skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Environment-Dependent Radiation Damage in Atmospheric Pressure X-ray Spectroscopy

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3];  [3]; ORCiD logo [4]
  1. Materials Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720, United States, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, United Kingdom
  2. Materials Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720, United States
  3. ALBA Synchrotron Light Source, Carrer de la Llum 2-26, 08290 Cerdanyola del Vallès, Barcelona, Spain
  4. Materials Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720, United States, Department of Materials Science and Engineering, University of California, Berkeley, California 94720, United States
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of Cambridge (United Kingdom)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); European Union (EU)
OSTI Identifier:
1411310
Alternate Identifier(s):
OSTI ID: 1508263; OSTI ID: 1604644
Grant/Contract Number:  
AC02-05CH11231; 656870
Resource Type:
Published Article
Journal Name:
Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry
Additional Journal Information:
Journal Name: Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry Journal Volume: 122 Journal Issue: 2; Journal ID: ISSN 1520-6106
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 54 ENVIRONMENTAL SCIENCES

Citation Formats

Weatherup, Robert S., Wu, Cheng Hao, Escudero, Carlos, Pérez-Dieste, Virginia, and Salmeron, Miquel B. Environment-Dependent Radiation Damage in Atmospheric Pressure X-ray Spectroscopy. United States: N. p., 2017. Web. doi:10.1021/acs.jpcb.7b06397.
Weatherup, Robert S., Wu, Cheng Hao, Escudero, Carlos, Pérez-Dieste, Virginia, & Salmeron, Miquel B. Environment-Dependent Radiation Damage in Atmospheric Pressure X-ray Spectroscopy. United States. doi:10.1021/acs.jpcb.7b06397.
Weatherup, Robert S., Wu, Cheng Hao, Escudero, Carlos, Pérez-Dieste, Virginia, and Salmeron, Miquel B. Mon . "Environment-Dependent Radiation Damage in Atmospheric Pressure X-ray Spectroscopy". United States. doi:10.1021/acs.jpcb.7b06397.
@article{osti_1411310,
title = {Environment-Dependent Radiation Damage in Atmospheric Pressure X-ray Spectroscopy},
author = {Weatherup, Robert S. and Wu, Cheng Hao and Escudero, Carlos and Pérez-Dieste, Virginia and Salmeron, Miquel B.},
abstractNote = {},
doi = {10.1021/acs.jpcb.7b06397},
journal = {Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry},
number = 2,
volume = 122,
place = {United States},
year = {2017},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1021/acs.jpcb.7b06397

Citation Metrics:
Cited by: 5 works
Citation information provided by
Web of Science

Figures / Tables:

Figure 1 Figure 1: (A) Cross-sectional schematic of the electrochemical cell for in situ XAS, showing the liquid flow through the cell and the three electrodes used to provide electrochemical control. A Si3N4(100 nm thick) membrane coated with a thin (∼50 nm thick) metal film is used as the working electrode (WE),more » a Ag wire is used as the pseudoreference electrode (RE), and a Pt wire is used as the counter electrode (CE). (B) CV of a Ni(50 nm) working electrode in an aqueous NaHCO3 (0.5 M) solution, measured at a scan rate of 10 mV/s without X-ray illumination. Vertical black arrows indicate the peaks related to Ni reduction (∼0.0 V) and oxidation (∼0.4 V). (C) Corresponding XAS of the Ni L2,3-edge measured with TEY mode in air at atmospheric pressure (black) and in an aqueous NaHCO3 (0.5 M) solution under open circuit (gray) and while held at the potentials indicated by the colored dots in (B). The acquisition time of each spectrum is ∼1320 s.« less

Save / Share:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.