Reversible control of magnetism in La0.67Sr0.33MnO3 through chemically-induced oxygen migration

Grutter, A. J.; Gilbert, D. A.; Alaan, U. S.; Arenholz, E.; Maranville, B. B.; Borchers, J. A.; Suzuki, Y.; Liu, Kai; Kirby, B. J.

doi:10.1063/1.4942645

Title: Reversible control of magnetism in La_0.67Sr_0.33MnO₃ through chemically-induced oxygen migration

Abstract

We demonstrate reversible control of magnetization and anisotropy in La_0.67Sr_0.33MnO₃ films through interfacial oxygen migration. Gd metal capping layers deposited onto La_0.67Sr_0.33MnO₃ leach oxygen from the film through a solid-state redox reaction to form porous Gd₂O₃. X-ray absorption and polarized neutron reflectometry measurements show Mn valence alterations consistent with high oxygen vacancy concentrations, resulting in suppressed magnetization and increased coercive fields. Effects of the oxygen migration are observed both at the interface and also throughout the majority of a 40 nm thick film, suggesting extensive diffusion of oxygen vacancies. After Gd-capped La_0.67Sr_0.33MnO₃ is exposed to atmospheric oxygen for a prolonged period of time, oxygen diffuses through the Gd₂O₃ layer and the magnetization of the La_0.67Sr_0.33MnO₃ returns to the uncapped value. In conclusion, these findings showcase perovskite heterostructures as ideal candidates for developing functional interfaces through chemically-induced oxygen migration.

Authors:

Grutter, A. J. ^[1];

^[1];

^[2]; Arenholz, E. ^[3];

^[1]; Borchers, J. A. ^[1]; Suzuki, Y. ^[4];

^[5]; Kirby, B. J. ^[1]

National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
Stanford Univ., CA (United States). Dept. of Materials Science and Engineering; Stanford Univ., CA (United States). Geballe Lab. for Advanced Materials
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Stanford Univ., CA (United States). Geballe Lab. for Advanced Materials; Stanford Univ., CA (United States). Dept. of Applied Physics
Univ. of California, Davis, CA (United States). Dept. of Physics

Publication Date:: 2016-02-22

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1418493

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Applied Physics Letters

Additional Journal Information:: Journal Volume: 108; Journal Issue: 8; Journal ID: ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Grutter, A. J., Gilbert, D. A., Alaan, U. S., Arenholz, E., Maranville, B. B., Borchers, J. A., Suzuki, Y., Liu, Kai, and Kirby, B. J. Reversible control of magnetism in La0.67Sr0.33MnO3 through chemically-induced oxygen migration.  United States: N. p., 2016. 
Web.  doi:10.1063/1.4942645.

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                    Grutter, A. J., Gilbert, D. A., Alaan, U. S., Arenholz, E., Maranville, B. B., Borchers, J. A., Suzuki, Y., Liu, Kai, & Kirby, B. J. Reversible control of magnetism in La0.67Sr0.33MnO3 through chemically-induced oxygen migration.  United States.  https://doi.org/10.1063/1.4942645

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                    Grutter, A. J., Gilbert, D. A., Alaan, U. S., Arenholz, E., Maranville, B. B., Borchers, J. A., Suzuki, Y., Liu, Kai, and Kirby, B. J. Mon .  
"Reversible control of magnetism in La0.67Sr0.33MnO3 through chemically-induced oxygen migration".  United States.  https://doi.org/10.1063/1.4942645.  https://www.osti.gov/servlets/purl/1418493.

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@article{osti_1418493,

  title        = {Reversible control of magnetism in La0.67Sr0.33MnO3 through chemically-induced oxygen migration},

  author       = {Grutter, A. J. and Gilbert, D. A. and Alaan, U. S. and Arenholz, E. and Maranville, B. B. and Borchers, J. A. and Suzuki, Y. and Liu, Kai and Kirby, B. J.},

  abstractNote = {We demonstrate reversible control of magnetization and anisotropy in La0.67Sr0.33MnO3 films through interfacial oxygen migration. Gd metal capping layers deposited onto La0.67Sr0.33MnO3 leach oxygen from the film through a solid-state redox reaction to form porous Gd2O3. X-ray absorption and polarized neutron reflectometry measurements show Mn valence alterations consistent with high oxygen vacancy concentrations, resulting in suppressed magnetization and increased coercive fields. Effects of the oxygen migration are observed both at the interface and also throughout the majority of a 40 nm thick film, suggesting extensive diffusion of oxygen vacancies. After Gd-capped La0.67Sr0.33MnO3 is exposed to atmospheric oxygen for a prolonged period of time, oxygen diffuses through the Gd2O3 layer and the magnetization of the La0.67Sr0.33MnO3 returns to the uncapped value. In conclusion, these findings showcase perovskite heterostructures as ideal candidates for developing functional interfaces through chemically-induced oxygen migration.},

  doi          = {10.1063/1.4942645},

  journal      = {Applied Physics Letters},

  number       = 8,

  volume       = 108,

  place        = {United States},

  year         = {2016},

  month        = {2}

}

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Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides
journal, May 2013

High-quality EuO thin films the easy way via topotactic transformation
journal, July 2015

Reversible Control of Co Magnetism by Voltage-Induced Oxidation
journal, December 2014

Magnetism at the interface between ferromagnetic and superconducting oxides
journal, April 2006

Metal-Insulator Transition and Its Relation to Magnetic Structure in $({LaMnO}_{3})_{2 n} / ({SrMnO}_{3})_{n}$ Superlattices
journal, June 2008

Control of the magnetic and magnetotransport properties of La0.67Sr0.33MnO3 thin films through epitaxial strain
journal, April 2008

EELS analysis of cation valence states and oxygen vacancies in magnetic oxides
journal, October 2000

Interfacial Ferromagnetism in ${LaNiO}_{3} / {CaMnO}_{3}$ Superlattices
journal, August 2013

Structural phases driven by oxygen vacancies at the La _0.7 Sr _0.3 MnO ₃ /SrTiO ₃ hetero-interface
journal, January 2015

Role of oxygen vacancies in resistive switching in Pt/Nb-doped SrTiO ₃
journal, November 2014

SOFT X-RAY ABSORPTION SPECTROSCOPY (Mn L _2,3 AND O K) IN MIXED VALENCE MANGANITES
journal, April 2002

Magneto-ionic control of interfacial magnetism
journal, November 2014

Oxygen vacancy migration in compressively strained SrTiO ₃
journal, January 2013

Flux penetration measurements and the harmonic magnetic response of hot isostatically pressed (Pb,Gd)Mo6S8
journal, April 1999

Oxygen content of La1−xSrxMnO3−y thin films and its relation to electric-magnetic properties
journal, April 2006

Mechanism of the Switchable Photovoltaic Effect in Ferroelectric BiFeO3
journal, June 2011

Evidence of direct correlation between out-of-plane lattice parameter and metal-insulator transition temperature in oxygen-depleted manganite thin films
journal, January 2012

Charge transfer and interfacial magnetism in (LaNiO $_{3}$ ) $_{n}$ /(LaMnO $_{3}$ ) $_{2}$ superlattices
journal, October 2013

Colossal Ionic Conductivity at Interfaces of Epitaxial ZrO2:Y2O3/SrTiO3 Heterostructures
journal, August 2008

Exchange bias in LaNiO3–LaMnO3 superlattices
journal, January 2012

Electronic band structure information of GdN extracted from x-ray absorption and emission spectroscopy
journal, January 2010

Tuning the entanglement between orbital reconstruction and charge transfer at a film surface
journal, February 2014

Orientation and thickness dependence of magnetization at the interfaces of highly spin-polarized manganite thin films
journal, March 2009

Stabilization of spin-zero Ru $^{4 +}$ through epitaxial strain in SrRuO $_{3}$ thin films
journal, December 2013

Modulation of resistance switching in Au/Nb:SrTiO ₃ Schottky junctions by ambient oxygen
journal, December 2012

Oxidation states of Mn and Fe in various compound oxide systems
journal, July 2006

The Effects of Gadolinium Incorporation Into Indium–Zinc–Oxide Thin-Film Transistors
journal, June 2012

Phase-sensitive specular neutron reflectometry for imaging the nanometer scale composition depth profile of thin-film materials
journal, February 2012

Magnetically asymmetric interfaces in a ${LaMnO}_{3} / {SrMnO}_{3}$ superlattice due to structural asymmetries
journal, May 2008

Influence of alkylphosphonic acid grafting on the electronic and magnetic properties of La2/3Sr1/3MnO3 surfaces
journal, October 2015

Interfacial Ferromagnetism and Exchange Bias in ${CaRuO}_{3} / {CaMnO}_{3}$ Superlattices
journal, November 2012

Determination of absorption coefficients for concentrated samples by fluorescence detection
journal, June 1993

Voltage‐Control of Magnetism in All‐Solid‐State and Solid/Liquid Magnetoelectric Composites
journal, February 2019

Engineering Oxygen Migration for Homogeneous Volume Resistive Switching in 3‐Terminal Devices
journal, November 2018

Peroxide Yield of the (001) La _0.6 Sr _0.4 MnO ₃ Surface as a Bifunctional Electrocatalyst for the Oxygen Reduction Reaction and Oxygen Evolution Reaction in Alkaline Media
journal, January 2019

Tunable Magnetism in Nanoporous CuNi Alloys by Reversible Voltage-Driven Element-Selective Redox Processes
journal, April 2018

Magneto-ionic control of magnetism using a solid-state proton pump
journal, November 2018

Electrolyte-gated magnetoelectric actuation: Phenomenology, materials, mechanisms, and prospective applications
journal, March 2019

Effect of oxygen stoichiometry on the magnetization profiles and negative magnetization in LSMO thin films
journal, September 2019

Superconductivity-driven negative interfacial magnetization in YBa ₂ Cu ₃ O _7−δ /SrTiO ₃ /La _0.67 Sr _0.33 MnO ₃ heterostructures
journal, January 2020

Voltage-Control of Magnetism in All-Solid-State and Solid/Liquid Magnetoelectric Composites
text, January 2019