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Title: Overcoming double-step CO 2 adsorption and minimizing water co-adsorption in bulky diamine-appended variants of Mg 2 (dobpdc)

Judicious choice of framework structure allows for single CO 2 adsorption steps with bulky primary , secondary diamines appended to metal–organic frameworks.
Authors:
 [1] ;  [1] ; ORCiD logo [1] ;  [2] ; ORCiD logo [3] ; ORCiD logo [4]
  1. Department of Chemistry, University of California, Berkeley, USA
  2. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, USA
  3. Corporate Strategic Research, ExxonMobil Research and Engineering Company, Annandale, USA
  4. Department of Chemistry, University of California, Berkeley, USA, Department of Chemical Engineering
Publication Date:
Grant/Contract Number:
AR00040; AC02-05CH11231; SC0001015
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 9; Journal Issue: 1; Related Information: CHORUS Timestamp: 2017-12-20 07:17:57; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1414318