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Title: Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet

A new octacyanotungstate( v ) singe chain magnet with an effective energy barrier of 39.7(3) cm −1 is achieved by enforcing Ising-like magnetic anisotropy via introduction of trigonal distortion with a fac -tridentate capping ligand.
Authors:
 [1] ; ORCiD logo [2] ;  [3] ;  [2] ; ORCiD logo [2] ;  [2] ; ORCiD logo [2]
  1. Department of Chemistry, Texas A & M University, College Station, USA, Department of Chemistry
  2. Department of Chemistry, Texas A & M University, College Station, USA
  3. Department of Chemistry, Southern University of Science and Technology, Shenzhen, P. R. China
Publication Date:
Grant/Contract Number:
FG02-02ER45999
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 1; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1410835