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Title: Redox-active ligand controlled selectivity of vanadium oxidation on Au(100)

Abstract

Metal–organic coordination networks at surfaces, formed by on-surface redox assembly, are of interest for designing specific and selective chemical function at surfaces for heterogeneous catalysts and other applications. The chemical reactivity of single-site transition metals in on-surface coordination networks, which is essential to these applications, has not previously been fully characterized. Here, we demonstrate with a surface-supported, single-site V system that not only are these sites active toward dioxygen activation, but the products of that reaction show much higher selectivity than traditional vanadium nanoparticles, leading to only one V-oxo product. We have studied the chemical reactivity of one-dimensional metal–organic vanadium – 3,6-di(2-pyridyl)-1,2,4,5-tetrazine (DPTZ) chains with O2. The electron-rich chains self-assemble through an on-surface redox process on the Au(100) surface and are characterized by X-ray photoelectron spectroscopy, scanning tunneling microscopy, high-resolution electron energy loss spectroscopy, and density functional theory. Reaction of V-DPTZ chains with O2 causes an increase in V oxidation state from VII to VIV, resulting in a single strongly bonded (DPTZ2-)VIVO product and spillover of O to the Au surface. DFT calculations confirm these products and also suggest new candidate intermediate states, providing mechanistic insight into this on-surface reaction. In contrast, the oxidation of ligand-free V is less completemore » and results in multiple oxygen-bound products. This demonstrates the high chemical selectivity of single-site metal centers in metal–ligand complexes at surfaces compared to metal nanoislands.« less

Authors:
 [1];  [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [3]; ORCiD logo [1];  [4]; ORCiD logo [1]; ORCiD logo [5]; ORCiD logo [1]; ORCiD logo [6]
  1. Department of Chemistry, Indiana University, Bloomington, USA
  2. Department of Chemistry, Indiana University, Bloomington, USA, NAVSEA Crane
  3. Department of Physics, University of Central Florida, Orlando, USA
  4. Department of Physics, Indiana University, Bloomington, USA
  5. Department of Physics, University of Central Florida, Orlando, USA, Donostia International Physics Center (DIPC)
  6. Department of Chemistry, Indiana University, Bloomington, USA, Department of Physics
Publication Date:
Research Org.:
Indiana Univ., Bloomington, IN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1416799
Alternate Identifier(s):
OSTI ID: 1505532; OSTI ID: 1726279
Grant/Contract Number:  
SC0016367
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 6; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United Kingdom
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Tempas, Christopher D., Morris, Tobias W., Wisman, David L., Le, Duy, Din, Naseem U., Williams, Christopher G., Wang, Miao, Polezhaev, Alexander V., Rahman, Talat S., Caulton, Kenneth G., and Tait, Steven L. Redox-active ligand controlled selectivity of vanadium oxidation on Au(100). United Kingdom: N. p., 2018. Web. doi:10.1039/C7SC04752E.
Tempas, Christopher D., Morris, Tobias W., Wisman, David L., Le, Duy, Din, Naseem U., Williams, Christopher G., Wang, Miao, Polezhaev, Alexander V., Rahman, Talat S., Caulton, Kenneth G., & Tait, Steven L. Redox-active ligand controlled selectivity of vanadium oxidation on Au(100). United Kingdom. https://doi.org/10.1039/C7SC04752E
Tempas, Christopher D., Morris, Tobias W., Wisman, David L., Le, Duy, Din, Naseem U., Williams, Christopher G., Wang, Miao, Polezhaev, Alexander V., Rahman, Talat S., Caulton, Kenneth G., and Tait, Steven L. Mon . "Redox-active ligand controlled selectivity of vanadium oxidation on Au(100)". United Kingdom. https://doi.org/10.1039/C7SC04752E.
@article{osti_1416799,
title = {Redox-active ligand controlled selectivity of vanadium oxidation on Au(100)},
author = {Tempas, Christopher D. and Morris, Tobias W. and Wisman, David L. and Le, Duy and Din, Naseem U. and Williams, Christopher G. and Wang, Miao and Polezhaev, Alexander V. and Rahman, Talat S. and Caulton, Kenneth G. and Tait, Steven L.},
abstractNote = {Metal–organic coordination networks at surfaces, formed by on-surface redox assembly, are of interest for designing specific and selective chemical function at surfaces for heterogeneous catalysts and other applications. The chemical reactivity of single-site transition metals in on-surface coordination networks, which is essential to these applications, has not previously been fully characterized. Here, we demonstrate with a surface-supported, single-site V system that not only are these sites active toward dioxygen activation, but the products of that reaction show much higher selectivity than traditional vanadium nanoparticles, leading to only one V-oxo product. We have studied the chemical reactivity of one-dimensional metal–organic vanadium – 3,6-di(2-pyridyl)-1,2,4,5-tetrazine (DPTZ) chains with O2. The electron-rich chains self-assemble through an on-surface redox process on the Au(100) surface and are characterized by X-ray photoelectron spectroscopy, scanning tunneling microscopy, high-resolution electron energy loss spectroscopy, and density functional theory. Reaction of V-DPTZ chains with O2 causes an increase in V oxidation state from VII to VIV, resulting in a single strongly bonded (DPTZ2-)VIVO product and spillover of O to the Au surface. DFT calculations confirm these products and also suggest new candidate intermediate states, providing mechanistic insight into this on-surface reaction. In contrast, the oxidation of ligand-free V is less complete and results in multiple oxygen-bound products. This demonstrates the high chemical selectivity of single-site metal centers in metal–ligand complexes at surfaces compared to metal nanoislands.},
doi = {10.1039/C7SC04752E},
journal = {Chemical Science},
number = 6,
volume = 9,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C7SC04752E

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Cited by: 7 works
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Figures / Tables:

Scheme 1 Scheme 1: Di-pyridinyltetrazine (DPTZ) and the M–L Polymer that forms after their redox assembly on the Au(100) surface.

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Works referenced in this record:

Efficient CO Oxidation at Low Temperature on Au(111)
journal, October 2006

  • Min, B. K.; Alemozafar, A. R.; Pinnaduwage, D.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 40
  • DOI: 10.1021/jp0616213

The preparation and reactivity of thin, ordered films of vanadium oxide on Au(111)
journal, July 1990


Growth, electronic properties and reactivity of vanadium deposited onto a thin alumina film
journal, July 1999


Comparison of Copper and Vanadium Homogeneous Catalysts for Aerobic Oxidation of Lignin Models
journal, May 2011

  • Sedai, Baburam; Díaz-Urrutia, Christian; Baker, R. Tom
  • ACS Catalysis, Vol. 1, Issue 7
  • DOI: 10.1021/cs200149v

Tackling CO Poisoning with Single-Atom Alloy Catalysts
journal, May 2016

  • Liu, Jilei; Lucci, Felicia R.; Yang, Ming
  • Journal of the American Chemical Society, Vol. 138, Issue 20
  • DOI: 10.1021/jacs.6b03339

Low-valence oxo-centred triruthenium complexes by bridging acetate substitution with pyrazolyldiazine or pyridinyltetrazine ligands
journal, January 2009

  • Dai, Feng-Rong; Ye, Heng-Yun; Li, Bin
  • Dalton Transactions, Issue 40
  • DOI: 10.1039/b908798b

A near planar disilver complex of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine
journal, March 2002

  • Constable, Edwin C.; Housecroft, Catherine E.; Kariuki, Benson M.
  • Inorganic Chemistry Communications, Vol. 5, Issue 3
  • DOI: 10.1016/S1387-7003(02)00329-5

Low temperature adsorption of oxygen on reduced V2O3(0001) surfaces
journal, April 2006


Metal-oxide boundary effects in vanadium oxide – Rh(111) inverse model catalysts: a RAIRS, STM and TPD study
journal, September 2007


The coordination chemistry of vanadium
journal, August 1966


Metal–organic framework materials as catalysts
journal, January 2009

  • Lee, JeongYong; Farha, Omar K.; Roberts, John
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
  • DOI: 10.1039/b807080f

Supported single-atom catalysts: synthesis, characterization, properties, and applications
journal, November 2017


Critical Literature Review of the Kinetics for the Oxidative Dehydrogenation of Propane over Well-Defined Supported Vanadium Oxide Catalysts
journal, September 2014

  • Carrero, C. A.; Schloegl, R.; Wachs, I. E.
  • ACS Catalysis, Vol. 4, Issue 10
  • DOI: 10.1021/cs5003417

Recent advances in vanadium catalyzed oxygen transfer reactions
journal, October 2011

  • Licini, Giulia; Conte, Valeria; Coletti, Alessia
  • Coordination Chemistry Reviews, Vol. 255, Issue 19-20
  • DOI: 10.1016/j.ccr.2011.05.004

Coordination chemistry of vanadium in metallopharmaceutical candidate compounds
journal, October 2001


Vanadium catalyzed aerobic carbon–carbon cleavage
journal, October 2015

  • Amadio, Emanuele; Di Lorenzo, Rosalia; Zonta, Cristiano
  • Coordination Chemistry Reviews, Vol. 301-302
  • DOI: 10.1016/j.ccr.2015.06.004

Metal-Ligand Cooperation
journal, September 2015

  • Khusnutdinova, Julia R.; Milstein, David
  • Angewandte Chemie International Edition, Vol. 54, Issue 42
  • DOI: 10.1002/anie.201503873

Direct visualization of quasi-ordered oxygen chain structures on Au(110)-(1 × 2)
journal, August 2016


Vanadium oxide monolayer catalysts Preparation, characterization and catalytic activity
journal, April 1991


Novel cytotoxic oxovanadium(IV) complexes: Influence of pyrazole-incorporated heterocyclic scaffolds on their biological response
journal, March 2017

  • Gajera, Sanjay B.; Mehta, Jugal V.; Kanthecha, Darshana N.
  • Applied Organometallic Chemistry, Vol. 31, Issue 11
  • DOI: 10.1002/aoc.3767

Oxygen Dissociation by Concerted Action of Di-Iron Centers in Metal–Organic Coordination Networks at Surfaces: Modeling Non-Heme Iron Enzymes
journal, December 2011

  • Fabris, Stefano; Stepanow, Sebastian; Lin, Nian
  • Nano Letters, Vol. 11, Issue 12
  • DOI: 10.1021/nl2031713

Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
journal, April 2013

  • Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar300361m

Homolytic Cleavage of Molecular Oxygen by Manganese Porphyrins Supported on Ag(111)
journal, April 2014

  • Murphy, Barry E.; Krasnikov, Sergey A.; Sergeeva, Natalia N.
  • ACS Nano, Vol. 8, Issue 5
  • DOI: 10.1021/nn501240j

Electrochromism in some thin‐film transition‐metal oxides characterized by x‐ray electron spectroscopy
journal, January 1978

  • Colton, Richard J.; Guzman, Alberto M.; Rabalais, J. Wayne
  • Journal of Applied Physics, Vol. 49, Issue 1
  • DOI: 10.1063/1.324349

Single-Atom Catalysts of Precious Metals for Electrochemical Reactions
journal, October 2017


Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts
journal, March 2016


A review of the growth of V2O5 films from 1885 to 2010
journal, January 2011


Controlled Metalation of Self-Assembled Porphyrin Nanoarrays in Two Dimensions
journal, February 2007

  • Auwärter, Willi; Weber-Bargioni, Alexander; Brink, Susan
  • ChemPhysChem, Vol. 8, Issue 2
  • DOI: 10.1002/cphc.200600675

Sintering of Catalytic Nanoparticles: Particle Migration or Ostwald Ripening?
journal, April 2013

  • Hansen, Thomas W.; DeLaRiva, Andrew T.; Challa, Sivakumar R.
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar3002427

Interface Properties of VOPc on Ni(111) and Graphene/Ni(111): Orientation-Dependent Charge Transfer
journal, April 2015

  • Adler, Hilmar; Paszkiewicz, Mateusz; Uihlein, Johannes
  • The Journal of Physical Chemistry C, Vol. 119, Issue 16
  • DOI: 10.1021/acs.jpcc.5b01485

Oxygen reduction catalytic characteristics of vanadium carbide and nitrogen doped vanadium carbide
journal, December 2015


Metal–organic and covalent organic frameworks as single-site catalysts
journal, January 2017

  • Rogge, S. M. J.; Bavykina, A.; Hajek, J.
  • Chemical Society Reviews, Vol. 46, Issue 11
  • DOI: 10.1039/C7CS00033B

Structural diversity among copper(i) ethylene adducts of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine
journal, January 2013

  • Maekawa, Masahiko; Miyazaki, Takeshi; Sugimoto, Kunihisa
  • Dalton Transactions, Vol. 42, Issue 12
  • DOI: 10.1039/c2dt32649c

Design of silica-tethered metal complexes for polymerization catalysis
journal, May 2005

  • Jones, Christopher W.; McKittrick, Michael W.; Nguyen, Joseph V.
  • Topics in Catalysis, Vol. 34, Issue 1-4
  • DOI: 10.1007/s11244-005-3790-8

Empirical atomic sensitivity factors for quantitative analysis by electron spectroscopy for chemical analysis
journal, October 1981

  • Wagner, C. D.; Davis, L. E.; Zeller, M. V.
  • Surface and Interface Analysis, Vol. 3, Issue 5
  • DOI: 10.1002/sia.740030506

Redox-active on-surface polymerization of single-site divalent cations from pure metals by a ketone-functionalized phenanthroline
journal, February 2015

  • Skomski, Daniel; Tempas, Christopher D.; Bukowski, Gregory S.
  • The Journal of Chemical Physics, Vol. 142, Issue 10
  • DOI: 10.1063/1.4906894

Water oxidation catalysis via immobilization of the dimanganese complex [Mn2(μ-O)2Cl(μ-O2CCH3)(bpy)2(H2O)](NO3)2 onto silica
journal, January 2013

  • Rumberger, Evan M. W.; Ahn, Hyun S.; Bell, Alexis T.
  • Dalton Transactions, Vol. 42, Issue 34
  • DOI: 10.1039/c3dt51472b

Novel Interface-Mediated Metastable Oxide Phases: Vanadium Oxides on Pd(111)
journal, August 2001


V2O5 nanoparticles obtained from a synthetic bariandite-like vanadium oxide: Synthesis, characterization and electrochemical behavior in an ionic liquid
journal, September 2009

  • Menezes, Willian G.; Reis, Dayane M.; Benedetti, Tânia M.
  • Journal of Colloid and Interface Science, Vol. 337, Issue 2
  • DOI: 10.1016/j.jcis.2009.05.050

Enhancement of O 2 Dissociation on Au(111) by Adsorbed Oxygen:  Implications for Oxidation Catalysis
journal, June 2005

  • Deng, Xingyi; Min, Byoung Koun; Guloy, Amado
  • Journal of the American Chemical Society, Vol. 127, Issue 25
  • DOI: 10.1021/ja050144j

Design and Synthesis of Vanadium Hydrazide Gels for Kubas-Type Hydrogen Adsorption: A New Class of Hydrogen Storage Materials
journal, August 2010

  • Hoang, Tuan K. A.; Webb, Michael I.; Mai, Hung V.
  • Journal of the American Chemical Society, Vol. 132, Issue 33
  • DOI: 10.1021/ja104926h

Direct Synthesis of Vanadium Phthalocyanine and Its Electronic and Magnetic States in Monolayers and Multilayers on Ag(111)
journal, April 2015

  • Eguchi, Keitaro; Nakagawa, Takeshi; Takagi, Yasumasa
  • The Journal of Physical Chemistry C, Vol. 119, Issue 18
  • DOI: 10.1021/jp512935v

Electronic structure of radical anionic binuclear organoplatinum complexes. A multiple frequency EPR investigation
journal, January 1998

  • Klein, Axel; McInnes, Eric J. L.; Scheiring, Thomas
  • Journal of the Chemical Society, Faraday Transactions, Vol. 94, Issue 19
  • DOI: 10.1039/a803057j

The surface reconstructions of the (100) crystal faces of iridium, platinum and gold
journal, February 1981


Highly Active and Recyclable Heterogeneous Iridium Pincer Catalysts for Transfer Dehydrogenation of Alkanes
journal, January 2009

  • Huang, Zheng; Brookhart, Maurice; Goldman, Alan S.
  • Advanced Synthesis & Catalysis, Vol. 351, Issue 1-2
  • DOI: 10.1002/adsc.200800615

The growth of vanadium oxide on alumina and titania single crystal surfaces
journal, January 1999

  • Madix, Robert J.; Biener, Jürgen; Bäumer, Marcus
  • Faraday Discussions, Vol. 114
  • DOI: 10.1039/a902737h

Determination of the V2p XPS binding energies for different vanadium oxidation states (V5+ to V0+)
journal, April 2004

  • Silversmit, Geert; Depla, Diederik; Poelman, Hilde
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 135, Issue 2-3
  • DOI: 10.1016/j.elspec.2004.03.004

Real-space observation of the reconstruction of Au(100)
journal, September 1984


Synthesis, structural characterization and electrochemical activity of oxidovanadium(IV/V) complexes of a diprotic ONS chelating ligand
journal, October 2010

  • Sutradhar, Manas; Roy Barman, Tannistha; Mukherjee, Gurunath
  • Inorganica Chimica Acta, Vol. 363, Issue 13
  • DOI: 10.1016/j.ica.2010.06.025

Organometallic synthesis, reactivity and catalysis in the solid state using well-defined single-site species
journal, March 2015

  • Pike, Sebastian D.; Weller, Andrew S.
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 373, Issue 2037
  • DOI: 10.1098/rsta.2014.0187

Catalysis science of supported vanadium oxide catalysts
journal, January 2013


Electrical Detection of Amine Ligation to a Metalloporphyrin via a Hybrid SOI-MOSFET
journal, February 2008

  • Takulapalli, Bharath R.; Laws, Gez M.; Liddell, Paul A.
  • Journal of the American Chemical Society, Vol. 130, Issue 7
  • DOI: 10.1021/ja076328a

Mobility and Reactivity of 4-Substituted TEMPO Derivatives in Metal–Organic Framework MIL-53(Al)
journal, May 2016

  • Poryvaev, A. S.; Sheveleva, A. M.; Kolokolov, D. I.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 19
  • DOI: 10.1021/acs.jpcc.6b02966

Spectroscopically Distinct Sites Present in Methyltrioxorhenium Grafted onto Silica−Alumina, and Their Abilities to Initiate Olefin Metathesis
journal, July 2007

  • Moses, Anthony W.; Raab, Christina; Nelson, Ryan C.
  • Journal of the American Chemical Society, Vol. 129, Issue 28
  • DOI: 10.1021/ja072707s

A new twist to 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine complexes of silver(i)
journal, January 2008

  • Constable, Edwin C.; Housecroft, Catherine E.; Neuburger, Markus
  • CrystEngComm, Vol. 10, Issue 8
  • DOI: 10.1039/b803006e

Formation of Vanadium Oxide Films on Cu3Au(100)
journal, September 2001


Two- and Three-Electron Oxidation of Single-Site Vanadium Centers at Surfaces by Ligand Design
journal, June 2015

  • Skomski, Daniel; Tempas, Christopher D.; Cook, Brian J.
  • Journal of the American Chemical Society, Vol. 137, Issue 24
  • DOI: 10.1021/jacs.5b03706

Vanadium oxide nanostructures on another oxide: The viewpoint from model catalysts studies
journal, October 2015

  • Artiglia, Luca; Agnoli, Stefano; Granozzi, Gaetano
  • Coordination Chemistry Reviews, Vol. 301-302
  • DOI: 10.1016/j.ccr.2014.12.015

Understanding domain symmetry in vanadium oxide phthalocyanine monolayers on Au (111)
journal, October 2014


The surface functionalisation of gold nanoparticles with metal complexes
journal, January 2008


Low-Temperature Dehydrogenation of Ethanol on Atomically Dispersed Gold Supported on ZnZrO x
journal, December 2015

  • Wang, Chongyang; Garbarino, Gabriella; Allard, Lawrence F.
  • ACS Catalysis, Vol. 6, Issue 1
  • DOI: 10.1021/acscatal.5b01593

Single-Site Heterogeneous Catalysts
journal, October 2005

  • Thomas, John Meurig; Raja, Robert; Lewis, Dewi W.
  • Angewandte Chemie International Edition, Vol. 44, Issue 40, p. 6456-6482
  • DOI: 10.1002/anie.200462473

Surface Organometallic and Coordination Chemistry toward Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities
journal, January 2016


Revealing the Presence of Mobile Molecules on the Surface
journal, December 2016

  • Antczak, G.; Boom, K.; Morgenstern, K.
  • The Journal of Physical Chemistry C, Vol. 121, Issue 1
  • DOI: 10.1021/acs.jpcc.6b11246

IR spectra of VO2 and V2O3
journal, October 1997


The Surface Trans Effect: Influence of Axial Ligands on the Surface Chemical Bonds of Adsorbed Metalloporphyrins
journal, April 2011

  • Hieringer, Wolfgang; Flechtner, Ken; Kretschmann, Andreas
  • Journal of the American Chemical Society, Vol. 133, Issue 16
  • DOI: 10.1021/ja1093502

Oxo(porphyrinato)vanadium(IV) as a standard for geoporphyrins
journal, January 2016


Thermochromic VO 2 Films Deposited by RF Magnetron Sputtering Using V 2 O 3 or V 2 O 5 Targets
journal, October 2000

  • Shigesato, Yuzo; Enomoto, Mikiko; Odaka, Hidehumi
  • Japanese Journal of Applied Physics, Vol. 39, Issue Part 1, No. 10
  • DOI: 10.1143/JJAP.39.6016

Anion−π Interactions as Controlling Elements in Self-Assembly Reactions of Ag(I) Complexes with π-Acidic Aromatic Rings
journal, May 2006

  • Schottel, Brandi L.; Chifotides, Helen T.; Shatruk, Mikhail
  • Journal of the American Chemical Society, Vol. 128, Issue 17
  • DOI: 10.1021/ja0606273

Self-Catalyzed Carbon Dioxide Adsorption by Metal–Organic Chains on Gold Surfaces
journal, July 2014


Metal−Organic Coordination Interactions in Fe−Terephthalic Acid Networks on Cu(100)
journal, February 2008

  • Tait, Steven L.; Wang, Yeliang; Costantini, Giovanni
  • Journal of the American Chemical Society, Vol. 130, Issue 6
  • DOI: 10.1021/ja0778186

Reactions of phosphinites with oxide surfaces: a new method for anchoring organic and organometallic complexes
journal, January 2011

  • Vicente, Brian C.; Huang, Zheng; Brookhart, Maurice
  • Dalton Transactions, Vol. 40, Issue 16
  • DOI: 10.1039/c0dt01369b

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Stereoselectivity and electrostatics in charge-transfer Mn- and Cs-TCNQ4 networks on Ag(100)
journal, January 2012

  • Abdurakhmanova, Nasiba; Floris, Andrea; Tseng, Tzu-Chun
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1942

Redox-Active On-Surface Assembly of Metal–Organic Chains with Single-Site Pt(II)
journal, July 2014

  • Skomski, Daniel; Tempas, Christopher D.; Smith, Kevin A.
  • Journal of the American Chemical Society, Vol. 136, Issue 28
  • DOI: 10.1021/ja504850f

Metal–Ligand Complexation through Redox Assembly at Surfaces Characterized by Vibrational Spectroscopy
journal, June 2017

  • Williams, Christopher G.; Wang, Miao; Skomski, Daniel
  • The Journal of Physical Chemistry C, Vol. 121, Issue 24
  • DOI: 10.1021/acs.jpcc.7b02809

Ultra thin V2O3 films grown on oxidized Si(111)
journal, September 2009


Nature, growth, and stability of vanadium oxides on Pd(111)
journal, July 1999

  • Leisenberger, F. P.; Surnev, S.; Vitali, L.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 17, Issue 4
  • DOI: 10.1116/1.581884

Deposition and characterization of stoichiometric films of V 2 O 5 on Pd(111)
journal, October 2017


Reaction of Au(111) with Sulfur and Oxygen: Scanning Tunneling Microscopic Study
journal, August 2005


Controlling Hydrogen Activation, Spillover, and Desorption with Pd–Au Single-Atom Alloys
journal, January 2016

  • Lucci, Felicia R.; Darby, Matthew T.; Mattera, Michael F. G.
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 3
  • DOI: 10.1021/acs.jpclett.5b02400

(V 2 O 5 ) n Gas-Phase Clusters ( n = 1−12) Compared to V 2 O 5 Crystal:  DFT Calculations
journal, September 2001

  • Vyboishchikov, Sergei F.; Sauer, Joachim
  • The Journal of Physical Chemistry A, Vol. 105, Issue 37
  • DOI: 10.1021/jp012294w

Lifting of the Au(100) surface reconstruction by Pt, Cr, Fe, and Cu adsorption
journal, December 2016


Digitized Charge Transfer Magnitude Determined by Metal–Organic Coordination Number
journal, March 2013

  • Yang, Hung-Hsiang; Chu, Yu-Hsun; Lu, Chun-I
  • ACS Nano, Vol. 7, Issue 3
  • DOI: 10.1021/nn4003715

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Multi‐electron Reduction Capacity and Multiple Binding Pockets in Metal–Organic Redox Assembly at Surfaces
journal, March 2019

  • Morris, Tobias W.; Huerfano, I. J.; Wang, Miao
  • Chemistry – A European Journal, Vol. 25, Issue 21
  • DOI: 10.1002/chem.201900002

Polycyclic N -oxides: high performing, low sensitivity energetic materials
journal, January 2019

  • Snyder, Christopher J.; Wells, Lucille A.; Chavez, David E.
  • Chemical Communications, Vol. 55, Issue 17
  • DOI: 10.1039/c8cc09653h