In Situ EXAFS-Derived Mechanism of Highly Reversible Tin Phosphide/Graphite Composite Anode for Li-Ion Batteries
Abstract
Abstract A novel Sn 4 P 3 /graphite composite anode material with superior capacity and cycling performance (651 mA h g −1 after 100 cycles) is investigated by in situ X‐ray absorption spectroscopy. Extended X‐ray absorption fine structure modeling and detailed analysis of local environment changes are correlated to the cell capacity and reveal the mechanism of lithiation/delithiation process. Results show that in the first two lithiation/delithiation cycles crystalline Sn 4 P 3 is fully converted to an amorphous SnP x phase, which in further cycles participates in reversible conversion and alloying reactions. The superior reversibility of this material is attributed to the highly dispersed SnP x in the graphite matrix, which provides enhanced electrical conductivity and prevents aggregation of Sn clusters during the lithiation/delithiation process. The gradual capacity fading in long‐term cycling is attributed to the observed increase in the size and the amount of metallic Sn clusters in the delithiated state, correlated to the reduced recovery of the SnP x phase. This paper reveals the mechanism responsible for the highly reversible tin phosphides and provides insights for improving the capacity and cycle life of conversion and alloying materials.
- Authors:
-
[3];
[1]
- Illinois Institute of Technology, Chicago, IL (United States). Dept. of Physics. CSRRI
- Ohio Univ., Athens, OH (United States). Center for Electrochemical Engineering Research. Chemical and Biomolecular Engineering Dept.
- Illinois Institute of Technology, Chicago, IL (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- USDOE Office of Science (SC); USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1431366
- Alternate Identifier(s):
- OSTI ID: 1413828
- Grant/Contract Number:
- AC02-06CH11357; AR000387; DE‐AC02‐06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 9; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 25 ENERGY STORAGE; X-ray absorption spectroscopy; tin phosphide graphite composites; reversibility mechanism; Li-ion battery anodes
Citation Formats
Ding, Yujia, Li, Zhe‐Fei, Timofeeva, Elena V., and Segre, Carlo U. In Situ EXAFS-Derived Mechanism of Highly Reversible Tin Phosphide/Graphite Composite Anode for Li-Ion Batteries. United States: N. p., 2017.
Web. doi:10.1002/aenm.201702134.
Ding, Yujia, Li, Zhe‐Fei, Timofeeva, Elena V., & Segre, Carlo U. In Situ EXAFS-Derived Mechanism of Highly Reversible Tin Phosphide/Graphite Composite Anode for Li-Ion Batteries. United States. https://doi.org/10.1002/aenm.201702134
Ding, Yujia, Li, Zhe‐Fei, Timofeeva, Elena V., and Segre, Carlo U. Mon .
"In Situ EXAFS-Derived Mechanism of Highly Reversible Tin Phosphide/Graphite Composite Anode for Li-Ion Batteries". United States. https://doi.org/10.1002/aenm.201702134. https://www.osti.gov/servlets/purl/1431366.
@article{osti_1431366,
title = {In Situ EXAFS-Derived Mechanism of Highly Reversible Tin Phosphide/Graphite Composite Anode for Li-Ion Batteries},
author = {Ding, Yujia and Li, Zhe‐Fei and Timofeeva, Elena V. and Segre, Carlo U.},
abstractNote = {Abstract A novel Sn 4 P 3 /graphite composite anode material with superior capacity and cycling performance (651 mA h g −1 after 100 cycles) is investigated by in situ X‐ray absorption spectroscopy. Extended X‐ray absorption fine structure modeling and detailed analysis of local environment changes are correlated to the cell capacity and reveal the mechanism of lithiation/delithiation process. Results show that in the first two lithiation/delithiation cycles crystalline Sn 4 P 3 is fully converted to an amorphous SnP x phase, which in further cycles participates in reversible conversion and alloying reactions. The superior reversibility of this material is attributed to the highly dispersed SnP x in the graphite matrix, which provides enhanced electrical conductivity and prevents aggregation of Sn clusters during the lithiation/delithiation process. The gradual capacity fading in long‐term cycling is attributed to the observed increase in the size and the amount of metallic Sn clusters in the delithiated state, correlated to the reduced recovery of the SnP x phase. This paper reveals the mechanism responsible for the highly reversible tin phosphides and provides insights for improving the capacity and cycle life of conversion and alloying materials.},
doi = {10.1002/aenm.201702134},
journal = {Advanced Energy Materials},
number = 9,
volume = 8,
place = {United States},
year = {Mon Dec 18 00:00:00 EST 2017},
month = {Mon Dec 18 00:00:00 EST 2017}
}
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Works referenced in this record:
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
In Situ X-Ray Absorption and Diffraction Study of the Li Reaction with a Tin Composite Oxide Glass
journal, January 2000
- Mansour, A. N.; Mukerjee, S.; Yang, X. Q.
- Journal of The Electrochemical Society, Vol. 147, Issue 3
Solvothermal preparation of tin phosphide as a long-life anode for advanced lithium and sodium ion batteries
journal, February 2016
- Liu, Shuling; Zhang, Hongzhe; Xu, Liqiang
- Journal of Power Sources, Vol. 304
Synergistic Na-Storage Reactions in Sn 4 P 3 as a High-Capacity, Cycle-stable Anode of Na-Ion Batteries
journal, March 2014
- Qian, Jiangfeng; Xiong, Ya; Cao, Yuliang
- Nano Letters, Vol. 14, Issue 4
In situ methods for Li-ion battery research: A review of recent developments
journal, August 2015
- Harks, P. P. R. M. L.; Mulder, F. M.; Notten, P. H. L.
- Journal of Power Sources, Vol. 288
Mössbauer spectra as a “fingerprint” in tin–lithium compounds: Applications to Li-ion batteries
journal, January 2007
- Robert, F.; Lippens, P. E.; Olivier-Fourcade, J.
- Journal of Solid State Chemistry, Vol. 180, Issue 1
Reversible Lithium Intercalation in Teardrop-Shaped Ultrafine SnP0.94 Particles: An Anode Material for Lithium-Ion Batteries
journal, January 2007
- Kim, Y.; Hwang, H.; Yoon, C. S.
- Advanced Materials, Vol. 19, Issue 1
EXPGUI , a graphical user interface for GSAS
journal, April 2001
- Toby, Brian H.
- Journal of Applied Crystallography, Vol. 34, Issue 2
Enhanced Electrochemical Stability of Sn-Carbon Nanotube Nanocapsules as Lithium-Ion Battery Anode
journal, October 2014
- Liu, Chun-jing; Huang, Hao; Cao, Guo-zhong
- Electrochimica Acta, Vol. 144
X-ray and Neutron Diffraction Studies on “Li 4.4 Sn”
journal, June 2003
- Lupu, Corina; Mao, Jiang-Gao; Rabalais, J. Wayne
- Inorganic Chemistry, Vol. 42, Issue 12
Pulsed-Laser-Deposited Sn[sub 4]P[sub 3] Electrodes for Lithium-Ion Batteries
journal, January 2009
- Wu, Ji-Jin; Fu, Zheng-Wen
- Journal of The Electrochemical Society, Vol. 156, Issue 1
Amorphous Carbon-Coated Tin Anode Material for Lithium Secondary Battery
journal, April 2005
- Noh, Mijung; Kwon, Yoojung; Lee, Hyojin
- Chemistry of Materials, Vol. 17, Issue 8
Superior Stable Self-Healing SnP 3 Anode for Sodium-Ion Batteries
journal, June 2015
- Fan, Xiulin; Mao, Jianfeng; Zhu, Yujie
- Advanced Energy Materials, Vol. 5, Issue 18
Reaction Mechanism of Tin Phosphide Anode by Mechanochemical Method for Lithium Secondary Batteries
journal, January 2004
- Kim, Young-Ugk; Lee, Churl Kyung; Sohn, Hun-Joon
- Journal of The Electrochemical Society, Vol. 151, Issue 6
On the Mechanism of the Electrochemical Reaction of Tin Phosphide with Lithium
journal, January 2006
- León, Bernardo; Corredor, Juan I.; Tirado, José L.
- Journal of The Electrochemical Society, Vol. 153, Issue 10
Synthesis of hollow spherical tin phosphides (Sn4P3) and their high adsorptive and electrochemical performance
journal, March 2016
- Liu, Shuling; Zhang, Hongzhe; Xu, Liqiang
- Journal of Crystal Growth, Vol. 438
Potential-Resolved In Situ X-ray Absorption Spectroscopy Study of Sn and SnO 2 Nanomaterial Anodes for Lithium-Ion Batteries
journal, January 2016
- Pelliccione, Christopher J.; Timofeeva, Elena V.; Segre, Carlo U.
- The Journal of Physical Chemistry C, Vol. 120, Issue 10
Preparation, structure and ionic conductivity of lithium phosphide
journal, April 1989
- Nazri, G.
- Solid State Ionics, Vol. 34, Issue 1-2
Best Practices for Operando Battery Experiments: Influences of X-ray Experiment Design on Observed Electrochemical Reactivity
journal, May 2015
- Borkiewicz, Olaf J.; Wiaderek, Kamila M.; Chupas, Peter J.
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 11
In Situ Electrochemistry of Rechargeable Battery Materials: Status Report and Perspectives
journal, June 2017
- Yang, Yijun; Liu, Xizheng; Dai, Zhonghua
- Advanced Materials, Vol. 29, Issue 31
In Situ X-ray Absorption Spectroscopy Study of the Capacity Fading Mechanism in Hybrid Sn 3 O 2 (OH) 2 /Graphite Battery Anode Nanomaterials
journal, January 2015
- Pelliccione, Christopher J.; Timofeeva, Elena V.; Segre, Carlo U.
- Chemistry of Materials, Vol. 27, Issue 2
Graphite–Tin composites as anode materials for lithium-ion batteries
journal, July 2001
- Wang, G. X.; Ahn, Jung-Ho; Lindsay, M. J.
- Journal of Power Sources, Vol. 97-98
The MRCAT insertion device beamline at the Advanced Photon Source
conference, January 2000
- Segre, C. U.
- The 11th US national synchrotron radiation instrumentation conference (SRI99), AIP Conference Proceedings
Li-alloy based anode materials for Li secondary batteries
journal, January 2010
- Park, Cheol-Min; Kim, Jae-Hun; Kim, Hansu
- Chemical Society Reviews, Vol. 39, Issue 8, p. 3115-3141
In situ XAS of the reaction mechanism of lithium with tin-based composite oxide glass
journal, May 1999
- Mansour, A. N.; Mukerjee, S.; Yang, X. Q.
- Journal of Synchrotron Radiation, Vol. 6, Issue 3
Lithium alloys and metal oxides as high-capacity anode materials for lithium-ion batteries
journal, October 2013
- Liang, Chu; Gao, Mingxia; Pan, Hongge
- Journal of Alloys and Compounds, Vol. 575
The true crystal structure of Li17M4 (M=Ge, Sn, Pb)–revised from Li22M5
journal, November 2001
- Goward, G. R.; Taylor, N. J.; Souza, D. C. S.
- Journal of Alloys and Compounds, Vol. 329, Issue 1-2, p. 82-91
In Situ Electrochemical XAFS Studies on an Iron Fluoride High-Capacity Cathode Material for Rechargeable Lithium Batteries
journal, May 2013
- Zhang, Wei; Duchesne, Paul N.; Gong, Zheng-Liang
- The Journal of Physical Chemistry C, Vol. 117, Issue 22
IFEFFIT : interactive XAFS analysis and FEFF fitting
journal, March 2001
- Newville, Matthew
- Journal of Synchrotron Radiation, Vol. 8, Issue 2
In Situ XAFS Study of the Capacity Fading Mechanisms in ZnO Anodes for Lithium-Ion Batteries
journal, January 2015
- Pelliccione, Christopher J.; Ding, Yujia; Timofeeva, Elena V.
- Journal of The Electrochemical Society, Vol. 162, Issue 10
Rutile-type compounds. IV. SiO2, GeO2 and a comparison with other rutile-type structures
journal, November 1971
- Baur, W. H.; Khan, A. A.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 27, Issue 11
Enhancement of capacity and cycle-life of SnP (0??1) anode for lithium secondary batteries
journal, February 2005
- Kim, Y.; Lee, S.; Lee, C.
- Journal of Power Sources, Vol. 141, Issue 1
X-Ray Investigations of the Tin-Phosphorus System.
journal, January 1970
- Olofsson, Olle; Aava, Ulf; Haaland, A.
- Acta Chemica Scandinavica, Vol. 24
Works referencing / citing this record:
Understanding of the Ultrastable K-Ion Storage of Carbonaceous Anode
journal, May 2018
- Liu, Lei; Chen, Yu; Xie, Yihao
- Advanced Functional Materials, Vol. 28, Issue 29
Empowering Metal Phosphides Anode with Catalytic Attribute toward Superior Cyclability for Lithium‐Ion Storage
journal, February 2019
- Yuan, Huadong; Wu, Min; Zheng, Jianhui
- Advanced Functional Materials, Vol. 29, Issue 17
Identifying the Origin and Contribution of Surface Storage in TiO 2 (B) Nanotube Electrode by In Situ Dynamic Valence State Monitoring
journal, July 2018
- Tang, Yuxin; Zhang, Yanyan; Malyi, Oleksandr I.
- Advanced Materials, Vol. 30, Issue 33
Sn 4 P 3 /TiC Composites as Li‐Ion Battery Anode with High Volumetric Capacity and Good Rate Capability
journal, May 2019
- Zhang, Jiaolong; Wang, Wenhui; Li, Baohua
- Energy Technology, Vol. 7, Issue 9
The Advances of Metal Sulfides and In Situ Characterization Methods beyond Li Ion Batteries: Sodium, Potassium, and Aluminum Ion Batteries
journal, November 2019
- Chen, Jingwei; Chua, Daniel H. C.; Lee, Pooi See
- Small Methods, Vol. 4, Issue 1
Characterization of Sn4P3–Carbon Composite Films for Lithium-Ion Battery Anode Fabricated by Aerosol Deposition
journal, July 2019
- Moritaka, Toki; Yamashita, Yuh; Tojo, Tomohiro
- Nanomaterials, Vol. 9, Issue 7