, Issue 36
New High Temperature Morphotropic Phase Boundary Piezoelectrics Based on Bi(Me)O 3 –PbTiO 3 Ceramics
journal, October 2001
- Eitel, Richard E.; Randall, Clive A.; Shrout, Thomas R.
- Japanese Journal of Applied Physics, Vol. 40, Issue Part 1, No. 10
Composition- and temperature-driven phase transition characteristics and associated electromechanical properties in Bi 0.5 Na 0.5 TiO 3 -based lead-free ceramics
journal, January 2016
- Bai, Wangfeng; Chen, Daqin; Zheng, Peng
- Dalton Transactions, Vol. 45, Issue 20
What can be Expected from Lead-Free Piezoelectric Materials?
journal, March 2010
- Damjanovic, Dragan; Klein, Naama; Li, Jin
- Functional Materials Letters, Vol. 03, Issue 01
Giant electric-field-induced strains in lead-free ceramics for actuator applications – status and perspective
journal, May 2012
- Jo, Wook; Dittmer, Robert; Acosta, Matias
- Journal of Electroceramics, Vol. 29, Issue 1
High temperature electronic properties of BaTiO3 – Bi(Zn1/2Ti1/2)O3 – BiInO3 for capacitor applications
journal, March 2012
- Raengthon, Natthaphon; Cann, David P.
- Journal of Electroceramics, Vol. 28, Issue 2-3
Structural, dielectric, and ferroelectric properties of the (1ߝx)PbTiO 3 -xBiAlO 3 solid solution
journal, October 2010
- Huichun Yu,
- IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control, Vol. 57, Issue 10
Piezoelectric Ceramics
journal, November 1958
- Jaffe, Hans
- Journal of the American Ceramic Society, Vol. 41, Issue 11
A dedicated powder diffraction beamline at the Advanced Photon Source: Commissioning and early operational results
journal, August 2008
- Wang, Jun; Toby, Brian H.; Lee, Peter L.
- Review of Scientific Instruments, Vol. 79, Issue 8
High Curie temperature perovskite BiInO 3 –PbTiO 3 ceramics
journal, July 2004
- Duan, Runrun; Speyer, Robert F.; Alberta, Edward
- Journal of Materials Research, Vol. 19, Issue 7
A morphotropic phase boundary system based on polarization rotation and polarization extension
journal, August 2010
- Damjanovic, Dragan
- Applied Physics Letters, Vol. 97, Issue 6
Electrostrictive and relaxor ferroelectric behavior in BiAlO 3 -modified BaTiO 3 lead-free ceramics
journal, March 2013
- Zheng, Shaoying; Odendo, Erika; Liu, Laijun
- Journal of Applied Physics, Vol. 113, Issue 9
A Pure Bismuth A Site Polar Perovskite Synthesized at Ambient Pressure
journal, November 2007
- Bridges, Craig A.; Allix, Mathieu; Suchomel, Matthew R.
- Angewandte Chemie International Edition, Vol. 46, Issue 46
Large piezoelectricity and dielectric permittivity in BaTiO 3 -xBaSnO 3 system: The role of phase coexisting
journal, April 2012
- Yao, Yonggang; Zhou, Chao; Lv, Duchao
- EPL (Europhysics Letters), Vol. 98, Issue 2
Works referencing / citing this record:
Low temperature synthesis route and structural characterization of (Bi 0.5 A 0.5 )(Sc 0.5 Nb 0.5 )O 3 ( A = K + and Na + ) perovskites
journal, January 2018
- Surta, T. Wesley; Manjón-Sanz, Alicia; Qian, Eric
- Inorganic Chemistry Frontiers, Vol. 5, Issue 5