On the elusive nature of oxygen binding at coordinatively unsaturated 3d transition metal centers in metal–organic frameworks
Abstract
Low and ambient temperature binding of oxygen, O2, in MOF-74, CPO-27-M (M = Mn, Co, Ni, Cu, Zn) framework materials remains in the physisorption regime, with energetics very similar to that of nitrogen, N2, sorption.
- Authors:
-
[1];
[4];
[1];
[5]
- Univ. of Bergen (Norway). Dept. of Chemistry
- Paul Scherrer Inst. (PSI), Villigen (Switzerland). Lab. for Neutron Scattering
- Helmholtz-Zentrum Berlin fur Materialien und Energie GmbH, Berlin (Germany)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
- Univ. of Milan (Italy). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE; European Union (EU)
- OSTI Identifier:
- 1410908
- Grant/Contract Number:
- AC05-00OR22725; 283883; 221596; 209339; 290605
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Chemistry Chemical Physics. PCCP
- Additional Journal Information:
- Journal Volume: 19; Journal Issue: 38; Journal ID: ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Rosnes, Mali H., Sheptyakov, Denis, Franz, Alexandra, Frontzek, Matthias, Dietzel, Pascal D. C., and Georgiev, Peter A. On the elusive nature of oxygen binding at coordinatively unsaturated 3d transition metal centers in metal–organic frameworks. United States: N. p., 2017.
Web. doi:10.1039/C7CP05119K.
Rosnes, Mali H., Sheptyakov, Denis, Franz, Alexandra, Frontzek, Matthias, Dietzel, Pascal D. C., & Georgiev, Peter A. On the elusive nature of oxygen binding at coordinatively unsaturated 3d transition metal centers in metal–organic frameworks. United States. https://doi.org/10.1039/C7CP05119K
Rosnes, Mali H., Sheptyakov, Denis, Franz, Alexandra, Frontzek, Matthias, Dietzel, Pascal D. C., and Georgiev, Peter A. Mon .
"On the elusive nature of oxygen binding at coordinatively unsaturated 3d transition metal centers in metal–organic frameworks". United States. https://doi.org/10.1039/C7CP05119K. https://www.osti.gov/servlets/purl/1410908.
@article{osti_1410908,
title = {On the elusive nature of oxygen binding at coordinatively unsaturated 3d transition metal centers in metal–organic frameworks},
author = {Rosnes, Mali H. and Sheptyakov, Denis and Franz, Alexandra and Frontzek, Matthias and Dietzel, Pascal D. C. and Georgiev, Peter A.},
abstractNote = {Low and ambient temperature binding of oxygen, O2, in MOF-74, CPO-27-M (M = Mn, Co, Ni, Cu, Zn) framework materials remains in the physisorption regime, with energetics very similar to that of nitrogen, N2, sorption.},
doi = {10.1039/C7CP05119K},
journal = {Physical Chemistry Chemical Physics. PCCP},
number = 38,
volume = 19,
place = {United States},
year = {2017},
month = {9}
}
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