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Title: High magnesium mobility in ternary spinel chalcogenides

Abstract

Magnesium batteries appear a viable alternative to overcome the safety and energy density limitations faced by current lithium-ion technology. The development of a competitive magnesium battery is plagued by the existing notion of poor magnesium mobility in solids. Here we demonstrate by using ab initio calculations, nuclear magnetic resonance, and impedance spectroscopy measurements that substantial magnesium ion mobility can indeed be achieved in close-packed frameworks (similar to 0.01-0.1 mS cm(-1) at 298 K), specifically in the magnesium scandium selenide spinel. Our theoretical predictions also indicate that high magnesium ion mobility is possible in other chalcogenide spinels, opening the door for the realization of other magnesium solid ionic conductors and the eventual development of an all-solid-state magnesium battery.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [3];  [4];  [5]; ORCiD logo [6];  [6];  [5]; ORCiD logo [7];  [3]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering; Shanghai Jiao Tong Univ. (China). Shanghai Jiao Tong Univ. Joint Inst.
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering; Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering
  4. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  5. Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering
  6. Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering
  7. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division
Publication Date:
Research Org.:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science - Office of Basic Energy Sciences - Joint Center for Energy Storage Research (JCESR)
OSTI Identifier:
1417619
Alternate Identifier(s):
OSTI ID: 1427174
Grant/Contract Number:  
AC02-05CH11231; AC02-06CH11357; 3F-31144
Resource Type:
Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 25 ENERGY STORAGE; batteries

Citation Formats

Canepa, Pieremanuele, Bo, Shou-Hang, Sai Gautam, Gopalakrishnan, Key, Baris, Richards, William D., Shi, Tan, Tian, Yaosen, Wang, Yan, Li, Juchuan, and Ceder, Gerbrand. High magnesium mobility in ternary spinel chalcogenides. United States: N. p., 2017. Web. doi:10.1038/s41467-017-01772-1.
Canepa, Pieremanuele, Bo, Shou-Hang, Sai Gautam, Gopalakrishnan, Key, Baris, Richards, William D., Shi, Tan, Tian, Yaosen, Wang, Yan, Li, Juchuan, & Ceder, Gerbrand. High magnesium mobility in ternary spinel chalcogenides. United States. https://doi.org/10.1038/s41467-017-01772-1
Canepa, Pieremanuele, Bo, Shou-Hang, Sai Gautam, Gopalakrishnan, Key, Baris, Richards, William D., Shi, Tan, Tian, Yaosen, Wang, Yan, Li, Juchuan, and Ceder, Gerbrand. Fri . "High magnesium mobility in ternary spinel chalcogenides". United States. https://doi.org/10.1038/s41467-017-01772-1. https://www.osti.gov/servlets/purl/1417619.
@article{osti_1417619,
title = {High magnesium mobility in ternary spinel chalcogenides},
author = {Canepa, Pieremanuele and Bo, Shou-Hang and Sai Gautam, Gopalakrishnan and Key, Baris and Richards, William D. and Shi, Tan and Tian, Yaosen and Wang, Yan and Li, Juchuan and Ceder, Gerbrand},
abstractNote = {Magnesium batteries appear a viable alternative to overcome the safety and energy density limitations faced by current lithium-ion technology. The development of a competitive magnesium battery is plagued by the existing notion of poor magnesium mobility in solids. Here we demonstrate by using ab initio calculations, nuclear magnetic resonance, and impedance spectroscopy measurements that substantial magnesium ion mobility can indeed be achieved in close-packed frameworks (similar to 0.01-0.1 mS cm(-1) at 298 K), specifically in the magnesium scandium selenide spinel. Our theoretical predictions also indicate that high magnesium ion mobility is possible in other chalcogenide spinels, opening the door for the realization of other magnesium solid ionic conductors and the eventual development of an all-solid-state magnesium battery.},
doi = {10.1038/s41467-017-01772-1},
journal = {Nature Communications},
number = 1,
volume = 8,
place = {United States},
year = {2017},
month = {11}
}

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Works referenced in this record:

Long-range Li+ dynamics in the lithium argyrodite Li7PSe6 as probed by rotating-frame spin–lattice relaxation NMR
journal, January 2013

  • Epp, V.; Gün, Ö.; Deiseroth, H. -J.
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 19
  • DOI: 10.1039/c3cp44379e

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries
journal, January 2014

  • Seino, Yoshikatsu; Ota, Tsuyoshi; Takada, Kazunori
  • Energy Environ. Sci., Vol. 7, Issue 2
  • DOI: 10.1039/C3EE41655K

A novel inorganic solid state ion conductor for rechargeable Mg batteries
journal, January 2014

  • Higashi, Shougo; Miwa, Kazutoshi; Aoki, Masakazu
  • Chem. Commun., Vol. 50, Issue 11
  • DOI: 10.1039/C3CC47097K

Hybrid functionals based on a screened Coulomb potential
journal, May 2003

  • Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias
  • The Journal of Chemical Physics, Vol. 118, Issue 18
  • DOI: 10.1063/1.1564060

First-principles evaluation of multi-valent cation insertion into orthorhombic V 2 O 5
journal, January 2015

  • Gautam, Gopalakrishnan Sai; Canepa, Pieremanuele; Malik, Rahul
  • Chemical Communications, Vol. 51, Issue 71
  • DOI: 10.1039/C5CC04947D

Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges
journal, February 2017

  • Canepa, Pieremanuele; Sai Gautam, Gopalakrishnan; Hannah, Daniel C.
  • Chemical Reviews, Vol. 117, Issue 5
  • DOI: 10.1021/acs.chemrev.6b00614

A high capacity thiospinel cathode for Mg batteries
journal, January 2016

  • Sun, Xiaoqi; Bonnick, Patrick; Duffort, Victor
  • Energy & Environmental Science, Vol. 9, Issue 7
  • DOI: 10.1039/C6EE00724D

Spinel compounds as multivalent battery cathodes: a systematic evaluation based on ab initio calculations
journal, January 2015

  • Liu, Miao; Rong, Ziqin; Malik, Rahul
  • Energy & Environmental Science, Vol. 8, Issue 3
  • DOI: 10.1039/C4EE03389B

On the Way to Rechargeable Mg Batteries: The Challenge of New Cathode Materials
journal, February 2010

  • Levi, E.; Gofer, Y.; Aurbach, D.
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm9016497

Ion transport in Ca2+, Sr2+, Ba2+, and Pb2+ beta″ aluminas
journal, November 1983


Trivalent Aluminum Ionic Conduction in the Aluminum Tungstate−Scandium Tungstate−Lutetium Tungstate Solid Solution System
journal, July 1998

  • Tamura, S.; Egawa, T.; Okazaki, Y.
  • Chemistry of Materials, Vol. 10, Issue 7
  • DOI: 10.1021/cm980115q

Influence of Inversion on Mg Mobility and Electrochemistry in Spinels
journal, September 2017

  • Sai Gautam, Gopalakrishnan; Canepa, Pieremanuele; Urban, Alexander
  • Chemistry of Materials, Vol. 29, Issue 18
  • DOI: 10.1021/acs.chemmater.7b02820

Magnesium ion dynamics in Mg(BH 4 ) 2(1−x) X 2x (X = Cl or AlH 4 ) from first-principles molecular dynamics simulations
journal, January 2014

  • Ikeshoji, Tamio; Tsuchida, Eiji; Takagi, Shigeyuki
  • RSC Adv., Vol. 4, Issue 3
  • DOI: 10.1039/C3RA42453G

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999


Treatment of the Impedance of Mixed Conductors Equivalent Circuit Model and Explicit Approximate Solutions
journal, January 1999

  • Jamnik, J.
  • Journal of The Electrochemical Society, Vol. 146, Issue 11
  • DOI: 10.1149/1.1392611

A lithium superionic conductor
journal, July 2011

  • Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro
  • Nature Materials, Vol. 10, Issue 9, p. 682-686
  • DOI: 10.1038/nmat3066

Direct Observation of Reversible Magnesium Ion Intercalation into a Spinel Oxide Host
journal, April 2015

  • Kim, Chunjoong; Phillips, Patrick J.; Key, Baris
  • Advanced Materials, Vol. 27, Issue 22
  • DOI: 10.1002/adma.201500083

Rare-Earth Transition-Metal Chalcogenides
journal, June 2002

  • Mitchell, Kwasi; Ibers, James A.
  • Chemical Reviews, Vol. 102, Issue 6
  • DOI: 10.1021/cr010319h

NMR relaxometry as a versatile tool to study Li ion dynamics in potential battery materials
journal, April 2012


What factors determine cation coordination numbers?
journal, December 1988


Evaluation of sulfur spinel compounds for multivalent battery cathode applications
journal, January 2016

  • Liu, Miao; Jain, Anubhav; Rong, Ziqin
  • Energy & Environmental Science, Vol. 9, Issue 10
  • DOI: 10.1039/C6EE01731B

Prototype systems for rechargeable magnesium batteries
journal, October 2000

  • Aurbach, D.; Lu, Z.; Schechter, A.
  • Nature, Vol. 407, Issue 6805, p. 724-727
  • DOI: 10.1038/35037553

Erratum: “Hybrid functionals based on a screened Coulomb potential” [J. Chem. Phys. 118, 8207 (2003)]
journal, June 2006

  • Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias
  • The Journal of Chemical Physics, Vol. 124, Issue 21
  • DOI: 10.1063/1.2204597

Fast-ion conduction and the structure of beta -Mg 3 Bi 2
journal, August 1994


Preparation and Properties of II-Ln[sub 2]-S[sub 4] Ternary Sulfides
journal, January 1973

  • Yim, W. M.; Fan, A. K.; Stofko, E. J.
  • Journal of The Electrochemical Society, Vol. 120, Issue 3
  • DOI: 10.1149/1.2403474

Ab initiomolecular dynamics for liquid metals
journal, January 1993


Cathode materials for magnesium and magnesium-ion based batteries
journal, March 2015

  • Huie, Matthew M.; Bock, David C.; Takeuchi, Esther S.
  • Coordination Chemistry Reviews, Vol. 287
  • DOI: 10.1016/j.ccr.2014.11.005

Mg rechargeable batteries: an on-going challenge
journal, January 2013

  • Yoo, Hyun Deog; Shterenberg, Ivgeni; Gofer, Yosef
  • Energy & Environmental Science, Vol. 6, Issue 8, p. 2265-2279
  • DOI: 10.1039/c3ee40871j

Extremely slow Li ion dynamics in monoclinic Li2TiO3—probing macroscopic jump diffusion via7Li NMR stimulated echoes
journal, January 2012

  • Ruprecht, Benjamin; Wilkening, Martin; Uecker, Reinhard
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 34
  • DOI: 10.1039/c2cp41662j

Impedance Spectroscopy as a Tool for Chemical and Electrochemical Analysis of Mixed Conductors: A Case Study of Ceria
journal, November 2005


Li Ion Dynamics in a LiAlO 2 Single Crystal Studied by 7 Li NMR Spectroscopy and Conductivity Measurements
journal, June 2012

  • Indris, Sylvio; Heitjans, Paul; Uecker, Reinhard
  • The Journal of Physical Chemistry C, Vol. 116, Issue 27
  • DOI: 10.1021/jp3042928

Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965


Formation of MgO during Chemical Magnesiation of Mg-Ion Battery Materials
journal, January 2015

  • Wang, H.; Senguttuvan, P.; Proffit, D. L.
  • ECS Electrochemistry Letters, Vol. 4, Issue 8
  • DOI: 10.1149/2.0051508eel

Materials Design Rules for Multivalent Ion Mobility in Intercalation Structures
journal, August 2015


Design principles for solid-state lithium superionic conductors
journal, August 2015

  • Wang, Yan; Richards, William Davidson; Ong, Shyue Ping
  • Nature Materials, Vol. 14, Issue 10
  • DOI: 10.1038/nmat4369

Compatibility issues between electrodes and electrolytes in solid-state batteries
journal, January 2017

  • Tian, Yaosen; Shi, Tan; Richards, William D.
  • Energy & Environmental Science, Vol. 10, Issue 5
  • DOI: 10.1039/C7EE00534B

Interlayer-Expanded Molybdenum Disulfide Nanocomposites for Electrochemical Magnesium Storage
journal, February 2015


Li 0.6 [Li 0.2 Sn 0.8 S 2 ] – a layered lithium superionic conductor
journal, January 2016

  • Holzmann, T.; Schoop, L. M.; Ali, M. N.
  • Energy & Environmental Science, Vol. 9, Issue 8
  • DOI: 10.1039/C6EE00633G

Solid electrolytes with multivalent cation conduction. 1. Conducting species in MgZrPO4 system
journal, March 1987


Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


A High Power Rechargeable Nonaqueous Multivalent Zn/V 2 O 5 Battery
journal, August 2016

  • Senguttuvan, Premkumar; Han, Sang-Don; Kim, Soojeong
  • Advanced Energy Materials, Vol. 6, Issue 24
  • DOI: 10.1002/aenm.201600826

Optimization methods for finding minimum energy paths
journal, April 2008

  • Sheppard, Daniel; Terrell, Rye; Henkelman, Graeme
  • The Journal of Chemical Physics, Vol. 128, Issue 13
  • DOI: 10.1063/1.2841941

Magnesium-ion battery-relevant electrochemistry of MgMn 2 O 4 : crystallite size effects and the notable role of electrolyte water content
journal, January 2017

  • Yin, Jiefu; Brady, Alexander B.; Takeuchi, Esther S.
  • Chemical Communications, Vol. 53, Issue 26
  • DOI: 10.1039/C7CC00265C

Divalent magnesium ion conducting characteristics in phosphate based solid electrolyte composites
journal, January 2000

  • Imanaka, Nobuhito; Okazaki, Yusuke; Adachi, Gin-ya
  • Journal of Materials Chemistry, Vol. 10, Issue 6
  • DOI: 10.1039/a909599c

A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode
journal, August 2016


Rietveld structure refinement of two high-pressure spinels: ZnIn2S4-II and MnIn2Se4-II
journal, August 1996


Quest for Nonaqueous Multivalent Secondary Batteries: Magnesium and Beyond
journal, October 2014

  • Muldoon, John; Bucur, Claudiu B.; Gregory, Thomas
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500049y

Optimization of divalent magnesium ion conduction in phosphate based polycrystalline solid electrolytes
journal, July 2001


Interface Stability in Solid-State Batteries
journal, December 2015


Na 3 PSe 4 : A Novel Chalcogenide Solid Electrolyte with High Ionic Conductivity
journal, October 2015


Trivalent Al 3+ Ion Conduction in Aluminum Tungstate Solid
journal, July 1997

  • Kobayashi, Yasuyuki; Egawa, Takashi; Tamura, Shinji
  • Chemistry of Materials, Vol. 9, Issue 7
  • DOI: 10.1021/cm970004b

The Intercalation Phase Diagram of Mg in V 2 O 5 from First-Principles
journal, May 2015


Diffusion and ionic conduction in nanocrystalline ceramics
journal, July 2003


Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction
journal, December 2015


Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets
journal, May 2021


Diffusion and Ionic Conduction in Nanocrystalline Ceramics
journal, January 2001


The intercalation phase diagram of Mg in V$_2$O$_5$ from first principles
text, January 2015


Influence of inversion on Mg mobility and electrochemistry in spinels
text, January 2017


Bonding and dynamical phenomena in MgO: A high temperature 17O and 25Mg NMR study
journal, May 1994

  • Fiske, Peter S.; Stebbins, Jonathan F.; Farnan, Ian
  • Physics and Chemistry of Minerals, Vol. 20, Issue 8
  • DOI: 10.1007/bf00211854

A lithium superionic conductor
journal, July 2011

  • Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro
  • Nature Materials, Vol. 10, Issue 9, p. 682-686
  • DOI: 10.1038/nmat3066

Optimization methods for finding minimum energy paths
journal, April 2008

  • Sheppard, Daniel; Terrell, Rye; Henkelman, Graeme
  • The Journal of Chemical Physics, Vol. 128, Issue 13
  • DOI: 10.1063/1.2841941

Treatment of the Impedance of Mixed Conductors Equivalent Circuit Model and Explicit Approximate Solutions
journal, January 1999

  • Jamnik, J.
  • Journal of The Electrochemical Society, Vol. 146, Issue 11
  • DOI: 10.1149/1.1392611

Extremely slow Li ion dynamics in monoclinic Li 2TiO 3 - Probing macroscopic jump diffusion via 7Li NMR stimulated echoes
text, January 2012

  • Ruprecht, Bernhard; Wilkening, Martin; Uecker, Reinhard
  • Cambridge : Royal Society of Chemistry
  • DOI: 10.15488/2163

Works referencing / citing this record:

The Unified Electrochemical Band Diagram Framework: Understanding the Driving Forces of Materials Electrochemistry
journal, August 2018

  • Young, Matthias J.; Holder, Aaron M.; Musgrave, Charles B.
  • Advanced Functional Materials, Vol. 28, Issue 41
  • DOI: 10.1002/adfm.201803439

Rechargeable Magnesium–Sulfur Battery Technology: State of the Art and Key Challenges
journal, September 2019

  • Wang, Peiwen; Buchmeiser, Michael R.
  • Advanced Functional Materials, Vol. 29, Issue 49
  • DOI: 10.1002/adfm.201905248

Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All-Solid-State Batteries
journal, April 2018

  • Park, Kern Ho; Bai, Qiang; Kim, Dong Hyeon
  • Advanced Energy Materials, Vol. 8, Issue 18
  • DOI: 10.1002/aenm.201800035

On the Balance of Intercalation and Conversion Reactions in Battery Cathodes
journal, April 2018

  • Hannah, Daniel C.; Sai Gautam, Gopalakrishnan; Canepa, Pieremanuele
  • Advanced Energy Materials, Vol. 8, Issue 20
  • DOI: 10.1002/aenm.201800379

Chemistry Design Towards a Stable Sulfide‐Based Superionic Conductor Li 4 Cu 8 Ge 3 S 12
journal, April 2019


Chemistry Design Towards a Stable Sulfide-Based Superionic Conductor Li 4 Cu 8 Ge 3 S 12
journal, April 2019

  • Wang, Yingqi; Lü, Xujie; Zheng, Chong
  • Angewandte Chemie International Edition, Vol. 58, Issue 23
  • DOI: 10.1002/anie.201901739

MgSc 2 Se 4 —A Magnesium Solid Ionic Conductor for All‐Solid‐State Mg Batteries?
journal, April 2019

  • Wang, Li‐Ping; Zhao‐Karger, Zhirong; Klein, Franziska
  • ChemSusChem, Vol. 12, Issue 10
  • DOI: 10.1002/cssc.201900225

Electrolyte for energy storage/conversion (Li+, Na+, Mg2+) devices based on PVC and their associated polymer: a comprehensive review
journal, February 2019


Fundamentals of inorganic solid-state electrolytes for batteries
journal, August 2019

  • Famprikis, Theodosios; Canepa, Pieremanuele; Dawson, James A.
  • Nature Materials, Vol. 18, Issue 12
  • DOI: 10.1038/s41563-019-0431-3

Designing solid-state electrolytes for safe, energy-dense batteries
journal, February 2020


Density functional theory calculations for evaluation of phosphorene as a potential anode material for magnesium batteries
journal, January 2018

  • Han, Xinpeng; Liu, Cheng; Sun, Jie
  • RSC Advances, Vol. 8, Issue 13
  • DOI: 10.1039/c7ra12400g

Anti-perovskite cathodes for lithium batteries
journal, January 2018

  • Lu, Ziheng; Ciucci, Francesco
  • Journal of Materials Chemistry A, Vol. 6, Issue 12
  • DOI: 10.1039/c7ta11074j

Controlled hydroxy-fluorination reaction of anatase to promote Mg 2+ mobility in rechargeable magnesium batteries
journal, January 2018

  • Ma, Jiwei; Koketsu, Toshinari; Morgan, Benjamin. J.
  • Chemical Communications, Vol. 54, Issue 72
  • DOI: 10.1039/c8cc04136a

Review of electrical energy storage technologies, materials and systems: challenges and prospects for large-scale grid storage
journal, January 2018

  • Gür, Turgut M.
  • Energy & Environmental Science, Vol. 11, Issue 10
  • DOI: 10.1039/c8ee01419a

Correlating lattice distortions, ion migration barriers, and stability in solid electrolytes
journal, January 2019

  • Kim, Kwangnam; Siegel, Donald J.
  • Journal of Materials Chemistry A, Vol. 7, Issue 7
  • DOI: 10.1039/c8ta10989c

PVP incorporated MoS 2 as a Mg ion host with enhanced capacity and durability
journal, January 2019

  • Wu, Canlong; Zhao, Guangyu; Gong, Shan
  • Journal of Materials Chemistry A, Vol. 7, Issue 9
  • DOI: 10.1039/c8ta12288a

Computational investigation of chalcogenide spinel conductors for all-solid-state Mg batteries
journal, January 2020

  • Koettgen, Julius; Bartel, Christopher J.; Ceder, Gerbrand
  • Chemical Communications, Vol. 56, Issue 13
  • DOI: 10.1039/c9cc09510a

The effect of protons on the Mg 2+ migration in an α-V 2 O 5 cathode for magnesium batteries: a first-principles investigation
journal, January 2019

  • Ni, Dixing; Shi, Jing; Xiong, Wan
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 14
  • DOI: 10.1039/c9cp00528e

Synthesis of ternary metal oxides as positive electrodes for Mg–Li hybrid ion batteries
journal, January 2020

  • Asif, Muhammad; Rashad, Muhammad; Ali, Zeeshan
  • Nanoscale, Vol. 12, Issue 2
  • DOI: 10.1039/c9nr08758c

A materials perspective on magnesium-ion-based solid-state electrolytes
journal, January 2020

  • Jaschin, Prem Wicram; Gao, Yirong; Li, Yao
  • Journal of Materials Chemistry A, Vol. 8, Issue 6
  • DOI: 10.1039/c9ta11729f

Computer modeling investigation of MgV 2 O 4 for Mg-ion batteries
journal, January 2020

  • Kuganathan, Navaratnarajah; Davazoglou, Konstantinos; Chroneos, Alexander
  • Journal of Applied Physics, Vol. 127, Issue 3
  • DOI: 10.1063/1.5139114

Evaluating transition metal oxides within DFT-SCAN and SCAN + U frameworks for solar thermochemical applications
journal, September 2018


On the Balance of Intercalation and Conversion Reactions in Battery Cathodes
text, January 2018


Magnesium-Sodium Hybrid Battery With High Voltage, Capacity and Cyclability
journal, December 2018


Recent Development of Mg Ion Solid Electrolyte
journal, February 2020


Evaluation of Mg compounds as coating materials in Mg batteries
text, January 2019