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Title: Ion irradiation-induced crystal structure changes in inverse spinel MgIn 2O 4

We performed 400 keV Ne and 200 keV He ion irradiations on fully inverse MgIn 2O 4 samples at cryogenic temperature (~ 77 K), in order to examine the influence of radiation-induced cation disordering on crystal structure. In the case of MgIn 2O 4 samples irradiated with Ne ions to a peak displacement damage dose of 4 displacements per atom (dpa), a spinel-to-rocksalt phase transformation was observed. Conversely, for MgIn 2O 4 samples irradiated with He ions to a peak displacement damage dose of 5 dpa, the only observed structural effect involved cation rearrangements from an inverse to a “random” spinel structure.
Authors:
ORCiD logo [1] ;  [1] ; ORCiD logo [1] ;  [2] ; ORCiD logo [1] ;  [3]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Xiamen Univ., Fujian (China). College of Energy
  3. Univ. of Tennessee, Knoxville, TN (United States). Dept. of Materials Science and Engineering
Publication Date:
Report Number(s):
LA-UR-16-24112
Journal ID: ISSN 1359-6462
Grant/Contract Number:
AC52-06NA25396
Type:
Accepted Manuscript
Journal Name:
Scripta Materialia
Additional Journal Information:
Journal Volume: 125; Journal Issue: C; Journal ID: ISSN 1359-6462
Publisher:
Elsevier
Research Org:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org:
USDOE Office of Science (SC). Basic Energy Sciences (BES) (SC-22); USDOE
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; spinel; rocksalt phase; MgIn2O4; irradiation
OSTI Identifier:
1411341
Alternate Identifier(s):
OSTI ID: 1359859

Tang, Ming, Valdez, James A., Wang, Yongqiang, Zhang, Jian, Uberuaga, Blas P., and Sickafus, Kurt E.. Ion irradiation-induced crystal structure changes in inverse spinel MgIn2O4. United States: N. p., Web. doi:10.1016/j.scriptamat.2016.07.009.
Tang, Ming, Valdez, James A., Wang, Yongqiang, Zhang, Jian, Uberuaga, Blas P., & Sickafus, Kurt E.. Ion irradiation-induced crystal structure changes in inverse spinel MgIn2O4. United States. doi:10.1016/j.scriptamat.2016.07.009.
Tang, Ming, Valdez, James A., Wang, Yongqiang, Zhang, Jian, Uberuaga, Blas P., and Sickafus, Kurt E.. 2016. "Ion irradiation-induced crystal structure changes in inverse spinel MgIn2O4". United States. doi:10.1016/j.scriptamat.2016.07.009. https://www.osti.gov/servlets/purl/1411341.
@article{osti_1411341,
title = {Ion irradiation-induced crystal structure changes in inverse spinel MgIn2O4},
author = {Tang, Ming and Valdez, James A. and Wang, Yongqiang and Zhang, Jian and Uberuaga, Blas P. and Sickafus, Kurt E.},
abstractNote = {We performed 400 keV Ne and 200 keV He ion irradiations on fully inverse MgIn2O4 samples at cryogenic temperature (~ 77 K), in order to examine the influence of radiation-induced cation disordering on crystal structure. In the case of MgIn2O4 samples irradiated with Ne ions to a peak displacement damage dose of 4 displacements per atom (dpa), a spinel-to-rocksalt phase transformation was observed. Conversely, for MgIn2O4 samples irradiated with He ions to a peak displacement damage dose of 5 dpa, the only observed structural effect involved cation rearrangements from an inverse to a “random” spinel structure.},
doi = {10.1016/j.scriptamat.2016.07.009},
journal = {Scripta Materialia},
number = C,
volume = 125,
place = {United States},
year = {2016},
month = {7}
}