Deconvoluting the Photonic and Electronic Response of 2D Materials: The Case of MoS2
Abstract
Evaluating and tuning the properties of two-dimensional (2D) materials is a major focus of advancing 2D science and technology. While many claim that the photonic properties of a 2D layer provide evidence that the material is "high quality", this may not be true for electronic performance. In this work, we deconvolute the photonic and electronic response of synthetic monolayer molybdenum disulfide. We demonstrate that enhanced photoluminescence can be robustly engineered via the proper choice of substrate, where growth of MoS2 on r-plane sapphire can yield > 100x enhancement in PL and carrier lifetime due to increased molybdenum-oxygen bonding compared to that of traditionally grown MoS2 on c-plane sapphire. These dramatic enhancements in optical properties are similar to those of super-acid treated MoS2 , and suggest that the electronic properties of the MoS2 are also superior. However, a direct comparison of the charge transport properties indicates that the enhanced PL due to increased Mo-O bonding leads to p-type compensation doping, and is accompanied by a 2x degradation in transport properties compared to MoS2 grown on c-plane sapphire. This work provides a foundation for understanding the link between photonic and electronic performance of 2D semiconducting layers, and demonstrates that they are notmore »
- Authors:
-
- Pennsylvania State Univ., University Park, PA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Univ. of Pittsburgh, PA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1416942
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Zhang, Kehao, Borys, Nicholas J., Bersch, Brian M., Bhimanapati, Ganesh R., Xu, Ke, Wang, Baoming, Wang, Ke, Labella, Michael, Williams, Teague A., Haque, Md Amanul., Barnard, Edward S., Fullerton-Shirey, Susan, Schuck, P. James, and Robinson, Joshua A. Deconvoluting the Photonic and Electronic Response of 2D Materials: The Case of MoS2. United States: N. p., 2017.
Web. doi:10.1038/s41598-017-16970-6.
Zhang, Kehao, Borys, Nicholas J., Bersch, Brian M., Bhimanapati, Ganesh R., Xu, Ke, Wang, Baoming, Wang, Ke, Labella, Michael, Williams, Teague A., Haque, Md Amanul., Barnard, Edward S., Fullerton-Shirey, Susan, Schuck, P. James, & Robinson, Joshua A. Deconvoluting the Photonic and Electronic Response of 2D Materials: The Case of MoS2. United States. https://doi.org/10.1038/s41598-017-16970-6
Zhang, Kehao, Borys, Nicholas J., Bersch, Brian M., Bhimanapati, Ganesh R., Xu, Ke, Wang, Baoming, Wang, Ke, Labella, Michael, Williams, Teague A., Haque, Md Amanul., Barnard, Edward S., Fullerton-Shirey, Susan, Schuck, P. James, and Robinson, Joshua A. Tue .
"Deconvoluting the Photonic and Electronic Response of 2D Materials: The Case of MoS2". United States. https://doi.org/10.1038/s41598-017-16970-6. https://www.osti.gov/servlets/purl/1416942.
@article{osti_1416942,
title = {Deconvoluting the Photonic and Electronic Response of 2D Materials: The Case of MoS2},
author = {Zhang, Kehao and Borys, Nicholas J. and Bersch, Brian M. and Bhimanapati, Ganesh R. and Xu, Ke and Wang, Baoming and Wang, Ke and Labella, Michael and Williams, Teague A. and Haque, Md Amanul. and Barnard, Edward S. and Fullerton-Shirey, Susan and Schuck, P. James and Robinson, Joshua A.},
abstractNote = {Evaluating and tuning the properties of two-dimensional (2D) materials is a major focus of advancing 2D science and technology. While many claim that the photonic properties of a 2D layer provide evidence that the material is "high quality", this may not be true for electronic performance. In this work, we deconvolute the photonic and electronic response of synthetic monolayer molybdenum disulfide. We demonstrate that enhanced photoluminescence can be robustly engineered via the proper choice of substrate, where growth of MoS2 on r-plane sapphire can yield > 100x enhancement in PL and carrier lifetime due to increased molybdenum-oxygen bonding compared to that of traditionally grown MoS2 on c-plane sapphire. These dramatic enhancements in optical properties are similar to those of super-acid treated MoS2 , and suggest that the electronic properties of the MoS2 are also superior. However, a direct comparison of the charge transport properties indicates that the enhanced PL due to increased Mo-O bonding leads to p-type compensation doping, and is accompanied by a 2x degradation in transport properties compared to MoS2 grown on c-plane sapphire. This work provides a foundation for understanding the link between photonic and electronic performance of 2D semiconducting layers, and demonstrates that they are not always correlated.},
doi = {10.1038/s41598-017-16970-6},
journal = {Scientific Reports},
number = 1,
volume = 7,
place = {United States},
year = {Tue Dec 05 00:00:00 EST 2017},
month = {Tue Dec 05 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Surface Structure of Protonated R-Sapphire (11̅02) Studied by Sum-Frequency Vibrational Spectroscopy
journal, March 2011
- Sung, Jaeho; Zhang, Luning; Tian, Chuanshan
- Journal of the American Chemical Society, Vol. 133, Issue 11
Surface Structure of Protonated R-Sapphire (11̅02) Studied by Sum-Frequency Vibrational Spectroscopy
journal, March 2011
- Sung, Jaeho; Zhang, Luning; Tian, Chuanshan
- Journal of the American Chemical Society, Vol. 133, Issue 11
Strong Photoluminescence Enhancement of MoS 2 through Defect Engineering and Oxygen Bonding
journal, May 2014
- Nan, Haiyan; Wang, Zilu; Wang, Wenhui
- ACS Nano, Vol. 8, Issue 6
Strong Photoluminescence Enhancement of MoS 2 through Defect Engineering and Oxygen Bonding
journal, May 2014
- Nan, Haiyan; Wang, Zilu; Wang, Wenhui
- ACS Nano, Vol. 8, Issue 6
Grains and grain boundaries in highly crystalline monolayer molybdenum disulfide
text, January 2013
- van der Zande, Arend M.; Huang, Pinshane Y.; Chenet, Daniel A.
- arXiv
In situ incorporation of a S, N doped carbon/sulfur composite for lithium sulfur batteries
journal, January 2015
- Yang, Zhigao; Dai, Yu; Wang, Shengping
- RSC Advances, Vol. 5, Issue 95
Vapor-Solid Growth of High Optical Quality MoS2 Monolayers With Near-Unity Valley Polarization
text, January 2013
- Wu, Sanfeng; Huang, Chunming; Aivazian, Grant
- arXiv
Single-layer MoS2 transistors
journal, January 2011
- Radisavljevic, B.; Radenovic, A.; Brivio, J.
- Nature Nanotechnology, Vol. 6, Issue 3, p. 147-150
Transport properties of monolayer MoS$_2$ grown by chemical vapour deposition
text, January 2014
- Schmidt, Hennrik; Wang, Shunfeng; Chu, Leiqiang
- arXiv
Role of Metal Contacts in Designing High-Performance Monolayer n-Type WSe 2 Field Effect Transistors
journal, April 2013
- Liu, Wei; Kang, Jiahao; Sarkar, Deblina
- Nano Letters, Vol. 13, Issue 5
Fundamental limits of exciton-exciton annihilation for light emission in transition metal dichalcogenide monolayers
journal, May 2016
- Yu, Yiling; Yu, Yifei; Xu, Chao
- Physical Review B, Vol. 93, Issue 20
Intrinsic Structural Defects in Monolayer Molybdenum Disulfide
journal, May 2013
- Zhou, Wu; Zou, Xiaolong; Najmaei, Sina
- Nano Letters, Vol. 13, Issue 6, p. 2615-2622
Impurities and Electronic Property Variations of Natural MoS 2 Crystal Surfaces
journal, August 2015
- Addou, Rafik; McDonnell, Stephen; Barrera, Diego
- ACS Nano, Vol. 9, Issue 9
Evolution of Electronic Structure in Atomically Thin Sheets of WS2 and WSe2
text, January 2012
- Zhao, Weijie; Ghorannevis, Zohreh; Chua, Leiqiang
- arXiv
Exploring atomic defects in molybdenum disulphide monolayers
journal, February 2015
- Hong, Jinhua; Hu, Zhixin; Probert, Matt
- Nature Communications, Vol. 6, Issue 1
Tunable Photoluminescence of Monolayer MoS 2 via Chemical Doping
journal, November 2013
- Mouri, Shinichiro; Miyauchi, Yuhei; Matsuda, Kazunari
- Nano Letters, Vol. 13, Issue 12
Reconfigurable Ion Gating of 2H-MoTe 2 Field-Effect Transistors Using Poly(ethylene oxide)-CsClO 4 Solid Polymer Electrolyte
journal, April 2015
- Xu, Huilong; Fathipour, Sara; Kinder, Erich W.
- ACS Nano, Vol. 9, Issue 5
Atomically Thin A New Direct-Gap Semiconductor
journal, September 2010
- Mak, Kin Fai; Lee, Changgu; Hone, James
- Physical Review Letters, Vol. 105, Issue 13, Article No.136805
Synthesis of Large-Area MoS2 Atomic Layers with Chemical Vapor Deposition
journal, March 2012
- Lee, Yi-Hsien; Zhang, Xin-Quan; Zhang, Wenjing
- Advanced Materials, Vol. 24, Issue 17, p. 2320-2325
Ab Initio Hartree-Fock Simulation of R-Plane Sapphire
journal, January 2012
- Stirner, Thomas; Sun, Jizhong; Aust, Martin
- Physics Procedia, Vol. 32
Near-unity photoluminescence quantum yield in MoS2
journal, November 2015
- Amani, M.; Lien, D. -H.; Kiriya, D.
- Science, Vol. 350, Issue 6264
Large-Area Epitaxial Monolayer MoS 2
journal, February 2015
- Dumcenco, Dumitru; Ovchinnikov, Dmitry; Marinov, Kolyo
- ACS Nano, Vol. 9, Issue 4
Grains and grain boundaries in highly crystalline monolayer molybdenum disulphide
journal, May 2013
- van der Zande, Arend M.; Huang, Pinshane Y.; Chenet, Daniel A.
- Nature Materials, Vol. 12, Issue 6, p. 554-561
Extraordinary Room-Temperature Photoluminescence in Triangular WS 2 Monolayers
journal, December 2012
- Gutiérrez, Humberto R.; Perea-López, Nestor; Elías, Ana Laura
- Nano Letters, Vol. 13, Issue 8
Emerging Device Applications for Semiconducting Two-Dimensional Transition Metal Dichalcogenides
text, January 2014
- Jariwala, Deep; Sangwan, Vinod K.; Lauhon, Lincoln J.
- arXiv
Visualizing nanoscale excitonic relaxation properties of disordered edges and grain boundaries in monolayer molybdenum disulfide
journal, August 2015
- Bao, Wei; Borys, Nicholas J.; Ko, Changhyun
- Nature Communications, Vol. 6, Issue 1
Vapour phase growth and grain boundary structure of molybdenum disulphide atomic layers
journal, June 2013
- Najmaei, Sina; Liu, Zheng; Zhou, Wu
- Nature Materials, Vol. 12, Issue 8, p. 754-759
Defects activated photoluminescence in two-dimensional semiconductors: interplay between bound, charged and free excitons
journal, September 2013
- Tongay, Sefaattin; Suh, Joonki; Ataca, Can
- Scientific Reports, Vol. 3, Issue 1
Giant photoluminescence enhancement in tungsten-diselenide–gold plasmonic hybrid structures
journal, May 2016
- Wang, Zhuo; Dong, Zhaogang; Gu, Yinghong
- Nature Communications, Vol. 7, Issue 1
Extraordinary Room-Temperature Photoluminescence in Triangular WS 2 Monolayers
journal, December 2012
- Gutiérrez, Humberto R.; Perea-López, Nestor; Elías, Ana Laura
- Nano Letters, Vol. 13, Issue 8
Defects activated photoluminescence in two-dimensional semiconductors: interplay between bound, charged and free excitons
journal, September 2013
- Tongay, Sefaattin; Suh, Joonki; Ataca, Can
- Scientific Reports, Vol. 3, Issue 1
Vapour phase growth and grain boundary structure of molybdenum disulphide atomic layers
journal, June 2013
- Najmaei, Sina; Liu, Zheng; Zhou, Wu
- Nature Materials, Vol. 12, Issue 8, p. 754-759
Piezoelectricity of single-atomic-layer MoS2 for energy conversion and piezotronics
journal, October 2014
- Wu, Wenzhuo; Wang, Lei; Li, Yilei
- Nature, Vol. 514, Issue 7523
Near-unity photoluminescence quantum yield in MoS2
journal, November 2015
- Amani, M.; Lien, D. -H.; Kiriya, D.
- Science, Vol. 350, Issue 6264
Piezoelectricity of single-atomic-layer MoS2 for energy conversion and piezotronics
journal, October 2014
- Wu, Wenzhuo; Wang, Lei; Li, Yilei
- Nature, Vol. 514, Issue 7523
The adhesion properties of the Ag/α-Al2O3() interface: an ab initio study
journal, July 2002
- Zhukovskii, Yu. F.; Kotomin, E. A.; Herschend, B.
- Surface Science, Vol. 513, Issue 2
EXAFS and XANES spectroscopy study of the oxidation and deprotonation of biotite
journal, December 1989
- Güttler, Bernd; Niemann, Wilhelm; Redfern, Simon A. T.
- Mineralogical Magazine, Vol. 53, Issue 373
Unravelling Orientation Distribution and Merging Behavior of Monolayer MoS 2 Domains on Sapphire
journal, December 2014
- Ji, Qingqing; Kan, Min; Zhang, Yu
- Nano Letters, Vol. 15, Issue 1
Electronic structure of , , and . I. Band-structure calculations and photoelectron spectroscopy
journal, April 1987
- Coehoorn, R.; Haas, C.; Dijkstra, J.
- Physical Review B, Vol. 35, Issue 12
2D materials advances: from large scale synthesis and controlled heterostructures to improved characterization techniques, defects and applications
journal, December 2016
- Lin, Zhong; McCreary, Amber; Briggs, Natalie
- 2D Materials, Vol. 3, Issue 4
Crystal truncation rod diffraction study of the α-Al2O3 (102) surface
journal, January 2002
- Trainor, Thomas P.; Eng, Peter J.; Brown, Gordon E.
- Surface Science, Vol. 496, Issue 3
Optoelectronic devices based on electrically tunable p–n diodes in a monolayer dichalcogenide
journal, March 2014
- Baugher, Britton W. H.; Churchill, Hugh O. H.; Yang, Yafang
- Nature Nanotechnology, Vol. 9, Issue 4
Synthesis of Large-Area MoS2 Atomic Layers with Chemical Vapor Deposition
journal, March 2012
- Lee, Yi-Hsien; Zhang, Xin-Quan; Zhang, Wenjing
- Advanced Materials, Vol. 24, Issue 17, p. 2320-2325
Recent Advances in Two-Dimensional Materials beyond Graphene
journal, October 2015
- Bhimanapati, Ganesh R.; Lin, Zhong; Meunier, Vincent
- ACS Nano, Vol. 9, Issue 12
Vapor–Solid Growth of High Optical Quality MoS 2 Monolayers with Near-Unity Valley Polarization
journal, March 2013
- Wu, Sanfeng; Huang, Chunming; Aivazian, Grant
- ACS Nano, Vol. 7, Issue 3
Anomalous Above-Gap Photoexcitations and Optical Signatures of Localized Charge Puddles in Monolayer Molybdenum Disulfide
journal, February 2017
- Borys, Nicholas J.; Barnard, Edward S.; Gao, Shiyuan
- ACS Nano, Vol. 11, Issue 2
Emerging Device Applications for Semiconducting Two-Dimensional Transition Metal Dichalcogenides
journal, January 2014
- Jariwala, Deep; Sangwan, Vinod K.; Lauhon, Lincoln J.
- ACS Nano, Vol. 8, Issue 2
Large-Area Epitaxial Monolayer MoS 2
journal, February 2015
- Dumcenco, Dumitru; Ovchinnikov, Dmitry; Marinov, Kolyo
- ACS Nano, Vol. 9, Issue 4
Reconfigurable Ion Gating of 2H-MoTe 2 Field-Effect Transistors Using Poly(ethylene oxide)-CsClO 4 Solid Polymer Electrolyte
journal, April 2015
- Xu, Huilong; Fathipour, Sara; Kinder, Erich W.
- ACS Nano, Vol. 9, Issue 5
Photoluminescence of monolayer MoS 2 on LaAlO 3 and SrTiO 3 substrates
journal, January 2014
- Li, Yuanyuan; Qi, Zeming; Liu, Miao
- Nanoscale, Vol. 6, Issue 24
Transport Properties of Monolayer MoS 2 Grown by Chemical Vapor Deposition
journal, March 2014
- Schmidt, Hennrik; Wang, Shunfeng; Chu, Leiqiang
- Nano Letters, Vol. 14, Issue 4
Tightly bound trions in monolayer MoS2
journal, December 2012
- Mak, Kin Fai; He, Keliang; Lee, Changgu
- Nature Materials, Vol. 12, Issue 3
Anomalous Above-Gap Photoexcitations and Optical Signatures of Localized Charge Puddles in Monolayer Molybdenum Disulfide
journal, February 2017
- Borys, Nicholas J.; Barnard, Edward S.; Gao, Shiyuan
- ACS Nano, Vol. 11, Issue 2
Atomic Step Formation on Sapphire Surface in Ultra-precision Manufacturing
journal, July 2016
- Wang, Rongrong; Guo, Dan; Xie, Guoxin
- Scientific Reports, Vol. 6, Issue 1
Tightly bound trions in monolayer MoS2
journal, December 2012
- Mak, Kin Fai; He, Keliang; Lee, Changgu
- Nature Materials, Vol. 12, Issue 3
Ultrasensitive photodetectors based on monolayer MoS2
journal, June 2013
- Lopez-Sanchez, Oriol; Lembke, Dominik; Kayci, Metin
- Nature Nanotechnology, Vol. 8, Issue 7
EXAFS and XANES spectroscopy study of the oxidation and deprotonation of biotite
journal, December 1989
- Güttler, Bernd; Niemann, Wilhelm; Redfern, Simon A. T.
- Mineralogical Magazine, Vol. 53, Issue 373
Evolution of Electronic Structure in Atomically Thin Sheets of WS 2 and WSe 2
journal, December 2012
- Zhao, Weijie; Ghorannevis, Zohreh; Chu, Leiqiang
- ACS Nano, Vol. 7, Issue 1
Intrinsic Structural Defects in Monolayer Molybdenum Disulfide
journal, May 2013
- Zhou, Wu; Zou, Xiaolong; Najmaei, Sina
- Nano Letters, Vol. 13, Issue 6, p. 2615-2622
Single-layer MoS2 transistors
journal, January 2011
- Radisavljevic, B.; Radenovic, A.; Brivio, J.
- Nature Nanotechnology, Vol. 6, Issue 3, p. 147-150
High-Performance Single Layered WSe2 p-FETs with Chemically Doped Contacts
journal, June 2012
- Fang, Hui; Chuang, Steven; Chang, Ting Chia
- Nano Letters, Vol. 12, Issue 7, p. 3788-3792
High Performance Multilayer MoS2Transistors with Scandium Contacts
journal, December 2012
- Das, Saptarshi; Chen, Hong-Yan; Penumatcha, Ashish Verma
- Nano Letters, Vol. 13, Issue 1, p. 100-105
Selective-area growth and controlled substrate coupling of transition metal dichalcogenides
journal, April 2017
- Bersch, Brian M.; Eichfeld, Sarah M.; Lin, Yu-Chuan
- 2D Materials, Vol. 4, Issue 2
Ab Initio Hartree-Fock Simulation of R-Plane Sapphire
journal, January 2012
- Stirner, Thomas; Sun, Jizhong; Aust, Martin
- Physics Procedia, Vol. 32
Role of Metal Contacts in Designing High-Performance Monolayer n-Type WSe 2 Field Effect Transistors
journal, April 2013
- Liu, Wei; Kang, Jiahao; Sarkar, Deblina
- Nano Letters, Vol. 13, Issue 5
Ultrasensitive and Broadband MoS 2 Photodetector Driven by Ferroelectrics
journal, September 2015
- Wang, Xudong; Wang, Peng; Wang, Jianlu
- Advanced Materials, Vol. 27, Issue 42
Unravelling Orientation Distribution and Merging Behavior of Monolayer MoS 2 Domains on Sapphire
journal, December 2014
- Ji, Qingqing; Kan, Min; Zhang, Yu
- Nano Letters, Vol. 15, Issue 1
Tunable Photoluminescence of Monolayer MoS 2 via Chemical Doping
journal, November 2013
- Mouri, Shinichiro; Miyauchi, Yuhei; Matsuda, Kazunari
- Nano Letters, Vol. 13, Issue 12
Exploring atomic defects in molybdenum disulphide monolayers
journal, February 2015
- Hong, Jinhua; Hu, Zhixin; Probert, Matt
- Nature Communications, Vol. 6, Issue 1
Visualizing nanoscale excitonic relaxation properties of disordered edges and grain boundaries in monolayer molybdenum disulfide
journal, August 2015
- Bao, Wei; Borys, Nicholas J.; Ko, Changhyun
- Nature Communications, Vol. 6, Issue 1
Giant photoluminescence enhancement in tungsten-diselenide–gold plasmonic hybrid structures
journal, May 2016
- Wang, Zhuo; Dong, Zhaogang; Gu, Yinghong
- Nature Communications, Vol. 7, Issue 1
Atomic Step Formation on Sapphire Surface in Ultra-precision Manufacturing
journal, July 2016
- Wang, Rongrong; Guo, Dan; Xie, Guoxin
- Scientific Reports, Vol. 6, Issue 1
Works referencing / citing this record:
A roadmap for electronic grade 2D materials
journal, January 2019
- Briggs, Natalie; Subramanian, Shruti; Lin, Zhong
- 2D Materials, Vol. 6, Issue 2
Probing the origin of lateral heterogeneities in synthetic monolayer molybdenum disulfide
journal, February 2019
- Zhang, Kehao; Wang, Yuanxi; Joshi, Jaydeep
- 2D Materials, Vol. 6, Issue 2
Doping of Two-Dimensional Semiconductors: A Rapid Review and Outlook
journal, January 2019
- Zhang, Kehao; Robinson, Joshua
- MRS Advances, Vol. 4, Issue 51-52
Perspective: 2D for beyond CMOS
journal, May 2018
- Robinson, Joshua A.
- APL Materials, Vol. 6, Issue 5
Recent Developments in Controlled Vapor‐Phase Growth of 2D Group 6 Transition Metal Dichalcogenides
journal, December 2018
- Kim, Se‐Yang; Kwak, Jinsung; Ciobanu, Cristian V.
- Advanced Materials, Vol. 31, Issue 20
Tuning the Electronic and Photonic Properties of Monolayer MoS 2 via In Situ Rhenium Substitutional Doping
journal, February 2018
- Zhang, Kehao; Bersch, Brian M.; Joshi, Jaydeep
- Advanced Functional Materials, Vol. 28, Issue 16
Recent advances in the preparation, characterization, and applications of two-dimensional heterostructures for energy storage and conversion
journal, January 2018
- Das, Pratteek; Fu, Qiang; Bao, Xinhe
- Journal of Materials Chemistry A, Vol. 6, Issue 44