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Title: Conversion of lanthanide glutarate chlorides with interstitial THF into lanthanide glutarates with unprecedented topologies

Abstract

Here, using slow diffusion methods at room temperature (RT), we obtained four isomorphous lanthanide glutarate chlorides, accommodating interstitial THF and water molecules, [Ln 2(Glut) 2Cl 2(H 2O) 8]·2H 2O·THF, with Ln = La , Ce, Pr, Nd. They assemble as 3-dimensional (3D) lanthanide (Ln) coordination polymers with LnO 10 coordination polyhedra. Their topology was elucidated to be a 4-coordinated sql net. slowly dissolve in water liberating the entrapped THF molecules and reassemble as regular Ln-glutarate hydrates when the solution is deprived of THF and water by slow evaporation. The new products crystallize as [Ln 2(Glut) 3(H 2O) 3]·5H 2O, with Ln = La, Ce, Pr, and [Nd 2(Glut) 3(H 2O) 2]·3.5H 2O.

Authors:
 [1];  [1];  [2];  [1]; ORCiD logo [3];  [1];  [1];  [1]
  1. Angelo State Univ., San Angelo, TX (United States)
  2. Purdue Univ., West Lafayette, IN (United States)
  3. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS) (SC-27); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1411360
Alternate Identifier(s):
OSTI ID: 1577222
Report Number(s):
LA-UR-17-27989
Journal ID: ISSN 0020-1693; TRN: US1800225
Grant/Contract Number:  
AC52-06NA25396
Resource Type:
Accepted Manuscript
Journal Name:
Inorganica Chimica Acta
Additional Journal Information:
Journal Volume: 471; Journal Issue: C; Journal ID: ISSN 0020-1693
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Inorganic and Physical Chemistry; MOF, Lanthanides

Citation Formats

Zehnder, Ralph A., Jenkins, James, Zeller, Matthias, Dempsey, Christian, Kozimor, Stosh Anthony, Jackson, Gregory, Gilbert, Katherine, and Smith, Matthew. Conversion of lanthanide glutarate chlorides with interstitial THF into lanthanide glutarates with unprecedented topologies. United States: N. p., 2017. Web. doi:10.1016/j.ica.2017.11.050.
Zehnder, Ralph A., Jenkins, James, Zeller, Matthias, Dempsey, Christian, Kozimor, Stosh Anthony, Jackson, Gregory, Gilbert, Katherine, & Smith, Matthew. Conversion of lanthanide glutarate chlorides with interstitial THF into lanthanide glutarates with unprecedented topologies. United States. doi:10.1016/j.ica.2017.11.050.
Zehnder, Ralph A., Jenkins, James, Zeller, Matthias, Dempsey, Christian, Kozimor, Stosh Anthony, Jackson, Gregory, Gilbert, Katherine, and Smith, Matthew. Sun . "Conversion of lanthanide glutarate chlorides with interstitial THF into lanthanide glutarates with unprecedented topologies". United States. doi:10.1016/j.ica.2017.11.050. https://www.osti.gov/servlets/purl/1411360.
@article{osti_1411360,
title = {Conversion of lanthanide glutarate chlorides with interstitial THF into lanthanide glutarates with unprecedented topologies},
author = {Zehnder, Ralph A. and Jenkins, James and Zeller, Matthias and Dempsey, Christian and Kozimor, Stosh Anthony and Jackson, Gregory and Gilbert, Katherine and Smith, Matthew},
abstractNote = {Here, using slow diffusion methods at room temperature (RT), we obtained four isomorphous lanthanide glutarate chlorides, accommodating interstitial THF and water molecules, [Ln2(Glut)2Cl2(H2O)8]·2H2O·THF, with Ln = La , Ce, Pr, Nd. They assemble as 3-dimensional (3D) lanthanide (Ln) coordination polymers with LnO10 coordination polyhedra. Their topology was elucidated to be a 4-coordinated sql net. slowly dissolve in water liberating the entrapped THF molecules and reassemble as regular Ln-glutarate hydrates when the solution is deprived of THF and water by slow evaporation. The new products crystallize as [Ln2(Glut)3(H2O)3]·5H2O, with Ln = La, Ce, Pr, and [Nd2(Glut)3(H2O)2]·3.5H2O.},
doi = {10.1016/j.ica.2017.11.050},
journal = {Inorganica Chimica Acta},
number = C,
volume = 471,
place = {United States},
year = {2017},
month = {11}
}

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Works referencing / citing this record:

CCDC 1558521: Experimental Crystal Structure Determination: NAWHOL01 : catena-[tris(μ-glutarato)-triaqua-di-lanthanum pentahydrate]
dataset, June 2017


CCDC 1558522: Experimental Crystal Structure Determination: NEMXEL : catena-[tris(μ-glutarato)-triaqua-di-cerium pentahydrate]
dataset, June 2017


CCDC 1558524: Experimental Crystal Structure Determination: NEMXOV : catena-[tris(μ-glutarato)-tetraaqua-di-neodymium hexahydrate]
dataset, June 2017