skip to main content

DOE PAGESDOE PAGES

Title: Highly effective ammonia removal in a series of Brønsted acidic porous polymers: investigation of chemical and structural variations

Efficient removal of ammonia from air is demonstrated in a series of Brønsted acidic porous polymers under dry and humid conditions. The impact of acidic group strength and their spatial distribution on the ammonia uptake is investigated systematically.
Authors:
 [1] ;  [2] ;  [3] ; ORCiD logo [1] ;  [1] ;  [1] ;  [4] ; ORCiD logo [3] ; ORCiD logo [4]
  1. Univ. of California, Berkeley, CA (United States)
  2. U. S. Army Research, Development, and Engineering Command, Aberdeen Proving Ground (United States)
  3. Univ. of Turin, Torino (Italy)
  4. Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Publication Date:
Grant/Contract Number:
AC02-05CH11231
Type:
Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 8; Journal Issue: 6; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Research Org:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
OSTI Identifier:
1413715

Barin, Gokhan, Peterson, Gregory W., Crocella, Valentina, Xu, Jun, Colwell, Kristen A., Nandy, Aditya, Reimer, Jeffrey A., Bordiga, Silvia, and Long, Jeffrey R.. Highly effective ammonia removal in a series of Brønsted acidic porous polymers: investigation of chemical and structural variations. United States: N. p., Web. doi:10.1039/c6sc05079d.
Barin, Gokhan, Peterson, Gregory W., Crocella, Valentina, Xu, Jun, Colwell, Kristen A., Nandy, Aditya, Reimer, Jeffrey A., Bordiga, Silvia, & Long, Jeffrey R.. Highly effective ammonia removal in a series of Brønsted acidic porous polymers: investigation of chemical and structural variations. United States. doi:10.1039/c6sc05079d.
Barin, Gokhan, Peterson, Gregory W., Crocella, Valentina, Xu, Jun, Colwell, Kristen A., Nandy, Aditya, Reimer, Jeffrey A., Bordiga, Silvia, and Long, Jeffrey R.. 2017. "Highly effective ammonia removal in a series of Brønsted acidic porous polymers: investigation of chemical and structural variations". United States. doi:10.1039/c6sc05079d. https://www.osti.gov/servlets/purl/1413715.
@article{osti_1413715,
title = {Highly effective ammonia removal in a series of Brønsted acidic porous polymers: investigation of chemical and structural variations},
author = {Barin, Gokhan and Peterson, Gregory W. and Crocella, Valentina and Xu, Jun and Colwell, Kristen A. and Nandy, Aditya and Reimer, Jeffrey A. and Bordiga, Silvia and Long, Jeffrey R.},
abstractNote = {Efficient removal of ammonia from air is demonstrated in a series of Brønsted acidic porous polymers under dry and humid conditions. The impact of acidic group strength and their spatial distribution on the ammonia uptake is investigated systematically.},
doi = {10.1039/c6sc05079d},
journal = {Chemical Science},
number = 6,
volume = 8,
place = {United States},
year = {2017},
month = {4}
}

Works referenced in this record:

Metal-organic frameworks with high capacity and selectivity for harmful gases
journal, August 2008
  • Britt, D.; Tranchemontagne, D.; Yaghi, O. M.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 33, p. 11623-11627
  • DOI: 10.1073/pnas.0804900105

Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
journal, March 2012

Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials
journal, August 2010
  • Farha, Omar K.; Hupp, Joseph T.
  • Accounts of Chemical Research, Vol. 43, Issue 8, p. 1166-1175
  • DOI: 10.1021/ar1000617

Hydrogen storage in metal–organic frameworks
journal, January 2009
  • Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
  • DOI: 10.1039/b802256a

Introduction to Metal–Organic Frameworks
journal, September 2011
  • Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 673-674
  • DOI: 10.1021/cr300014x

Ammonia Vapor Removal by Cu3(BTC)2 and Its Characterization by MAS NMR
journal, August 2009
  • Peterson, Gregory W.; Wagner, George W.; Balboa, Alex
  • The Journal of Physical Chemistry C, Vol. 113, Issue 31, p. 13906-13917
  • DOI: 10.1021/jp902736z

Exceptional ammonia uptake by a covalent organic framework
journal, February 2010
  • Doonan, Christian J.; Tranchemontagne, David J.; Glover, T. Grant
  • Nature Chemistry, Vol. 2, Issue 3, p. 235-238
  • DOI: 10.1038/nchem.548

Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011
  • O’Keeffe, Michael; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 675-702
  • DOI: 10.1021/cr200205j

Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage
journal, January 2006
  • McKeown, Neil B.; Budd, Peter M.
  • Chemical Society Reviews, Vol. 35, Issue 8, p. 675-683
  • DOI: 10.1039/b600349d

Porous Organic Polymers in Catalysis Opportunities and Challenges
journal, May 2011
  • Kaur, Parminder; Hupp, Joseph T.; Nguyen, SonBinh T.
  • ACS Catalysis, Vol. 1, Issue 7, p. 819-835
  • DOI: 10.1021/cs200131g

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
  • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
  • DOI: 10.1021/cr2003272

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
journal, July 2009
  • Furukawa, Hiroyasu; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8875-8883
  • DOI: 10.1021/ja9015765

Hybrid porous solids past, present, future
journal, January 2008
  • Férey, Gérard
  • Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214
  • DOI: 10.1039/B618320B

MOF-74 building unit has a direct impact on toxic gas adsorption
journal, January 2011
  • Grant Glover, T.; Peterson, Gregory W.; Schindler, Bryan J.
  • Chemical Engineering Science, Vol. 66, Issue 2, p. 163-170
  • DOI: 10.1016/j.ces.2010.10.002

Metal–Organic Frameworks for Separations
journal, September 2011
  • Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
  • Chemical Reviews, Vol. 112, Issue 2, p. 869-932
  • DOI: 10.1021/cr200190s

Nanoporous organic polymer networks
journal, April 2012

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Functional Materials: From Hard to Soft Porous Frameworks
journal, October 2010
  • Thomas, Arne
  • Angewandte Chemie International Edition, Vol. 49, Issue 45, p. 8328-8344
  • DOI: 10.1002/anie.201000167

Soft porous crystals
journal, November 2009
  • Horike, Satoshi; Shimomura, Satoru; Kitagawa, Susumu
  • Nature Chemistry, Vol. 1, Issue 9, p. 695-704
  • DOI: 10.1038/nchem.444