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Title: Collapsed tetragonal phase transition in LaRu 2 P 2

Here, the structural properties of LaRu 2P 2 under external pressure have been studied up to 14 GPa, employing high-energy x-ray diffraction in a diamond-anvil pressure cell. At ambient conditions, LaRu 2P 2 (I4/ mmm) has a tetragonal structure with a bulk modulus of B = 105(2) GPa and exhibits superconductivity at T c = 4.1 K. With the application of pressure, LaRu 2P 2 undergoes a phase transition to a collapsed tetragonal (cT) state with a bulk modulus of B = 175(5) GPa. At the transition, the c-lattice parameter exhibits a sharp decrease with a concurrent increase of the a-lattice parameter. The cT phase transition in LaRu 2P 2 is consistent with a second-order transition, and was found to be temperature dependent, increasing from P = 3.9(3) GPa at 160 K to P = 4.6(3) GPa at 300 K. In total, our data are consistent with the cT transition being near, but slightly above 2 GPa at 5 K where superconductivity is suppressed. Finally, we compare the effect of physical and chemical pressure in the RRu 2P 2 ( R = Y, La–Er, Yb) isostructural series of compounds and find them to be analogous.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1]
  1. Ames Lab. and Iowa State Univ., Ames, IA (United States)
Publication Date:
Report Number(s):
IS-J-9507
Journal ID: ISSN 2469-9950; PRBMDO
Grant/Contract Number:
GBMF4411; AC02-07CH111358; AC02-06CH11357; NA0001974; FG02-94ER14466; EAR-11-57758; EAR-1128799
Type:
Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 96; Journal Issue: 18; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
OSTI Identifier:
1410346
Alternate Identifier(s):
OSTI ID: 1408263

Drachuck, Gil, Sapkota, Aashish, Jayasekara, Wageesha T., Kothapalli, Karunakar, Bud'ko, Sergey L., Goldman, Alan I., Kreyssig, Andreas, and Canfield, Paul C.. Collapsed tetragonal phase transition in LaRu2P2. United States: N. p., Web. doi:10.1103/PhysRevB.96.184509.
Drachuck, Gil, Sapkota, Aashish, Jayasekara, Wageesha T., Kothapalli, Karunakar, Bud'ko, Sergey L., Goldman, Alan I., Kreyssig, Andreas, & Canfield, Paul C.. Collapsed tetragonal phase transition in LaRu2P2. United States. doi:10.1103/PhysRevB.96.184509.
Drachuck, Gil, Sapkota, Aashish, Jayasekara, Wageesha T., Kothapalli, Karunakar, Bud'ko, Sergey L., Goldman, Alan I., Kreyssig, Andreas, and Canfield, Paul C.. 2017. "Collapsed tetragonal phase transition in LaRu2P2". United States. doi:10.1103/PhysRevB.96.184509. https://www.osti.gov/servlets/purl/1410346.
@article{osti_1410346,
title = {Collapsed tetragonal phase transition in LaRu2P2},
author = {Drachuck, Gil and Sapkota, Aashish and Jayasekara, Wageesha T. and Kothapalli, Karunakar and Bud'ko, Sergey L. and Goldman, Alan I. and Kreyssig, Andreas and Canfield, Paul C.},
abstractNote = {Here, the structural properties of LaRu2P2 under external pressure have been studied up to 14 GPa, employing high-energy x-ray diffraction in a diamond-anvil pressure cell. At ambient conditions, LaRu2P2 (I4/mmm) has a tetragonal structure with a bulk modulus of B = 105(2) GPa and exhibits superconductivity at Tc = 4.1 K. With the application of pressure, LaRu2P2 undergoes a phase transition to a collapsed tetragonal (cT) state with a bulk modulus of B = 175(5) GPa. At the transition, the c-lattice parameter exhibits a sharp decrease with a concurrent increase of the a-lattice parameter. The cT phase transition in LaRu2P2 is consistent with a second-order transition, and was found to be temperature dependent, increasing from P = 3.9(3) GPa at 160 K to P = 4.6(3) GPa at 300 K. In total, our data are consistent with the cT transition being near, but slightly above 2 GPa at 5 K where superconductivity is suppressed. Finally, we compare the effect of physical and chemical pressure in the RRu2P2 (R = Y, La–Er, Yb) isostructural series of compounds and find them to be analogous.},
doi = {10.1103/PhysRevB.96.184509},
journal = {Physical Review B},
number = 18,
volume = 96,
place = {United States},
year = {2017},
month = {11}
}

Works referenced in this record:

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976