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Title: Bimetallic Ag-Pt Sub-nanometer Supported Clusters as Highly Efficient and Robust Oxidation Catalysts

Authors:
 [1]; ORCiD logo [2];  [2];  [3]; ORCiD logo [1]; ORCiD logo [1];  [2];  [2];  [4];  [4];  [5];  [3];  [6];  [6];  [7];  [8]; ORCiD logo [9]; ORCiD logo [10]
  1. CNR-ICCOM & IPCF, Consiglio Nazionale delle Ricerche, Pisa Italy
  2. Materials Science Division, Argonne National Laboratory, Lemont IL USA
  3. Harish-Chandra Research Institute, HBNI, Chhatnag Road Jhunsi Allahabad 211019 India
  4. Institut für Physik, Universität Rostock, Rostock Germany
  5. X-ray Science Division, Argonne National Laboratory, Lemont IL USA
  6. Chemistry Division, Bhabha Atomic Research Centre, Trombay Mumbai- 400 085 India
  7. East Tokyo Laboratory, Genesis Research Institute, Inc., Ichikawa Chiba 272-0001 Japan
  8. Cluster Research Laboratory, Toyota Technological Institute: in, East Tokyo Laboratory, Genesis Research Institute, Inc. Ichikawa, Chiba 272-0001 Japan
  9. Materials Science Division, Argonne National Laboratory, Lemont IL USA, Nanoscience and Technology Division, Argonne National Laboratory, Lemont IL USA, Institute for Molecular Engineering, University of Chicago, Chicago IL USA
  10. CNR-ICCOM & IPCF, Consiglio Nazionale delle Ricerche, Pisa Italy, Materials and Process Simulation Center, California Institute of Technology, Pasadena CA USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1415151
Grant/Contract Number:  
AC- 02-06CH11357, DE-AC-02-06CH11357; Grant Number 15K04594
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition) Journal Volume: 57 Journal Issue: 5; Journal ID: ISSN 1433-7851
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Negreiros, Fabio R., Halder, Avik, Yin, Chunrong, Singh, Akansha, Barcaro, Giovanni, Sementa, Luca, Tyo, Eric C., Pellin, Michael J., Bartling, Stephan, Meiwes-Broer, Karl-Heinz, Seifert, Sönke, Sen, Prasenjit, Nigam, Sandeep, Majumder, Chiranjib, Fukui, Nobuyuki, Yasumatsu, Hisato, Vajda, Stefan, and Fortunelli, Alessandro. Bimetallic Ag-Pt Sub-nanometer Supported Clusters as Highly Efficient and Robust Oxidation Catalysts. Germany: N. p., 2017. Web. doi:10.1002/anie.201709784.
Negreiros, Fabio R., Halder, Avik, Yin, Chunrong, Singh, Akansha, Barcaro, Giovanni, Sementa, Luca, Tyo, Eric C., Pellin, Michael J., Bartling, Stephan, Meiwes-Broer, Karl-Heinz, Seifert, Sönke, Sen, Prasenjit, Nigam, Sandeep, Majumder, Chiranjib, Fukui, Nobuyuki, Yasumatsu, Hisato, Vajda, Stefan, & Fortunelli, Alessandro. Bimetallic Ag-Pt Sub-nanometer Supported Clusters as Highly Efficient and Robust Oxidation Catalysts. Germany. doi:10.1002/anie.201709784.
Negreiros, Fabio R., Halder, Avik, Yin, Chunrong, Singh, Akansha, Barcaro, Giovanni, Sementa, Luca, Tyo, Eric C., Pellin, Michael J., Bartling, Stephan, Meiwes-Broer, Karl-Heinz, Seifert, Sönke, Sen, Prasenjit, Nigam, Sandeep, Majumder, Chiranjib, Fukui, Nobuyuki, Yasumatsu, Hisato, Vajda, Stefan, and Fortunelli, Alessandro. Fri . "Bimetallic Ag-Pt Sub-nanometer Supported Clusters as Highly Efficient and Robust Oxidation Catalysts". Germany. doi:10.1002/anie.201709784.
@article{osti_1415151,
title = {Bimetallic Ag-Pt Sub-nanometer Supported Clusters as Highly Efficient and Robust Oxidation Catalysts},
author = {Negreiros, Fabio R. and Halder, Avik and Yin, Chunrong and Singh, Akansha and Barcaro, Giovanni and Sementa, Luca and Tyo, Eric C. and Pellin, Michael J. and Bartling, Stephan and Meiwes-Broer, Karl-Heinz and Seifert, Sönke and Sen, Prasenjit and Nigam, Sandeep and Majumder, Chiranjib and Fukui, Nobuyuki and Yasumatsu, Hisato and Vajda, Stefan and Fortunelli, Alessandro},
abstractNote = {},
doi = {10.1002/anie.201709784},
journal = {Angewandte Chemie (International Edition)},
number = 5,
volume = 57,
place = {Germany},
year = {2017},
month = {12}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/anie.201709784

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Cited by: 7 works
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Works referenced in this record:

Catalytic CO oxidation reaction studies on lithographically fabricated platinum nanowire arrays with different oxide supports
journal, October 2006


Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects
journal, April 2010


Pd–Au bimetallic catalysts: understanding alloy effects from planar models and (supported) nanoparticles
journal, January 2012

  • Gao, Feng; Goodman, D. Wayne
  • Chemical Society Reviews, Vol. 41, Issue 24
  • DOI: 10.1039/c2cs35160a

CO Oxidation on Au Nanoparticles Supported on ZrO 2 : Role of Metal/Oxide Interface and Oxide Reducibility
journal, February 2017


CO Oxidation as a Prototypical Reaction for Heterogeneous Processes
journal, September 2011

  • Freund, Hans-Joachim; Meijer, Gerard; Scheffler, Matthias
  • Angewandte Chemie International Edition, Vol. 50, Issue 43
  • DOI: 10.1002/anie.201101378

Preparation of intense multi-element metal cluster ions with single composition
journal, September 2009


Structure of bimetallic clusters
journal, April 1987


Concepts in theoretical heterogeneous ultrananocatalysis
journal, July 2014


Catalysis by clusters with precise numbers of atoms
journal, July 2015


Alumina-supported sub-nanometer Pt 10 clusters: amorphization and role of the support material in a highly active CO oxidation catalyst
journal, January 2017

  • Yin, Chunrong; Negreiros, Fabio R.; Barcaro, Giovanni
  • Journal of Materials Chemistry A, Vol. 5, Issue 10
  • DOI: 10.1039/C6TA10989F

Does enhanced oxygen activation always facilitate CO oxidation on gold clusters?
journal, September 2015

  • Mondal, Krishnakanta; Banerjee, Arup; Fortunelli, Alessandro
  • Journal of Computational Chemistry, Vol. 36, Issue 29
  • DOI: 10.1002/jcc.24194

Reactive scattering of clusters and cluster ions from solid surfaces
journal, September 2003


Adsorption of Small Hydrocarbons on the Three-Fold PdGa Surfaces: The Road to Selective Hydrogenation
journal, August 2014

  • Prinz, Jan; Pignedoli, Carlo A.; Stöckl, Quirin S.
  • Journal of the American Chemical Society, Vol. 136, Issue 33
  • DOI: 10.1021/ja505936b

Catalytic Oxidation of Carbon Monoxide on Monodispersed Platinum Clusters:  Each Atom Counts
journal, April 1999

  • Heiz, U.; Sanchez, A.; Abbet, S.
  • Journal of the American Chemical Society, Vol. 121, Issue 13
  • DOI: 10.1021/ja983616l

Reactivity of supported platinum nanoclusters studied by in situ GISAXS: clusters stability under hydrogen
journal, October 2006

  • Winans, Randall E.; Vajda, Stefan; Ballentine, Gregory E.
  • Topics in Catalysis, Vol. 39, Issue 3-4
  • DOI: 10.1007/s11244-006-0050-5

Magic silver cluster on a MgO(100) terrace with defects
journal, October 2007


Gasphasenkatalyse mit atomaren und Cluster-Metall-Ionen: ultimative “Single-Site”-Katalysatoren
journal, March 2005


Atomic Resolution Observation of a Size-Dependent Change in the Ripening Modes of Mass-Selected Au Nanoclusters Involved in CO Oxidation
journal, November 2015

  • Hu, Kuo-Juei; Plant, Simon R.; Ellis, Peter R.
  • Journal of the American Chemical Society, Vol. 137, Issue 48
  • DOI: 10.1021/jacs.5b08720

Generating Highly Active Partially Oxidized Platinum during Oxidation of Carbon Monoxide over Pt/Al 2 O 3 : In Situ, Time-Resolved, and High-Energy-Resolution X-Ray Absorption Spectroscopy
journal, October 2008

  • Singh, Jagdeep; Alayon, Evalyn M. C.; Tromp, Moniek
  • Angewandte Chemie International Edition, Vol. 47, Issue 48
  • DOI: 10.1002/anie.200803427

Generation of intense and cold beam of Pt-Ag bi-element cluster ions having single-composition
journal, March 2011


Catalytic oxidation of CO by platinum group metals: from ultrahigh vacuum to elevated pressures
journal, August 2002


Die CO-Oxidation als Modellreaktion für heterogene Prozesse
journal, September 2011

  • Freund, Hans-Joachim; Meijer, Gerard; Scheffler, Matthias
  • Angewandte Chemie, Vol. 123, Issue 43
  • DOI: 10.1002/ange.201101378

Complementary Active Sites Cause Size-Selective Reactivity of Aluminum Cluster Anions with Water
journal, January 2009


Recent advances in the chemistry of gas phase transition metal clusters
journal, January 1990


A Magic Pd−Ag Binary Cluster on the F s -Defected MgO(100) Surface
journal, August 2007

  • Barcaro, Giovanni; Fortunelli, Alessandro
  • The Journal of Physical Chemistry C, Vol. 111, Issue 30
  • DOI: 10.1021/jp072263m

Interaction and Reaction of Ethylene and Oxygen on Six-Atom Silver Clusters Supported on LTA Zeolite
journal, October 2009

  • Baldansuren, Amgalanbaatar; Dilger, Herbert; Eichel, Rüdiger-A.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 45
  • DOI: 10.1021/jp906480q

Gas-Phase Catalysis by Atomic and Cluster Metal Ions: The Ultimate Single-Site Catalysts
journal, March 2005

  • Böhme, Diethard K.; Schwarz, Helmut
  • Angewandte Chemie International Edition, Vol. 44, Issue 16
  • DOI: 10.1002/anie.200461698

Simultaneous measurement of X-ray small angle scattering, absorption and reactivity: A continuous flow catalysis reactor
journal, September 2011

  • Lee, Sungsik; Lee, Byeongdu; Seifert, Soenke
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 649, Issue 1
  • DOI: 10.1016/j.nima.2010.12.172

Activation of Molecular Oxygen and the Nature of the Active Oxygen Species for CO Oxidation on Oxide Supported Au Catalysts
journal, December 2013

  • Widmann, D.; Behm, R. J.
  • Accounts of Chemical Research, Vol. 47, Issue 3
  • DOI: 10.1021/ar400203e

Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane
journal, February 2009

  • Vajda, Stefan; Pellin, Michael J.; Greeley, Jeffrey P.
  • Nature Materials, Vol. 8, Issue 3
  • DOI: 10.1038/nmat2384

CO Oxidation by Subnanometer Ag x Au 3– x Supported Clusters via Density Functional Theory Simulations
journal, July 2012

  • Negreiros, F. R.; Sementa, L.; Barcaro, G.
  • ACS Catalysis, Vol. 2, Issue 9
  • DOI: 10.1021/cs300275v