Near-field spectroscopic investigation of dual-band heavy fermion metamaterials
Abstract
Broadband tunability is a central theme in contemporary nanophotonics and metamaterials research. Combining metamaterials with phase change media offers a promising approach to achieve such tunability, which requires a comprehensive investigation of the electromagnetic responses of novel materials at subwavelength scales. In this work, we demonstrate an innovative way to tailor band-selective electromagnetic responses at the surface of a heavy fermion compound, samarium sulfide (SmS). By utilizing the intrinsic, pressure sensitive, and multi-band electron responses of SmS, we create a proof-of-principle heavy fermion metamaterial, which is fabricated and characterized using scanning near-field microscopes with < 50 nm spatial resolution. The optical responses at the infrared and visible frequency ranges can be selectively and separately tuned via modifying the occupation of the 4f and 5d band electrons. The unique pressure, doping, and temperature tunability demonstrated represents a paradigm shift for nanoscale metamaterial and metasurface design.
- Authors:
-
- Stony Brook Univ., NY (United States)
- Univ. of Texas, Austin, TX (United States)
- Iowa State Univ., Ames, IA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Texas A & M Univ., College Station, TX (United States)
- National Inst. for Materials Science (NIMS), Tsukuba (Japan)
- Inst. for Molecular Science, Okasaki (Japan)
- Inst. for Molecular Science, Okasaki (Japan); Toyota Technological Inst., Nagoya (Japan)
- Inst. for Molecular Science, Okasaki (Japan); Nagoya Univ. (Japan)
- Nagoya Univ. (Japan)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- SC-22.3 USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division
- OSTI Identifier:
- 1416943
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Gilbert Corder, Stephanie N., Chen, Xinzhong, Zhang, Shaoqing, Hu, Fengrui, Zhang, Jiawei, Luan, Yilong, Logan, Jack A., Ciavatti, Thomas, Bechtel, Hans A., Martin, Michael C., Aronson, Meigan, Suzuki, Hiroyuki S., Kimura, Shin-ichi, Iizuka, Takuya, Fei, Zhe, Imura, Keiichiro, Sato, Noriaki K., Tao, Tiger H., and Liu, Mengkun. Near-field spectroscopic investigation of dual-band heavy fermion metamaterials. United States: N. p., 2017.
Web. doi:10.1038/s41467-017-02378-3.
Gilbert Corder, Stephanie N., Chen, Xinzhong, Zhang, Shaoqing, Hu, Fengrui, Zhang, Jiawei, Luan, Yilong, Logan, Jack A., Ciavatti, Thomas, Bechtel, Hans A., Martin, Michael C., Aronson, Meigan, Suzuki, Hiroyuki S., Kimura, Shin-ichi, Iizuka, Takuya, Fei, Zhe, Imura, Keiichiro, Sato, Noriaki K., Tao, Tiger H., & Liu, Mengkun. Near-field spectroscopic investigation of dual-band heavy fermion metamaterials. United States. https://doi.org/10.1038/s41467-017-02378-3
Gilbert Corder, Stephanie N., Chen, Xinzhong, Zhang, Shaoqing, Hu, Fengrui, Zhang, Jiawei, Luan, Yilong, Logan, Jack A., Ciavatti, Thomas, Bechtel, Hans A., Martin, Michael C., Aronson, Meigan, Suzuki, Hiroyuki S., Kimura, Shin-ichi, Iizuka, Takuya, Fei, Zhe, Imura, Keiichiro, Sato, Noriaki K., Tao, Tiger H., and Liu, Mengkun. Fri .
"Near-field spectroscopic investigation of dual-band heavy fermion metamaterials". United States. https://doi.org/10.1038/s41467-017-02378-3. https://www.osti.gov/servlets/purl/1416943.
@article{osti_1416943,
title = {Near-field spectroscopic investigation of dual-band heavy fermion metamaterials},
author = {Gilbert Corder, Stephanie N. and Chen, Xinzhong and Zhang, Shaoqing and Hu, Fengrui and Zhang, Jiawei and Luan, Yilong and Logan, Jack A. and Ciavatti, Thomas and Bechtel, Hans A. and Martin, Michael C. and Aronson, Meigan and Suzuki, Hiroyuki S. and Kimura, Shin-ichi and Iizuka, Takuya and Fei, Zhe and Imura, Keiichiro and Sato, Noriaki K. and Tao, Tiger H. and Liu, Mengkun},
abstractNote = {Broadband tunability is a central theme in contemporary nanophotonics and metamaterials research. Combining metamaterials with phase change media offers a promising approach to achieve such tunability, which requires a comprehensive investigation of the electromagnetic responses of novel materials at subwavelength scales. In this work, we demonstrate an innovative way to tailor band-selective electromagnetic responses at the surface of a heavy fermion compound, samarium sulfide (SmS). By utilizing the intrinsic, pressure sensitive, and multi-band electron responses of SmS, we create a proof-of-principle heavy fermion metamaterial, which is fabricated and characterized using scanning near-field microscopes with < 50 nm spatial resolution. The optical responses at the infrared and visible frequency ranges can be selectively and separately tuned via modifying the occupation of the 4f and 5d band electrons. The unique pressure, doping, and temperature tunability demonstrated represents a paradigm shift for nanoscale metamaterial and metasurface design.},
doi = {10.1038/s41467-017-02378-3},
journal = {Nature Communications},
number = 1,
volume = 8,
place = {United States},
year = {Fri Dec 22 00:00:00 EST 2017},
month = {Fri Dec 22 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Negative refractive index metamaterials
journal, July 2006
- Padilla, Willie J.; Basov, Dimitri N.; Smith, David R.
- Materials Today, Vol. 9, Issue 7-8
Effect of Configuration Crossover on the Electronic Raman Scattering by Multiplets
journal, March 1981
- Güntherodt, G.; Jayaraman, A.; Anastassakis, E.
- Physical Review Letters, Vol. 46, Issue 13
Flat optics with designer metasurfaces
journal, February 2014
- Yu, Nanfang; Capasso, Federico
- Nature Materials, Vol. 13, Issue 2, p. 139-150
Basic Aspects of The Quantum Theory of Solids: Order and Elementary Excitations
book, January 2010
- Khomskii, Daniel I.
Sketched oxide single-electron transistor
journal, April 2011
- Cheng, Guanglei; Siles, Pablo F.; Bi, Feng
- Nature Nanotechnology, Vol. 6, Issue 6
Spectroscopically Observed Valence Mixing in SmS and Related Compounds
journal, July 1974
- Freeouf, J. L.; Eastman, D. E.; Grobman, W. D.
- Physical Review Letters, Vol. 33, Issue 3
Active Optical Metasurfaces Based on Defect-Engineered Phase-Transition Materials
journal, January 2016
- Rensberg, Jura; Zhang, Shuyan; Zhou, You
- Nano Letters, Vol. 16, Issue 2
Low-energy electronic structure of intermediate-valence "golden" SmS
journal, November 1984
- Travaglini, G.; Wachter, P.
- Physical Review B, Vol. 30, Issue 10
Nano-FTIR Absorption Spectroscopy of Molecular Fingerprints at 20 nm Spatial Resolution
journal, July 2012
- Huth, Florian; Govyadinov, Alexander; Amarie, Sergiu
- Nano Letters, Vol. 12, Issue 8
Ultrabroadband infrared nanospectroscopic imaging
journal, May 2014
- Bechtel, H. A.; Muller, E. A.; Olmon, R. L.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 20
Optical studies of semiconductor to metal transition in Sm1−xYxS
conference, January 1975
- Guntherodt, G.; Holtzberg, F.
- AIP Conference Proceedings Vol. 24
Infrared nanoscopy of strained semiconductors
journal, January 2009
- Huber, A. J.; Ziegler, A.; Köck, T.
- Nature Nanotechnology, Vol. 4, Issue 3
Memory Metamaterials
journal, August 2009
- Driscoll, T.; Kim, H. -T.; Chae, B. -G.
- Science, Vol. 325, Issue 5947
Metamaterial electro-optic switch of nanoscale thickness
journal, April 2010
- Sámson, Z. L.; MacDonald, K. F.; De Angelis, F.
- Applied Physics Letters, Vol. 96, Issue 14
Universality and Critical Behavior at the Mott Transition
journal, October 2003
- Limelette, P.
- Science, Vol. 302, Issue 5642
The thermally induced metal–semiconducting phase transition of samarium monosulfide (SmS) thin films
journal, December 2009
- Rogers, E.; Smet, P. F.; Dorenbos, P.
- Journal of Physics: Condensed Matter, Vol. 22, Issue 1
A Roadmap for Metamaterials
journal, January 2011
- Zheludev, Nikolay I.
- Optics and Photonics News, Vol. 22, Issue 3
Superconducting metamaterials
journal, July 2005
- Ricci, Michael; Orloff, Nathan; Anlage, Steven M.
- Applied Physics Letters, Vol. 87, Issue 3
Plasmon hybridization in graphene metamaterials
journal, June 2013
- Ishikawa, Atsushi; Tanaka, Takuo
- Applied Physics Letters, Vol. 102, Issue 25
Quantitative Measurement of Local Infrared Absorption and Dielectric Function with Tip-Enhanced Near-Field Microscopy
journal, April 2013
- Govyadinov, Alexander A.; Amenabar, Iban; Huth, Florian
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 9
Metamaterials and Negative Refractive Index
journal, August 2004
- Smith, D. R.; Pendry, J. B.; Wiltshire, M. C. K.
- Science, Vol. 305, Issue 5685, p. 788-792
Topological Properties and the Dynamical Crossover from Mixed-Valence to Kondo-Lattice Behavior in the Golden Phase of SmS
journal, April 2015
- Kang, Chang-Jong; Choi, Hong Chul; Kim, Kyoo
- Physical Review Letters, Vol. 114, Issue 16
Electronic structure of Sm monochalcogenides
journal, December 1976
- Batlogg, B.; Kaldis, E.; Schlegel, A.
- Physical Review B, Vol. 14, Issue 12
Unified understanding of the valence transition in the rare-earth monochalcogenides under pressure
text, January 2013
- Jarrige, Ignace; Yamaoka, Hitoshi; Rueff, Jean-Pascal
- arXiv
Universality and Critical Behavior at the Mott transition
text, January 2004
- Limelette, P.; Georges, A.; Jerome, D.
- arXiv
Superconducting Metamaterials
text, January 2005
- Ricci, Michael; Orloff, Nathan; Anlage, Steven M.
- arXiv
Works referencing / citing this record:
Modern Scattering‐Type Scanning Near‐Field Optical Microscopy for Advanced Material Research
journal, April 2019
- Chen, Xinzhong; Hu, Debo; Mescall, Ryan
- Advanced Materials
Phase‐Change Hyperbolic Heterostructures for Nanopolaritonics: A Case Study of hBN/VO 2
journal, February 2019
- Dai, Siyuan; Zhang, Jiawei; Ma, Qiong
- Advanced Materials, Vol. 31, Issue 18
A Multilayer Film Based Selective Thermal Emitter for Infrared Stealth Technology
journal, October 2018
- Peng, Liang; Liu, Dongqing; Cheng, Haifeng
- Advanced Optical Materials, Vol. 6, Issue 23
Nanoimaging and Nanospectroscopy of Polaritons with Time Resolved s ‐SNOM
journal, September 2019
- Yao, Ziheng; Xu, Suheng; Hu, Debo
- Advanced Optical Materials, Vol. 8, Issue 5
Giant isotropic negative thermal expansion in Y-doped samarium monosulfides by intra-atomic charge transfer
journal, January 2019
- Takenaka, Koshi; Asai, Daigo; Kaizu, Ryoichi
- Scientific Reports, Vol. 9, Issue 1
A novel electrochemiluminescent emitter of europium hydroxide nanorods and its application in bioanalysis
journal, January 2019
- Tian, Chunyuan; Wang, Li; Luan, Feng
- Chemical Communications, Vol. 55, Issue 83
Photo-induced charge density distribution in metal surfaces and its extraction with apertureless near-field optics
journal, April 2019
- Chui, S. T.; Chen, Xinzhong; Hu, Hai
- Journal of Physics: Condensed Matter, Vol. 31, Issue 24
Effects of Y substitution on the electronic structure and charge dynamics of SmS
journal, December 2019
- Yokoyama, Y.; Hasegawa, H.; Mizuno, Y.
- Physical Review B, Vol. 100, Issue 24
Simultaneous scanning near-field optical and X-ray diffraction microscopy for correlative nanoscale structure–property characterization
journal, August 2019
- Li, Qian; Marks, Samuel D.; Bean, Sunil
- Journal of Synchrotron Radiation, Vol. 26, Issue 5
Switchable Piezoresistive SmS Thin Films on Large Area
journal, October 2019
- Sousanis, Andreas; Poelman, Dirk; Detavernier, Christophe
- Sensors, Vol. 19, Issue 20