Tuning of Polyoxopalladate Macroanionic Hydration Shell via Countercation Interaction
Abstract
Abstract Three types of macroanion–countercation interactions in dilute solution, decided by the strength of electrostatic attraction and the change of hydration shells are reported: minor interaction between macroanions [MO 8 Pd 12 (SeO 3 ) 8 ] 6− (M=Zn 2+ or Ni 2+ ) and monovalent cations (Na + , K + , Rb + , Cs + ), leaving their hydration shells intact (solvent‐separated ion‐pairs); strong binding between macroanions and divalent cations (Sr 2+ , Ba 2+ ) to form solvent‐shared ion‐pairs with partial dehydration; very strong electrostatic attraction between macroanions and Y 3+ ion with contact ion‐pairs formation by severely breaking their original hydration shells and forming new ones. In addition, divalent cations can help the macroanions self‐assemble into hollow spherical blackberry structures through counterion‐mediated attraction, whereas macroanions with mono‐ or trivalent cations only stay as discrete ions due to either weak interaction or a small number of bound countercations.
- Authors:
-
[1];
[1]
- The Univ. of Akron, Akron, OH (United States)
- Jacobs Univ., Bremen (Germany)
- Northern Illinois Univ., DeKalb, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- University of Akron; National Science Foundation (NSF); German Research Foundation (DFG); Jacobs University Bremen gGmbH; USDOE
- OSTI Identifier:
- 1471520
- Alternate Identifier(s):
- OSTI ID: 1418418
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Volume: 24; Journal Issue: 12; Journal ID: ISSN 0947-6539
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; hydration shell; ion pair; macroion; polypalladate; thermodynamics
Citation Formats
He, Jiazhi, Li, Hui, Yang, Peng, Haso, Fadi, Wu, Jiayingzi, Li, Tao, Kortz, Ulrich, and Liu, Tianbo. Tuning of Polyoxopalladate Macroanionic Hydration Shell via Countercation Interaction. United States: N. p., 2017.
Web. doi:10.1002/chem.201705873.
He, Jiazhi, Li, Hui, Yang, Peng, Haso, Fadi, Wu, Jiayingzi, Li, Tao, Kortz, Ulrich, & Liu, Tianbo. Tuning of Polyoxopalladate Macroanionic Hydration Shell via Countercation Interaction. United States. https://doi.org/10.1002/chem.201705873
He, Jiazhi, Li, Hui, Yang, Peng, Haso, Fadi, Wu, Jiayingzi, Li, Tao, Kortz, Ulrich, and Liu, Tianbo. Sat .
"Tuning of Polyoxopalladate Macroanionic Hydration Shell via Countercation Interaction". United States. https://doi.org/10.1002/chem.201705873. https://www.osti.gov/servlets/purl/1471520.
@article{osti_1471520,
title = {Tuning of Polyoxopalladate Macroanionic Hydration Shell via Countercation Interaction},
author = {He, Jiazhi and Li, Hui and Yang, Peng and Haso, Fadi and Wu, Jiayingzi and Li, Tao and Kortz, Ulrich and Liu, Tianbo},
abstractNote = {Abstract Three types of macroanion–countercation interactions in dilute solution, decided by the strength of electrostatic attraction and the change of hydration shells are reported: minor interaction between macroanions [MO 8 Pd 12 (SeO 3 ) 8 ] 6− (M=Zn 2+ or Ni 2+ ) and monovalent cations (Na + , K + , Rb + , Cs + ), leaving their hydration shells intact (solvent‐separated ion‐pairs); strong binding between macroanions and divalent cations (Sr 2+ , Ba 2+ ) to form solvent‐shared ion‐pairs with partial dehydration; very strong electrostatic attraction between macroanions and Y 3+ ion with contact ion‐pairs formation by severely breaking their original hydration shells and forming new ones. In addition, divalent cations can help the macroanions self‐assemble into hollow spherical blackberry structures through counterion‐mediated attraction, whereas macroanions with mono‐ or trivalent cations only stay as discrete ions due to either weak interaction or a small number of bound countercations.},
doi = {10.1002/chem.201705873},
journal = {Chemistry - A European Journal},
number = 12,
volume = 24,
place = {United States},
year = {Sat Dec 23 00:00:00 EST 2017},
month = {Sat Dec 23 00:00:00 EST 2017}
}
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