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Title: One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction

Abstract

For a one-pot protocol, effecting 14-fold bromination with elemental bromine, has afforded copper β-octabromo-meso-tris(2,6-dibromo-3,5-dimethoxyphenyl)corrole, a new bis-pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, which in turn could be readily complexed to Mn III and Au III. Finally, a single-crystal X-ray structure was obtained for the MnIII complex.

Authors:
 [1];  [1];  [2]; ORCiD logo [1]
  1. Arctic Univ. of Norway, Tromso (Norway). Dept. of Chemistry
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1413720
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
ChemistryOpen
Additional Journal Information:
Journal Volume: 6; Journal Issue: 2; Journal ID: ISSN 2191-1363
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; bis-pocket corrole; bromination; complex synthesis; copper; x-ray diffraction

Citation Formats

Norheim, Hans-Kristian, Schneider, Christian, Gagnon, Kevin J., and Ghosh, Abhik. One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction. United States: N. p., 2017. Web. doi:10.1002/open.201600168.
Norheim, Hans-Kristian, Schneider, Christian, Gagnon, Kevin J., & Ghosh, Abhik. One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction. United States. doi:10.1002/open.201600168.
Norheim, Hans-Kristian, Schneider, Christian, Gagnon, Kevin J., and Ghosh, Abhik. Tue . "One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction". United States. doi:10.1002/open.201600168. https://www.osti.gov/servlets/purl/1413720.
@article{osti_1413720,
title = {One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction},
author = {Norheim, Hans-Kristian and Schneider, Christian and Gagnon, Kevin J. and Ghosh, Abhik},
abstractNote = {For a one-pot protocol, effecting 14-fold bromination with elemental bromine, has afforded copper β-octabromo-meso-tris(2,6-dibromo-3,5-dimethoxyphenyl)corrole, a new bis-pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, which in turn could be readily complexed to MnIII and AuIII. Finally, a single-crystal X-ray structure was obtained for the MnIII complex.},
doi = {10.1002/open.201600168},
journal = {ChemistryOpen},
number = 2,
volume = 6,
place = {United States},
year = {2017},
month = {2}
}

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