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This content will become publicly available on September 18, 2018

Title: On the elusive nature of oxygen binding at coordinatively unsaturated 3d transition metal centers in metal–organic frameworks

Low and ambient temperature binding of oxygen, O 2, in MOF-74, CPO-27-M (M = Mn, Co, Ni, Cu, Zn) framework materials remains in the physisorption regime, with energetics very similar to that of nitrogen, N 2, sorption.
Authors:
ORCiD logo [1] ;  [2] ;  [3] ; ORCiD logo [4] ; ORCiD logo [1] ; ORCiD logo [5]
  1. Univ. of Bergen (Norway). Dept. of Chemistry
  2. Paul Scherrer Inst. (PSI), Villigen (Switzerland). Lab. for Neutron Scattering
  3. Helmholtz-Zentrum Berlin fur Materialien und Energie GmbH, Berlin (Germany)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
  5. Univ. of Milan (Italy). Dept. of Chemistry
Publication Date:
Grant/Contract Number:
AC05-00OR22725; 283883; 221596; 209339; 290605
Type:
Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print); Journal Volume: 19; Journal Issue: 38; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE; European Union (EU)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1410908