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Title: Diphosphine-protected ultrasmall gold nanoclusters: opened icosahedral Au 13 and heart-shaped Au 8 clusters

Two ultrasmall gold clusters, Au 13 and Au 8 , were identified as a distorted I h icosahedral Au 13 and edge-shared “core + 4 exo ” structure Au 8 S 2 cores, respectively. They showed interesting luminescence and electrochemical properties.
Authors:
 [1] ;  [1] ;  [2] ; ORCiD logo [2] ;  [1] ;  [1] ;  [1] ; ORCiD logo [1]
  1. Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan
  2. Department of Chemistry, Kansas State University, Manhattan, USA
Publication Date:
Grant/Contract Number:
SC0012273
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 9; Journal Issue: 5; Related Information: CHORUS Timestamp: 2018-01-31 09:06:36; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1414486