Lattice parameter evolution in Pt nanoparticles during photo-thermally induced sintering and grain growth

Kelly, B. G.; Loether, A.; DiChiara, A. D.; Henning, R.; DeCamp, M. F.; Unruh, K. M.

doi:10.1016/j.jpcs.2017.04.009

Title: Lattice parameter evolution in Pt nanoparticles during photo-thermally induced sintering and grain growth

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Abstract

An in-situ optical pump/x-ray probe technique has been used to study the size dependent lattice parameter of Pt nanoparticles subjected to picosecond duration optical laser pulses. The as-prepared Pt nanoparticles exhibited a contracted lattice parameter consistent with the response of an isolated elastic sphere to a compressive surface stress. During photo-thermally induced sintering and grain growth, however, the Pt lattice parameter did not evolve with the inverse particle size dependence predicted by simple surface stress models. Lastly, the observed behavior could be attributed to the combined effects of a compressive surface/interface stress and a tensile stress arising from intergranular material.

Authors:: Kelly, B. G.; Loether, A.; DiChiara, A. D.; Henning, R.; DeCamp, M. F.; Unruh, K. M.

Publication Date:: Thu Apr 20 00:00:00 EDT 2017

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Institutes of Health (NIH); National Science Foundation (NSF)

OSTI Identifier:: 1367892

Alternate Identifier(s):: OSTI ID: 1413389

Grant/Contract Number:: AC02-06CH11357; DMR140076; R24GM111072

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Physics and Chemistry of Solids

Additional Journal Information:: Journal Volume: 108; Journal Issue: C; Journal ID: ISSN 0022-3697

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 77 NANOSCIENCE AND NANOTECHNOLOGY; Laser annealing; Intergranular stress; Lattice parameter; Nanostructured materials; Surface/interface stress

Citation Formats


                    Kelly, B. G., Loether, A., DiChiara, A. D., Henning, R., DeCamp, M. F., and Unruh, K. M. Lattice parameter evolution in Pt nanoparticles during photo-thermally induced sintering and grain growth.  United States: N. p., 2017. 
Web.  doi:10.1016/j.jpcs.2017.04.009.

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                    Kelly, B. G., Loether, A., DiChiara, A. D., Henning, R., DeCamp, M. F., & Unruh, K. M. Lattice parameter evolution in Pt nanoparticles during photo-thermally induced sintering and grain growth.  United States.  https://doi.org/10.1016/j.jpcs.2017.04.009

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                    Kelly, B. G., Loether, A., DiChiara, A. D., Henning, R., DeCamp, M. F., and Unruh, K. M. Thu .  
"Lattice parameter evolution in Pt nanoparticles during photo-thermally induced sintering and grain growth".  United States.  https://doi.org/10.1016/j.jpcs.2017.04.009.  https://www.osti.gov/servlets/purl/1367892.

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@article{osti_1367892,

  title        = {Lattice parameter evolution in Pt nanoparticles during photo-thermally induced sintering and grain growth},

  author       = {Kelly, B. G. and Loether, A. and DiChiara, A. D. and Henning, R. and DeCamp, M. F. and Unruh, K. M.},

  abstractNote = {An in-situ optical pump/x-ray probe technique has been used to study the size dependent lattice parameter of Pt nanoparticles subjected to picosecond duration optical laser pulses. The as-prepared Pt nanoparticles exhibited a contracted lattice parameter consistent with the response of an isolated elastic sphere to a compressive surface stress. During photo-thermally induced sintering and grain growth, however, the Pt lattice parameter did not evolve with the inverse particle size dependence predicted by simple surface stress models. Lastly, the observed behavior could be attributed to the combined effects of a compressive surface/interface stress and a tensile stress arising from intergranular material.},

  doi          = {10.1016/j.jpcs.2017.04.009},

  journal      = {Journal of Physics and Chemistry of Solids},

  number       = C,

  volume       = 108,

  place        = {United States},

  year         = {Thu Apr 20 00:00:00 EDT 2017},

  month        = {Thu Apr 20 00:00:00 EDT 2017}

}

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