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Title: Diphosphine-protected ultrasmall gold nanoclusters: opened icosahedral Au 13 and heart-shaped Au 8 clusters

Abstract

Two ultrasmall gold clusters, Au 13 and Au 8 , were identified as a distorted I h icosahedral Au 13 and edge-shared “core + 4 exo ” structure Au 8 S 2 cores, respectively. They showed interesting luminescence and electrochemical properties.

Authors:
 [1];  [1];  [2]; ORCiD logo [2];  [1];  [1];  [1]; ORCiD logo [1]
  1. Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan
  2. Department of Chemistry, Kansas State University, Manhattan, USA
Publication Date:
Research Org.:
Kansas State Univ., Manhattan, KS (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1414486
Alternate Identifier(s):
OSTI ID: 1506064
Grant/Contract Number:  
SC0012273
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 5; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Zhang, Shan-Shan, Feng, Lei, Senanayake, Ravithree D., Aikens, Christine M., Wang, Xing-Po, Zhao, Quan-Qin, Tung, Chen-Ho, and Sun, Di. Diphosphine-protected ultrasmall gold nanoclusters: opened icosahedral Au 13 and heart-shaped Au 8 clusters. United Kingdom: N. p., 2018. Web. doi:10.1039/C7SC03566G.
Zhang, Shan-Shan, Feng, Lei, Senanayake, Ravithree D., Aikens, Christine M., Wang, Xing-Po, Zhao, Quan-Qin, Tung, Chen-Ho, & Sun, Di. Diphosphine-protected ultrasmall gold nanoclusters: opened icosahedral Au 13 and heart-shaped Au 8 clusters. United Kingdom. doi:10.1039/C7SC03566G.
Zhang, Shan-Shan, Feng, Lei, Senanayake, Ravithree D., Aikens, Christine M., Wang, Xing-Po, Zhao, Quan-Qin, Tung, Chen-Ho, and Sun, Di. Mon . "Diphosphine-protected ultrasmall gold nanoclusters: opened icosahedral Au 13 and heart-shaped Au 8 clusters". United Kingdom. doi:10.1039/C7SC03566G.
@article{osti_1414486,
title = {Diphosphine-protected ultrasmall gold nanoclusters: opened icosahedral Au 13 and heart-shaped Au 8 clusters},
author = {Zhang, Shan-Shan and Feng, Lei and Senanayake, Ravithree D. and Aikens, Christine M. and Wang, Xing-Po and Zhao, Quan-Qin and Tung, Chen-Ho and Sun, Di},
abstractNote = {Two ultrasmall gold clusters, Au 13 and Au 8 , were identified as a distorted I h icosahedral Au 13 and edge-shared “core + 4 exo ” structure Au 8 S 2 cores, respectively. They showed interesting luminescence and electrochemical properties.},
doi = {10.1039/C7SC03566G},
journal = {Chemical Science},
number = 5,
volume = 9,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C7SC03566G

Citation Metrics:
Cited by: 12 works
Citation information provided by
Web of Science

Figures / Tables:

Fig. 1 Fig. 1: (a) The X-ray crystal structure of cationic [Au13(dppm)6]5+. Thermal contours are drawn at the 50% probability level. Color labels: purple, Au; orange, P; and gray, C. H atoms and Cl⁻ ions are omitted. (b) The positive mode of the HRESI-MS of SD/Au1∙5Cl dissolved in CH2Cl2. Inset: comparison ofmore » themeasured (black trace) and simulated (red trace) isotopic patterns of [Au13(dppm)6]3+. (c and e) Top view of the kernel structure of Au13 along the C3 axis with the crystallographically unique Au atoms labelled. (d and f) Side view of the kernel structure of Au13. The three cyan edges denote the longer Au–Au separations (3.4995(5) Å).« less

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      Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.