Stable isotopic composition of perchlorate and nitrate accumulated in plants: Hydroponic experiments and field data

doi:10.1016/j.scitotenv.2017.03.223

Title: Stable isotopic composition of perchlorate and nitrate accumulated in plants: Hydroponic experiments and field data

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Publication Date:: 2017-10-01

Sponsoring Org.:: USDOE

OSTI Identifier:: 1416052

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Science of the Total Environment

Additional Journal Information:: Journal Name: Science of the Total Environment Journal Volume: 595 Journal Issue: C; Journal ID: ISSN 0048-9697

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

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                    Estrada, Nubia Luz, Böhlke, J. K., Sturchio, Neil C., Gu, Baohua, Harvey, Greg, Burkey, Kent O., Grantz, David A., McGrath, Margaret T., Anderson, Todd A., Rao, Balaji, Sevanthi, Ritesh, Hatzinger, Paul B., and Jackson, W. Andrew. Stable isotopic composition of perchlorate and nitrate accumulated in plants: Hydroponic experiments and field data.  Netherlands: N. p., 2017. 
        Web.  doi:10.1016/j.scitotenv.2017.03.223.

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                    Estrada, Nubia Luz, Böhlke, J. K., Sturchio, Neil C., Gu, Baohua, Harvey, Greg, Burkey, Kent O., Grantz, David A., McGrath, Margaret T., Anderson, Todd A., Rao, Balaji, Sevanthi, Ritesh, Hatzinger, Paul B., & Jackson, W. Andrew. Stable isotopic composition of perchlorate and nitrate accumulated in plants: Hydroponic experiments and field data.  Netherlands.  doi:10.1016/j.scitotenv.2017.03.223.

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                    Estrada, Nubia Luz, Böhlke, J. K., Sturchio, Neil C., Gu, Baohua, Harvey, Greg, Burkey, Kent O., Grantz, David A., McGrath, Margaret T., Anderson, Todd A., Rao, Balaji, Sevanthi, Ritesh, Hatzinger, Paul B., and Jackson, W. Andrew. Sun .  
        "Stable isotopic composition of perchlorate and nitrate accumulated in plants: Hydroponic experiments and field data".  Netherlands.  doi:10.1016/j.scitotenv.2017.03.223.

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@article{osti_1416052,

  title        = {Stable isotopic composition of perchlorate and nitrate accumulated in plants: Hydroponic experiments and field data},

  author       = {Estrada, Nubia Luz and Böhlke, J. K. and Sturchio, Neil C. and Gu, Baohua and Harvey, Greg and Burkey, Kent O. and Grantz, David A. and McGrath, Margaret T. and Anderson, Todd A. and Rao, Balaji and Sevanthi, Ritesh and Hatzinger, Paul B. and Jackson, W. Andrew},

  abstractNote = {},

  doi          = {10.1016/j.scitotenv.2017.03.223},

  journal      = {Science of the Total Environment},

  number       = C,

  volume       = 595,

  place        = {Netherlands},

  year         = {2017},

  month        = {10}

}

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DOI: 10.1016/j.scitotenv.2017.03.223

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Stable isotopic composition of perchlorate and nitrate accumulated in plants: Hydroponic experiments and field data

Journal Article Estrada, Nubia Luz ; Böhlke, J. K. ; Sturchio, Neil C. ; ... - Science of the Total Environment

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Perchlorate (ClO4-) has been detected over an expansive area in groundwater and soils in the southwestern United States. Because of its wide distribution, much of the ClO4- is presumed to be from natural sources, primarily atmospheric deposition and accumulation. The objective of this study was to evaluate the range of the isotopic composition of natural ClO4- indigenous to the southwestern U.S. Stable isotope ratios of Cl and O were determined for ClO4- collected from numerous sources, including: groundwater from several locations in the southern high plains (SHP) of Texas and New Mexico and the middle Rio Grande Basin in Newmore »« less
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Perchlorate (ClO ₄ ^-) is a common trace constituent of water, soils, and plants; it has both natural and synthetic sources and is subject to biodegradation. The stable isotope ratios of Cl and O provide three independent quantities for ClO ₄ ^- source attribution and natural attenuation studies: δ ³⁷Cl, δ ¹⁸O, and δ ¹⁷O (or Δ ¹⁷O or ¹⁷Δ) values. Finally, documented reference materials, calibration schemes, methods, and interferences will improve the reliability of such studies.
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