Deliberate modification of the solid electrolyte interphase (SEI) during lithiation of magnetite, Fe3O4: impact on electrochemistry
Abstract
Here, magnetite is a conversion anode material displaying multi-electron transfer during lithiation and delithiation. The solid electrolyte interphase (SEI) on magnetite, Fe3O4, electrodes for lithium ion batteries was deliberately modified through the use of fluoroethylene carbonate (FEC) electrolyte additive, improving both capacity retention and rate capability. Analysis showed reduction of FEC at higher voltage compared to non-fluorinated solvents with formation of a modified lithium flouride containing electrode surface.
- Authors:
-
[2];
[3]
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Stony Brook Univ., Stony Brook, NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1411145
- Report Number(s):
- BNL-114733-2017-JA
Journal ID: ISSN 1359-7345; TRN: US1800183
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 53; Journal Issue: 98; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Bock, David C., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Deliberate modification of the solid electrolyte interphase (SEI) during lithiation of magnetite, Fe3O4: impact on electrochemistry. United States: N. p., 2017.
Web. doi:10.1039/C7CC07142F.
Bock, David C., Marschilok, Amy C., Takeuchi, Kenneth J., & Takeuchi, Esther S. Deliberate modification of the solid electrolyte interphase (SEI) during lithiation of magnetite, Fe3O4: impact on electrochemistry. United States. https://doi.org/10.1039/C7CC07142F
Bock, David C., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Mon .
"Deliberate modification of the solid electrolyte interphase (SEI) during lithiation of magnetite, Fe3O4: impact on electrochemistry". United States. https://doi.org/10.1039/C7CC07142F. https://www.osti.gov/servlets/purl/1411145.
@article{osti_1411145,
title = {Deliberate modification of the solid electrolyte interphase (SEI) during lithiation of magnetite, Fe3O4: impact on electrochemistry},
author = {Bock, David C. and Marschilok, Amy C. and Takeuchi, Kenneth J. and Takeuchi, Esther S.},
abstractNote = {Here, magnetite is a conversion anode material displaying multi-electron transfer during lithiation and delithiation. The solid electrolyte interphase (SEI) on magnetite, Fe3O4, electrodes for lithium ion batteries was deliberately modified through the use of fluoroethylene carbonate (FEC) electrolyte additive, improving both capacity retention and rate capability. Analysis showed reduction of FEC at higher voltage compared to non-fluorinated solvents with formation of a modified lithium flouride containing electrode surface.},
doi = {10.1039/C7CC07142F},
journal = {ChemComm},
number = 98,
volume = 53,
place = {United States},
year = {Mon Nov 20 00:00:00 EST 2017},
month = {Mon Nov 20 00:00:00 EST 2017}
}
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Works referencing / citing this record:
Scalable Synthesis of an Artificial Polydopamine Solid‐Electrolyte‐Interface‐Assisted 3D rGO/Fe 3 O 4 @PDA Hydrogel for a Highly Stable Anode with Enhanced Lithium‐Ion‐Storage Properties
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