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Title: Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet

Abstract

A new octacyanotungstate( v ) singe chain magnet with an effective energy barrier of 39.7(3) cm −1 is achieved by enforcing Ising-like magnetic anisotropy via introduction of trigonal distortion with a fac -tridentate capping ligand.

Authors:
 [1]; ORCiD logo [2];  [3];  [2]; ORCiD logo [2];  [2]; ORCiD logo [2]
  1. Department of Chemistry, Texas A & M University, College Station, USA, Department of Chemistry
  2. Department of Chemistry, Texas A & M University, College Station, USA
  3. Department of Chemistry, Southern University of Science and Technology, Shenzhen, P. R. China
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1410835
Grant/Contract Number:  
FG02-02ER45999
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 1; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Zhang, Yuan-Zhu, Dolinar, Brian S., Liu, Shihao, Brown, Andrew J., Zhang, Xuan, Wang, Zhao-Xi, and Dunbar, Kim R. Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet. United Kingdom: N. p., 2018. Web. doi:10.1039/C7SC02925J.
Zhang, Yuan-Zhu, Dolinar, Brian S., Liu, Shihao, Brown, Andrew J., Zhang, Xuan, Wang, Zhao-Xi, & Dunbar, Kim R. Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet. United Kingdom. https://doi.org/10.1039/C7SC02925J
Zhang, Yuan-Zhu, Dolinar, Brian S., Liu, Shihao, Brown, Andrew J., Zhang, Xuan, Wang, Zhao-Xi, and Dunbar, Kim R. Mon . "Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet". United Kingdom. https://doi.org/10.1039/C7SC02925J.
@article{osti_1410835,
title = {Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet},
author = {Zhang, Yuan-Zhu and Dolinar, Brian S. and Liu, Shihao and Brown, Andrew J. and Zhang, Xuan and Wang, Zhao-Xi and Dunbar, Kim R.},
abstractNote = {A new octacyanotungstate( v ) singe chain magnet with an effective energy barrier of 39.7(3) cm −1 is achieved by enforcing Ising-like magnetic anisotropy via introduction of trigonal distortion with a fac -tridentate capping ligand.},
doi = {10.1039/C7SC02925J},
journal = {Chemical Science},
number = 1,
volume = 9,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C7SC02925J

Citation Metrics:
Cited by: 35 works
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Works referenced in this record:

Rational Design of a Photomagnetic Chain: Bridging Single-Molecule Magnets with a Spin-Crossover Complex
journal, September 2013

  • Ababei, Rodica; Pichon, Céline; Roubeau, Olivier
  • Journal of the American Chemical Society, Vol. 135, Issue 39
  • DOI: 10.1021/ja407570n

Single-chain magnets: beyond the Glauber model
journal, January 2013

  • Zhang, Wei-Xiong; Ishikawa, Ryuta; Breedlove, Brian
  • RSC Advances, Vol. 3, Issue 12
  • DOI: 10.1039/c2ra22675h

Cyanide-bridged WVMnIII single-chain magnet based on an octacoordinate [W(CN)6(phen)]− anion
journal, February 2012


Cyanide-Bridged Iron(III)–Cobalt(II) Double Zigzag Ferromagnetic Chains: Two New Molecular Magnetic Nanowires
journal, April 2003

  • Lescouëzec, Rodrigue; Vaissermann, Jacqueline; Ruiz-Pérez, Catalina
  • Angewandte Chemie International Edition, Vol. 42, Issue 13
  • DOI: 10.1002/anie.200250243

Syntheses of tris(pyrazolyl)methane ligands and {[tris(pyrazolyl)methane]Mn(CO)3}SO3CF3 complexes: comparison of ligand donor properties
journal, August 2000

  • Reger, Daniel L.; Grattan, T. Christian; Brown, Kenneth J.
  • Journal of Organometallic Chemistry, Vol. 607, Issue 1-2
  • DOI: 10.1016/S0022-328X(00)00290-4

Time‐Dependent Statistics of the Ising Model
journal, February 1963

  • Glauber, Roy J.
  • Journal of Mathematical Physics, Vol. 4, Issue 2
  • DOI: 10.1063/1.1703954

Zero-field slow magnetic relaxation from single Co(ii) ion: a transition metal single-molecule magnet with high anisotropy barrier
journal, January 2013

  • Zhu, Yuan-Yuan; Cui, Chang; Zhang, Yi-Quan
  • Chemical Science, Vol. 4, Issue 4
  • DOI: 10.1039/c3sc21893g

Shape maps and polyhedral interconversion paths in transition metal chemistry
journal, September 2005

  • Alvarez, S.; Alemany, P.; Casanova, D.
  • Coordination Chemistry Reviews, Vol. 249, Issue 17-18
  • DOI: 10.1016/j.ccr.2005.03.031

Realization of a Magnet Using an Antiferromagnetic Phase of Single-Chain Magnets
journal, April 2009


Intermolecular Contact-Tuned Magnetic Nature in One-Dimensional 3d−5d Bimetallic Systems: From a Metamagnet to a Single-Chain Magnet
journal, November 2008

  • Choi, Seok Woo; Kwak, Hyun Young; Yoon, Jung Hee
  • Inorganic Chemistry, Vol. 47, Issue 22
  • DOI: 10.1021/ic801699p

Octacyanotungstate(v)-based square W2M2 (M = Co, Mn) complexes: synthesis, structure and magnetic properties
journal, January 2010

  • Wang, Jun; Xu, Youg-Lu; Zhou, Hong-Bo
  • Dalton Transactions, Vol. 39, Issue 14
  • DOI: 10.1039/b924203a

Slow Dynamics of the Magnetization in One-Dimensional Coordination Polymers: Single-Chain Magnets
journal, April 2009

  • Miyasaka, Hitoshi; Julve, Miguel; Yamashita, Masahiro
  • Inorganic Chemistry, Vol. 48, Issue 8
  • DOI: 10.1021/ic802050j

Large magnetic anisotropy in mononuclear metal complexes
journal, April 2015

  • Gómez-Coca, Silvia; Aravena, Daniel; Morales, Roser
  • Coordination Chemistry Reviews, Vol. 289-290
  • DOI: 10.1016/j.ccr.2015.01.021

Controlled association of single-molecule magnets (SMMs) into coordination networks: towards a new generation of magnetic materials
journal, January 2012

  • Jeon, Ie-Rang; Clérac, Rodolphe
  • Dalton Transactions, Vol. 41, Issue 32
  • DOI: 10.1039/c2dt30906h

Coexistence of Long-Range Ferromagnetic Ordering and Glassy Behavior in One-Dimensional Bimetallic Cyano-Bridged Polymers
journal, September 2003

  • Li, Dongfeng; Zheng, Limin; Zhang, Yuanzhu
  • Inorganic Chemistry, Vol. 42, Issue 19
  • DOI: 10.1021/ic034539k

Single-molecule magnet engineering: building-block approaches
journal, January 2014

  • Pedersen, Kasper S.; Bendix, Jesper; Clérac, Rodolphe
  • Chem. Commun., Vol. 50, Issue 34
  • DOI: 10.1039/C4CC00339J

One-Dimensional Cyanide-Bridged Mn III W V Bimetallic Complexes: Metamagnetism, Spontaneous Resolution, and Slow Magnetic Relaxation
journal, October 2009

  • Choi, Seok Woo; Ryu, Dae Won; Lee, Jin Wuk
  • Inorganic Chemistry, Vol. 48, Issue 19
  • DOI: 10.1021/ic901610j

Switchable Fe/Co Prussian blue networks and molecular analogues
journal, January 2016

  • Aguilà, David; Prado, Yoann; Koumousi, Evangelia S.
  • Chemical Society Reviews, Vol. 45, Issue 1
  • DOI: 10.1039/C5CS00321K

The preparation of Cs3Mo(CN)8�2H2O and Cs3W(CN)8�2H2O
journal, June 1975

  • Bok, L. D. C.; Leipoldt, J. G.; Basson, S. S.
  • Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 415, Issue 1
  • DOI: 10.1002/zaac.19754150111

Cyanocomplexes with one-dimensional structures: preparations, crystal structures and magnetic properties
journal, January 2002


A Single-Chain Magnet Tape Based on Hexacyanomanganate(III)
journal, March 2015

  • Zhang, Yuan-Zhu; Zhao, Han-Hua; Funck, Edward
  • Angewandte Chemie International Edition, Vol. 54, Issue 19
  • DOI: 10.1002/anie.201410664

A canted antiferromagnetic ordered phase of cyanido-bridged MnIII2ReIV single-chain magnets
journal, January 2012

  • Bhowmick, Indrani; Hillard, Elizabeth A.; Dechambenoit, Pierre
  • Chemical Communications, Vol. 48, Issue 78
  • DOI: 10.1039/c2cc34066f

First Heterotrimetallic {3 d-4 d-4 f} Single Chain Magnet, Constructed from Anisotropic High-Spin Heterometallic Nodes and Paramagnetic Spacers
journal, November 2009

  • Visinescu, Diana; Madalan, Augustin M.; Andruh, Marius
  • Chemistry - A European Journal, Vol. 15, Issue 44
  • DOI: 10.1002/chem.200902408

Single-Chain Magnets Based on Octacyanotungstate with the Highest Energy Barriers for Cyanide Compounds
journal, April 2016

  • Wei, Rong-Min; Cao, Fan; Li, Jing
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep24372

Reduced Anionic Mn 12 Molecules with Half-Integer Ground States as Single-Molecule Magnets
journal, November 1999

  • Aubin, Sheila M. J.; Sun, Ziming; Pardi, Luca
  • Inorganic Chemistry, Vol. 38, Issue 23
  • DOI: 10.1021/ic990613g

A Cobalt Pyrenylnitronylnitroxide Single-Chain Magnet with High Coercivity and Record Blocking Temperature
journal, March 2014

  • Vaz, Maria G. F.; Cassaro, Rafael A. Allão; Akpinar, Handan
  • Chemistry - A European Journal, Vol. 20, Issue 18
  • DOI: 10.1002/chem.201304852

Three-Dimensional Antiferromagnetic Order of Single-Chain Magnets: A New Approach to Design Molecule-Based Magnets
journal, March 2010

  • Miyasaka, Hitoshi; Takayama, Karin; Saitoh, Ayumi
  • Chemistry - A European Journal, Vol. 16, Issue 12
  • DOI: 10.1002/chem.200902861

The impact of ligands upon topology and functionality of octacyanidometallate-based assemblies
journal, September 2012

  • Nowicka, Beata; Korzeniak, Tomasz; Stefańczyk, Olaf
  • Coordination Chemistry Reviews, Vol. 256, Issue 17-18
  • DOI: 10.1016/j.ccr.2012.04.008

Conjunction of Chirality and Slow Magnetic Relaxation in the Supramolecular Network Constructed of Crossed Cyano-Bridged Co II –W V Molecular Chains
journal, September 2012

  • Chorazy, Szymon; Nakabayashi, Koji; Imoto, Kenta
  • Journal of the American Chemical Society, Vol. 134, Issue 39
  • DOI: 10.1021/ja307520k

Single-Chain Magnet (NEt 4 )[Mn 2 (5-MeOsalen) 2 Fe(CN) 6 ] Made of Mn III −Fe III −Mn III Trinuclear Single-Molecule Magnet with an S T = 9 / 2 Spin Ground State
journal, March 2005

  • Ferbinteanu, Marilena; Miyasaka, Hitoshi; Wernsdorfer, Wolfgang
  • Journal of the American Chemical Society, Vol. 127, Issue 9
  • DOI: 10.1021/ja0468123

A Redox-Switchable Single-Molecule Magnet Incorporating [Re(CN) 7 ] 3-
journal, March 2008

  • Freedman, Danna E.; Jenkins, David M.; Iavarone, Anthony T.
  • Journal of the American Chemical Society, Vol. 130, Issue 10
  • DOI: 10.1021/ja077527x

Evidence for Single-Chain Magnet Behavior in a Mn III −Ni II Chain Designed with High Spin Magnetic Units:  A Route to High Temperature Metastable Magnets
journal, October 2002

  • Clérac, Rodolphe; Miyasaka, Hitoshi; Yamashita, Masahiro
  • Journal of the American Chemical Society, Vol. 124, Issue 43
  • DOI: 10.1021/ja0203115

The Observation of Superparamagnetic Behavior in Molecular Nanowires
journal, July 2004

  • Wang, Shi; Zuo, Jing-Lin; Gao, Song
  • Journal of the American Chemical Society, Vol. 126, Issue 29
  • DOI: 10.1021/ja0483995

Mononuclear Single-Molecule Magnets: Tailoring the Magnetic Anisotropy of First-Row Transition-Metal Complexes
journal, April 2013

  • Gomez-Coca, Silvia; Cremades, Eduard; Aliaga-Alcalde, Núria
  • Journal of the American Chemical Society, Vol. 135, Issue 18
  • DOI: 10.1021/ja4015138

Strategies towards single-chain magnets
journal, May 2010

  • Sun, Hao-Ling; Wang, Zhe-Ming; Gao, Song
  • Coordination Chemistry Reviews, Vol. 254, Issue 9-10
  • DOI: 10.1016/j.ccr.2010.02.010

First Fe(ii)-based cyano-bridged single molecule magnet [CrIIIFeII2] with a large anisotropy
journal, January 2010

  • Zhang, Yuan-Zhu; Wang, Bing-Wu; Sato, Osamu
  • Chemical Communications, Vol. 46, Issue 37
  • DOI: 10.1039/c0cc01581d

Enhanced Ion Anisotropy by Nonconventional Coordination Geometry: Single-Chain Magnet Behavior for a [{Fe II L} 2 {Nb IV (CN) 8 }] Helical Chain Compound Designed with Heptacoordinate Fe II
journal, May 2010

  • Venkatakrishnan, Thengarai S.; Sahoo, Shaon; Bréfuel, Nicolas
  • Journal of the American Chemical Society, Vol. 132, Issue 17
  • DOI: 10.1021/ja9089389

Spin canting, metamagnetism, and single-chain magnetic behaviour in a cyano-bridged homospin iron( ii ) compound
journal, January 2015

  • Shao, Dong; Zhang, Shao-Liang; Zhao, Xin-Hua
  • Chemical Communications, Vol. 51, Issue 21
  • DOI: 10.1039/C4CC10003D

Cobalt(II)-Nitronyl Nitroxide Chains as Molecular Magnetic Nanowires
journal, May 2001


One-dimensional square- and ladder-type architectures incorporating octacyanometallates of molybdenum(V) and tungsten(V)
journal, November 2013


Design of One-Dimensional Coordination Networks from a Macrocyclic {3d-4f} Single-Molecule Magnet Precursor Linked by [W(CN) 8 ] 3– Anions
journal, November 2013

  • Dhers, Sébastien; Feltham, Humphrey L. C.; Clérac, Rodolphe
  • Inorganic Chemistry, Vol. 52, Issue 23
  • DOI: 10.1021/ic402248y

[ReCl 4 (CN) 2 ] 2− : A High Magnetic Anisotropy Building Unit Giving Rise to the Single-Chain Magnets (DMF) 4 MReCl 4 (CN) 2 (M = Mn, Fe, Co, Ni)
journal, March 2010

  • Harris, T. David; Bennett, Miriam V.; Clérac, Rodolphe
  • Journal of the American Chemical Society, Vol. 132, Issue 11
  • DOI: 10.1021/ja910963x

A Single-Molecule Magnet Based on Heptacyanomolybdate with the Highest Energy Barrier for a Cyanide Compound
journal, August 2013

  • Qian, Kun; Huang, Xing-Cai; Zhou, Chun
  • Journal of the American Chemical Society, Vol. 135, Issue 36
  • DOI: 10.1021/ja4067833

First principles approach to the electronic structure, magnetic anisotropy and spin relaxation in mononuclear 3d-transition metal single molecule magnets
journal, April 2015

  • Atanasov, Mihail; Aravena, Daniel; Suturina, Elizaveta
  • Coordination Chemistry Reviews, Vol. 289-290
  • DOI: 10.1016/j.ccr.2014.10.015