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Title: One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction

For a one-pot protocol, effecting 14-fold bromination with elemental bromine, has afforded copper β-octabromo-meso-tris(2,6-dibromo-3,5-dimethoxyphenyl)corrole, a new bis-pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, which in turn could be readily complexed to Mn III and Au III. Finally, a single-crystal X-ray structure was obtained for the MnIII complex.
Authors:
 [1] ;  [1] ;  [2] ; ORCiD logo [1]
  1. Arctic Univ. of Norway, Tromso (Norway). Dept. of Chemistry
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
Publication Date:
Grant/Contract Number:
AC02-05CH11231
Type:
Accepted Manuscript
Journal Name:
ChemistryOpen
Additional Journal Information:
Journal Volume: 6; Journal Issue: 2; Journal ID: ISSN 2191-1363
Publisher:
ChemPubSoc Europe
Research Org:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; bis-pocket corrole; bromination; complex synthesis; copper; x-ray diffraction
OSTI Identifier:
1413720