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Title: Hybrid molecular/enzymatic catalytic cascade for complete electro-oxidation of glycerol using a promiscuous NAD-dependent formate dehydrogenase from Candida boidinii

The formate dehydrogenase fromCandida boidiniiwas combined with NH 2-TEMPO to form a novel hybrid anode to oxidize glycerol to carbon dioxide at near-neutral pH.
Authors:
 [1] ;  [2] ; ORCiD logo [3] ;  [1] ;  [2] ; ORCiD logo [1]
  1. Univ. of Utah, Salt Lake City, UT (United States). Dept. of Chemistry and Materials Science and Engineering
  2. Univ. of New Mexico, Albuquerque, NM (United States). Center for Micro-Engineered Materials (CMEM), Dept. of Chemical and Biological Engineering
  3. Univ. of New Mexico, Albuquerque, NM (United States). Center for Micro-Engineered Materials (CMEM), Dept. of Chemical and Biological Engineering; Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Report Number(s):
LA-UR-17-20927
Journal ID: ISSN 1359-7345; CHCOFS; TRN: US1800400
Grant/Contract Number:
AC52-06NA25396; W911NF1410263
Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 53; Journal Issue: 39; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Research Org:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org:
US Army Research Office (ARO); USDOE
Country of Publication:
United States
Language:
English
Subject:
59 BASIC BIOLOGICAL SCIENCES; Biological Science; Material Science
OSTI Identifier:
1412894