One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction

Norheim, Hans-Kristian; Schneider, Christian; Gagnon, Kevin J.; Ghosh, Abhik

doi:10.1002/open.201600168

Title: One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction

Journal Article · 13 February 2017 · ChemistryOpen

DOI: https://doi.org/10.1002/open.201600168 · OSTI ID:1413720

Norheim, Hans-Kristian ^[1]; Schneider, Christian ^[1]; Gagnon, Kevin J. ^[2];

^[1]

Arctic Univ. of Norway, Tromso (Norway). Dept. of Chemistry
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source

For a one-pot protocol, effecting 14-fold bromination with elemental bromine, has afforded copper β-octabromo-meso-tris(2,6-dibromo-3,5-dimethoxyphenyl)corrole, a new bis-pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, which in turn could be readily complexed to Mn^III and Au^III. Finally, a single-crystal X-ray structure was obtained for the MnIII complex.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1413720

Journal Information:: ChemistryOpen, Journal Name: ChemistryOpen Journal Issue: 2 Vol. 6; ISSN 2191-1363

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
bis-pocket corrole
bromination
complex synthesis
copper
x-ray diffraction

Title: One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction

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