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Title: Nanoimprinted High-Refractive Index Active Photonic Nanostructures Based on Quantum Dots for Visible Light

Abstract

A novel method to realizing printed active photonic devices was developed using nanoimprint lithography (NIL), combining a printable high-refractive index material and colloidal CdSe/CdS quantum dots (QDs) for applications in the visible region. Active media QDs were applied in two different ways: embedded inside a printable high-refractive index matrix to form an active printable hybrid nanocomposite, and used as a uniform coating on top of printed photonic devices. As a proof-of-demonstration for printed active photonic devices, two-dimensional (2-D) photonic crystals as well as 1D and 2D photonic nanocavities were successfully fabricated following a simple reverse-nanoimprint process. We observed enhanced photoluminescence from the 2D photonic crystal and the 1D nanocavities. Outstandingly, the process presented in this study is fully compatible with large-scale manufacturing where the patterning areas are only limited by the size of the corresponding mold. This work shows that the integration of active media and functional materials is a promising approach to the realization of integrated photonics for visible light using high throughput technologies. We believe that this work represents a powerful and cost-effective route for the development of numerous nanophotonic structures and devices that will lead to the emergence of new applications.

Authors:
 [1];  [1];  [2];  [2];  [2];  [2];  [1]
  1. aBeam Technologies, Hayward, CA (United States)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1416941
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Pina-Hernandez, Carlos, Koshelev, Alexander, Dhuey, Scott, Sassolini, Simone, Sainato, Michela, Cabrini, Stefano, and Munechika, Keiko. Nanoimprinted High-Refractive Index Active Photonic Nanostructures Based on Quantum Dots for Visible Light. United States: N. p., 2017. Web. doi:10.1038/s41598-017-17732-0.
Pina-Hernandez, Carlos, Koshelev, Alexander, Dhuey, Scott, Sassolini, Simone, Sainato, Michela, Cabrini, Stefano, & Munechika, Keiko. Nanoimprinted High-Refractive Index Active Photonic Nanostructures Based on Quantum Dots for Visible Light. United States. doi:10.1038/s41598-017-17732-0.
Pina-Hernandez, Carlos, Koshelev, Alexander, Dhuey, Scott, Sassolini, Simone, Sainato, Michela, Cabrini, Stefano, and Munechika, Keiko. Fri . "Nanoimprinted High-Refractive Index Active Photonic Nanostructures Based on Quantum Dots for Visible Light". United States. doi:10.1038/s41598-017-17732-0. https://www.osti.gov/servlets/purl/1416941.
@article{osti_1416941,
title = {Nanoimprinted High-Refractive Index Active Photonic Nanostructures Based on Quantum Dots for Visible Light},
author = {Pina-Hernandez, Carlos and Koshelev, Alexander and Dhuey, Scott and Sassolini, Simone and Sainato, Michela and Cabrini, Stefano and Munechika, Keiko},
abstractNote = {A novel method to realizing printed active photonic devices was developed using nanoimprint lithography (NIL), combining a printable high-refractive index material and colloidal CdSe/CdS quantum dots (QDs) for applications in the visible region. Active media QDs were applied in two different ways: embedded inside a printable high-refractive index matrix to form an active printable hybrid nanocomposite, and used as a uniform coating on top of printed photonic devices. As a proof-of-demonstration for printed active photonic devices, two-dimensional (2-D) photonic crystals as well as 1D and 2D photonic nanocavities were successfully fabricated following a simple reverse-nanoimprint process. We observed enhanced photoluminescence from the 2D photonic crystal and the 1D nanocavities. Outstandingly, the process presented in this study is fully compatible with large-scale manufacturing where the patterning areas are only limited by the size of the corresponding mold. This work shows that the integration of active media and functional materials is a promising approach to the realization of integrated photonics for visible light using high throughput technologies. We believe that this work represents a powerful and cost-effective route for the development of numerous nanophotonic structures and devices that will lead to the emergence of new applications.},
doi = {10.1038/s41598-017-17732-0},
journal = {Scientific Reports},
number = 1,
volume = 7,
place = {United States},
year = {2017},
month = {12}
}

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Works referenced in this record:

A quantum dot nanoimprinted DFB laser
journal, November 2009

  • Lavchiev, V. M.; Saeed, Ahmed; Pogany, D.
  • IOP Conference Series: Materials Science and Engineering, Vol. 6
  • DOI: 10.1088/1757-899X/6/1/012028

Efficient White-Light-Emitting Diodes Fabricated from Highly Fluorescent Copper Indium Sulfide Core/Shell Quantum Dots
journal, May 2012

  • Song, Woo-Seuk; Yang, Heesun
  • Chemistry of Materials, Vol. 24, Issue 10
  • DOI: 10.1021/cm300837z

Imprint Lithography with 25-Nanometer Resolution
journal, April 1996


Direct Patterning of TiO 2 Using Step-and-Flash Imprint Lithography
journal, January 2012

  • Ganesan, Ramakrishnan; Dumond, Jarrett; Saifullah, Mohammad S. M.
  • ACS Nano, Vol. 6, Issue 2
  • DOI: 10.1021/nn204405k

Printable photonic crystals with high refractive index for applications in visible light
journal, February 2016


Silicon-based photonic crystal nanocavity light emitters
journal, November 2006

  • Makarova, Maria; Vuckovic, Jelena; Sanda, Hiroyuki
  • Applied Physics Letters, Vol. 89, Issue 22
  • DOI: 10.1063/1.2396903

Printable planar lightwave circuits with a high refractive index
journal, July 2014


Refractive index dependence of L3 photonic crystal nano-cavities
journal, January 2007

  • Adawi, A. M.; Chalcraft, A. R.; Whittaker, D. M.
  • Optics Express, Vol. 15, Issue 22
  • DOI: 10.1364/OE.15.014299

Full-colour quantum dot displays fabricated by transfer printing
journal, February 2011


Nanoimprint Lithography: Methods and Material Requirements
journal, February 2007


Spontaneous Emission Control in Micropillar Cavities Containing a Fluorescent Molecular Dye
journal, March 2006

  • Adawi, A. M.; Cadby, A.; Connolly, L. G.
  • Advanced Materials, Vol. 18, Issue 6
  • DOI: 10.1002/adma.200502099

Highly efficient quantum dot near-infrared light-emitting diodes
journal, February 2016


Patterning Fluorescent Quantum Dot Nanocomposites by Reactive Inkjet Printing
journal, January 2015


Direct Patterning of CdSe Quantum Dots into Sub-100 nm Structures
journal, March 2010

  • Hampton, Meredith J.; Templeton, Joseph L.; DeSimone, Joseph M.
  • Langmuir, Vol. 26, Issue 5
  • DOI: 10.1021/la904787k

Red, green and blue lasing enabled by single-exciton gain in colloidal quantum dot films
journal, April 2012

  • Dang, Cuong; Lee, Joonhee; Breen, Craig
  • Nature Nanotechnology, Vol. 7, Issue 5
  • DOI: 10.1038/nnano.2012.61

Resonant grating waveguide structures
journal, January 1997

  • Rosenblatt, D.; Sharon, A.; Friesem, A. A.
  • IEEE Journal of Quantum Electronics, Vol. 33, Issue 11
  • DOI: 10.1109/3.641320

Polarized quantum dot emission in electrohydrodynamic jet printed photonic crystals
journal, August 2015

  • See, Gloria G.; Xu, Lu; Sutanto, Erick
  • Applied Physics Letters, Vol. 107, Issue 5
  • DOI: 10.1063/1.4927648

High-Q, low index-contrast polymeric photonic crystal nanobeam cavities
journal, January 2011

  • Quan, Qimin; Burgess, Ian B.; Tang, Sindy K. Y.
  • Optics Express, Vol. 19, Issue 22
  • DOI: 10.1364/OE.19.022191

Colloidal quantum-dot light-emitting diodes with metal-oxide charge transport layers
journal, March 2008


Photo-induced hybrid nanopatterning of titanium dioxide via direct imprint lithography
journal, January 2010

  • Park, Hyeong-Ho; Choi, Dae-Geun; Zhang, Xin
  • Journal of Materials Chemistry, Vol. 20, Issue 10
  • DOI: 10.1039/b921343k

Selection of Metal Oxide Charge Transport Layers for Colloidal Quantum Dot LEDs
journal, October 2009

  • Wood, V.; Panzer, M. J.; Halpert, J. E.
  • ACS Nano, Vol. 3, Issue 11
  • DOI: 10.1021/nn901074r

Pressureless nanoimprinting of anatase TiO2 precursor films
journal, March 2011

  • Richmond, Dustin A.; Zhang, Qifeng; Cao, Guozhong
  • Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 29, Issue 2
  • DOI: 10.1116/1.3562955

Synthesis and Micrometer-Scale Assembly of Colloidal CdSe/CdS Nanorods Prepared by a Seeded Growth Approach
journal, October 2007

  • Carbone, Luigi; Nobile, Concetta; De Giorgi, Milena
  • Nano Letters, Vol. 7, Issue 10
  • DOI: 10.1021/nl0717661

“Flash” Synthesis of CdSe/CdS Core–Shell Quantum Dots
journal, December 2013

  • Cirillo, Marco; Aubert, Tangi; Gomes, Raquel
  • Chemistry of Materials, Vol. 26, Issue 2
  • DOI: 10.1021/cm403518a

Enhanced quantum dot optical down-conversion using asymmetric 2D photonic crystals
journal, January 2011


Direct imprinting of high resolution TiO 2 nanostructures
journal, June 2010


High-Resolution Patterns of Quantum Dots Formed by Electrohydrodynamic Jet Printing for Light-Emitting Diodes
journal, January 2015

  • Kim, Bong Hoon; Onses, M. Serdar; Lim, Jong Bin
  • Nano Letters, Vol. 15, Issue 2
  • DOI: 10.1021/nl503779e

Ultralow-threshold electrically pumped quantum-dot photonic-crystal nanocavity laser
journal, April 2011


Controlling the Spontaneous Emission Rate of Single Quantum Dots in a Two-Dimensional Photonic Crystal
journal, July 2005


High-Temperature Photoluminescence of CdSe/CdS Core/Shell Nanoheterostructures
journal, May 2014

  • Diroll, Benjamin T.; Murray, Christopher B.
  • ACS Nano, Vol. 8, Issue 6
  • DOI: 10.1021/nn5021314

Two-Dimensional Photonic Crystal Resist Membrane Nanocavity Embedding Colloidal Dot-in-a-Rod Nanocrystals
journal, January 2008

  • Martiradonna, Luigi; Carbone, Luigi; Tandaechanurat, Aniwat
  • Nano Letters, Vol. 8, Issue 1
  • DOI: 10.1021/nl0725751

A route for fabricating printable photonic devices with sub-10 nm resolution
journal, January 2013


Quantum dot solar cells
journal, April 2002