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Title: Deliberate modification of the solid electrolyte interphase (SEI) during lithiation of magnetite, Fe 3O 4: impact on electrochemistry

Abstract

Here, magnetite is a conversion anode material displaying multi-electron transfer during lithiation and delithiation. The solid electrolyte interphase (SEI) on magnetite, Fe 3O 4, electrodes for lithium ion batteries was deliberately modified through the use of fluoroethylene carbonate (FEC) electrolyte additive, improving both capacity retention and rate capability. Analysis showed reduction of FEC at higher voltage compared to non-fluorinated solvents with formation of a modified lithium flouride containing electrode surface.

Authors:
 [1]; ORCiD logo [2];  [2]; ORCiD logo [3]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States)
  2. Stony Brook Univ., Stony Brook, NY (United States)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1411145
Report Number(s):
[BNL-114733-2017-JA]
[Journal ID: ISSN 1359-7345; TRN: US1800183]
Grant/Contract Number:  
[SC0012704]
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
[ Journal Volume: 53; Journal Issue: 98]; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Bock, David C., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Deliberate modification of the solid electrolyte interphase (SEI) during lithiation of magnetite, Fe3O4: impact on electrochemistry. United States: N. p., 2017. Web. doi:10.1039/C7CC07142F.
Bock, David C., Marschilok, Amy C., Takeuchi, Kenneth J., & Takeuchi, Esther S. Deliberate modification of the solid electrolyte interphase (SEI) during lithiation of magnetite, Fe3O4: impact on electrochemistry. United States. doi:10.1039/C7CC07142F.
Bock, David C., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Mon . "Deliberate modification of the solid electrolyte interphase (SEI) during lithiation of magnetite, Fe3O4: impact on electrochemistry". United States. doi:10.1039/C7CC07142F. https://www.osti.gov/servlets/purl/1411145.
@article{osti_1411145,
title = {Deliberate modification of the solid electrolyte interphase (SEI) during lithiation of magnetite, Fe3O4: impact on electrochemistry},
author = {Bock, David C. and Marschilok, Amy C. and Takeuchi, Kenneth J. and Takeuchi, Esther S.},
abstractNote = {Here, magnetite is a conversion anode material displaying multi-electron transfer during lithiation and delithiation. The solid electrolyte interphase (SEI) on magnetite, Fe3O4, electrodes for lithium ion batteries was deliberately modified through the use of fluoroethylene carbonate (FEC) electrolyte additive, improving both capacity retention and rate capability. Analysis showed reduction of FEC at higher voltage compared to non-fluorinated solvents with formation of a modified lithium flouride containing electrode surface.},
doi = {10.1039/C7CC07142F},
journal = {ChemComm},
number = [98],
volume = [53],
place = {United States},
year = {2017},
month = {11}
}

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Cited by: 8 works
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