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This content will become publicly available on October 2, 2018

Title: Novel Layered Supercell Structure from Bi 2AlMnO 6 for Multifunctionalities

Layered materials, e.g., graphene and transition metal (di)chalcogenides, holding great promises in nanoscale device applications have been extensively studied in fundamental chemistry, solid state physics and materials research areas. In parallel, layered oxides (e.g., Aurivillius and Ruddlesden–Popper phases) present an attractive class of materials both because of their rich physics behind and potential device applications. In this work, we report a novel layered oxide material with self-assembled layered supercell structure consisting of two mismatch-layered sublattices of [Bi 3O 3+δ] and [MO 2] 1.84 (M = Al/Mn, simply named BAMO), i.e., alternative layered stacking of two mutually incommensurate sublattices made of a three-layer-thick Bi–O slab and a one-layer-thick Al/Mn–O octahedra slab in the out-of-plane direction. Strong room-temperature ferromagnetic and piezoelectric responses as well as anisotropic optical property have been demonstrated with great potentials in various device applications. Furthermore, the realization of the novel BAMO layered supercell structure in this work has paved an avenue toward exploring and designing new materials with multifunctionalities.
Authors:
ORCiD logo [1] ;  [2] ;  [3] ;  [4] ;  [4] ;  [4] ;  [4] ;  [4] ; ORCiD logo [5] ;  [2] ;  [2] ; ORCiD logo [6] ;  [4] ; ORCiD logo [1]
  1. Purdue Univ., West Lafayette, IN (United States); Texas A & M Univ., College Station, TX (United States)
  2. Normandie Univ., Caen Cedex (France)
  3. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
  4. Purdue Univ., West Lafayette, IN (United States)
  5. Texas A & M Univ., College Station, TX (United States)
  6. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Report Number(s):
SAND-2017-12811J
Journal ID: ISSN 1530-6984; 659047; TRN: US1800206
Grant/Contract Number:
AC04-94AL85000
Type:
Accepted Manuscript
Journal Name:
Nano Letters
Additional Journal Information:
Journal Volume: 17; Journal Issue: 11; Journal ID: ISSN 1530-6984
Publisher:
American Chemical Society
Research Org:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org:
USDOE National Nuclear Security Administration (NNSA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; anisotropy; bismuth; incommensurate; layered oxide
OSTI Identifier:
1411236