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Title: Solid Electrolyte Layers by Solution Deposition

Abstract

Abstract Solid state batteries hold the promise of enhanced safety and higher energy density over conventional lithium‐ion batteries with flammable organic electrolytes. However, advancement of solid electrolyte materials has yet to translate into practical batteries due to the need to process the powders into thin sheets with high pressure compaction and high temperature sintering. Here, a new strategy is developed for synthesizing sulfide‐based solid electrolyte using low‐temperature solution processing, which is a simple and potentially cost‐effective way to make a thin solid electrolyte layer. By controlling the stoichiometric ratio of Li 2 S and S, soluble polysulfides are produced in diethylene glycol dimethyl ether, which are reacted with P 2 S 5 to form a conductive Li 3 PS 4 solid electrolyte. It is demonstrated that a dense solid electrolyte layer can be directly formed on Li metal with a high quality electrolyte/electrode interface, producing a solid electrolyte with promising electrochemical performance. Also, first‐principles calculations are conducted to elucidate the formation mechanisms behind the soluble intermediates and the solid electrolyte layers.

Authors:
 [1];  [2];  [1];  [1];  [1];  [1];  [2];  [1]
+ Show Author Affiliations
  1. Department of Nanoengineering University of California, San Diego La Jolla CA 92093 USA
  2. Graduate School of Energy Environment Water Sustainability (EEWS) Korea Advanced Institute of Science and Technology (KAIST) 291 Daehak‐ro Yuseong‐gu Daejeon 34141 Republic of Korea
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1418180
Grant/Contract Number:  
DE‐AR0000781
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Materials Interfaces
Additional Journal Information:
Journal Name: Advanced Materials Interfaces Journal Volume: 5 Journal Issue: 8; Journal ID: ISSN 2196-7350
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Lim, Hee‐Dae, Lim, Hyung‐Kyu, Xing, Xing, Lee, Byoung‐Sun, Liu, Haodong, Coaty, Christopher, Kim, Hyungjun, and Liu, Ping. Solid Electrolyte Layers by Solution Deposition. Germany: N. p., 2018. Web. doi:10.1002/admi.201701328.
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Lim, Hee‐Dae, Lim, Hyung‐Kyu, Xing, Xing, Lee, Byoung‐Sun, Liu, Haodong, Coaty, Christopher, Kim, Hyungjun, & Liu, Ping. Solid Electrolyte Layers by Solution Deposition. Germany. https://doi.org/10.1002/admi.201701328
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Lim, Hee‐Dae, Lim, Hyung‐Kyu, Xing, Xing, Lee, Byoung‐Sun, Liu, Haodong, Coaty, Christopher, Kim, Hyungjun, and Liu, Ping. Fri . "Solid Electrolyte Layers by Solution Deposition". Germany. https://doi.org/10.1002/admi.201701328.
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@article{osti_1418180,
title = {Solid Electrolyte Layers by Solution Deposition},
author = {Lim, Hee‐Dae and Lim, Hyung‐Kyu and Xing, Xing and Lee, Byoung‐Sun and Liu, Haodong and Coaty, Christopher and Kim, Hyungjun and Liu, Ping},
abstractNote = {Abstract Solid state batteries hold the promise of enhanced safety and higher energy density over conventional lithium‐ion batteries with flammable organic electrolytes. However, advancement of solid electrolyte materials has yet to translate into practical batteries due to the need to process the powders into thin sheets with high pressure compaction and high temperature sintering. Here, a new strategy is developed for synthesizing sulfide‐based solid electrolyte using low‐temperature solution processing, which is a simple and potentially cost‐effective way to make a thin solid electrolyte layer. By controlling the stoichiometric ratio of Li 2 S and S, soluble polysulfides are produced in diethylene glycol dimethyl ether, which are reacted with P 2 S 5 to form a conductive Li 3 PS 4 solid electrolyte. It is demonstrated that a dense solid electrolyte layer can be directly formed on Li metal with a high quality electrolyte/electrode interface, producing a solid electrolyte with promising electrochemical performance. Also, first‐principles calculations are conducted to elucidate the formation mechanisms behind the soluble intermediates and the solid electrolyte layers.},
doi = {10.1002/admi.201701328},
journal = {Advanced Materials Interfaces},
number = 8,
volume = 5,
place = {Germany},
year = {Fri Jan 26 00:00:00 EST 2018},
month = {Fri Jan 26 00:00:00 EST 2018}
}
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Journal Article:
Free Publicly Available Full Text
Accepted Manuscript (Publisher)
Publisher's Version of Record
https://doi.org/10.1002/admi.201701328
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