0D-2D and 1D-2D Semiconductor Hybrids Composed of All Inorganic Perovskite Nanocrystals and Single-Layer Graphene with Improved Light Harvesting
Abstract
In this study, inorganic cesium lead iodide (CsPbI3) perovskite nanoparticles (PNPs) and perovskite nanowires (PNWs) with single-layer graphene (SLG) are combined to obtain 0D–2D PNP–SLG and 1D–2D PNW–SLG hybrids with improved light harvesting. Time-resolved single-nanostructure photoluminescence studies of PNPs, PNWs, and related hybrids reveal (i) quasi-two-state photoluminescence blinking in PNPs, (ii) highly polarized photoluminescence emitted by PNWs and (iii) efficient interfacial electron transfer between perovskite nanostructures and SLG in both PNP–SLG and PNW–SLG hybrids. Thus, doping of poorly absorbing, highly conductive SLG with perovskite nanocrystals and nanowires provides a simple, yet efficient path to obtain hybrids with increased light-harvesting properties for potential utilization in the next-generation photodetectors and photovoltaic devices, including polarization sensitive photodetectors.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN); Stony Brook Univ., NY (United States). Dept. of Materials Science and Chemical Engineering
- Syracuse Univ., NY (United States). Dept. of Chemistry
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1414964
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Particle & Particle Systems Characterization
- Additional Journal Information:
- Journal Name: Particle & Particle Systems Characterization Journal Volume: 35 Journal Issue: 2; Journal ID: ISSN 0934-0866
- Publisher:
- Wiley
- Country of Publication:
- Germany
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Chen, Jia-Shiang, Doane, Tennyson L., Li, Mingxing, Zang, Huidong, Maye, Mathew M., and Cotlet, Mircea. 0D-2D and 1D-2D Semiconductor Hybrids Composed of All Inorganic Perovskite Nanocrystals and Single-Layer Graphene with Improved Light Harvesting. Germany: N. p., 2017.
Web. doi:10.1002/ppsc.201700310.
Chen, Jia-Shiang, Doane, Tennyson L., Li, Mingxing, Zang, Huidong, Maye, Mathew M., & Cotlet, Mircea. 0D-2D and 1D-2D Semiconductor Hybrids Composed of All Inorganic Perovskite Nanocrystals and Single-Layer Graphene with Improved Light Harvesting. Germany. https://doi.org/10.1002/ppsc.201700310
Chen, Jia-Shiang, Doane, Tennyson L., Li, Mingxing, Zang, Huidong, Maye, Mathew M., and Cotlet, Mircea. Wed .
"0D-2D and 1D-2D Semiconductor Hybrids Composed of All Inorganic Perovskite Nanocrystals and Single-Layer Graphene with Improved Light Harvesting". Germany. https://doi.org/10.1002/ppsc.201700310.
@article{osti_1414964,
title = {0D-2D and 1D-2D Semiconductor Hybrids Composed of All Inorganic Perovskite Nanocrystals and Single-Layer Graphene with Improved Light Harvesting},
author = {Chen, Jia-Shiang and Doane, Tennyson L. and Li, Mingxing and Zang, Huidong and Maye, Mathew M. and Cotlet, Mircea},
abstractNote = {In this study, inorganic cesium lead iodide (CsPbI3) perovskite nanoparticles (PNPs) and perovskite nanowires (PNWs) with single-layer graphene (SLG) are combined to obtain 0D–2D PNP–SLG and 1D–2D PNW–SLG hybrids with improved light harvesting. Time-resolved single-nanostructure photoluminescence studies of PNPs, PNWs, and related hybrids reveal (i) quasi-two-state photoluminescence blinking in PNPs, (ii) highly polarized photoluminescence emitted by PNWs and (iii) efficient interfacial electron transfer between perovskite nanostructures and SLG in both PNP–SLG and PNW–SLG hybrids. Thus, doping of poorly absorbing, highly conductive SLG with perovskite nanocrystals and nanowires provides a simple, yet efficient path to obtain hybrids with increased light-harvesting properties for potential utilization in the next-generation photodetectors and photovoltaic devices, including polarization sensitive photodetectors.},
doi = {10.1002/ppsc.201700310},
journal = {Particle & Particle Systems Characterization},
number = 2,
volume = 35,
place = {Germany},
year = {Wed Dec 27 00:00:00 EST 2017},
month = {Wed Dec 27 00:00:00 EST 2017}
}
https://doi.org/10.1002/ppsc.201700310
Web of Science
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