Investigation of a Structural Phase Transition and Magnetic Structure of Na2BaFe(VO4)2: A Triangular Magnetic Lattice with a Ferromagnetic Ground State
Abstract
The structural and magnetic properties of a glaserite-type Na2BaFe(VO4)2 compound, featuring a triangular magnetic lattice of Fe2+ (S = 2), are reported. Temperature dependent X-ray single crystal studies indicate that at room temperature the system adopts a trigonal P$$\bar{3}$$m1 structure and undergoes a structural phase transition to a C2/c monoclinic phase slightly below room temperature (Ts = 288 K). This structural transition involves a tilting of Fe–O–V bond angles and strongly influences the magnetic correlation within the Fe triangular lattice. The magnetic susceptibility measurements reveal a ferromagnetic transition near 7 K. Single crystal neutron diffraction confirms the structural distortion and the ferromagnetic spin ordering in Na2BaFe(VO4)2. The magnetic structure of the ordered state is modeled in the magnetic space group C2'/c' that implies a ferromagnetic order of the a and c moment components and antiferromagnetic arrangement for the b components. Altogether, the Fe magnetic moments form ferromagnetic layers that are stacked along the c-axis, where the spins point along one of the (111) facets of the FeO6 octahedron.
- Authors:
-
[2];
[2];
[2];
[1];
- Clemson Univ., Clemson, SC (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1415912
- Alternate Identifier(s):
- OSTI ID: 1468008
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganic Chemistry
- Additional Journal Information:
- Journal Volume: 56; Journal Issue: 24; Journal ID: ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Sanjeewa, Liurukara D., Garlea, Vasile O., McGuire, Michael A., Frontzek, Matthias D., McMillen, Colin D., Fulle, Kyle, and Kolis, Joseph W. Investigation of a Structural Phase Transition and Magnetic Structure of Na2BaFe(VO4)2: A Triangular Magnetic Lattice with a Ferromagnetic Ground State. United States: N. p., 2017.
Web. doi:10.1021/acs.inorgchem.7b02024.
Sanjeewa, Liurukara D., Garlea, Vasile O., McGuire, Michael A., Frontzek, Matthias D., McMillen, Colin D., Fulle, Kyle, & Kolis, Joseph W. Investigation of a Structural Phase Transition and Magnetic Structure of Na2BaFe(VO4)2: A Triangular Magnetic Lattice with a Ferromagnetic Ground State. United States. https://doi.org/10.1021/acs.inorgchem.7b02024
Sanjeewa, Liurukara D., Garlea, Vasile O., McGuire, Michael A., Frontzek, Matthias D., McMillen, Colin D., Fulle, Kyle, and Kolis, Joseph W. Thu .
"Investigation of a Structural Phase Transition and Magnetic Structure of Na2BaFe(VO4)2: A Triangular Magnetic Lattice with a Ferromagnetic Ground State". United States. https://doi.org/10.1021/acs.inorgchem.7b02024. https://www.osti.gov/servlets/purl/1415912.
@article{osti_1415912,
title = {Investigation of a Structural Phase Transition and Magnetic Structure of Na2BaFe(VO4)2: A Triangular Magnetic Lattice with a Ferromagnetic Ground State},
author = {Sanjeewa, Liurukara D. and Garlea, Vasile O. and McGuire, Michael A. and Frontzek, Matthias D. and McMillen, Colin D. and Fulle, Kyle and Kolis, Joseph W.},
abstractNote = {The structural and magnetic properties of a glaserite-type Na2BaFe(VO4)2 compound, featuring a triangular magnetic lattice of Fe2+ (S = 2), are reported. Temperature dependent X-ray single crystal studies indicate that at room temperature the system adopts a trigonal P$\bar{3}$m1 structure and undergoes a structural phase transition to a C2/c monoclinic phase slightly below room temperature (Ts = 288 K). This structural transition involves a tilting of Fe–O–V bond angles and strongly influences the magnetic correlation within the Fe triangular lattice. The magnetic susceptibility measurements reveal a ferromagnetic transition near 7 K. Single crystal neutron diffraction confirms the structural distortion and the ferromagnetic spin ordering in Na2BaFe(VO4)2. The magnetic structure of the ordered state is modeled in the magnetic space group C2'/c' that implies a ferromagnetic order of the a and c moment components and antiferromagnetic arrangement for the b components. Altogether, the Fe magnetic moments form ferromagnetic layers that are stacked along the c-axis, where the spins point along one of the (111) facets of the FeO6 octahedron.},
doi = {10.1021/acs.inorgchem.7b02024},
journal = {Inorganic Chemistry},
number = 24,
volume = 56,
place = {United States},
year = {Thu Dec 07 00:00:00 EST 2017},
month = {Thu Dec 07 00:00:00 EST 2017}
}
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Figures / Tables:
Table 1: Structure Refinements of Na2BaFe(VO4)2 at 300 and 100 K Determined by Single Crystal X-ray Diffraction
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Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.