High magnesium mobility in ternary spinel chalcogenides
Abstract
Magnesium batteries appear a viable alternative to overcome the safety and energy density limitations faced by current lithium-ion technology. The development of a competitive magnesium battery is plagued by the existing notion of poor magnesium mobility in solids. Here we demonstrate by using ab initio calculations, nuclear magnetic resonance, and impedance spectroscopy measurements that substantial magnesium ion mobility can indeed be achieved in close-packed frameworks (similar to 0.01-0.1 mS cm(-1) at 298 K), specifically in the magnesium scandium selenide spinel. Our theoretical predictions also indicate that high magnesium ion mobility is possible in other chalcogenide spinels, opening the door for the realization of other magnesium solid ionic conductors and the eventual development of an all-solid-state magnesium battery.
- Authors:
-
[1];
[3];
[6];
[7];
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering; Shanghai Jiao Tong Univ. (China). Shanghai Jiao Tong Univ. Joint Inst.
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering; Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering
- Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering
- Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science - Office of Basic Energy Sciences - Joint Center for Energy Storage Research (JCESR)
- OSTI Identifier:
- 1417619
- Alternate Identifier(s):
- OSTI ID: 1427174
- Grant/Contract Number:
- AC02-05CH11231; AC02-06CH11357; 3F-31144
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; batteries
Citation Formats
Canepa, Pieremanuele, Bo, Shou-Hang, Sai Gautam, Gopalakrishnan, Key, Baris, Richards, William D., Shi, Tan, Tian, Yaosen, Wang, Yan, Li, Juchuan, and Ceder, Gerbrand. High magnesium mobility in ternary spinel chalcogenides. United States: N. p., 2017.
Web. doi:10.1038/s41467-017-01772-1.
Canepa, Pieremanuele, Bo, Shou-Hang, Sai Gautam, Gopalakrishnan, Key, Baris, Richards, William D., Shi, Tan, Tian, Yaosen, Wang, Yan, Li, Juchuan, & Ceder, Gerbrand. High magnesium mobility in ternary spinel chalcogenides. United States. https://doi.org/10.1038/s41467-017-01772-1
Canepa, Pieremanuele, Bo, Shou-Hang, Sai Gautam, Gopalakrishnan, Key, Baris, Richards, William D., Shi, Tan, Tian, Yaosen, Wang, Yan, Li, Juchuan, and Ceder, Gerbrand. Fri .
"High magnesium mobility in ternary spinel chalcogenides". United States. https://doi.org/10.1038/s41467-017-01772-1. https://www.osti.gov/servlets/purl/1417619.
@article{osti_1417619,
title = {High magnesium mobility in ternary spinel chalcogenides},
author = {Canepa, Pieremanuele and Bo, Shou-Hang and Sai Gautam, Gopalakrishnan and Key, Baris and Richards, William D. and Shi, Tan and Tian, Yaosen and Wang, Yan and Li, Juchuan and Ceder, Gerbrand},
abstractNote = {Magnesium batteries appear a viable alternative to overcome the safety and energy density limitations faced by current lithium-ion technology. The development of a competitive magnesium battery is plagued by the existing notion of poor magnesium mobility in solids. Here we demonstrate by using ab initio calculations, nuclear magnetic resonance, and impedance spectroscopy measurements that substantial magnesium ion mobility can indeed be achieved in close-packed frameworks (similar to 0.01-0.1 mS cm(-1) at 298 K), specifically in the magnesium scandium selenide spinel. Our theoretical predictions also indicate that high magnesium ion mobility is possible in other chalcogenide spinels, opening the door for the realization of other magnesium solid ionic conductors and the eventual development of an all-solid-state magnesium battery.},
doi = {10.1038/s41467-017-01772-1},
journal = {Nature Communications},
number = 1,
volume = 8,
place = {United States},
year = {2017},
month = {11}
}
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