Suppression of magnetostructural transition on GdSiGe thin film after thermal cyclings
Abstract
The influence of thermal cycling on the microstructure, magnetic phase transition and magnetic entropy change of a Gd5Si1.3Ge2.7 thin film up to 1000 cycles is investigated. The authors found that after 1000 cycles a strong reduction of the crystallographic phase responsible for the magnetostructural transition (Orthorhombic II phase) occurs. We attribute this to the chemical disorder, caused by the large number of expansion/compression cycles that the Orthorhombic II phase undergoes across the magnetostructural transition. The suppression of the magnetostructural transition corresponds to a drastic decrease of the thin film magnetic entropy change. Our results reveal the importance of studying the thermal/magnetic cycles influence on magnetostructural transitions as they can damage a real-life device.
- Authors:
-
- Univ. of Porto (Portugal). Inst. of Nanoscience and Nanotechnology
- Iowa State Univ., Ames, IA (United States). Dept. of Electrical and Computer Engineering
- (United States)
- Ames Lab. and Iowa State Univ., Ames, IA (United States)
- (United States). Division of Materials Science and Engineering
- Publication Date:
- Research Org.:
- Ames Lab., Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1347912
- Alternate Identifier(s):
- OSTI ID: 1413530
- Report Number(s):
- IS-J 9227
Journal ID: ISSN 0040-6090; PII: S0040609016305211
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Thin Solid Films
- Additional Journal Information:
- Journal Volume: 621; Journal Issue: C; Journal ID: ISSN 0040-6090
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Thermal cycling; Magnetocaloric effect; Thin films; Microstructure
Citation Formats
Pires, A. L., Belo, J. H., Gomes, I. T., Hadimani, R. L., Ames Lab. and Iowa State Univ., Ames, IA, Schlagel, D. L., Lograsso, T. A., Ames Lab., Ames, IA, Jiles, D. C., Ames Lab. and Iowa State Univ., Ames, IA, Lopes, A. M. L., Araújo, J. P., and Pereira, A. M. Suppression of magnetostructural transition on GdSiGe thin film after thermal cyclings. United States: N. p., 2016.
Web. doi:10.1016/j.tsf.2016.09.013.
Pires, A. L., Belo, J. H., Gomes, I. T., Hadimani, R. L., Ames Lab. and Iowa State Univ., Ames, IA, Schlagel, D. L., Lograsso, T. A., Ames Lab., Ames, IA, Jiles, D. C., Ames Lab. and Iowa State Univ., Ames, IA, Lopes, A. M. L., Araújo, J. P., & Pereira, A. M. Suppression of magnetostructural transition on GdSiGe thin film after thermal cyclings. United States. https://doi.org/10.1016/j.tsf.2016.09.013
Pires, A. L., Belo, J. H., Gomes, I. T., Hadimani, R. L., Ames Lab. and Iowa State Univ., Ames, IA, Schlagel, D. L., Lograsso, T. A., Ames Lab., Ames, IA, Jiles, D. C., Ames Lab. and Iowa State Univ., Ames, IA, Lopes, A. M. L., Araújo, J. P., and Pereira, A. M. Thu .
"Suppression of magnetostructural transition on GdSiGe thin film after thermal cyclings". United States. https://doi.org/10.1016/j.tsf.2016.09.013. https://www.osti.gov/servlets/purl/1347912.
@article{osti_1347912,
title = {Suppression of magnetostructural transition on GdSiGe thin film after thermal cyclings},
author = {Pires, A. L. and Belo, J. H. and Gomes, I. T. and Hadimani, R. L. and Ames Lab. and Iowa State Univ., Ames, IA and Schlagel, D. L. and Lograsso, T. A. and Ames Lab., Ames, IA and Jiles, D. C. and Ames Lab. and Iowa State Univ., Ames, IA and Lopes, A. M. L. and Araújo, J. P. and Pereira, A. M.},
abstractNote = {The influence of thermal cycling on the microstructure, magnetic phase transition and magnetic entropy change of a Gd5Si1.3Ge2.7 thin film up to 1000 cycles is investigated. The authors found that after 1000 cycles a strong reduction of the crystallographic phase responsible for the magnetostructural transition (Orthorhombic II phase) occurs. We attribute this to the chemical disorder, caused by the large number of expansion/compression cycles that the Orthorhombic II phase undergoes across the magnetostructural transition. The suppression of the magnetostructural transition corresponds to a drastic decrease of the thin film magnetic entropy change. Our results reveal the importance of studying the thermal/magnetic cycles influence on magnetostructural transitions as they can damage a real-life device.},
doi = {10.1016/j.tsf.2016.09.013},
journal = {Thin Solid Films},
number = C,
volume = 621,
place = {United States},
year = {Thu Sep 08 00:00:00 EDT 2016},
month = {Thu Sep 08 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Developments in magnetocaloric refrigeration
journal, November 2005
- Brück, Ekkes
- Journal of Physics D: Applied Physics, Vol. 38, Issue 23
Thirty years of near room temperature magnetic cooling: Where we are today and future prospects
journal, September 2008
- Gschneidner, K. A.; Pecharsky, V. K.
- International Journal of Refrigeration, Vol. 31, Issue 6, p. 945-961
Magnetocaloric effect: A review of the thermodynamic cycles in magnetic refrigeration
journal, January 2013
- Romero Gómez, J.; Ferreiro Garcia, R.; De Miguel Catoira, A.
- Renewable and Sustainable Energy Reviews, Vol. 17
Enhancement of the magnetocaloric effect driven by changes in the crystal structure of Al-doped GGG, Gd 3 Ga 5−x Al x O 12 (0 ≤x ≤5)
journal, March 2014
- Sackville Hamilton, A. C.; Lampronti, G. I.; Rowley, S. E.
- Journal of Physics: Condensed Matter, Vol. 26, Issue 11
Recent developments in magnetocaloric materials
journal, May 2005
- Gschneidner, K. A.; Pecharsky, V. K.; Tsokol, A. O.
- Reports on Progress in Physics, Vol. 68, Issue 6, p. 1479-1539
The giant magnetocaloric effect of Gd5Si1.95Ge2.05 enhanced by Sn doping
journal, October 2006
- Li, J. Q.; Sun, W. A.; Jian, Y. X.
- Journal of Applied Physics, Vol. 100, Issue 7
Understanding the role played by Fe on the tuning of magnetocaloric effect in Tb5Si2Ge2
journal, March 2011
- Pereira, A. M.; dos Santos, A. M.; Magen, C.
- Applied Physics Letters, Vol. 98, Issue 12
Phase control studies in Gd5Si2Ge2 giant magnetocaloric compound
journal, July 2012
- Belo, J. H.; Pereira, A. M.; Ventura, J.
- Journal of Alloys and Compounds, Vol. 529
Tailoring the magnetism of Tb Si Ge compounds by La substitution
journal, July 2012
- Belo, J. H.; Pereira, A. M.; Araújo, J. P.
- Physical Review B, Vol. 86, Issue 1
Phase relationship, microstructure and magnetocaloric effect in Gd 1− x (Si 0.5 Ge 0.5 ) x alloys
journal, February 2008
- Manivel Raja, M.; Gopalan, R.; Rajkumar, D. M.
- Journal of Physics D: Applied Physics, Vol. 41, Issue 5
Phase Competitions behind the Giant Magnetic Entropy Variation: Gd5Si2Ge2 and Tb5Si2Ge2 Case Studies
journal, July 2014
- Pires, Ana; Belo, João; Lopes, Armandina
- Entropy, Vol. 16, Issue 7
Giant Magnetocaloric Effect in
journal, June 1997
- Pecharsky, V. K.; Gschneidner, Jr., K. A.
- Physical Review Letters, Vol. 78, Issue 23, p. 4494-4497
Contributions to the entropy change in melt-spun LaFe 11.6 Si 1.4
journal, March 2010
- Morrison, K.; Lyubina, J.; Moore, J. D.
- Journal of Physics D: Applied Physics, Vol. 43, Issue 13
Influence of thermal hysteresis and field cycling on the magnetocaloric effect in LaFe11.6Si1.4
journal, March 2013
- Skokov, K. P.; Müller, K. -H.; Moore, J. D.
- Journal of Alloys and Compounds, Vol. 552
Asymmetric first-order transition and interlocked particle state in magnetocaloric La(Fe,Si) 13 : Asymmetric first-order transition and interlocked particle state in magnetocaloric La(Fe,Si)
journal, January 2015
- Waske, Anja; Giebeler, Lars; Weise, Bruno
- physica status solidi (RRL) - Rapid Research Letters, Vol. 9, Issue 2
Dynamics of the First-Order Metamagnetic Transition in Magnetocaloric La(Fe,Si) 13 : Reducing Hysteresis
journal, November 2014
- Lovell, Edmund; Pereira, André M.; Caplin, A. David
- Advanced Energy Materials, Vol. 5, Issue 6
Giant magnetocaloric effect driven by structural transitions
journal, May 2012
- Liu, Jian; Gottschall, Tino; Skokov, Konstantin P.
- Nature Materials, Vol. 11, Issue 7
The magnetocaloric effect in thermally cycled polycrystalline Ni-Mn-Ga
journal, April 2012
- Booth, Ryan A.; Majetich, Sara A.
- Journal of Applied Physics, Vol. 111, Issue 7
Transformations in the alloy induced by the temperature and magnetic-field cycling through the first-order magnetic-martensitic phase transition
journal, January 2001
- Levin, E. M.; Pecharsky, A. O.; Pecharsky, V. K.
- Physical Review B, Vol. 63, Issue 6
Anomalous behavior of the electrical resistivity in the giant magnetocaloric compound
journal, April 2003
- Sousa, J. B.; Braga, M. E.; Correia, F. C.
- Physical Review B, Vol. 67, Issue 13
Multi-step and anomalous reproducible behaviour of the electrical resistivity near the first-order magnetostructural transition of Gd 5 (Si 0.1 Ge 0.9 ) 4
journal, April 2005
- Sousa, J. B.; Pereira, A. M.; Correia, F. C.
- Journal of Physics: Condensed Matter, Vol. 17, Issue 15
Thermopower behavior in the Gd5(Si0.1Ge0.9)4 magnetocaloric compound from 4 to 300 K
journal, April 2002
- Sousa, J. B.; Braga, M. E.; Correia, F. C.
- Journal of Applied Physics, Vol. 91, Issue 7
Direct observation of the magnetic-field-induced entropy change in Gd5(SixGe1−x)4 giant magnetocaloric alloys
journal, June 2005
- Casanova, Fèlix; Labarta, Amílcar; Batlle, Xavier
- Applied Physics Letters, Vol. 86, Issue 26
Magnetocaloric effect in rare earth-based bulk metallic glasses
journal, April 2010
- Luo, Q.; Wang, W. H.
- Journal of Alloys and Compounds, Vol. 495, Issue 1
Room temperature magnetocaloric effect and refrigerant capacitance in La 0.7 Sr 0.3 MnO 3 nanotube arrays
journal, August 2014
- Kumaresavanji, M.; Sousa, C. T.; Pires, A.
- Applied Physics Letters, Vol. 105, Issue 8
Gd5(Si,Ge)4 thin film displaying large magnetocaloric and strain effects due to magnetostructural transition
journal, January 2015
- Hadimani, Ravi L.; Silva, Joao H. B.; Pereira, Andre M.
- Applied Physics Letters, Vol. 106, Issue 3
Multi-energy conversion of Gd 5 (Si 2 Ge 2 )-poly (vinylidene fluoride), a hybrid material
journal, August 2014
- Ozaydin, M. F.; Liang, H.
- Applied Physics Letters, Vol. 105, Issue 6
Novel Design of La(Fe,Si)13 Alloys Towards High Magnetic Refrigeration Performance
journal, August 2010
- Lyubina, Julia; Schäfer, Rudolf; Martin, Norbert
- Advanced Materials, Vol. 22, Issue 33
Magnetocaloric effect and improved relative cooling power in (La 0.7 Sr 0.3 MnO 3 /SrRuO 3 ) superlattices
journal, January 2011
- Zhang, Q.; Thota, S.; Guillou, F.
- Journal of Physics: Condensed Matter, Vol. 23, Issue 5
Bulk and high-energy ball-milled Gd5Si2Ge2: Comparative study of magnetic and magnetocaloric properties
journal, January 2011
- Giovanna do Couto, Giselle; Svitlyk, Volodymyr; Jafelicci, Miguel
- Solid State Sciences, Vol. 13, Issue 1
Influence of short time milling in R5(Si,Ge)4, R=Gd and Tb, magnetocaloric materials
journal, November 2015
- Pires, A. L.; Belo, J. H.; Turcaud, J.
- Materials & Design, Vol. 85, p. 32-38
Phase-Coexistence and Thermal Hysteresis in Samples Comprising Adventitiously Doped MnAs Nanocrystals: Programming of Aggregate Properties in Magnetostructural Nanomaterials
journal, June 2014
- Zhang, Yanhua; Regmi, Rajesh; Liu, Yi
- ACS Nano, Vol. 8, Issue 7
On the determination of the magnetic entropy change in materials with first-order transitions
journal, November 2009
- Caron, L.; Ou, Z. Q.; Nguyen, T. T.
- Journal of Magnetism and Magnetic Materials, Vol. 321, Issue 21
The room temperature metastable/stable phase relationships in the pseudo-binary Gd5Si4–Gd5Ge4 system
journal, May 2002
- Pecharsky, A. O.; Gschneidner, K. A.; Pecharsky, V. K.
- Journal of Alloys and Compounds, Vol. 338, Issue 1-2
Annealing influence on the magnetostructural transition in Gd5Si1.3Ge2.7 thin films
journal, November 2015
- Pires, A. L.; Belo, J. H.; Gomes, I. T.
- Materials Letters, Vol. 159
The crystal structure of Gd5Si4
journal, January 1972
- Iglesias, Juan E.; Steinfink, Hugo
- Journal of the Less Common Metals, Vol. 26, Issue 1
Crystal structures of compounds in the pseudobinary system Gd5Ge4–La5Ge4
journal, October 2003
- Yang, H. F.; Rao, G. H.; Liu, G. Y.
- Journal of Alloys and Compounds, Vol. 361, Issue 1-2
Acoustic emission across the magnetostructural transition of the giant magnetocaloric
journal, January 2006
- Pérez-Reche, Francisco-José; Casanova, Fèlix; Vives, Eduard
- Physical Review B, Vol. 73, Issue 1
Field step size and temperature effects on the character of the magnetostructural transformation in a single crystal
journal, October 2007
- Ouyang, Z. W.; Pecharsky, V. K.; Gschneidner, K. A.
- Physical Review B, Vol. 76, Issue 13
Local probing of arrested kinetics in Gd 5 Ge 4
journal, October 2008
- Moore, J. D.; Perkins, G. K.; Morrison, K.
- Journal of Physics: Condensed Matter, Vol. 20, Issue 46
Metastable magnetic response across the antiferromagnetic to ferromagnetic transition in
journal, December 2004
- Chattopadhyay, M. K.; Manekar, M. A.; Pecharsky, A. O.
- Physical Review B, Vol. 70, Issue 21
Ion irradiation induced modifications of nanostructured Ni–Mn–Sn ferromagnetic shape memory alloy thin films
journal, December 2011
- Vishnoi, R.; Singhal, R.; Asokan, K.
- Thin Solid Films, Vol. 520, Issue 5
Works referencing / citing this record:
Magnetocaloric materials: From micro- to nanoscale
journal, November 2018
- Belo, João H.; Pires, Ana L.; Araújo, João P.
- Journal of Materials Research, Vol. 34, Issue 1
Managing hysteresis of Gd 5 Si 2 Ge 2 by magnetic field cycling
journal, December 2019
- Biswas, Anis; Mudryk, Yaroslav; Pathak, Arjun K.
- Journal of Applied Physics, Vol. 126, Issue 24