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Title: Cu-Decorated ZnO Nanorod Array Integrated Structured Catalysts for Low-Pressure CO 2 Hydrogenation to Methanol

Authors:
 [1];  [1];  [1];  [1];  [1];  [1]
  1. Department of Materials Science and Engineering and Institute of Materials Science, University of Connecticut, Storrs CT 06269-3136 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1410830
Grant/Contract Number:  
EE0006854
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Materials Interfaces
Additional Journal Information:
Journal Name: Advanced Materials Interfaces Journal Volume: 5 Journal Issue: 3; Journal ID: ISSN 2196-7350
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Du, Shoucheng, Tang, Wenxiang, Lu, Xingxu, Wang, Sibo, Guo, Yanbing, and Gao, Pu-Xian. Cu-Decorated ZnO Nanorod Array Integrated Structured Catalysts for Low-Pressure CO 2 Hydrogenation to Methanol. Germany: N. p., 2017. Web. doi:10.1002/admi.201700730.
Du, Shoucheng, Tang, Wenxiang, Lu, Xingxu, Wang, Sibo, Guo, Yanbing, & Gao, Pu-Xian. Cu-Decorated ZnO Nanorod Array Integrated Structured Catalysts for Low-Pressure CO 2 Hydrogenation to Methanol. Germany. doi:10.1002/admi.201700730.
Du, Shoucheng, Tang, Wenxiang, Lu, Xingxu, Wang, Sibo, Guo, Yanbing, and Gao, Pu-Xian. Fri . "Cu-Decorated ZnO Nanorod Array Integrated Structured Catalysts for Low-Pressure CO 2 Hydrogenation to Methanol". Germany. doi:10.1002/admi.201700730.
@article{osti_1410830,
title = {Cu-Decorated ZnO Nanorod Array Integrated Structured Catalysts for Low-Pressure CO 2 Hydrogenation to Methanol},
author = {Du, Shoucheng and Tang, Wenxiang and Lu, Xingxu and Wang, Sibo and Guo, Yanbing and Gao, Pu-Xian},
abstractNote = {},
doi = {10.1002/admi.201700730},
journal = {Advanced Materials Interfaces},
number = 3,
volume = 5,
place = {Germany},
year = {2017},
month = {12}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/admi.201700730

Citation Metrics:
Cited by: 3 works
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Works referenced in this record:

The role of metal oxides in promoting a copper catalyst for methanol synthesis
journal, January 1994

  • Fujitani, T.; Saito, M.; Kanai, Y.
  • Catalysis Letters, Vol. 25, Issue 3-4
  • DOI: 10.1007/BF00816307

In Situ Electron Energy Loss Spectroscopy Studies of Gas-Dependent Metal−Support Interactions in Cu/ZnO Catalysts
journal, August 2003

  • Wagner, Jakob B.; Hansen, Poul L.; Molenbroek, Alfons M.
  • The Journal of Physical Chemistry B, Vol. 107, Issue 31
  • DOI: 10.1021/jp0277863

Selective Electroreduction of CO 2 toward Ethylene on Nano Dendritic Copper Catalysts at High Current Density
journal, January 2017

  • Reller, Christian; Krause, Ralf; Volkova, Elena
  • Advanced Energy Materials, Vol. 7, Issue 12
  • DOI: 10.1002/aenm.201602114

Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol
journal, March 2014

  • Studt, Felix; Sharafutdinov, Irek; Abild-Pedersen, Frank
  • Nature Chemistry, Vol. 6, Issue 4
  • DOI: 10.1038/nchem.1873

Catalytic performance for CO2 conversion to methanol of gallium-promoted copper-based catalysts: influence of metallic precursors
journal, November 2001

  • Toyir, Jamil; Ramı́rez de la Piscina, Pilar; Fierro, José Luis G.
  • Applied Catalysis B: Environmental, Vol. 34, Issue 4
  • DOI: 10.1016/S0926-3373(01)00203-X

Atom-Resolved Imaging of Dynamic Shape Changes in Supported Copper Nanocrystals
journal, March 2002


Nanostructured Zinc Oxide Nanorods with Copper Nanoparticles as a Microreformation Catalyst
journal, September 2009

  • Lin, Yan-Gu; Hsu, Yu-Kuei; Chen, San-Yuan
  • Angewandte Chemie International Edition, Vol. 48, Issue 41
  • DOI: 10.1002/anie.200902907

In situ XRD and HRTEM studies on the evolution of the Cu/ZnO methanol synthesis catalyst during its reduction and re-oxidation
journal, January 2004

  • Yurieva, Tamara M.; Plyasova, Lyudmila M.; Zaikovskii, Vladimir I.
  • Physical Chemistry Chemical Physics, Vol. 6, Issue 18
  • DOI: 10.1039/b407728h

An improved N2O-method for measuring Cu-dispersion
journal, July 2004


Quantifying the promotion of Cu catalysts by ZnO for methanol synthesis
journal, May 2016


Methanol synthesis from CO2 and H2 over gallium promoted copper-based supported catalysts. Effect of hydrocarbon impurities in the CO2/H2 source
journal, October 2001

  • Toyir, Jamil; de la Piscina, Pilar Ramírez; Llorca, Jordi
  • Physical Chemistry Chemical Physics, Vol. 3, Issue 21
  • DOI: 10.1039/b105235g

Active sites for CO 2 hydrogenation to methanol on Cu/ZnO catalysts
journal, March 2017


Understanding low temperature oxidation activity of nanoarray-based monolithic catalysts: from performance observation to structural and chemical insights
journal, December 2016

  • Du, Shoucheng; Tang, Wenxiang; Guo, Yanbing
  • Emission Control Science and Technology, Vol. 3, Issue 1
  • DOI: 10.1007/s40825-016-0054-y

Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions
journal, February 2015

  • Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte
  • Angewandte Chemie, Vol. 127, Issue 15
  • DOI: 10.1002/ange.201411581

The chemical modification seen in the Cu/ZnO methanol synthesis catalysts
journal, January 2000


Yttria-Stabilized Zirconia Supported Copper Oxide Catalyst
journal, May 1996

  • Dow, Wei-Ping; Wang, Yu-Piao; Huang, Ta-Jen
  • Journal of Catalysis, Vol. 160, Issue 2
  • DOI: 10.1006/jcat.1996.0135

Fe-Doped CoP Nanoarray: A Monolithic Multifunctional Catalyst for Highly Efficient Hydrogen Generation
journal, October 2016


Preparation of a coprecipitated Cu/ZnO catalyst for the methanol synthesis from CO2 — effects of the calcination and reduction conditions on the catalytic performance
journal, February 2001


CO2 hydrogenation to methanol over Cu/ZnO/ZrO2 catalysts prepared by precipitation-reduction method
journal, August 2016


Gas Conversion to Liquid Fuels and Chemicals: The Methanol Route‐Catalysis and Processes Development
journal, January 2009


Influence of ZrO 2 Structure and Copper Electronic State on Activity of Cu/ZrO 2 Catalysts in Methanol Synthesis from CO 2
journal, September 2014

  • Samson, K.; Śliwa, M.; Socha, R. P.
  • ACS Catalysis, Vol. 4, Issue 10
  • DOI: 10.1021/cs500979c

Development of highly stable catalyst for methanol synthesis from carbon dioxide
journal, January 2014


Hydrogenation of CO2 to methanol over CuCeTiO catalysts
journal, June 2017


An overview of current status of carbon dioxide capture and storage technologies
journal, November 2014

  • Leung, Dennis Y. C.; Caramanna, Giorgio; Maroto-Valer, M. Mercedes
  • Renewable and Sustainable Energy Reviews, Vol. 39
  • DOI: 10.1016/j.rser.2014.07.093

Mechanism of the hydrogenation of CO2 to methanol on a Cu(100) surface: dipped adcluster model study
journal, November 1999


Fabrication and photoresponse of ZnO nanowires/CuO coaxial heterojunction
journal, January 2013


Synthesis, characterization and activity pattern of Cu–ZnO/ZrO2 catalysts in the hydrogenation of carbon dioxide to methanol
journal, July 2007


The role of copper particle size in low pressure methanol synthesis via CO 2 hydrogenation over Cu/ZnO catalysts
journal, January 2015

  • Karelovic, Alejandro; Ruiz, Patricio
  • Catalysis Science & Technology, Vol. 5, Issue 2
  • DOI: 10.1039/C4CY00848K

Facile synthesis of ZnO nanopencil arrays for photoelectrochemical water splitting
journal, July 2014


Nano-array based monolithic catalysts: Concept, rational materials design and tunable catalytic performance
journal, December 2015


Worldwide innovations in the development of carbon capture technologies and the utilization of CO2
journal, January 2012

  • Markewitz, Peter; Kuckshinrichs, Wilhelm; Leitner, Walter
  • Energy & Environmental Science, Vol. 5, Issue 6
  • DOI: 10.1039/c2ee03403d

Methanol synthesis reactions over a CuZr based catalyst investigated using periodic variations of reactant concentrations
journal, August 2001


High-Performance Electrolytic Oxygen Evolution in Neutral Media Catalyzed by a Cobalt Phosphate Nanoarray
journal, December 2016


Beyond Oil and Gas: The Methanol Economy
journal, April 2005


Effects of oxide carriers on surface functionality and process performance of the Cu–ZnO system in the synthesis of methanol via CO2 hydrogenation
journal, April 2013


In Situ Investigations of Structural Changes in Cu/ZnO Catalysts
journal, September 2000

  • Grunwaldt, J. -D; Molenbroek, A. M.; Topsøe, N. -Y
  • Journal of Catalysis, Vol. 194, Issue 2
  • DOI: 10.1006/jcat.2000.2930

The role of copper and zinc oxide in methanol synthesis catalysts
journal, January 1990

  • Burch, Robert; Golunski, Stanislaw E.; Spencer, Michael S.
  • Journal of the Chemical Society, Faraday Transactions, Vol. 86, Issue 15
  • DOI: 10.1039/ft9908602683

Catalytic valorization of CO2 via methanol synthesis with Ga-promoted Cu–ZnO–ZrO2 catalysts
journal, October 2013

  • Ladera, Rosa; Pérez-Alonso, Francisco J.; González-Carballo, Juan M.
  • Applied Catalysis B: Environmental, Vol. 142-143
  • DOI: 10.1016/j.apcatb.2013.05.019

Hydrogenation of CO2 to methanol and CO on Cu/ZnO/Al2O3: Is there a common intermediate or not?
journal, August 2015


Methanol Synthesis and Reverse Water–Gas Shift Kinetics over Cu(110) Model Catalysts: Structural Sensitivity
journal, July 1996


Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2
journal, July 2014


Surface active structure of ultra-fine Cu/ZrO2 catalysts used for the CO2+H2 to methanol reaction
journal, September 2001


Thermodynamic investigation of methanol and dimethyl ether synthesis from CO2 Hydrogenation
journal, March 2000

  • Shen, Wen-Jie; Jun, Ki-Won; Choi, Ho-Suk
  • Korean Journal of Chemical Engineering, Vol. 17, Issue 2
  • DOI: 10.1007/BF02707145

Enhanced photoresponse of ZnO nanorods-based self-powered photodetector by piezotronic interface engineering
journal, October 2014


Intermetallic GaPd 2 Nanoparticles on SiO 2 for Low-Pressure CO 2 Hydrogenation to Methanol: Catalytic Performance and In Situ Characterization
journal, September 2015

  • Fiordaliso, Elisabetta M.; Sharafutdinov, Irek; Carvalho, Hudson W. P.
  • ACS Catalysis, Vol. 5, Issue 10
  • DOI: 10.1021/acscatal.5b01271

Effect of pressure on the mechanisms of the CO2/H2 reaction on a CO-precipitated CuO/ZnO/Al2O3 catalyst
journal, April 2011

  • Sahki, Rachid; Benlounes, Ouarda; Chérifi, Ouiza
  • Reaction Kinetics, Mechanisms and Catalysis, Vol. 103, Issue 2
  • DOI: 10.1007/s11144-011-0311-6

Construction of Cu/ZrO2/Al2O3 composites for ethanol synthesis: Synergies of ternary sites for cascade reaction
journal, May 2015


Role of Lattice Strain and Defects in Copper Particles on the Activity of Cu/ZnO/Al2O3 Catalysts for Methanol Synthesis
journal, September 2007

  • Kasatkin, Igor; Kurr, Patrick; Kniep, Benjamin
  • Angewandte Chemie International Edition, Vol. 46, Issue 38
  • DOI: 10.1002/anie.200702600

Transient behavior of Cu/ZnO-based methanol synthesis catalysts
journal, February 2009


Development of an active Ga2O3 supported palladium catalyst for the synthesis of methanol from carbon dioxide and hydrogen
journal, May 1995


Hydrogenation of CO2 to methanol over In2O3 catalyst
journal, December 2015


The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
journal, April 2012


Methanol technology developments for the new millennium
journal, November 2001


The Potential Applications of Nanoporous Materials for the Adsorption, Separation, and Catalytic Conversion of Carbon Dioxide
journal, March 2014

  • Sneddon, Gregor; Greenaway, Alex; Yiu, Humphrey H. P.
  • Advanced Energy Materials, Vol. 4, Issue 10
  • DOI: 10.1002/aenm.201301873

Dispersion and surface states of copper catalysts by temperature-programmed-reduction of oxidized surfaces (s-TPR)
journal, March 2005


Impact of K and Ba promoters on CO 2 hydrogenation over Cu/Al 2 O 3 catalysts at high pressure
journal, January 2013

  • Bansode, Atul; Tidona, Bruno; von Rohr, Philipp Rudolf
  • Catal. Sci. Technol., Vol. 3, Issue 3
  • DOI: 10.1039/C2CY20604H

Bimetallic Pd–Cu catalysts for selective CO2 hydrogenation to methanol
journal, July 2015


The Role of the Oxide Component in the Development of Copper Composite Catalysts for Methanol Synthesis
journal, May 2013

  • Zander, Stefan; Kunkes, Edward L.; Schuster, Manfred E.
  • Angewandte Chemie International Edition, Vol. 52, Issue 25
  • DOI: 10.1002/anie.201301419

Atomic-scale studies of metallic nanocluster catalysts by in situ high-resolution transmission electron microscopy
journal, January 2006


The changing nature of the active site of Cu-Zn-Zr catalysts for the CO2 hydrogenation reaction to methanol
journal, June 2014


Highly effective conversion of CO2 to methanol over supported and promoted copper-based catalysts: influence of support and promoter
journal, February 2001

  • Toyir, Jamil; de la Piscina, Pilar Ramı́rez; Fierro, José Luis G.
  • Applied Catalysis B: Environmental, Vol. 29, Issue 3
  • DOI: 10.1016/S0926-3373(00)00205-8

Scalable continuous flow synthesis of ZnO nanorod arrays in 3-D ceramic honeycomb substrates for low-temperature desulfurization
journal, January 2017

  • Wang, Sibo; Wu, Yunchao; Miao, Ran
  • CrystEngComm, Vol. 19, Issue 34
  • DOI: 10.1039/C7CE00921F

Hydrogenation of CO2 to value-added products—A review and potential future developments
journal, March 2014

  • Saeidi, Samrand; Amin, Nor Aishah Saidina; Rahimpour, Mohammad Reza
  • Journal of CO2 Utilization, Vol. 5
  • DOI: 10.1016/j.jcou.2013.12.005

Nanocrystalline zirconia as catalyst support in methanol synthesis
journal, January 2005


Zinc oxide nanorods based catalysts for hydrogen production by steam reforming of methanol
journal, April 2012


Fundamental studies of methanol synthesis from CO2 hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(0001̄)
journal, January 2010

  • Yang, Yixiong; Evans, Jaime; Rodriguez, Jose A.
  • Physical Chemistry Chemical Physics, Vol. 12, Issue 33
  • DOI: 10.1039/c001484b

Mechanism of Methanol Synthesis on Cu through CO 2 and CO Hydrogenation
journal, February 2011

  • Grabow, L. C.; Mavrikakis, M.
  • ACS Catalysis, Vol. 1, Issue 4
  • DOI: 10.1021/cs200055d

High Efficiency Cu-ZnO Hydrogenation Catalyst: The Tailoring of Cu-ZnO Interface Sites by Molecular Layer Deposition
journal, August 2015