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Title: Overcoming double-step CO 2 adsorption and minimizing water co-adsorption in bulky diamine-appended variants of Mg 2(dobpdc)

Abstract

Alkyldiamine-functionalized variants of the metal–organic framework Mg 2(dobpdc) (dobpdc 4- = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) are promising for CO 2 capture applications owing to their unique step-shaped CO 2 adsorption profiles resulting from the cooperative formation of ammonium carbamate chains. Primary,secondary (1°,2°) alkylethylenediamine-appended variants are of particular interest because of their low CO 2 step pressures (≤1 mbar at 40 °C), minimal adsorption/desorption hysteresis, and high thermal stability. Herein, we demonstrate that further increasing the size of the alkyl group on the secondary amine affords enhanced stability against diamine volatilization, but also leads to surprising two-step CO 2 adsorption/desorption profiles. This two-step behavior likely results from steric interactions between ammonium carbamate chains induced by the asymmetrical hexagonal pores of Mg 2(dobpdc) and leads to decreased CO 2 working capacities and increased water co-adsorption under humid conditions. To minimize these unfavorable steric interactions, we targeted diamine-appended variants of the isoreticularly expanded framework Mg 2(dotpdc) (dotpdc 4- = 4,4''-dioxido-[1,1':4',1''-terphenyl]-3,3''-dicarboxylate), reported here for the first time, and the previously reported isomeric framework Mg-IRMOF-74-II or Mg 2(pc-dobpdc) (pc-dobpdc 4- = 3,3'-dioxidobiphenyl-4,4'-dicarboxylate, pc = para-carboxylate), which, in contrast to Mg 2(dobpdc), possesses uniformally hexagonal pores. By minimizing the steric interactions between ammonium carbamate chains, these frameworks enable amore » single CO 2 adsorption/desorption step in all cases, as well as decreased water co-adsorption and increased stability to diamine loss. Functionalization of Mg 2(pc-dobpdc) with large diamines such as N-(n-heptyl)ethylenediamine results in optimal adsorption behavior, highlighting the advantage of tuning both the pore shape and the diamine size for the development of new adsorbents for carbon capture applications.« less

Authors:
 [1];  [1]; ORCiD logo [1];  [2]; ORCiD logo [3]; ORCiD logo [4]
  1. Univ. of California, Berkeley, CA (United States). Dept. of Chemistry
  2. Harvard Univ., Cambridge, MA (United States). Dept. of Chemistry and Chemical Biology
  3. ExxonMobil Research and Engineering Company, Annandale, NJ (United States)
  4. Univ. of California, Berkeley, CA (United States). Dept. of Chemistry. Dept. of Chemical Engineering; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); ExxonMobil Research and Engineering Company (United States); National Inst. of Health (NIH) (United States)
OSTI Identifier:
1414318
Alternate Identifier(s):
OSTI ID: 1433097
Grant/Contract Number:  
AC02-05CH11231; AR00040; SC0001015; F32GM120799
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Milner, Phillip J., Martell, Jeffrey D., Siegelman, Rebecca L., Gygi, David, Weston, Simon C., and Long, Jeffrey R. Overcoming double-step CO2 adsorption and minimizing water co-adsorption in bulky diamine-appended variants of Mg2(dobpdc). United States: N. p., 2017. Web. doi:10.1039/c7sc04266c.
Milner, Phillip J., Martell, Jeffrey D., Siegelman, Rebecca L., Gygi, David, Weston, Simon C., & Long, Jeffrey R. Overcoming double-step CO2 adsorption and minimizing water co-adsorption in bulky diamine-appended variants of Mg2(dobpdc). United States. doi:10.1039/c7sc04266c.
Milner, Phillip J., Martell, Jeffrey D., Siegelman, Rebecca L., Gygi, David, Weston, Simon C., and Long, Jeffrey R. Thu . "Overcoming double-step CO2 adsorption and minimizing water co-adsorption in bulky diamine-appended variants of Mg2(dobpdc)". United States. doi:10.1039/c7sc04266c.
@article{osti_1414318,
title = {Overcoming double-step CO2 adsorption and minimizing water co-adsorption in bulky diamine-appended variants of Mg2(dobpdc)},
author = {Milner, Phillip J. and Martell, Jeffrey D. and Siegelman, Rebecca L. and Gygi, David and Weston, Simon C. and Long, Jeffrey R.},
abstractNote = {Alkyldiamine-functionalized variants of the metal–organic framework Mg2(dobpdc) (dobpdc4- = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) are promising for CO2 capture applications owing to their unique step-shaped CO2 adsorption profiles resulting from the cooperative formation of ammonium carbamate chains. Primary,secondary (1°,2°) alkylethylenediamine-appended variants are of particular interest because of their low CO2 step pressures (≤1 mbar at 40 °C), minimal adsorption/desorption hysteresis, and high thermal stability. Herein, we demonstrate that further increasing the size of the alkyl group on the secondary amine affords enhanced stability against diamine volatilization, but also leads to surprising two-step CO2 adsorption/desorption profiles. This two-step behavior likely results from steric interactions between ammonium carbamate chains induced by the asymmetrical hexagonal pores of Mg2(dobpdc) and leads to decreased CO2 working capacities and increased water co-adsorption under humid conditions. To minimize these unfavorable steric interactions, we targeted diamine-appended variants of the isoreticularly expanded framework Mg2(dotpdc) (dotpdc4- = 4,4''-dioxido-[1,1':4',1''-terphenyl]-3,3''-dicarboxylate), reported here for the first time, and the previously reported isomeric framework Mg-IRMOF-74-II or Mg2(pc-dobpdc) (pc-dobpdc4- = 3,3'-dioxidobiphenyl-4,4'-dicarboxylate, pc = para-carboxylate), which, in contrast to Mg2(dobpdc), possesses uniformally hexagonal pores. By minimizing the steric interactions between ammonium carbamate chains, these frameworks enable a single CO2 adsorption/desorption step in all cases, as well as decreased water co-adsorption and increased stability to diamine loss. Functionalization of Mg2(pc-dobpdc) with large diamines such as N-(n-heptyl)ethylenediamine results in optimal adsorption behavior, highlighting the advantage of tuning both the pore shape and the diamine size for the development of new adsorbents for carbon capture applications.},
doi = {10.1039/c7sc04266c},
journal = {Chemical Science},
number = 1,
volume = 9,
place = {United States},
year = {2017},
month = {10}
}

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Free Publicly Available Full Text
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DOI: 10.1039/c7sc04266c

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Works referenced in this record:

Adsorption Equilibrium of Binary Mixtures of Carbon Dioxide and Water Vapor on Zeolites 5A and 13X
journal, September 2010

  • Wang, Yu; LeVan, M. Douglas
  • Journal of Chemical & Engineering Data, Vol. 55, Issue 9
  • DOI: 10.1021/je100053g

Postsynthetic modification of metal–organic frameworks—a progress report
journal, January 2011

  • Tanabe, Kristine K.; Cohen, Seth M.
  • Chem. Soc. Rev., Vol. 40, Issue 2
  • DOI: 10.1039/C0CS00031K

Capture of carbon dioxide from flue gas on TEPA-grafted metal-organic framework Mg2(dobdc)
journal, October 2013


M2(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal–Organic Frameworks Exhibiting Increased Charge Density and Enhanced H2 Binding at the Open Metal Sites
journal, August 2014

  • Kapelewski, Matthew T.; Geier, Stephen J.; Hudson, Matthew R.
  • Journal of the American Chemical Society, Vol. 136, Issue 34, p. 12119-12129
  • DOI: 10.1021/ja506230r

Adsorption of CO2 and H2O on supported amine sorbents
journal, January 2014


Carbon Dioxide Capture: Prospects for New Materials
journal, July 2010

  • D'Alessandro, Deanna M.; Smit, Berend; Long, Jeffrey R.
  • Angewandte Chemie International Edition, Vol. 49, Issue 35, p. 6058-6082
  • DOI: 10.1002/anie.201000431

Putting an ultrahigh concentration of amine groups into a metal–organic framework for CO 2 capture at low pressures
journal, January 2016

  • Liao, Pei-Qin; Chen, Xun-Wei; Liu, Si-Yang
  • Chemical Science, Vol. 7, Issue 10
  • DOI: 10.1039/C6SC00836D

Tuning the Adsorption-Induced Phase Change in the Flexible Metal–Organic Framework Co(bdp)
journal, November 2016

  • Taylor, Mercedes K.; Runčevski, Tomče; Oktawiec, Julia
  • Journal of the American Chemical Society, Vol. 138, Issue 45
  • DOI: 10.1021/jacs.6b09155

Hydrogen Storage in the Expanded Pore Metal–Organic Frameworks M 2 (dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn)
journal, February 2016


Stepwise and hysteretic sorption of N 2 , O 2 , CO 2 , and H 2 gases in a porous metal–organic framework [Zn2(BPnDC)2(bpy)]
journal, January 2010

  • Park, Hye Jeong; Suh, Myunghyun Paik
  • Chem. Commun., Vol. 46, Issue 4
  • DOI: 10.1039/B913067E

Amine degradation in CO2 capture. I. A review
journal, September 2012


A Diaminopropane-Appended Metal–Organic Framework Enabling Efficient CO 2 Capture from Coal Flue Gas via a Mixed Adsorption Mechanism
journal, September 2017

  • Milner, Phillip J.; Siegelman, Rebecca L.; Forse, Alexander C.
  • Journal of the American Chemical Society, Vol. 139, Issue 38
  • DOI: 10.1021/jacs.7b07612

Carbon Capture and Sequestration
journal, September 2009


Strategies for Characterization of Large-Pore Metal-Organic Frameworks by Combined Experimental and Computational Methods
journal, October 2009

  • Bae, Youn-Sang; Dubbeldam, David; Nelson, Andrew
  • Chemistry of Materials, Vol. 21, Issue 20
  • DOI: 10.1021/cm803218f

Moisture-Resistant and Superhydrophobic Metal−Organic Frameworks Obtained via Postsynthetic Modification
journal, April 2010

  • Nguyen, Joseph G.; Cohen, Seth M.
  • Journal of the American Chemical Society, Vol. 132, Issue 13
  • DOI: 10.1021/ja100900c

Carbon capture and storage update
journal, January 2014

  • Boot-Handford, Matthew E.; Abanades, Juan C.; Anthony, Edward J.
  • Energy Environ. Sci., Vol. 7, Issue 1
  • DOI: 10.1039/C3EE42350F

Photochemical Removal of Mercury from Flue Gas
journal, October 2002

  • Granite, Evan J.; Pennline, Henry W.
  • Industrial & Engineering Chemistry Research, Vol. 41, Issue 22
  • DOI: 10.1021/ie020251b

Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
journal, August 2011

  • Li, Jian-Rong; Ma, Yuguang; McCarthy, M. Colin
  • Coordination Chemistry Reviews, Vol. 255, Issue 15-16
  • DOI: 10.1016/j.ccr.2011.02.012

Double-Step Gate Phenomenon in CO 2 Sorption of an Elastic Layer-Structured MOF
journal, September 2016


Amine-functionalized metal–organic frameworks: structure, synthesis and applications
journal, January 2016

  • Lin, Yichao; Kong, Chunlong; Chen, Liang
  • RSC Advances, Vol. 6, Issue 39
  • DOI: 10.1039/C6RA01536K

Oxidative Degradation of Aqueous Amine Solutions of MEA, AMP, MDEA, Pz: A Review
journal, January 2013


Carbon dioxide capturing technologies: a review focusing on metal organic framework materials (MOFs)
journal, December 2013

  • Sabouni, Rana; Kazemian, Hossein; Rohani, Sohrab
  • Environmental Science and Pollution Research, Vol. 21, Issue 8
  • DOI: 10.1007/s11356-013-2406-2

Functionalisation of MOF open metal sites with pendant amines for CO2 capture
journal, January 2012

  • Montoro, Carmen; García, Elena; Calero, Sofía
  • Journal of Materials Chemistry, Vol. 22, Issue 20
  • DOI: 10.1039/c2jm16770k

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

  • Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
  • Science, Vol. 295, Issue 5554, p. 469-472
  • DOI: 10.1126/science.1067208

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011

  • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
  • DOI: 10.1021/cr2003272

Highly Selective Carbon Dioxide Uptake by [Cu(bpy- n ) 2 (SiF 6 )] (bpy-1 = 4,4′-Bipyridine; bpy-2 = 1,2-Bis(4-pyridyl)ethene)
journal, February 2012

  • Burd, Stephen D.; Ma, Shengqian; Perman, Jason A.
  • Journal of the American Chemical Society, Vol. 134, Issue 8
  • DOI: 10.1021/ja211340t

Exceptional CO 2 working capacity in a heterodiamine-grafted metal–organic framework
journal, January 2015

  • Lee, Woo Ram; Jo, Hyuna; Yang, Li-Ming
  • Chemical Science, Vol. 6, Issue 7
  • DOI: 10.1039/C5SC01191D

Double−Step Gas Sorption of a Two−Dimensional Metal−Organic Framework
journal, October 2007

  • Kondo, Atsushi; Noguchi, Hiroshi; Carlucci, Lucia
  • Journal of the American Chemical Society, Vol. 129, Issue 41
  • DOI: 10.1021/ja073568h

A Fine-Tuned Fluorinated MOF Addresses the Needs for Trace CO 2 Removal and Air Capture Using Physisorption
journal, July 2016

  • Bhatt, Prashant M.; Belmabkhout, Youssef; Cadiau, Amandine
  • Journal of the American Chemical Society, Vol. 138, Issue 29
  • DOI: 10.1021/jacs.6b05345

Controlling Cooperative CO 2 Adsorption in Diamine-Appended Mg 2 (dobpdc) Metal–Organic Frameworks
journal, July 2017

  • Siegelman, Rebecca L.; McDonald, Thomas M.; Gonzalez, Miguel I.
  • Journal of the American Chemical Society, Vol. 139, Issue 30
  • DOI: 10.1021/jacs.7b05858

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
journal, April 2012

  • McDonald, Thomas M.; Lee, Woo Ram; Mason, Jarad A.
  • Journal of the American Chemical Society, Vol. 134, Issue 16, p. 7056-7065
  • DOI: 10.1021/ja300034j

CO 2 Capture and Separations Using MOFs: Computational and Experimental Studies
journal, April 2017


Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
journal, February 2013

  • Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.
  • Nature, Vol. 495, Issue 7439, p. 80-84
  • DOI: 10.1038/nature11893

Fluorous Metal–Organic Frameworks with Superior Adsorption and Hydrophobic Properties toward Oil Spill Cleanup and Hydrocarbon Storage
journal, November 2011

  • Yang, Chi; Kaipa, Ushasree; Mather, Qian Zhang
  • Journal of the American Chemical Society, Vol. 133, Issue 45, p. 18094-18097
  • DOI: 10.1021/ja208408n

Progress in adsorption-based CO 2 capture by metal–organic frameworks
journal, January 2012

  • Liu, Jian; Thallapally, Praveen K.; McGrail, B. Peter
  • Chem. Soc. Rev., Vol. 41, Issue 6
  • DOI: 10.1039/C1CS15221A

Recent advances in carbon dioxide capture with metal-organic frameworks
journal, August 2012

  • Liu, Yangyang; Wang, Zhiyong U.; Zhou, Hong-Cai
  • Greenhouse Gases: Science and Technology, Vol. 2, Issue 4
  • DOI: 10.1002/ghg.1296

Hydrophobic and moisture-stable metal–organic frameworks
journal, January 2015

  • Fernandez, Carlos A.; Nune, Satish K.; Annapureddy, Harsha V.
  • Dalton Transactions, Vol. 44, Issue 30
  • DOI: 10.1039/C5DT00606F

Post-Combustion CO2 Capture Using Solid Sorbents: A Review
journal, September 2011

  • Samanta, Arunkumar; Zhao, An; Shimizu, George K. H.
  • Industrial & Engineering Chemistry Research, Vol. 51, Issue 4, p. 1438-1463
  • DOI: 10.1021/ie200686q

Analysis and Status of Post-Combustion Carbon Dioxide Capture Technologies
journal, October 2011

  • Bhown, Abhoyjit S.; Freeman, Brice C.
  • Environmental Science & Technology, Vol. 45, Issue 20
  • DOI: 10.1021/es104291d

Materials challenges for the development of solid sorbents for post-combustion carbon capture
journal, January 2012

  • Drage, Trevor C.; Snape, Colin E.; Stevens, Lee A.
  • J. Mater. Chem., Vol. 22, Issue 7
  • DOI: 10.1039/C2JM12592G

Simultaneous in Situ X-ray Diffraction and Calorimetric Studies as a Tool To Evaluate Gas Adsorption in Microporous Materials
journal, December 2015

  • Woerner, William R.; Plonka, Anna M.; Chen, Xianyin
  • The Journal of Physical Chemistry C, Vol. 120, Issue 1
  • DOI: 10.1021/acs.jpcc.5b10159

Multistep N 2 Breathing in the Metal−Organic Framework Co(1,4-benzenedipyrazolate)
journal, October 2010

  • Salles, Fabrice; Maurin, Guillaume; Serre, Christian
  • Journal of the American Chemical Society, Vol. 132, Issue 39
  • DOI: 10.1021/ja104357r

Effect of Amine Surface Coverage on the Co-Adsorption of CO 2 and Water: Spectral Deconvolution of Adsorbed Species
journal, November 2014

  • Didas, Stephanie A.; Sakwa-Novak, Miles A.; Foo, Guo Shiou
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 23
  • DOI: 10.1021/jz502032c

Third-Generation Breathing Metal–Organic Framework with Selective, Stepwise, Reversible, and Hysteretic Adsorption Properties
journal, October 2013

  • Sanda, Suresh; Parshamoni, Srinivasulu; Konar, Sanjit
  • Inorganic Chemistry, Vol. 52, Issue 22
  • DOI: 10.1021/ic402095u

Dual-responsive nanoparticles that aggregate under the simultaneous action of light and CO 2
journal, January 2015

  • Lee, Ji-Woong; Klajn, Rafal
  • Chemical Communications, Vol. 51, Issue 11
  • DOI: 10.1039/C4CC08541H

Introduction to Metal–Organic Frameworks
journal, September 2011

  • Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 673-674
  • DOI: 10.1021/cr300014x

Design of amine-functionalized metal–organic frameworks for CO 2 separation: the more amine, the better?
journal, January 2016

  • Qiao, Zhiwei; Wang, Nanyi; Jiang, Jianwen
  • Chemical Communications, Vol. 52, Issue 5
  • DOI: 10.1039/C5CC07171B

Amine Scrubbing for CO2 Capture
journal, September 2009


Applications of Pore-Expanded Mesoporous Silica. 2. Development of a High-Capacity, Water-Tolerant Adsorbent for CO 2
journal, October 2005

  • Franchi, Robert S.; Harlick, Peter J. E.; Sayari, Abdelhamid
  • Industrial & Engineering Chemistry Research, Vol. 44, Issue 21
  • DOI: 10.1021/ie0504194

Influence of Moisture on CO 2 Separation from Gas Mixture by a Nanoporous Adsorbent Based on Polyethylenimine-Modified Molecular Sieve MCM-41
journal, October 2005

  • Xu, Xiaochun; Song, Chunshan; Miller, Bruce G.
  • Industrial & Engineering Chemistry Research, Vol. 44, Issue 21
  • DOI: 10.1021/ie050382n

Probing the mechanism of CO 2 capture in diamine-appended metal–organic frameworks using measured and simulated X-ray spectroscopy
journal, January 2015

  • Drisdell, Walter S.; Poloni, Roberta; McDonald, Thomas M.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 33
  • DOI: 10.1039/C5CP02951A

Seven Post-synthetic Covalent Reactions in Tandem Leading to Enzyme-like Complexity within Metal–Organic Framework Crystals
journal, June 2016

  • Fracaroli, Alejandro M.; Siman, Peter; Nagib, David A.
  • Journal of the American Chemical Society, Vol. 138, Issue 27
  • DOI: 10.1021/jacs.6b04204

An ethylenediamine-grafted Y zeolite: a highly regenerable carbon dioxide adsorbent via temperature swing adsorption without urea formation
journal, January 2016

  • Kim, Chaehoon; Cho, Hae Sung; Chang, Shuai
  • Energy & Environmental Science, Vol. 9, Issue 5
  • DOI: 10.1039/C6EE00601A

Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources
journal, September 2009

  • Choi, Sunho; Drese, Jeffrey H.; Jones, Christopher W.
  • ChemSusChem, Vol. 2, Issue 9, p. 796-854
  • DOI: 10.1002/cssc.200900036

Carbon Capture and Storage: How Green Can Black Be?
journal, September 2009


Application of a High-Throughput Analyzer in Evaluating Solid Adsorbents for Post-Combustion Carbon Capture via Multicomponent Adsorption of CO 2 , N 2 , and H 2 O
journal, April 2015

  • Mason, Jarad A.; McDonald, Thomas M.; Bae, Tae-Hyun
  • Journal of the American Chemical Society, Vol. 137, Issue 14
  • DOI: 10.1021/jacs.5b00838

Mechanisms and Kinetics for Sorption of CO 2 on Bicontinuous Mesoporous Silica Modified with n -Propylamine
journal, September 2011

  • Bacsik, Zoltán; Ahlsten, Nanna; Ziadi, Asraa
  • Langmuir, Vol. 27, Issue 17
  • DOI: 10.1021/la202033p

A review on solid adsorbents for carbon dioxide capture
journal, March 2015


Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47
journal, October 2005

  • Bourrelly, Sandrine; Llewellyn, Philip L.; Serre, Christian
  • Journal of the American Chemical Society, Vol. 127, Issue 39
  • DOI: 10.1021/ja054668v

Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption
journal, January 2011

  • Mason, Jarad A.; Sumida, Kenji; Herm, Zoey R.
  • Energy & Environmental Science, Vol. 4, Issue 8, p. 3030-3040
  • DOI: 10.1039/c1ee01720a

New Insights into the Interactions of CO 2 with Amine-Functionalized Silica
journal, December 2008

  • Serna-Guerrero, Rodrigo; Da’na, Enshirah; Sayari, Abdelhamid
  • Industrial & Engineering Chemistry Research, Vol. 47, Issue 23
  • DOI: 10.1021/ie801186g

Stabilization of Amine-Containing CO 2 Adsorbents: Dramatic Effect of Water Vapor
journal, May 2010

  • Sayari, Abdelhamid; Belmabkhout, Youssef
  • Journal of the American Chemical Society, Vol. 132, Issue 18
  • DOI: 10.1021/ja1013773

Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe 2 (dobdc) Analogues
journal, October 2016

  • Xiao, Dianne J.; Oktawiec, Julia; Milner, Phillip J.
  • Journal of the American Chemical Society, Vol. 138, Issue 43
  • DOI: 10.1021/jacs.6b08417

Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
journal, June 2014

  • Fracaroli, Alejandro M.; Furukawa, Hiroyasu; Suzuki, Mitsuharu
  • Journal of the American Chemical Society, Vol. 136, Issue 25, p. 8863-8866
  • DOI: 10.1021/ja503296c

Solid amine sorbents for CO 2 capture by chemical adsorption: A review
journal, March 2017


Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials
journal, January 2009

  • Nelson, Andrew P.; Farha, Omar K.; Mulfort, Karen L.
  • Journal of the American Chemical Society, Vol. 131, Issue 2, p. 458-460
  • DOI: 10.1021/ja808853q

Superhydrophobic perfluorinated metal–organic frameworks
journal, January 2013

  • Chen, Teng-Hao; Popov, Ilya; Zenasni, Oussama
  • Chemical Communications, Vol. 49, Issue 61
  • DOI: 10.1039/c3cc41564c

Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015

  • McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian
  • Nature, Vol. 519, Issue 7543
  • DOI: 10.1038/nature14327

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Hydrophobic pillared square grids for selective removal of CO 2 from simulated flue gas
journal, January 2015

  • Elsaidi, Sameh K.; Mohamed, Mona H.; Schaef, Herbert T.
  • Chemical Communications, Vol. 51, Issue 85
  • DOI: 10.1039/C5CC06577A

Water adsorption in MOFs: fundamentals and applications
journal, January 2014

  • Canivet, Jérôme; Fateeva, Alexandra; Guo, Youmin
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00078A

Double-step CO 2 sorption and guest-induced single-crystal-to-single-crystal transformation in a flexible porous framework
journal, January 2015

  • Wu, Wei-Ping; Li, Zhi-Sen; Liu, Bo
  • Dalton Transactions, Vol. 44, Issue 22
  • DOI: 10.1039/C5DT00460H

Large-Pore Apertures in a Series of Metal-Organic Frameworks
journal, May 2012


    Works referencing / citing this record:

    CO 2 Capture and Separations Using MOFs: Computational and Experimental Studies
    journal, April 2017


    Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47
    journal, October 2005

    • Bourrelly, Sandrine; Llewellyn, Philip L.; Serre, Christian
    • Journal of the American Chemical Society, Vol. 127, Issue 39
    • DOI: 10.1021/ja054668v

    Cooperative adsorption of carbon disulfide in diamine-appended metal–organic frameworks
    journal, December 2018

    • McGuirk, C. Michael; Siegelman, Rebecca L.; Drisdell, Walter S.
    • Nature Communications, Vol. 9, Issue 1
    • DOI: 10.1038/s41467-018-07458-6

    Highly Selective Carbon Dioxide Uptake by [Cu(bpy- n ) 2 (SiF 6 )] (bpy-1 = 4,4′-Bipyridine; bpy-2 = 1,2-Bis(4-pyridyl)ethene)
    journal, February 2012

    • Burd, Stephen D.; Ma, Shengqian; Perman, Jason A.
    • Journal of the American Chemical Society, Vol. 134, Issue 8
    • DOI: 10.1021/ja211340t

    Third-Generation Breathing Metal–Organic Framework with Selective, Stepwise, Reversible, and Hysteretic Adsorption Properties
    journal, October 2013

    • Sanda, Suresh; Parshamoni, Srinivasulu; Konar, Sanjit
    • Inorganic Chemistry, Vol. 52, Issue 22
    • DOI: 10.1021/ic402095u

    Influence of Moisture on CO 2 Separation from Gas Mixture by a Nanoporous Adsorbent Based on Polyethylenimine-Modified Molecular Sieve MCM-41
    journal, October 2005

    • Xu, Xiaochun; Song, Chunshan; Miller, Bruce G.
    • Industrial & Engineering Chemistry Research, Vol. 44, Issue 21
    • DOI: 10.1021/ie050382n

    Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption
    journal, January 2011

    • Mason, Jarad A.; Sumida, Kenji; Herm, Zoey R.
    • Energy & Environmental Science, Vol. 4, Issue 8, p. 3030-3040
    • DOI: 10.1039/c1ee01720a

    Double−Step Gas Sorption of a Two−Dimensional Metal−Organic Framework
    journal, October 2007

    • Kondo, Atsushi; Noguchi, Hiroshi; Carlucci, Lucia
    • Journal of the American Chemical Society, Vol. 129, Issue 41
    • DOI: 10.1021/ja073568h

    Oxidative Degradation of Aqueous Amine Solutions of MEA, AMP, MDEA, Pz: A Review
    journal, January 2013


    Carbon Dioxide Capture: Prospects for New Materials
    journal, July 2010

    • D'Alessandro, Deanna M.; Smit, Berend; Long, Jeffrey R.
    • Angewandte Chemie International Edition, Vol. 49, Issue 35, p. 6058-6082
    • DOI: 10.1002/anie.201000431

    Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
    journal, June 2014

    • Fracaroli, Alejandro M.; Furukawa, Hiroyasu; Suzuki, Mitsuharu
    • Journal of the American Chemical Society, Vol. 136, Issue 25, p. 8863-8866
    • DOI: 10.1021/ja503296c

    Superhydrophobic perfluorinated metal–organic frameworks
    journal, January 2013

    • Chen, Teng-Hao; Popov, Ilya; Zenasni, Oussama
    • Chemical Communications, Vol. 49, Issue 61
    • DOI: 10.1039/c3cc41564c

    Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe 2 (dobdc) Analogues
    journal, October 2016

    • Xiao, Dianne J.; Oktawiec, Julia; Milner, Phillip J.
    • Journal of the American Chemical Society, Vol. 138, Issue 43
    • DOI: 10.1021/jacs.6b08417

    Tuning the Adsorption-Induced Phase Change in the Flexible Metal–Organic Framework Co(bdp)
    journal, November 2016

    • Taylor, Mercedes K.; Runčevski, Tomče; Oktawiec, Julia
    • Journal of the American Chemical Society, Vol. 138, Issue 45
    • DOI: 10.1021/jacs.6b09155

    Applications of Pore-Expanded Mesoporous Silica. 2. Development of a High-Capacity, Water-Tolerant Adsorbent for CO 2
    journal, October 2005

    • Franchi, Robert S.; Harlick, Peter J. E.; Sayari, Abdelhamid
    • Industrial & Engineering Chemistry Research, Vol. 44, Issue 21
    • DOI: 10.1021/ie0504194

    Recent advances in carbon dioxide capture with metal-organic frameworks
    journal, August 2012

    • Liu, Yangyang; Wang, Zhiyong U.; Zhou, Hong-Cai
    • Greenhouse Gases: Science and Technology, Vol. 2, Issue 4
    • DOI: 10.1002/ghg.1296

    Stabilization of Amine-Containing CO 2 Adsorbents: Dramatic Effect of Water Vapor
    journal, May 2010

    • Sayari, Abdelhamid; Belmabkhout, Youssef
    • Journal of the American Chemical Society, Vol. 132, Issue 18
    • DOI: 10.1021/ja1013773

    Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
    journal, March 2015

    • McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian
    • Nature, Vol. 519, Issue 7543
    • DOI: 10.1038/nature14327

    Strategies for Characterization of Large-Pore Metal-Organic Frameworks by Combined Experimental and Computational Methods
    journal, October 2009

    • Bae, Youn-Sang; Dubbeldam, David; Nelson, Andrew
    • Chemistry of Materials, Vol. 21, Issue 20
    • DOI: 10.1021/cm803218f

    Simultaneous in Situ X-ray Diffraction and Calorimetric Studies as a Tool To Evaluate Gas Adsorption in Microporous Materials
    journal, December 2015

    • Woerner, William R.; Plonka, Anna M.; Chen, Xianyin
    • The Journal of Physical Chemistry C, Vol. 120, Issue 1
    • DOI: 10.1021/acs.jpcc.5b10159

    Mechanisms and Kinetics for Sorption of CO 2 on Bicontinuous Mesoporous Silica Modified with n -Propylamine
    journal, September 2011

    • Bacsik, Zoltán; Ahlsten, Nanna; Ziadi, Asraa
    • Langmuir, Vol. 27, Issue 17
    • DOI: 10.1021/la202033p

    Seven Post-synthetic Covalent Reactions in Tandem Leading to Enzyme-like Complexity within Metal–Organic Framework Crystals
    journal, June 2016

    • Fracaroli, Alejandro M.; Siman, Peter; Nagib, David A.
    • Journal of the American Chemical Society, Vol. 138, Issue 27
    • DOI: 10.1021/jacs.6b04204

    Double-Step Gate Phenomenon in CO 2 Sorption of an Elastic Layer-Structured MOF
    journal, September 2016


    Introduction to Metal–Organic Frameworks
    journal, September 2011

    • Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
    • Chemical Reviews, Vol. 112, Issue 2, p. 673-674
    • DOI: 10.1021/cr300014x

    A review on solid adsorbents for carbon dioxide capture
    journal, March 2015


    Cobalt substitution in a flexible metal–organic framework: modulating a soft paddle-wheel unit for tunable gate-opening adsorption
    journal, January 2019

    • Zhu, Jiaxing; Chen, Junye; Qiu, Tianze
    • Dalton Transactions, Vol. 48, Issue 21
    • DOI: 10.1039/c9dt00115h

    New Insights into the Interactions of CO 2 with Amine-Functionalized Silica
    journal, December 2008

    • Serna-Guerrero, Rodrigo; Da’na, Enshirah; Sayari, Abdelhamid
    • Industrial & Engineering Chemistry Research, Vol. 47, Issue 23
    • DOI: 10.1021/ie801186g

    Amine degradation in CO2 capture. I. A review
    journal, September 2012


    Large-Pore Apertures in a Series of Metal-Organic Frameworks
    journal, May 2012


    Carbon Dioxide Capture in Metal–Organic Frameworks
    journal, September 2011

    • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
    • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
    • DOI: 10.1021/cr2003272

    Photochemical Removal of Mercury from Flue Gas
    journal, October 2002

    • Granite, Evan J.; Pennline, Henry W.
    • Industrial & Engineering Chemistry Research, Vol. 41, Issue 22
    • DOI: 10.1021/ie020251b

    Moisture-Resistant and Superhydrophobic Metal−Organic Frameworks Obtained via Postsynthetic Modification
    journal, April 2010

    • Nguyen, Joseph G.; Cohen, Seth M.
    • Journal of the American Chemical Society, Vol. 132, Issue 13
    • DOI: 10.1021/ja100900c

    Carbon Capture and Sequestration
    journal, September 2009


    The Chemistry and Applications of Metal-Organic Frameworks
    journal, August 2013

    • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
    • Science, Vol. 341, Issue 6149, p. 1230444-1230444
    • DOI: 10.1126/science.1230444

    Fluorous Metal–Organic Frameworks with Superior Adsorption and Hydrophobic Properties toward Oil Spill Cleanup and Hydrocarbon Storage
    journal, November 2011

    • Yang, Chi; Kaipa, Ushasree; Mather, Qian Zhang
    • Journal of the American Chemical Society, Vol. 133, Issue 45, p. 18094-18097
    • DOI: 10.1021/ja208408n

    Adsorption Equilibrium of Binary Mixtures of Carbon Dioxide and Water Vapor on Zeolites 5A and 13X
    journal, September 2010

    • Wang, Yu; LeVan, M. Douglas
    • Journal of Chemical & Engineering Data, Vol. 55, Issue 9
    • DOI: 10.1021/je100053g

    Solid amine sorbents for CO 2 capture by chemical adsorption: A review
    journal, March 2017


    Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
    journal, January 2002

    • Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
    • Science, Vol. 295, Issue 5554, p. 469-472
    • DOI: 10.1126/science.1067208

    Carbon Capture and Storage: How Green Can Black Be?
    journal, September 2009


    Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources
    journal, September 2009

    • Choi, Sunho; Drese, Jeffrey H.; Jones, Christopher W.
    • ChemSusChem, Vol. 2, Issue 9, p. 796-854
    • DOI: 10.1002/cssc.200900036

    Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials
    journal, January 2009

    • Nelson, Andrew P.; Farha, Omar K.; Mulfort, Karen L.
    • Journal of the American Chemical Society, Vol. 131, Issue 2, p. 458-460
    • DOI: 10.1021/ja808853q

    Controlling Cooperative CO 2 Adsorption in Diamine-Appended Mg 2 (dobpdc) Metal–Organic Frameworks
    journal, July 2017

    • Siegelman, Rebecca L.; McDonald, Thomas M.; Gonzalez, Miguel I.
    • Journal of the American Chemical Society, Vol. 139, Issue 30
    • DOI: 10.1021/jacs.7b05858

    Hydrogen Storage in the Expanded Pore Metal–Organic Frameworks M 2 (dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn)
    journal, February 2016


    Multistep N 2 Breathing in the Metal−Organic Framework Co(1,4-benzenedipyrazolate)
    journal, October 2010

    • Salles, Fabrice; Maurin, Guillaume; Serre, Christian
    • Journal of the American Chemical Society, Vol. 132, Issue 39
    • DOI: 10.1021/ja104357r

    A Fine-Tuned Fluorinated MOF Addresses the Needs for Trace CO 2 Removal and Air Capture Using Physisorption
    journal, July 2016

    • Bhatt, Prashant M.; Belmabkhout, Youssef; Cadiau, Amandine
    • Journal of the American Chemical Society, Vol. 138, Issue 29
    • DOI: 10.1021/jacs.6b05345

    Analysis and Status of Post-Combustion Carbon Dioxide Capture Technologies
    journal, October 2011

    • Bhown, Abhoyjit S.; Freeman, Brice C.
    • Environmental Science & Technology, Vol. 45, Issue 20
    • DOI: 10.1021/es104291d

    Application of a High-Throughput Analyzer in Evaluating Solid Adsorbents for Post-Combustion Carbon Capture via Multicomponent Adsorption of CO 2 , N 2 , and H 2 O
    journal, April 2015

    • Mason, Jarad A.; McDonald, Thomas M.; Bae, Tae-Hyun
    • Journal of the American Chemical Society, Vol. 137, Issue 14
    • DOI: 10.1021/jacs.5b00838

    Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
    journal, April 2012

    • McDonald, Thomas M.; Lee, Woo Ram; Mason, Jarad A.
    • Journal of the American Chemical Society, Vol. 134, Issue 16, p. 7056-7065
    • DOI: 10.1021/ja300034j

    Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
    journal, February 2013

    • Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.
    • Nature, Vol. 495, Issue 7439, p. 80-84
    • DOI: 10.1038/nature11893

    Carbon dioxide capturing technologies: a review focusing on metal organic framework materials (MOFs)
    journal, December 2013

    • Sabouni, Rana; Kazemian, Hossein; Rohani, Sohrab
    • Environmental Science and Pollution Research, Vol. 21, Issue 8
    • DOI: 10.1007/s11356-013-2406-2

    Amine Scrubbing for CO2 Capture
    journal, September 2009


    Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
    journal, August 2011

    • Li, Jian-Rong; Ma, Yuguang; McCarthy, M. Colin
    • Coordination Chemistry Reviews, Vol. 255, Issue 15-16
    • DOI: 10.1016/j.ccr.2011.02.012

    M2(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal–Organic Frameworks Exhibiting Increased Charge Density and Enhanced H2 Binding at the Open Metal Sites
    journal, August 2014

    • Kapelewski, Matthew T.; Geier, Stephen J.; Hudson, Matthew R.
    • Journal of the American Chemical Society, Vol. 136, Issue 34, p. 12119-12129
    • DOI: 10.1021/ja506230r

    A Diaminopropane-Appended Metal–Organic Framework Enabling Efficient CO 2 Capture from Coal Flue Gas via a Mixed Adsorption Mechanism
    journal, September 2017

    • Milner, Phillip J.; Siegelman, Rebecca L.; Forse, Alexander C.
    • Journal of the American Chemical Society, Vol. 139, Issue 38
    • DOI: 10.1021/jacs.7b07612

    Adsorption of CO2 and H2O on supported amine sorbents
    journal, January 2014


    Effect of Amine Surface Coverage on the Co-Adsorption of CO 2 and Water: Spectral Deconvolution of Adsorbed Species
    journal, November 2014

    • Didas, Stephanie A.; Sakwa-Novak, Miles A.; Foo, Guo Shiou
    • The Journal of Physical Chemistry Letters, Vol. 5, Issue 23
    • DOI: 10.1021/jz502032c

    Functionalisation of MOF open metal sites with pendant amines for CO2 capture
    journal, January 2012

    • Montoro, Carmen; García, Elena; Calero, Sofía
    • Journal of Materials Chemistry, Vol. 22, Issue 20
    • DOI: 10.1039/c2jm16770k

    Post-Combustion CO2 Capture Using Solid Sorbents: A Review
    journal, September 2011

    • Samanta, Arunkumar; Zhao, An; Shimizu, George K. H.
    • Industrial & Engineering Chemistry Research, Vol. 51, Issue 4, p. 1438-1463
    • DOI: 10.1021/ie200686q