Sulfidation of Iron-Based Materials: A Review of Processes and Implications for Water Treatment and Remediation

Fan, Dimin; Lan, Ying; Tratnyek, Paul G.; Johnson, Richard L.; Filip, Jan; O’Carroll, Denis M.; Nunez Garcia, Ariel; Agrawal, Abinash

doi:10.1021/acs.est.7b04177

Title: Sulfidation of Iron-Based Materials: A Review of Processes and Implications for Water Treatment and Remediation

Authors:

Fan, Dimin ^[1]; Lan, Ying ^[2];

^[2]; Johnson, Richard L. ^[2]; Filip, Jan ^[3];

^[4]; Nunez Garcia, Ariel ^[5]; Agrawal, Abinash ^[6]

Oak Ridge Institute for Science and Education (ORISE) Fellow, Office of Superfund Remediation and Technology Innovation, U.S. Environmental Protection Agency, 2777 Crystal Drive, Arlington, Virginia 22202, United States
OHSU-PSU School of Public Health, Oregon Health & Science University, 3181 SW Sam Jackson Park Road, Portland, Oregon 97239, United States
Regional Centre of Advanced Technologies and Materials, Palacký University Olomouc, Šlechtitelů 27, CZ-78371 Olomouc, Czech Republic
School of Civil and Environmental Engineering, Connected Water Initiative, University of New South Wales, Manly Vale, New South Wales 2093, Australia
Department of Civil and Environmental Engineering, Western University, 1151 Richmond St., London, Ontario Canada
Department of Earth and Environmental Sciences, Wright State University, Wright State University, 3640 Colonel Glenn Highway, Dayton, Ohio 45435, United States

Publication Date:: Wed Nov 01 00:00:00 EDT 2017

Sponsoring Org.:: USDOE

OSTI Identifier:: 1412008

Resource Type:: Published Article

Journal Name:: Environmental Science and Technology

Additional Journal Information:: Journal Name: Environmental Science and Technology Journal Volume: 51 Journal Issue: 22; Journal ID: ISSN 0013-936X

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Fan, Dimin, Lan, Ying, Tratnyek, Paul G., Johnson, Richard L., Filip, Jan, O’Carroll, Denis M., Nunez Garcia, Ariel, and Agrawal, Abinash. Sulfidation of Iron-Based Materials: A Review of Processes and Implications for Water Treatment and Remediation.  United States: N. p., 2017. 
Web.  doi:10.1021/acs.est.7b04177.

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                    Fan, Dimin, Lan, Ying, Tratnyek, Paul G., Johnson, Richard L., Filip, Jan, O’Carroll, Denis M., Nunez Garcia, Ariel, & Agrawal, Abinash. Sulfidation of Iron-Based Materials: A Review of Processes and Implications for Water Treatment and Remediation.  United States.  https://doi.org/10.1021/acs.est.7b04177

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                    Fan, Dimin, Lan, Ying, Tratnyek, Paul G., Johnson, Richard L., Filip, Jan, O’Carroll, Denis M., Nunez Garcia, Ariel, and Agrawal, Abinash. Wed .  
"Sulfidation of Iron-Based Materials: A Review of Processes and Implications for Water Treatment and Remediation".  United States.  https://doi.org/10.1021/acs.est.7b04177.

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@article{osti_1412008,

  title        = {Sulfidation of Iron-Based Materials: A Review of Processes and Implications for Water Treatment and Remediation},

  author       = {Fan, Dimin and Lan, Ying and Tratnyek, Paul G. and Johnson, Richard L. and Filip, Jan and O’Carroll, Denis M. and Nunez Garcia, Ariel and Agrawal, Abinash},

  abstractNote = {},

  doi          = {10.1021/acs.est.7b04177},

  journal      = {Environmental Science and Technology},

  number       = 22,

  volume       = 51,

  place        = {United States},

  year         = {Wed Nov 01 00:00:00 EDT 2017},

  month        = {Wed Nov 01 00:00:00 EDT 2017}

}

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Kinetics of Trichloroethene Reduction by Zerovalent Iron and Tin: Pretreatment Effect, Apparent Activation Energy, and Intermediate Products
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Su, Chunming; Puls, Robert W.
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The diversity of aluminum-based drinking water treatment residuals for use in environmental remediation

Journal Article Wallace, Samuel M. ; Zhang, Yuchi ; Zhou, Lang ; ... - Environmental Science: Water Research & Technology

Drinking water treatment residuals (DWTRs) are complex mixtures of organic and inorganic phases generally disposed of as waste materials.
https://doi.org/10.1039/D2EW00387B
Selection of water treatment processes special study. [Uranium Mill Tailings Remedial Action (UMTRA) Project]

Technical Report

Characterization of the level and extent of groundwater contamination in the vicinity of Title I mill sites began during the surface remedial action stage (Phase 1) of the Uranium Mill Tailings Remedial Action (UMTRA) Project. Some of the contamination in the aquifer(s) at the abandoned sites is attributable to milling activities during the years the mills were in operation. The restoration of contaminated aquifers is to be undertaken in Phase II of the UMTRA Project. To begin implementation of Phase II, DOE requested that groundwater restoration methods and technologies be investigated by the Technical Assistance Contractor (TAC). and that themore »« less

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Title: Sulfidation of Iron-Based Materials: A Review of Processes and Implications for Water Treatment and Remediation

Citation Formats

Aerobic oxidation of mackinawite (FeS) and its environmental implication for arsenic mobilization journal, June 2010

Influence of Na2S on the degradation kinetics of CCl4 in the presence of very pure iron journal, June 2008

Influence of Soil Minerals on the Rates and Products of Abiotic Transformation of Carbon Tetrachloride in Anaerobic Soils and Sediments journal, March 2009

Removal of Inorganic Contaminants from Aqueous Solutions: Evaluation of the Remediation Efficiency and of the Environmental Impact of a Zero-Valent Iron Substrate journal, August 2014

Sequestration of Ag(I) from aqueous solution as Ag(0) nanostructures by nanoscale zero valent iron (nZVI) journal, November 2015

Investigating the Role of Atomic Hydrogen on Chloroethene Reactions with Iron Using Tafel Analysis and Electrochemical Impedance Spectroscopy journal, September 2003

Oxidative Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent Iron journal, June 2014

Carbon Tetrachloride Reduction by Fe2+,S2-, and FeS with vitamin B12 as Organic Amendment journal, January 2002

Kinetics of Halogenated Organic Compound Degradation by Iron Metal journal, January 1996

Sorption of Mercuric Ion by Synthetic Nanocrystalline Mackinawite (FeS) journal, November 2007

Microscopic and Spectroscopic Characterization of Hg(II) Immobilization by Mackinawite (FeS) journal, October 2010

The tortoise versus the hare - Possible advantages of microparticulate zerovalent iron (mZVI) over nanoparticulate zerovalent iron (nZVI) in aerobic degradation of contaminants journal, November 2016

Effect of Amorphous FeS Semiconductor on the Corrosion Behavior of Pipe Steel in H 2 S-Containing Environments journal, October 2016

Facile Synthesis and Characterization of Fe/FeS Nanoparticles for Environmental Applications journal, May 2011

Role of Ni/Fe Nanoparticle Composition on the Degradation of Trichloroethylene from Water journal, August 2005

Transformation of mackinawite to greigite by trichloroethylene and tetrachloroethylene journal, January 2016

Effects of Solution Composition and pH on the Reductive Dechlorination of Hexachloroethane by Iron Sulfide journal, May 1998

Kinetics of the Transformation of Trichloroethylene and Tetrachloroethylene by Iron Sulfide journal, June 1999

Treatment of inorganic contaminants using permeable reactive barriers journal, September 2000

Mechanisms and Products of Surface-Mediated Reductive Dehalogenation of Carbon Tetrachloride by Fe(II) on Goethite journal, April 2004

Arsenic mobility in the ambient sulfidic environment: Sorption of arsenic(V) and arsenic(III) onto disordered mackinawite journal, July 2005

Removal of hexavalent chromium from solutions by mackinawite, tetragonal FeS journal, September 2004

Transformation of carbon tetrachloride by bisulfide treated goethite, hematite, magnetite, and kaolinite journal, April 2006

Factors Controlling In Situ Biogeochemical Transformation of Trichloroethene: Field Survey journal, August 2014

Effects of Sulfidation, Magnetization, and Oxygenation on Azo Dye Reduction by Zerovalent Iron journal, October 2016

Uranium(VI) Reduction by Iron(II) Monosulfide Mackinawite journal, February 2012

Mesoporous sulfur-modified iron oxide as an effective Fenton-like catalyst for degradation of bisphenol A journal, May 2016

Photoeffects on the Reduction of Carbon Tetrachloride by Zero-Valent Iron journal, February 1998

Impact of iron sulfide transformation on trichloroethylene degradation journal, April 2010

Reductive Immobilization of Rhenium in Soil and Groundwater Using Pyrite Nanoparticles journal, November 2015

Factors Controlling In Situ Biogeochemical Transformation of Trichloroethene: Column Study journal, August 2014

Reductive dissolution of iron(III) (hydr)oxides by hydrogen sulfide journal, June 1992

pH-dependent degradation of p-nitrophenol by sulfidated nanoscale zerovalent iron under aerobic or anoxic conditions journal, December 2016

Oxidative degradation of benzoic acid using Fe 0 - and sulfidized Fe 0 -activated persulfate: A comparative study journal, May 2017

Transformation of Chlorinated Methanes by Nanoscale Iron Particles journal, November 1999

The effect of pre-corrosion on the corrosion rate of steel in neutral solutions containing sulphide: relevance to microbially influenced corrosion journal, December 1992

Poisoning effects of arsenic species on H adsorption and kinetic behaviour of the H2 evolution reaction at Pt in KOH solution journal, October 1995

Effects of Iron Purity and Groundwater Characteristics on Rates and Products in the Degradation of Carbon Tetrachloride by Iron Metal journal, March 2004

Reductive Sequestration of Pertechnetate ( 99 TcO 4 – ) by Nano Zerovalent Iron (nZVI) Transformed by Abiotic Sulfide journal, May 2013

Hydrodechlorination of Trichloroethylene to Hydrocarbons Using Bimetallic Nickel−Iron Nanoparticles journal, December 2002

Polymorphous FeS corrosion products of pipeline steel under highly sour conditions journal, January 2016

Role of Thiosulfate in the Corrosion of Steels: A Review journal, September 2015

Abiotic transformation of hexabromocyclododecane by sulfidated nanoscale zerovalent iron: Kinetics, mechanism and influencing factors journal, September 2017

Nanoscale zero-valent iron (nZVI): Aspects of the core-shell structure and reactions with inorganic species in water journal, November 2010

The limitations of applying zero-valent iron technology in contaminants sequestration and the corresponding countermeasures: The development in zero-valent iron technology in the last two decades (1994–2014) journal, May 2015

The Formation of Ferrous Monosulfide Polymorphs during the Corrosion of Iron by Aqueous Hydrogen Sulfide at 21°C journal, January 1980

Coupled Effect of Ferrous Ion and Oxygen on the Electron Selectivity of Zerovalent Iron for Selenate Sequestration journal, April 2017

Selenite Reduction by Mackinawite, Magnetite and Siderite: XAS Characterization of Nanosized Redox Products journal, March 2008

Conflicting processes in the wetland plant rhizosphere: Metal retention or mobilization? journal, January 2003

Effect of Particle Age (Fe 0 Content) and Solution pH On NZVI Reactivity: H 2 Evolution and TCE Dechlorination journal, October 2006

Formation of Ferrihydrite and Associated Iron Corrosion Products in Permeable Reactive Barriers of Zero-Valent Iron journal, December 2002

Electrical and Magnetic Properties of Sulfides journal, January 2006

Fe(II)- and sulfide-facilitated reduction of 99Tc(VII)O4− in microbially reduced hyporheic zone sediments journal, July 2014

Impact of nZVI stability on mobility in porous media journal, February 2013

Distinguishing Abiotic and Biotic Transformation of Tetrachloroethylene and Trichloroethylene by Stable Carbon Isotope Fractionation journal, October 2007

The chemistry of the hydrogen sulfide and iron sulfide systems in natural waters journal, March 1987

Methods for characterizing the fate and effects of nano zerovalent iron during groundwater remediation journal, October 2015

Field and Laboratory Studies of Carbon Tetrachloride Transformation in a Sandy Aquifer under Sulfate Reducing Conditions journal, April 1999

Transformations of mercury, iron, and sulfur during the reductive dissolution of iron oxyhydroxide by sulfide journal, February 2007

Reduction of Chlorinated Methanes by Nano-Sized Zero-Valent Iron. Kinetics, Pathways, and Effect of Reaction Conditions journal, March 2006

The role of thiosulfates in the pitting corrosion of Fe-17Cr alloys in neutral chloride solution: Electrochemical and XPS study journal, May 1997

Magnetic sulfide-modified nanoscale zerovalent iron (S-nZVI) for dissolved metal ion removal journal, May 2015

Long-Term Performance of Permeable Reactive Barriers Using Zero-Valent Iron: Geochemical and Microbiological Effects journal, July 2003

Mechanochemically Sulfidated Microscale Zero Valent Iron: Pathways, Kinetics, Mechanism, and Efficiency of Trichloroethylene Dechlorination journal, October 2017

Oxidative dissolution of UO2 in a simulated groundwater containing synthetic nanocrystalline mackinawite journal, February 2013

Effects of Natural Organic Matter, Anthropogenic Surfactants, and Model Quinones on the Reduction of Contaminants by Zero-Valent Iron journal, December 2001

Uraninite oxidation and dissolution induced by manganese oxide: A redox reaction between two insoluble minerals journal, January 2013

Reductive Dechlorination Pathways of Tetrachloroethylene and Trichloroethylene and Subsequent Transformation of Their Dechlorination Products by Mackinawite (FeS) in the Presence of Metals journal, November 2007

pH Dependence of Carbon Tetrachloride Reductive Dechlorination by Magnetite journal, September 2004

Characterization of corrosion products in the permeable reactive barriers journal, December 2000

The mobility of zinc, cadmium, copper, lead, iron and arsenic in ground water as a function of redox potential and pH journal, May 1985

Performance Evaluation of a Zerovalent Iron Reactive Barrier: Mineralogical Characteristics journal, October 2000

Enhanced reductive dechlorination of trichloroethylene by sulfidated nanoscale zerovalent iron journal, July 2015

Synthesizing Nanoscale Iron Particles for Rapid and Complete Dechlorination of TCE and PCBs journal, July 1997

Electron efficiency of nZVI does not change with variation of environmental parameters journal, December 2015

Weak magnetic field accelerates chromate removal by zero-valent iron journal, May 2015

Direct Synthesis of Novel and Reactive Sulfide-modified Nano Iron through Nanoparticle Seeding for Improved Cadmium-Contaminated Water Treatment journal, April 2016

Kinetics of the Transformation of Halogenated Aliphatic Compounds by Iron Sulfide journal, February 2000

Aerobic oxidation of mackinawite (FeS) and its environmental implication for arsenic mobilization
journal, June 2010

Influence of Na2S on the degradation kinetics of CCl4 in the presence of very pure iron
journal, June 2008

Influence of Soil Minerals on the Rates and Products of Abiotic Transformation of Carbon Tetrachloride in Anaerobic Soils and Sediments
journal, March 2009

Removal of Inorganic Contaminants from Aqueous Solutions: Evaluation of the Remediation Efficiency and of the Environmental Impact of a Zero-Valent Iron Substrate
journal, August 2014

Sequestration of Ag(I) from aqueous solution as Ag(0) nanostructures by nanoscale zero valent iron (nZVI)
journal, November 2015

Investigating the Role of Atomic Hydrogen on Chloroethene Reactions with Iron Using Tafel Analysis and Electrochemical Impedance Spectroscopy
journal, September 2003

Oxidative Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent Iron
journal, June 2014

Carbon Tetrachloride Reduction by Fe2+,S2-, and FeS with vitamin B12 as Organic Amendment
journal, January 2002

Kinetics of Halogenated Organic Compound Degradation by Iron Metal
journal, January 1996

Sorption of Mercuric Ion by Synthetic Nanocrystalline Mackinawite (FeS)
journal, November 2007

Microscopic and Spectroscopic Characterization of Hg(II) Immobilization by Mackinawite (FeS)
journal, October 2010

The tortoise versus the hare - Possible advantages of microparticulate zerovalent iron (mZVI) over nanoparticulate zerovalent iron (nZVI) in aerobic degradation of contaminants
journal, November 2016

Effect of Amorphous FeS Semiconductor on the Corrosion Behavior of Pipe Steel in H ₂ S-Containing Environments
journal, October 2016

Facile Synthesis and Characterization of Fe/FeS Nanoparticles for Environmental Applications
journal, May 2011

Role of Ni/Fe Nanoparticle Composition on the Degradation of Trichloroethylene from Water
journal, August 2005

Transformation of mackinawite to greigite by trichloroethylene and tetrachloroethylene
journal, January 2016

Effects of Solution Composition and pH on the Reductive Dechlorination of Hexachloroethane by Iron Sulfide
journal, May 1998

Kinetics of the Transformation of Trichloroethylene and Tetrachloroethylene by Iron Sulfide
journal, June 1999

Treatment of inorganic contaminants using permeable reactive barriers
journal, September 2000

Mechanisms and Products of Surface-Mediated Reductive Dehalogenation of Carbon Tetrachloride by Fe(II) on Goethite
journal, April 2004

Arsenic mobility in the ambient sulfidic environment: Sorption of arsenic(V) and arsenic(III) onto disordered mackinawite
journal, July 2005

Removal of hexavalent chromium from solutions by mackinawite, tetragonal FeS
journal, September 2004

Transformation of carbon tetrachloride by bisulfide treated goethite, hematite, magnetite, and kaolinite
journal, April 2006

Factors Controlling In Situ Biogeochemical Transformation of Trichloroethene: Field Survey
journal, August 2014

Effects of Sulfidation, Magnetization, and Oxygenation on Azo Dye Reduction by Zerovalent Iron
journal, October 2016

Uranium(VI) Reduction by Iron(II) Monosulfide Mackinawite
journal, February 2012

Mesoporous sulfur-modified iron oxide as an effective Fenton-like catalyst for degradation of bisphenol A
journal, May 2016

Photoeffects on the Reduction of Carbon Tetrachloride by Zero-Valent Iron
journal, February 1998

Impact of iron sulfide transformation on trichloroethylene degradation
journal, April 2010

Reductive Immobilization of Rhenium in Soil and Groundwater Using Pyrite Nanoparticles
journal, November 2015

Factors Controlling In Situ Biogeochemical Transformation of Trichloroethene: Column Study
journal, August 2014

Reductive dissolution of iron(III) (hydr)oxides by hydrogen sulfide
journal, June 1992

pH-dependent degradation of p-nitrophenol by sulfidated nanoscale zerovalent iron under aerobic or anoxic conditions
journal, December 2016

Oxidative degradation of benzoic acid using Fe 0 - and sulfidized Fe 0 -activated persulfate: A comparative study
journal, May 2017

Transformation of Chlorinated Methanes by Nanoscale Iron Particles
journal, November 1999

The effect of pre-corrosion on the corrosion rate of steel in neutral solutions containing sulphide: relevance to microbially influenced corrosion
journal, December 1992

Poisoning effects of arsenic species on H adsorption and kinetic behaviour of the H2 evolution reaction at Pt in KOH solution
journal, October 1995

Effects of Iron Purity and Groundwater Characteristics on Rates and Products in the Degradation of Carbon Tetrachloride by Iron Metal
journal, March 2004

Reductive Sequestration of Pertechnetate ( ⁹⁹ TcO ₄ ^– ) by Nano Zerovalent Iron (nZVI) Transformed by Abiotic Sulfide
journal, May 2013

Hydrodechlorination of Trichloroethylene to Hydrocarbons Using Bimetallic Nickel−Iron Nanoparticles
journal, December 2002

Polymorphous FeS corrosion products of pipeline steel under highly sour conditions
journal, January 2016

Role of Thiosulfate in the Corrosion of Steels: A Review
journal, September 2015

Abiotic transformation of hexabromocyclododecane by sulfidated nanoscale zerovalent iron: Kinetics, mechanism and influencing factors
journal, September 2017

Nanoscale zero-valent iron (nZVI): Aspects of the core-shell structure and reactions with inorganic species in water
journal, November 2010

The limitations of applying zero-valent iron technology in contaminants sequestration and the corresponding countermeasures: The development in zero-valent iron technology in the last two decades (1994–2014)
journal, May 2015

The Formation of Ferrous Monosulfide Polymorphs during the Corrosion of Iron by Aqueous Hydrogen Sulfide at 21°C
journal, January 1980

Coupled Effect of Ferrous Ion and Oxygen on the Electron Selectivity of Zerovalent Iron for Selenate Sequestration
journal, April 2017

Selenite Reduction by Mackinawite, Magnetite and Siderite: XAS Characterization of Nanosized Redox Products
journal, March 2008

Conflicting processes in the wetland plant rhizosphere: Metal retention or mobilization?
journal, January 2003

Effect of Particle Age (Fe ⁰ Content) and Solution pH On NZVI Reactivity: H ₂ Evolution and TCE Dechlorination
journal, October 2006

Formation of Ferrihydrite and Associated Iron Corrosion Products in Permeable Reactive Barriers of Zero-Valent Iron
journal, December 2002

Electrical and Magnetic Properties of Sulfides
journal, January 2006

Fe(II)- and sulfide-facilitated reduction of 99Tc(VII)O4− in microbially reduced hyporheic zone sediments
journal, July 2014

Impact of nZVI stability on mobility in porous media
journal, February 2013

Distinguishing Abiotic and Biotic Transformation of Tetrachloroethylene and Trichloroethylene by Stable Carbon Isotope Fractionation
journal, October 2007

The chemistry of the hydrogen sulfide and iron sulfide systems in natural waters
journal, March 1987

Methods for characterizing the fate and effects of nano zerovalent iron during groundwater remediation
journal, October 2015

Field and Laboratory Studies of Carbon Tetrachloride Transformation in a Sandy Aquifer under Sulfate Reducing Conditions
journal, April 1999

Transformations of mercury, iron, and sulfur during the reductive dissolution of iron oxyhydroxide by sulfide
journal, February 2007

Reduction of Chlorinated Methanes by Nano-Sized Zero-Valent Iron. Kinetics, Pathways, and Effect of Reaction Conditions
journal, March 2006

The role of thiosulfates in the pitting corrosion of Fe-17Cr alloys in neutral chloride solution: Electrochemical and XPS study
journal, May 1997

Magnetic sulfide-modified nanoscale zerovalent iron (S-nZVI) for dissolved metal ion removal
journal, May 2015

Long-Term Performance of Permeable Reactive Barriers Using Zero-Valent Iron: Geochemical and Microbiological Effects
journal, July 2003

Mechanochemically Sulfidated Microscale Zero Valent Iron: Pathways, Kinetics, Mechanism, and Efficiency of Trichloroethylene Dechlorination
journal, October 2017

Oxidative dissolution of UO2 in a simulated groundwater containing synthetic nanocrystalline mackinawite
journal, February 2013

Effects of Natural Organic Matter, Anthropogenic Surfactants, and Model Quinones on the Reduction of Contaminants by Zero-Valent Iron
journal, December 2001

Uraninite oxidation and dissolution induced by manganese oxide: A redox reaction between two insoluble minerals
journal, January 2013

Reductive Dechlorination Pathways of Tetrachloroethylene and Trichloroethylene and Subsequent Transformation of Their Dechlorination Products by Mackinawite (FeS) in the Presence of Metals
journal, November 2007

pH Dependence of Carbon Tetrachloride Reductive Dechlorination by Magnetite
journal, September 2004

Characterization of corrosion products in the permeable reactive barriers
journal, December 2000

The mobility of zinc, cadmium, copper, lead, iron and arsenic in ground water as a function of redox potential and pH
journal, May 1985

Performance Evaluation of a Zerovalent Iron Reactive Barrier: Mineralogical Characteristics
journal, October 2000

Enhanced reductive dechlorination of trichloroethylene by sulfidated nanoscale zerovalent iron
journal, July 2015

Synthesizing Nanoscale Iron Particles for Rapid and Complete Dechlorination of TCE and PCBs
journal, July 1997

Electron efficiency of nZVI does not change with variation of environmental parameters
journal, December 2015

Weak magnetic field accelerates chromate removal by zero-valent iron
journal, May 2015

Direct Synthesis of Novel and Reactive Sulfide-modified Nano Iron through Nanoparticle Seeding for Improved Cadmium-Contaminated Water Treatment
journal, April 2016

Kinetics of the Transformation of Halogenated Aliphatic Compounds by Iron Sulfide
journal, February 2000

Immobilization of Mercury by Carboxymethyl Cellulose Stabilized Iron Sulfide Nanoparticles: Reaction Mechanisms and Effects of Stabilizer and Water Chemistry
journal, March 2014

Arsenic sorption to nanoparticulate mackinawite (FeS): An examination of phosphate competition
journal, November 2016