Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent
Abstract
Trimethyltin fluoride (Me₃SnF) is a mild and selective reagent for the installation of actinide fluoride bonds as demonstrated by the room temperature synthesis of a variety of organometallic and inorganic thorium(IV), uranium(IV), and uranium(V) fluoride complexes ((1,2,4-tBu₃C₅H₂)₂ThF₂, (C₅Me₅)₂U(F)(O-2,6-iPr₂C₆H₃), U(F)(O-2,6-tBu₂C₆H₃)₃, U(F)[N(SiMe₃)₂]₃ (C₅Me₅)₂UF₂(L) (L = O=PMe₃, O=PPh₃, O=PCy₃), and (C₅Me₅)₂U(F)(=N-2,6-iPr₂C₆H₃)) from their corresponding chloride, bromide, and iodide analogues. From these reactions, the new (C₅Me₅)₂UF₂(L) (L = O=PPh₃, O=PCy₃) uranium fluoride complexes were isolated and characterized by NMR spectroscopy and X-ray crystallography.
- Authors:
-
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Vermont, Burlington, VT (United States)
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Publication Date:
- Research Org.:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1412907
- Report Number(s):
- LA-UR-17-27961
Journal ID: ISSN 1434-1948
- Grant/Contract Number:
- AC52-06NA25396
- Resource Type:
- Accepted Manuscript
- Journal Name:
- European Journal of Inorganic Chemistry
- Additional Journal Information:
- Journal Volume: 2018; Journal Issue: 11; Journal ID: ISSN 1434-1948
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Kagan, Benjamin D., Lichtscheidl, Alejandro G., Erickson, Karla A., Monreal, Marisa J., Scott, Brian L., Nelson, Andrew T., and Kiplinger, Jaqueline Loetsch. Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent. United States: N. p., 2017.
Web. doi:10.1002/ejic.201701232.
Kagan, Benjamin D., Lichtscheidl, Alejandro G., Erickson, Karla A., Monreal, Marisa J., Scott, Brian L., Nelson, Andrew T., & Kiplinger, Jaqueline Loetsch. Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent. United States. https://doi.org/10.1002/ejic.201701232
Kagan, Benjamin D., Lichtscheidl, Alejandro G., Erickson, Karla A., Monreal, Marisa J., Scott, Brian L., Nelson, Andrew T., and Kiplinger, Jaqueline Loetsch. Tue .
"Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent". United States. https://doi.org/10.1002/ejic.201701232. https://www.osti.gov/servlets/purl/1412907.
@article{osti_1412907,
title = {Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent},
author = {Kagan, Benjamin D. and Lichtscheidl, Alejandro G. and Erickson, Karla A. and Monreal, Marisa J. and Scott, Brian L. and Nelson, Andrew T. and Kiplinger, Jaqueline Loetsch},
abstractNote = {Trimethyltin fluoride (Me₃SnF) is a mild and selective reagent for the installation of actinide fluoride bonds as demonstrated by the room temperature synthesis of a variety of organometallic and inorganic thorium(IV), uranium(IV), and uranium(V) fluoride complexes ((1,2,4-tBu₃C₅H₂)₂ThF₂, (C₅Me₅)₂U(F)(O-2,6-iPr₂C₆H₃), U(F)(O-2,6-tBu₂C₆H₃)₃, U(F)[N(SiMe₃)₂]₃ (C₅Me₅)₂UF₂(L) (L = O=PMe₃, O=PPh₃, O=PCy₃), and (C₅Me₅)₂U(F)(=N-2,6-iPr₂C₆H₃)) from their corresponding chloride, bromide, and iodide analogues. From these reactions, the new (C₅Me₅)₂UF₂(L) (L = O=PPh₃, O=PCy₃) uranium fluoride complexes were isolated and characterized by NMR spectroscopy and X-ray crystallography.},
doi = {10.1002/ejic.201701232},
journal = {European Journal of Inorganic Chemistry},
number = 11,
volume = 2018,
place = {United States},
year = {2017},
month = {11}
}
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