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Title: [Ti 8 Zr 2 O 12 (COO) 16 ] Cluster: An Ideal Inorganic Building Unit for Photoactive Metal–Organic Frameworks

Authors:
 [1];  [1];  [2];  [3];  [1]; ORCiD logo [4];  [1];  [1];  [1]; ORCiD logo [2]; ORCiD logo [1];  [3];  [3];  [3]; ORCiD logo [5]
  1. Department of Chemistry, Texas A&,M University, College Station, Texas 77843-3255, United States
  2. Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Suzhou Nano Science and Technology, Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China
  3. Berzelii Centre EXSELENT on Porous Materials and Inorganic and Structural Chemistry, Department of Materials and Environmental Chemistry, Stockholm University, Stockholm 106 91, Sweden
  4. School of Physics and Optoelectronics, Xiangtan University, Xiangtan 411105, P. R. China
  5. Department of Chemistry, Texas A&,M University, College Station, Texas 77843-3255, United States, Department of Materials Science and Engineering, Texas A&,M University, College Station, Texas 77843-3003, United States
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS); Texas A & M Univ., College Station, TX (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Fossil Energy (FE)
OSTI Identifier:
1410591
Alternate Identifier(s):
OSTI ID: 1470113; OSTI ID: 1508267
Grant/Contract Number:  
SC0001015; FE0026472; AC02-06CH11357
Resource Type:
Published Article
Journal Name:
ACS Central Science
Additional Journal Information:
Journal Name: ACS Central Science Journal Volume: 4 Journal Issue: 1; Journal ID: ISSN 2374-7943
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; membrane; carbon capture; materials and chemistry by design; synthesis (novel materials); synthesis (self-assembly); synthesis (scalable processing)

Citation Formats

Yuan, Shuai, Qin, Jun-Sheng, Xu, Hai-Qun, Su, Jie, Rossi, Daniel, Chen, Yuanping, Zhang, Liangliang, Lollar, Christina, Wang, Qi, Jiang, Hai-Long, Son, Dong Hee, Xu, Hongyi, Huang, Zhehao, Zou, Xiaodong, and Zhou, Hong-Cai. [Ti 8 Zr 2 O 12 (COO) 16 ] Cluster: An Ideal Inorganic Building Unit for Photoactive Metal–Organic Frameworks. United States: N. p., 2017. Web. doi:10.1021/acscentsci.7b00497.
Yuan, Shuai, Qin, Jun-Sheng, Xu, Hai-Qun, Su, Jie, Rossi, Daniel, Chen, Yuanping, Zhang, Liangliang, Lollar, Christina, Wang, Qi, Jiang, Hai-Long, Son, Dong Hee, Xu, Hongyi, Huang, Zhehao, Zou, Xiaodong, & Zhou, Hong-Cai. [Ti 8 Zr 2 O 12 (COO) 16 ] Cluster: An Ideal Inorganic Building Unit for Photoactive Metal–Organic Frameworks. United States. doi:10.1021/acscentsci.7b00497.
Yuan, Shuai, Qin, Jun-Sheng, Xu, Hai-Qun, Su, Jie, Rossi, Daniel, Chen, Yuanping, Zhang, Liangliang, Lollar, Christina, Wang, Qi, Jiang, Hai-Long, Son, Dong Hee, Xu, Hongyi, Huang, Zhehao, Zou, Xiaodong, and Zhou, Hong-Cai. Wed . "[Ti 8 Zr 2 O 12 (COO) 16 ] Cluster: An Ideal Inorganic Building Unit for Photoactive Metal–Organic Frameworks". United States. doi:10.1021/acscentsci.7b00497.
@article{osti_1410591,
title = {[Ti 8 Zr 2 O 12 (COO) 16 ] Cluster: An Ideal Inorganic Building Unit for Photoactive Metal–Organic Frameworks},
author = {Yuan, Shuai and Qin, Jun-Sheng and Xu, Hai-Qun and Su, Jie and Rossi, Daniel and Chen, Yuanping and Zhang, Liangliang and Lollar, Christina and Wang, Qi and Jiang, Hai-Long and Son, Dong Hee and Xu, Hongyi and Huang, Zhehao and Zou, Xiaodong and Zhou, Hong-Cai},
abstractNote = {},
doi = {10.1021/acscentsci.7b00497},
journal = {ACS Central Science},
number = 1,
volume = 4,
place = {United States},
year = {2017},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1021/acscentsci.7b00497

Citation Metrics:
Cited by: 26 works
Citation information provided by
Web of Science

Figures / Tables:

Figure 1 Figure 1: Coordination compounds based on [Ti8Zr2O12(RCOO)16] cluster. (a) [Zr6O4(OH)4(COO)12] cluster; (b) the relationship between [Zr6O4(OH)4(COO)12] and [Ti8Zr2O12(COO)16] clusters; (c) [Ti8Zr2O12(COO)16] cluster; (d−h) discrete [Ti8Zr2O12(RCOO)16] clusters formed with different carboxylate ligands; (i) and (j) MOFs based on [Ti8Zr2O12(RCOO)16] clusters and different carboxylate linkers.

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Works referencing / citing this record:

Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping
journal, June 2018

  • Castells-Gil, Javier; Padial, Natalia M.; Almora-Barrios, Neyvis
  • Angewandte Chemie International Edition, Vol. 57, Issue 28
  • DOI: 10.1002/anie.201802089

Assembly of a Wheel-Like Eu 24 Ti 8 Cluster under the Guidance of High-Resolution Electrospray Ionization Mass Spectrometry
journal, July 2018

  • Zheng, Hao; Du, Ming-Hao; Lin, Shui-Chao
  • Angewandte Chemie International Edition, Vol. 57, Issue 34
  • DOI: 10.1002/anie.201806757

Titanium-Carboxylate Metal-Organic Framework Based on an Unprecedented Ti-Oxo Chain Cluster
journal, October 2018

  • Keum, Yesub; Park, Seonghun; Chen, Ying-Pin
  • Angewandte Chemie International Edition, Vol. 57, Issue 45
  • DOI: 10.1002/anie.201809762

De novo synthesis of mesoporous photoactive titanium( iv )–organic frameworks with MIL-100 topology
journal, January 2019

  • Castells-Gil, Javier; M. Padial, Natalia; Almora-Barrios, Neyvis
  • Chemical Science, Vol. 10, Issue 15
  • DOI: 10.1039/c8sc05218b

Tunable titanium metal–organic frameworks with infinite 1D Ti–O rods for efficient visible-light-driven photocatalytic H 2 evolution
journal, January 2019

  • Li, Changqing; Xu, Hui; Gao, Junkuo
  • Journal of Materials Chemistry A, Vol. 7, Issue 19
  • DOI: 10.1039/c9ta01942a

Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping
journal, June 2018

  • Castells-Gil, Javier; Padial, Natalia M.; Almora-Barrios, Neyvis
  • Angewandte Chemie International Edition, Vol. 57, Issue 28
  • DOI: 10.1002/anie.201802089

Assembly of a Wheel-Like Eu 24 Ti 8 Cluster under the Guidance of High-Resolution Electrospray Ionization Mass Spectrometry
journal, July 2018

  • Zheng, Hao; Du, Ming-Hao; Lin, Shui-Chao
  • Angewandte Chemie International Edition, Vol. 57, Issue 34
  • DOI: 10.1002/anie.201806757

Titanium-Carboxylate Metal-Organic Framework Based on an Unprecedented Ti-Oxo Chain Cluster
journal, October 2018

  • Keum, Yesub; Park, Seonghun; Chen, Ying-Pin
  • Angewandte Chemie International Edition, Vol. 57, Issue 45
  • DOI: 10.1002/anie.201809762

De novo synthesis of mesoporous photoactive titanium( iv )–organic frameworks with MIL-100 topology
journal, January 2019

  • Castells-Gil, Javier; M. Padial, Natalia; Almora-Barrios, Neyvis
  • Chemical Science, Vol. 10, Issue 15
  • DOI: 10.1039/c8sc05218b

Tunable titanium metal–organic frameworks with infinite 1D Ti–O rods for efficient visible-light-driven photocatalytic H 2 evolution
journal, January 2019

  • Li, Changqing; Xu, Hui; Gao, Junkuo
  • Journal of Materials Chemistry A, Vol. 7, Issue 19
  • DOI: 10.1039/c9ta01942a

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