Converting Wind Energy to Ammonia at Lower Pressure
Abstract
Renewable wind energy can be used to make ammonia. However, wind-generated ammonia costs about twice of that made from a traditional fossil-fuel driven process. To reduce the production cost, we replace the conventional ammonia condensation with a selective absorber containing metal halides, e.g. calcium chloride, operating at near synthesis temperatures. With this reaction-absorption process, ammonia can be synthesized at 20 bar from air, water, and wind-generated electricity, with rates comparable to the conventional process running at 150-300 bar. In our reaction-absorption process, the rate of ammonia synthesis is now controlled not by the chemical reaction, but largely by the pump used to recycle the unreacted gases. The results suggest an alternative route to distributed ammonia manufacture which can locally supply nitrogen fertilizer and also a method to capture stranded wind energy as a carbon-neutral liquid fuel.
- Authors:
-
- Univ. of Minnesota, Minneapolis, MN (United States). Dept. of Chemical Engineering and Materials Science
- Univ. of Minnesota, Morris, MN (United States). West Central Research and Outreach Center
- Publication Date:
- Research Org.:
- Univ. of Minnesota, Minneapolis, MN (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1412658
- Alternate Identifier(s):
- OSTI ID: 1434926
- Grant/Contract Number:
- AR0000804
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Sustainable Chemistry & Engineering
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2168-0485
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 10 SYNTHETIC FUELS; 17 WIND ENERGY; 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 74 ATOMIC AND MOLECULAR PHYSICS; Absorption; Energy storage; Mechanism; Metal halides; Reaction; 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Malmali, Mahdi, Reese, Michael, McCormick, Alon V., and Cussler, E. L. Converting Wind Energy to Ammonia at Lower Pressure. United States: N. p., 2017.
Web. doi:10.1021/acssuschemeng.7b03159.
Malmali, Mahdi, Reese, Michael, McCormick, Alon V., & Cussler, E. L. Converting Wind Energy to Ammonia at Lower Pressure. United States. https://doi.org/10.1021/acssuschemeng.7b03159
Malmali, Mahdi, Reese, Michael, McCormick, Alon V., and Cussler, E. L. Tue .
"Converting Wind Energy to Ammonia at Lower Pressure". United States. https://doi.org/10.1021/acssuschemeng.7b03159. https://www.osti.gov/servlets/purl/1412658.
@article{osti_1412658,
title = {Converting Wind Energy to Ammonia at Lower Pressure},
author = {Malmali, Mahdi and Reese, Michael and McCormick, Alon V. and Cussler, E. L.},
abstractNote = {Renewable wind energy can be used to make ammonia. However, wind-generated ammonia costs about twice of that made from a traditional fossil-fuel driven process. To reduce the production cost, we replace the conventional ammonia condensation with a selective absorber containing metal halides, e.g. calcium chloride, operating at near synthesis temperatures. With this reaction-absorption process, ammonia can be synthesized at 20 bar from air, water, and wind-generated electricity, with rates comparable to the conventional process running at 150-300 bar. In our reaction-absorption process, the rate of ammonia synthesis is now controlled not by the chemical reaction, but largely by the pump used to recycle the unreacted gases. The results suggest an alternative route to distributed ammonia manufacture which can locally supply nitrogen fertilizer and also a method to capture stranded wind energy as a carbon-neutral liquid fuel.},
doi = {10.1021/acssuschemeng.7b03159},
journal = {ACS Sustainable Chemistry & Engineering},
number = 1,
volume = 6,
place = {United States},
year = {Tue Nov 07 00:00:00 EST 2017},
month = {Tue Nov 07 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
How a century of ammonia synthesis changed the world
journal, September 2008
- Erisman, Jan Willem; Sutton, Mark A.; Galloway, James
- Nature Geoscience, Vol. 1, Issue 10
Ammonia synthesis: The bellwether reaction in heterogeneous catalysis
journal, September 1994
- Boudart, M.
- Topics in Catalysis, Vol. 1, Issue 3-4
Exploring the limits: A low-pressure, low-temperature Haber–Bosch process
journal, April 2014
- Vojvodic, Aleksandra; Medford, Andrew James; Studt, Felix
- Chemical Physics Letters, Vol. 598
Catalytic Synthesis of Ammonia—A “Never-Ending Story”?
journal, May 2003
- Schlögl, Robert
- Angewandte Chemie International Edition, Vol. 42, Issue 18
The irreversible momentum of clean energy
journal, January 2017
- Obama, Barack
- Science, Vol. 355, Issue 6321
Grid of the future
journal, March 2009
- Ipakchi, Ali; Albuyeh, Farrokh
- IEEE Power and Energy Magazine, Vol. 7, Issue 2
Materials Challenges Facing Electrical Energy Storage
journal, April 2008
- Whittingham, M. Stanley
- MRS Bulletin, Vol. 33, Issue 4
Towards an ammonia-mediated hydrogen economy?
journal, January 2006
- Christensen, Claus Hviid; Johannessen, Tue; Sørensen, Rasmus Zink
- Catalysis Today, Vol. 111, Issue 1-2
Optimization of the Automotive Ammonia Fuel Cycle Using P-Graphs
journal, August 2017
- Angeles, Donna A.; Are, Kristian Ray Angelo G.; Aviso, Kathleen B.
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 9
Network integration of distributed power generation
journal, April 2002
- Dondi, Peter; Bayoumi, Deia; Haederli, Christoph
- Journal of Power Sources, Vol. 106, Issue 1-2
Performance of a Small-Scale Haber Process
journal, March 2016
- Reese, Michael; Marquart, Cory; Malmali, Mahdi
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 13
Bottom-Up Design of a Copper-Ruthenium Nanoparticulate Catalyst for Low-Temperature Ammonia Oxidation
journal, June 2017
- Chakraborty, Debasish; Damsgaard, Christian Danvad; Silva, Hugo
- Angewandte Chemie, Vol. 129, Issue 30
Ammonia Synthesis at Reduced Pressure via Reactive Separation
journal, August 2016
- Malmali, Mahdi; Wei, Yongming; McCormick, Alon
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 33
Column absorption for reproducible cyclic separation in small scale ammonia synthesis
journal, February 2017
- Wagner, Kevin; Malmali, Mahdi; Smith, Collin
- AIChE Journal, Vol. 63, Issue 7
Ammonia Synthesis at Low Pressure
journal, January 2017
- Cussler, Edward; McCormick, Alon; Reese, Michael
- Journal of Visualized Experiments, Issue 126
Indirect, Reversible High-Density Hydrogen Storage in Compact Metal Ammine Salts
journal, July 2008
- Sørensen, Rasmus Z.; Hummelshøj, Jens S.; Klerke, Asbjørn
- Journal of the American Chemical Society, Vol. 130, Issue 27
Ammonia for hydrogen storage: challenges and opportunities
journal, January 2008
- Klerke, Asbjørn; Christensen, Claus Hviid; Nørskov, Jens K.
- Journal of Materials Chemistry, Vol. 18, Issue 20
Ammonia Absorption on Alkaline Earth Halides as Ammonia Separation and Storage Procedure
journal, January 2004
- Liu, Chun Yi; Aika, Ken-ichi
- Bulletin of the Chemical Society of Japan, Vol. 77, Issue 1
Generation of Nanopores during Desorption of NH 3 from Mg(NH 3 ) 6 Cl 2
journal, January 2006
- Hummelshøj, Jens S.; Sørensen, Rasmus Zink; Kustova, Marina Yu.
- Journal of the American Chemical Society, Vol. 128, Issue 1
Rate equation and mechanism of ammonia synthesis at industrial conditions
journal, February 1964
- Nielsen, A.
- Journal of Catalysis, Vol. 3, Issue 1
Surface science as the basis for the understanding of the catalytic synthesis of ammonia
journal, November 1987
- Stoltze, Per
- Physica Scripta, Vol. 36, Issue 5
Bridging the "Pressure Gap" between Ultrahigh-Vacuum Surface Physics and High-Pressure Catalysis
journal, November 1985
- Stoltze, P.; Nørskov, J. K.
- Physical Review Letters, Vol. 55, Issue 22
An interpretation of the high-pressure kinetics of ammonia synthesis based on a microscopic model
journal, March 1988
- Stoltze, P.
- Journal of Catalysis, Vol. 110, Issue 1
Modelling of ammonia synthesis kinetics
journal, February 1992
- Bowker, M.
- Catalysis Today, Vol. 12, Issue 2-3
The application of surface kinetic data to the industrial synthesis of ammonia
journal, January 1988
- Bowker, M.; Parker, I.; Waugh, K. C.
- Surface Science, Vol. 197, Issue 1-2
Extrapolation of the kinetics of model ammonia synthesis catalysts to industrially relevant temperatures and pressures
journal, January 1985
- Bowker, M.; Parker, I. B.; Waugh, K. C.
- Applied Catalysis, Vol. 14
Ammonia Synthesis over a Multipromoted Iron Catalyst: Extended Set of Activity Measurements, Microkinetic Model, and Hydrogen Inhibition
journal, November 1999
- Sehested, Jens; Jacobsen, Claus J. H.; Törnqvist, Eric
- Journal of Catalysis, Vol. 188, Issue 1
Works referencing / citing this record:
Sustainable Non‐Thermal Plasma‐Assisted Nitrogen Fixation—Synergistic Catalysis
journal, July 2019
- Peng, Peng; Schiappacasse, Charles; Zhou, Nan
- ChemSusChem, Vol. 12, Issue 16
Optimisation of the Autothermal NH3 Production Process for Power-to-Ammonia
journal, December 2019
- Cheema, Izzat Iqbal; Krewer, Ulrike
- Processes, Vol. 8, Issue 1
Effect of the TiO 2 crystal structure on the activity of TiO 2 -supported platinum catalysts for ammonia synthesis via the NO–CO–H 2 O reaction
journal, January 2019
- Kobayashi, Keisuke; Atsumi, Ryousuke; Manaka, Yuichi
- Catalysis Science & Technology, Vol. 9, Issue 11
Current and future role of Haber–Bosch ammonia in a carbon-free energy landscape
text, January 2020
- Smith, Collin; Hill, Alfred K.; Torrente-Murciano, Laura
- Apollo - University of Cambridge Repository