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Title: On the elusive nature of oxygen binding at coordinatively unsaturated 3d transition metal centers in metal–organic frameworks

Journal Article · · Physical Chemistry Chemical Physics. PCCP
DOI: https://doi.org/10.1039/C7CP05119K · OSTI ID:1410908
ORCiD logo [1];  [2];  [3]; ORCiD logo [4]; ORCiD logo [1]; ORCiD logo [5]
  1. Univ. of Bergen (Norway). Dept. of Chemistry
  2. Paul Scherrer Inst. (PSI), Villigen (Switzerland). Lab. for Neutron Scattering
  3. Helmholtz-Zentrum Berlin fur Materialien und Energie GmbH, Berlin (Germany)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
  5. Univ. of Milan (Italy). Dept. of Chemistry
+ Show Author Affiliations

Low and ambient temperature binding of oxygen, O2, in MOF-74, CPO-27-M (M = Mn, Co, Ni, Cu, Zn) framework materials remains in the physisorption regime, with energetics very similar to that of nitrogen, N2, sorption.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
European Union (EU); USDOE
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1410908
Journal Information:
Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 38 Vol. 19; ISSN 1463-9076; ISSN PPCPFQ
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY