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Title: Stability of Residual Oxides in Oxide-Derived Copper Catalysts for Electrochemical CO 2 Reduction Investigated with 18 O Labeling

Authors:
ORCiD logo [1]; ORCiD logo [1]
  1. Joint Center for Artificial Photosynthesis and Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley CA 94720 USA, Department of Materials Science and Engineering, University of California, Berkeley CA 94720 USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1412579
Grant/Contract Number:  
SC0004993
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 130 Journal Issue: 2; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Lum, Yanwei, and Ager, Joel W. Stability of Residual Oxides in Oxide-Derived Copper Catalysts for Electrochemical CO 2 Reduction Investigated with 18 O Labeling. Germany: N. p., 2017. Web. doi:10.1002/ange.201710590.
Lum, Yanwei, & Ager, Joel W. Stability of Residual Oxides in Oxide-Derived Copper Catalysts for Electrochemical CO 2 Reduction Investigated with 18 O Labeling. Germany. doi:10.1002/ange.201710590.
Lum, Yanwei, and Ager, Joel W. Fri . "Stability of Residual Oxides in Oxide-Derived Copper Catalysts for Electrochemical CO 2 Reduction Investigated with 18 O Labeling". Germany. doi:10.1002/ange.201710590.
@article{osti_1412579,
title = {Stability of Residual Oxides in Oxide-Derived Copper Catalysts for Electrochemical CO 2 Reduction Investigated with 18 O Labeling},
author = {Lum, Yanwei and Ager, Joel W.},
abstractNote = {},
doi = {10.1002/ange.201710590},
journal = {Angewandte Chemie},
number = 2,
volume = 130,
place = {Germany},
year = {2017},
month = {12}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/ange.201710590

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Works referenced in this record:

CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
journal, April 2012

  • Li, Christina W.; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234
  • DOI: 10.1021/ja3010978

Cu metal embedded in oxidized matrix catalyst to promote CO 2 activation and CO dimerization for electrochemical reduction of CO 2
journal, June 2017

  • Xiao, Hai; Goddard, William A.; Cheng, Tao
  • Proceedings of the National Academy of Sciences
  • DOI: 10.1073/pnas.1702405114

Oxidation of Polycrystalline Copper Thin Films at Ambient Conditions
journal, January 2008

  • Platzman, Ilia; Brener, Reuven; Haick, Hossam
  • The Journal of Physical Chemistry C, Vol. 112, Issue 4
  • DOI: 10.1021/jp076981k

Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO 2 over Cu Nanowire Arrays
journal, April 2016

  • Ma, Ming; Djanashvili, Kristina; Smith, Wilson A.
  • Angewandte Chemie, Vol. 128, Issue 23
  • DOI: 10.1002/ange.201601282

Electrochemical CO 2 Reduction: Recent Advances and Current Trends
journal, September 2014

  • Jones, John-Paul; Prakash, G. K. Surya; Olah, George A.
  • Israel Journal of Chemistry, Vol. 54, Issue 10
  • DOI: 10.1002/ijch.201400081

Electrochemical CO 2 reduction on Cu 2 O-derived copper nanoparticles: controlling the catalytic selectivity of hydrocarbons
journal, January 2014

  • Kas, Recep; Kortlever, Ruud; Milbrat, Alexander
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 24
  • DOI: 10.1039/C4CP01520G

Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
journal, April 2014

  • Li, Christina W.; Ciston, Jim; Kanan, Matthew W.
  • Nature, Vol. 508, Issue 7497
  • DOI: 10.1038/nature13249

Electrochemical CO2 Reduction on Metal Electrodes
book, January 2008


Plasma-Activated Copper Nanocube Catalysts for Efficient Carbon Dioxide Electroreduction to Hydrocarbons and Alcohols
journal, April 2017


Influence on the oxidation kinetics of metals by control of the structure of oxide scales
journal, December 1976


Early and transient stages of Cu oxidation: Atomistic insights from theoretical simulations and in situ experiments
journal, October 2016


New model for low-temperature oxidation of copper single crystal
journal, July 2013


Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
journal, August 2014

  • Kuhl, Kendra P.; Hatsukade, Toru; Cave, Etosha R.
  • Journal of the American Chemical Society, Vol. 136, Issue 40
  • DOI: 10.1021/ja505791r

Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts
journal, March 2015

  • Ren, Dan; Deng, Yilin; Handoko, Albertus Denny
  • ACS Catalysis, Vol. 5, Issue 5
  • DOI: 10.1021/cs502128q

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015

  • Roberts, F. Sloan; Kuhl, Kendra P.; Nilsson, Anders
  • Angewandte Chemie, Vol. 127, Issue 17
  • DOI: 10.1002/ange.201412214

Electrocatalytic Production of C3-C4 Compounds by Conversion of CO 2 on a Chloride-Induced Bi-Phasic Cu 2 O-Cu Catalyst
journal, October 2015

  • Lee, Seunghwa; Kim, Dahee; Lee, Jaeyoung
  • Angewandte Chemie International Edition, Vol. 54, Issue 49
  • DOI: 10.1002/anie.201505730

Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO 2 over Cu Nanowire Arrays
journal, April 2016

  • Ma, Ming; Djanashvili, Kristina; Smith, Wilson A.
  • Angewandte Chemie International Edition, Vol. 55, Issue 23
  • DOI: 10.1002/anie.201601282

Optimizing C–C Coupling on Oxide-Derived Copper Catalysts for Electrochemical CO 2 Reduction
journal, June 2017

  • Lum, Yanwei; Yue, Binbin; Lobaccaro, Peter
  • The Journal of Physical Chemistry C, Vol. 121, Issue 26
  • DOI: 10.1021/acs.jpcc.7b03673

Atomistic details of oxide surfaces and surface oxidation: the example of copper and its oxides
journal, November 2015


Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
journal, June 2016

  • Mistry, Hemma; Varela, Ana Sofia; Bonifacio, Cecile S.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12123

Comparison Study on the Stability of Copper Nanowires and Their Oxidation Kinetics in Gas and Liquid
journal, February 2016


New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

  • Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee21234j

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015

  • Roberts, F. Sloan; Kuhl, Kendra P.; Nilsson, Anders
  • Angewandte Chemie International Edition, Vol. 54, Issue 17
  • DOI: 10.1002/anie.201412214

Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts
journal, July 2015

  • Verdaguer-Casadevall, Arnau; Li, Christina W.; Johansson, Tobias P.
  • Journal of the American Chemical Society, Vol. 137, Issue 31
  • DOI: 10.1021/jacs.5b06227

Electrocatalytic Production of C3-C4 Compounds by Conversion of CO 2 on a Chloride-Induced Bi-Phasic Cu 2 O-Cu Catalyst
journal, October 2015


Sustainable hydrocarbon fuels by recycling CO 2 and H 2 O with renewable or nuclear energy
journal, January 2011

  • Graves, Christopher; Ebbesen, Sune D.; Mogensen, Mogens
  • Renewable and Sustainable Energy Reviews, Vol. 15, Issue 1
  • DOI: 10.1016/j.rser.2010.07.014

A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles
journal, March 2016


Subsurface Oxygen in Oxide-Derived Copper Electrocatalysts for Carbon Dioxide Reduction
journal, December 2016

  • Eilert, André; Cavalca, Filippo; Roberts, F. Sloan
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 1
  • DOI: 10.1021/acs.jpclett.6b02273